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M 7.2 earthquake. Matsushima et al. [2002] recorded the coseismic EM variations that accompanied the
seismic waves in 1999 Mw7.4 İzmit earthquake and its aftershocks. They proposed that those EM variations
might be caused by the motion of the conductive ground in the geomagnetic field. Similar coseismic EM
fields were also observed in other places [Ujihara et al., 2004; Honkura et al., 2004; Abdul Azeez et al., 2009;
Tang et al., 2010]. Yamazaki [2012] studied the coseismic magnetic field arising from the motional induction
effect from the plane-wave point of view. His numerical result showed that the coseismic magnetic field can
reach the order of 0.1 nT, which is detectable. Recently, reports on the observed circularly polarized coseismic
electric field [Honkura et al., 2009; Kuriki et al., 2011; Matsushima et al., 2013] provided evidences for the role of
the Earth’s magnetic field in generating EM disturbances. Moreover, observations of the tsunami-induced
magnetic variations [Manoj et al., 2011; Toh et al., 2011; Utada et al., 2011; Ichihara et al., 2013] were further
evidences which indicate that the conductive seawater moving across the Earth’s magnetic field can also
generate observable variations in the magnetic field.
Besides the coseismic EM signals, EM waves in connection with the motional induction effect were also
measured. Haines et al. [2007] conducted a series of field experiments for the purpose of understanding
seismoelectric phenomenon of electrokinetic nature. By striking a sledgehammer on the hammer plate
which can be taken as a vertical point force, they detected the expected seismoelectric direct field (actually
EM waves arising from the electrokinetic effect) which can be explained by a vertical electric dipole.
Fortuitously, they detected another kind of EM waves which cannot be explained by the electrokinetic effect.
Haines et al. [2007] called this kind of EM waves the Lorentz fields and proposed that it was generated by the
motion of the metal hammer plate with velocity v in the Earth’s magnetic field B0 because such a kind of
Lorentz field cannot be measured if a plastic hammer plate is used. They explained the Lorentz fields by a
horizontal electric dipole which is orientated along the direction v × B0 and the radiation pattern of this
horizontal dipole agreed with the data well.
These previous studies have supported the motional induction effect to be an effective mechanism to
generate earthquake-induced EM fields. However, understanding of the coupling between the EM field and
the elastic wave arising from such a mechanism is not sufficient. Yamazaki [2012] studied the magnetic
variations accompanying the seismic wave, but the formulations he presented were based on the plane-
wave theory. Note that EM signals were often observed near the earthquake sources. For example, the
measurement sites where Matsushima et al. [2002] recorded the coseismic EM signals were very close to the
epicenter, from several kilometers to several tens of kilometers. The plane-wave assumption turns to be
inappropriate when the source-receiver distance becomes very small and in this situation the source effect
needs to be taken into account. Therefore, in this study we investigate the property of the EM disturbances
resulting from the motional induction effect in an alternative way, that is, to solve the closed-form solutions
of the electric and magnetic fields in a uniform full space. By modeling the earthquake as a double-couple
source, we solve the Green’s functions of the electric and magnetic fields arising from the motional induction
effect. The process is similar to solving the seismoelectromagnetic fields due to the electrokinetic effect
[Gao and Hu, 2010].
Note that there are also some other candidate mechanisms that can convert the mechanical energy into
the EM variations, e.g., the piezoelectric effect [Ogawa and Utada, 2000a, 2000b; Huang, 2002], the
piezomagnetic effect [Stacey and Johnston, 1972; Yamazaki, 2011, 2013], and the electrokinetic effect
[Pride, 1994; Haartsen and Pride, 1997; Gao and Hu, 2010; Ren et al., 2012; Gao et al., 2013a, 2013b]. It is possible
that part or all of these mechanisms contribute to the mechanoelectric conversion simultaneously, but
contribution from each mechanism differs. Therefore, comparison between the EM fields arising from
different mechanisms is indispensable, and it can help distinguishing one mechanism from the other and
also benefit the explanation as well as the understanding of the anomalous EM changes observed in real
earthquake events. In this article we shall compare the motional induction effect with the electrokinetic
effect since the latter is a very popular mechanism associating the EM fields with the seismic waves and has
been studied a lot.
The present article is organized as follows. In the next section we first present the governing equations that
couple the elastodynamic equations with Maxwell equations and solve the Green’s functions of the electric
and magnetic fields generated by a single-point force. Then we derive the expressions of the electric and
magnetic fields generated by a moment tensor source which is frequently used to model an earthquake
caused by a fault slip. In section 3 we make numerical simulations and apply them to explaining the coseismic
EM data observed during actual earthquake and the Lorentz fields observed in the field experiments made
by Haines et al. [2007]. In section 4 comparison is made between the motional induction effect and the
electrokinetic effect.
2. Theoretical Formulations
2.1. Green’s Functions due to a Single-Point Force
In this study we describe the motional induction effect by coupling the elastodynamic equations governing
the propagation of the elastic waves with Maxwell equations controlling the propagation of the EM waves.
Assuming a time dependence of e iωt, the coupling equations can be expressed as
ðH GÞ∇∇ u þ G∇2 u þ ω2 ρu ¼ F; (1)
J ¼ σ0 E þ σ0 vB0 ; (2)
∇E ¼ iωμH; (3)
∇H ¼ iωεE þ J þ Jc ; (4)
where u is the displacement vector; E is the electric field; H is the magnetic field; F is the body force density;
B0 is the ambient geomagnetic field; ω is the angular frequency; G and H = λ + 2G are the elastic moduli of the
medium with λ representing the Lamé constant; and ρ, σ0, ε, and μ are the density, conductivity, dielectric
permittivity, and permeability of the medium, respectively. All the parameters of the medium are set to be
constant since we shall solve the wave fields in a full-space model. v = iωu is the velocity, and σ0v × B0
represents the induction electric current via which the elastic and EM energies are coupled. Jc is an applied
current-density source, and here we ignore it since a mechanical source is used in this study. We also
ignore the feedback of the induced EM fields on the seismic wave because these induced EM fields are
usually weak (typically on the orders of 1 μV/m and 0.1 nT, respectively) and they would exert negligible
impacts on the seismic wavefields. Therefore, the one-way-coupling governing equations (1)–(4) is
appropriate since we focus on the EM responses induced by a mechanical source.
By substituting equations (2) and (4) into equation (3), one can obtain
where eε ¼ ε σ0 =ðiωÞ is the equivalent dielectric permittivity. Equations (1) and (5) are in the frequency-
space domain. It is convenient to solve these two equations by transforming them into the wave number
domain. We define a pair of forward and inverse Fourier transforms as follows:
u ∫
eðkÞ ¼ uðrÞeikr dr; (6)
∫ueðkÞe
1
uðrÞ ¼ ikr
dk; (7)
ð2πÞ3
where r = xiei is the position vector and ei is the coordinate unit vector. Here we use an orthogonal coordinal
system. k ¼ k ^k is the wave vector in which ^k denotes the direction of the wave propagation. Let the source
be a single-point force which is located at position r′ ¼ xi′ ei
F ¼ F0 δðr r′ Þ: (8)
By applying the forward Fourier transform defined in equation (6) to equations (1) and (5), we have
eðkÞ ¼ F0 eikr′ ;
Gk 2 þ ω2 ρ I ðH GÞkk u (9)
k 2 ω2eεμ I kk e e B0 ;
EðkÞ ¼ ω2 μσ0 u (10)
1
ðI αkkÞ1 ¼ I kk (11)
k 2 1α
(α is an arbitrary constant), we solve equations (9) and (10), and obtain the displacement and the electric field
2 3
1 1 1
eðkÞ ¼ 4 2
u I 2 2 kk þ kk5 F0 eikr′ ; (12)
G k ω2 s2s ω ss H k ω s s ω
2 2 2 2 2
p p
e ω2 μσ0 kk
EðkÞ ¼ I eB0 Þ;
ðu (13)
k ω2 εeμ
2 ω2 εeμ
where ss and sp are the slownesses of the S and P waves, respectively, and they are expressed as
rffiffiffi
ρ
ss ¼ ; (14)
G
rffiffiffi
ρ
sp ¼ : (15)
H
e
EðkÞ ¼
½ 2
1
2
G k ω sem k ω ss
2 2 2 2
B0 I 2
1
Gss ω k ω s2em k 2 ω2 s2s
2 2 2
B0 kk
1
þ 2 B0 kk
Hs2p ω2 k
2
ω2 s2em k ω2 s2p
1
ω2 s2em G k 2 ω2 s2em k 2 ω2 s2s
kkB0 F0 ω2 μσ0 eikr′ ; (16)
where
pffiffiffiffiffiffi
sem ¼ εeμ (17)
is the slowness of the EM wave. eεμ has two square roots that are conjugated since it is complex. Here we
choose the root which has a nonnegative imaginary part. This constrain guarantees that the EM wave will
have nonincreased amplitude during its propagation. The displacement and electric field shown in equations
(12) and (16) are in the frequency-wavenumber domain. To get their responses in frequency-space domain,
we apply the inverse Fourier transform defined in equation (7) to equations (12) and (16), respectively. After a
lengthy algebraic manipulation (detailed in Appendix A), one gets
where ^B 0 ¼ BB00 ¼ ^Bi ei and B0 = |B0| are the direction vector and amplitude of the ambient geomagnetic
field, respectively. r = |r r′| is the source-receiver distance, and ^r ¼ rr ^
r ¼ ri ei is the unit vector pointing
′
from the source to the receiver. Gu ðrj ^rÞ and GE ðrj ^rÞ are the Green’s functions of the displacement and
F F
the electric field, respectively. Aem1, Aem2, As1, As2, and Ap are amplitudes, and their expression are detailed
in Appendix A. Since the electric field has been solved, one can easily get the magnetic field by using
equation (3):
1
HðrÞ ¼ ∇EðrÞ ¼ GFH ðrjr′ ÞF0
iωμ
1 n iωsem eiωsem r ^ eiωsem r ^
¼ Aem1 B 0^r ^B 0 ^r I Aem1 2
B 0^r ^B 0 ^r I
iωμ 4πr 4πr
iωsem eiωsem r ^
^
eiωsem r ^
Aem2 B 0^r B 0 ^r ^r^r þ Aem2 2
2 B 0^r þ ^r^B 0 þ ^B0 ^r I 6 ^B 0 ^r ^r^r
4πr 4πr
eiωsem r i 1
þ Aem2 3^B 0^r þ 3^r^B 0 þ 3 ^B 0 ^r I 15 ^B 0 ^r ^r^r
4π ωsem r 3 ω sem r
2 2 4
eiωsp r i 1 o
Ap 2 2 4 3^B 0^rþ 3^r^B 0 þ 3 ^B 0 ^r I 15 ^B 0 ^r ^r^r F0 : (20)
4π ωsp r 3 ω sp r
GFH ðrj^rÞ is the Green’s function of the magnetic field generated by the single-point force. One can easily
prove that
iωss r
eiωss r i 1 e
∇ As1 ^r^r^B 0 þ As1 I^B 0 3^r^r^B 0 ¼ 0: (21)
4πr ωss r 2 ω2 s2s r 3 4π
Thus, the terms with the amplitude As1 appearing in the expression of the electric field in equation (19) vanish
in that of the magnetic field in equation (20).
The propagation terms eiωss r and eiωsp r in equation (18) indicate that the seismic disturbance can propagate
with the velocities of the S and P waves. This is a phenomenon as known to all that a single-point force source
can generate elastic S and P waves. Notice that the terms eiωss r and eiωsp r also exist in equations (19) and (20),
implying that there are electric and magnetic perturbations which propagate at the S and P wave velocities.
In other words, the P and S waves can produce electric and magnetic signals during their propagations.
Furthermore, there are also propagation terms eiωsem r in equations (19) and (20), indicating that the electric
and magnetic fields can travel at the EM wave velocity. This implies that a single-point force can generate an
EM wave arising from the motional induction effect as well.
2.2. Wave Field due to Moment Tensor Sources
Since the EM signals were usually measured during actual earthquake events [e.g., Matsushima et al., 2002], it
is necessary to consider an earthquake source. Most earthquakes are generated by fault slips and can be
described mathematically by the moment tensors. In seismology [Aki and Richards, 2002], the displacement
due to a moment tensor in the frequency domain is expressed as
∂GFu;ij
ui ¼ Mjk ; (22)
∂r ′k
where Mjk is the jkth component of the moment tensor and GFu;ij is the Green’s function of the displacement
due to a single-point force.
Equation (22) is also valid for the displacement u, the electric field E, and the magnetic H for the elastic-
EM-coupling problem. Using equation (22) and the Green’s function of u shown in the brace in equation (18),
one easily gets that
1 iωss eiωss r 1 iωsp eiωsp r T
uðrjr′ Þ ¼ M^r ^rT M^r ^r þ ^r M^r ^r
G 4πr H 4πr
iωss r
1e
þ trðMÞ^r þ MT^rþ 2M^r 6 ^rT M^r ^r
G 4πr 2
1 eiωsp r
trðMÞ^r þ MT^r þ M^r 6 ^rT M^r ^r
H 4πr 2
1 eiωss r i 1
þ 3trðMÞ^r þ 3MT^r þ 3M^r 15 ^rT M^r ^r
G 4π ωss r 3 ω2 s2s r 4
!
1 eiωsp r i 1
3trðMÞ^r þ 3MT^r þ 3M^r 15 ^rT M^r ^r ; (23)
H 4π ωsp r 3 ω2 s2p r 4
where tr(M) = M11 + M22 + M33 is the trace of the moment tensor. The electric field can be obtained in a
similar way
iωsem iωsem r 1 eiωsem r 2 eiωsem r i 1 3
Eðrjr′ Þ ¼ Aem1 e Eem1 þ E þ E
4πr 4πr 2 em1 4π ωsem r 3 ω2 s2em r 4 em1
iωsem eiωsem r 1 eiωsem r 2 eiωsem r i 1 3
þ Aem2 Eem2 þ E þ E
4πr 4πr 2 em2 4π ωsem r 3 ω2 s2em r 4 em2
iωss r iωss r
iωss iωss r 1 e 2 e i 1 3
þ As1 e Es1 þ E þ E (24)
4πr 4πr 2 s1
4π ωss r 3 ω2 s2s r 4 s1
iωseiωss r 1 eiωss r 2 eiωss r i 1 3
þ As2 Es2 þ E þ E
4πr 4πr 2 s2 4π ωss r 3 ω2 s2s r 4 s2
" ! #
iωsp eiωsp r 1 eiωsp r 2 eiωsp r i 1 3
þ Ap Ep E E ;
4πr 4πr 2 p 4π ωsp r 3 ω2 s2p r 4 p
where
h T
Eem1 ¼ ^B 0 ðM^r Þ ^r^B 0 M^r ^r;
1
(25)
T h T i
Eem1 ¼ 2^B 0 ðM^r Þ þ ^r^B 0 M þ ^B 0 M : I ^r 6 ^r^B 0 M^r ^r;
2
(26)
T h T i
Eem1 ¼ Es1 ¼ 3^B 0 ðM^r Þ þ 3 ^r^B 0 M þ 3 ^B 0 M : I ^r 15 ^r^B 0 M^r ^r;
3 3
(27)
Eem2 ¼ Ep ¼ ^rT M^r ^B 0 ^r;
1 1
(28)
Eem2 ¼ Ep ¼ ^B 0 ðM^r Þ þ trðMÞ^B 0 ^r þ ^B 0 MT^r 6 ^rT M^r ^B 0 ^r ;
2 2
(29)
Eem2 ¼ Es2 ¼ Ep ¼ 3^B 0 ðM^r Þ þ 3trðMÞ^B 0 ^r þ 3^B 0 MT^r 15 ^rT M^r ^B 0 ^r;
3 3 3
(30)
h T i
^r^B 0 M^r ^r;
1
Es1 ¼ (31)
T h T i
Es1 ¼ ^B 0 ðM^r Þ þ ^r^B 0 M þ ^B 0 M : I ^r 6 ^r^B 0 M^r ^r;
2
(32)
Es2 ¼ ^B 0 ðM^r Þ ^rT M^r ^B 0 ^r;
1
(33)
Es2 ¼ 2^B 0 ðM^r Þ þ trðMÞ^B 0 ^r þ ^B 0 MT^r 6 ^rT M^r ^B 0 ^r:
2
(34)
The symbol “:” in the third term of the right side of equation (26) denotes a double inner product, that is,
^ 0 M : I ¼ B^l Mjk εljm em ek : δst es et ¼ B^l Mjk εljm δst ðem es Þðek et Þ ¼ B^l Mjk εljm δmk ;
B (35)
where εljm is the permutation symbol. Similarly, we obtain the magnetic field generated by the moment tensor
2 2 iωsem r
1 ω sem e 1 eiωsem r iωsem 1 2
H rjr′ ¼ Aem1 Hem1 þ 2 þ 3 Hem1
iωμ 4πr 4π r r
2 2 iωsem r
1 ω sem2 e 1 iωs em2 e iωsem r
2 eiωsem r 3 eiωsem r i 1 4
þ Aem2 Hem2 H H H
iωμ 4πr 4πr 2 em2
4πr 3 em2 4π ωsem r 4 ω2 s2em r 5 em
2 2 iωss r
1 ω ss e 1 iωss e iωss r
2 e iωss r
3 e iωss r
i 1 4
þ As2 Hs2 þ H þ H H
iωμ 4πr 4πr 2 s2
4πr 3 s2
4π ωss r 4 ω2 s2s r 5 s2
" ! #
1 ω2 s2p eiωsp r 1 iωsp eiωsp r 2 eiωsp r 3 eiωsp r i 1 4
þ Ap Hp þ H þ H þ Hp : (36)
iωμ 4πr 4πr 2 p
4πr 3 p 4π ωsp r 4 ω2 s2p r 5
In equation (36),
Hem1 ¼ ^rT M^r ^B 0 ^rT ^B 0 M^r;
1
(37)
Hem1 ¼ trðMÞ^B 0 3 ^rT M^r ^B 0 M^B 0 þ 3 ^rT ^B 0 ðM^r Þ;
2
(38)
Hem2 ¼ Hp ¼ ^rT M^r ^B 0 ^rT M^r ^rT ^B 0 ^r;
1 1
(39)
T
Hem2 ¼ Hp ¼ trðMÞ^B 0 þ ^B 0 M^r ^r þ 4ð^rT M^r Þ^B 0 þ ^rT M^B 0 ^r þ ^rT ^B 0 trðMÞ^r
2 2
þ ^rT ^B 0 MT^r 10ð^rT M^r Þ ^rT ^B 0 ^rþ ^rT ^B 0 ðM^r Þ; (40)
T
Hem2 ¼ Hp ¼ 2trðMÞ^B 0 6 ^B 0 M^r ^r 9ð^rT M^r Þ^B 0 6 ^rT M^B 0 ^r
3 3
6 ^rT ^B 0 trðMÞ^r 6 ^rT ^B 0 MT^r þ 45ð^rT M^r Þ ^rT ^B 0 ^r
þ MT ^B 0 þM^B 0 6 ^rT ^B 0 ðM^r Þ; (41)
T
Hem2 ¼ Hs2 ¼ Hp ¼ 3trðMÞ^B 0 15 ^B 0 M^r ^r 15ð^rT M^r Þ^B 0
4 4 4
15 ^rT M^B 0 ^r 15 ^rT ^B 0 trðMÞ^r 15 ^rT ^B 0 MT^r
þ 105ð^rT M^r Þ ^rT ^B 0 ^r þ 3MT ^B 0 þ 3M^B 0 15 ^rT ^B 0 M^r; (42)
Hs2 ¼ ^rT M^r ^rT ^B 0 ^r ^rT ^B 0 M^r;
1
(43)
T
Hs2 ¼ ^B 0 M^r ^r ð^rT M^r Þ^B 0 ^rT M^B 0 ^r ð^rT B0 ÞtrðMÞ^r
2
^rT ^B 0 MT^r þ 10ð^rT M^r Þ ^rT ^B 0 ^r þ M^B 0 4 ^rT ^B 0 ðM^r Þ; (44)
3
Hs2 ¼ trðMÞB0 þ 6 B0 T M^r ^r þ 6ð^rT M^r ÞB0 þ 6ð^rT MB0 Þ^r þ 6ð^rT B0 ÞtrðMÞ^r
þ 6ð^rT B0 Þ MT^r 45ð^rT M^r Þð^rT B0 Þ^r MT B0 2MB0 þ 9ð^rT B0 ÞðM^r Þ: (45)
Figure 1. (a) Distributions of the epicenter (star), the seismic station (solid circle), and the MT measurement site (triangle).
Their locations are (32.57°N, 105.42°E), (33.35°N, 104.99°E), and (33.34°N, 105.02°E), respectively. (b) Full-space geological
model for the theoretical simulation in this study. A Cartesian coordinates system is set up on the Earth’s surface with x, y,
and z indicating the north, east, and downward directions, respectively.
During this aftershock, a seismic station (solid circle in Figure 1) which is located at (33.35°N, 104.99°E) and
about 99 km northwest of the epicenter, recorded the seismic waves by an accelerometer with a sampling
frequency of 200 Hz. In the meanwhile, a magnetotelluric (MT) monitoring instrument (triangle in Figure 1a)
that is located at (33.34°N, 105.02°E) and about 3 km southeast to the seismic station, recorded the electric,
and magnetic variations. The sampling frequency of the electric and magnetic signals is 24 Hz. The MT
instrument was equipped and began working 3 days before the occurrence of this earthquake by
the researchers of the Institute of Geology, China Earthquake Administration [Tang et al., 2010]. The topmost
three plots of Figure 2 show the acceleration signals recorded at the seismic station, from which we can see that
the P wave arrived about 15 s after the occurrence of the earthquake. The remaining five plots of Figure 2
display the two components of the electric field and three components of the magnetic field measured by
the MT equipment. We can see clear coseismic EM disturbances that approximately share the same arrival
time with the P wave since the MT equipment is very close to the seismic station (only 3 km). The S wave that
arrived about 25 s after the earthquake occurrence produced more significant coseismic EM responses
because of its larger amplitude. The acceleration corresponding to the S wave is on the order of 0.1 m/s2,
while the coseismic electric and magnetic fields are on the order of 1 μV/m and 0.1 nT, respectively. In this
section we shall make a simple estimation of these coseismic EM signals on the basis of the motional
induction effect. The purpose is to investigate whether the EM fields caused by such an effect can reach the
amplitudes of the real EM data.
Here we consider a full-space geological model because the theoretical formulations we derived in the
former section is a full-space solution. As shown in Figure 1b a Cartesian coordinate system (o, x, y, z) is
constructed with the original point o locating at the hypocenter, and x, y, and z denoting the positive north,
positive east, and downward directions, respectively. The coordinates of the seismic station are (x = 86.8 km,
y = 40 km, z = 27 km) and those of the MT measurement site are (x = 85.7 km, y = 37.5 km, z = 27 km).
The parameters of the medium for the calculation are listed in Table 1 (elastic medium 1). For the source
mechanism of this earthquake, we use the global centroid-moment tensor solution which gives the strike,
dip, rake, and depth of the source as 59°, 84°, 178°, and 27 km, respectively. The scalar moment is
M0 = 1.59 × 1018 N m corresponding to an Mw6.1 earthquake. The time function we use is a Ricker wavelet
with a dominant frequency of f0 = 0.6 Hz and a time delay t0 = 1/f0:
h i 22 2
s0 ðtÞ ¼ 1 2π2 f 20 ðt t 0 Þ2 eπ f 0 ðtt0 Þ : (46)
Using the formulas shown in equations (23), (24), and (36) as well as the parameters listed in Table 1, we
calculate the seismic and EM signals and plotted their waveforms in Figure 3. Figures 3a and 3b show the
Figure 4. Layout of the seismoelectric experiment conducted by Haines et al. [2007]. (a) Circular electrode array with 12
radial and 12 tangential channels in a horizontal plane. Small black circles represent electrode, and dashed lines indicate
the pairs across which the voltage was measured. (b) Side and (c) map views of the creation of the Lorentz field. The
horizontal component of the hammer plate velocity v crossed with the vertical component of the Earth’s magnetic field B0
creates an electric field EF in the conductive hammer plate [after Haines et al., 2007].
Table 2. Parameters of the Porous Medium (Sandstone) Used for Simulating the Seismic and EM Wavefields due to the
Electrokinetic Effect
Parameter Symbol Value or Range (Unit)
a
Porosity ϕ 0.19
a 15 2
Permeability κ0 70 × 10 (m )
a
Formation factor F 17.7
Tortuosity α∞ 3.36
Solid grain bulk modulus Ks 35.7 (GPa)
b
Frame bulk modulus Kb 15 (GPa)
Shear modulus G 14.7 (GPa)
Fluid bulk modulus Kf 2.25 (GPa)
b 3
Solid grain density ρs 2650 (kg/m )
3
Fluid density ρf 1000 (kg/m )
Solid relative permittivity εs 4
5
Salinity of the pore fluid Cf 10 ~ 5 (mol/L)
c
Fluid relative permittivity εr 78.24 ~ 36.1
11 11
Effective permittivity of the porous medium ε 5.15 × 10 ~ 7.26 × 10 (F/m)
c
Fluid viscosity η 1.9 ~ 3 (Pa s)
c
Zeta potential ζ 89.9 ~ 31.1 (mV)
c 5
Rock conductivity σ0 11.3 × 10 ~ 1.4 ( S/m)
c 10
Low-frequency electrokinetic coupling coefficient L0 13.9 ~ 1.88 (×10 sC/kg)
a
The porosity, the permeability, and the formation factor are chosen as the same values with the sandstone used in
the work by Jaafar et al. [2009].
b
The frame bulk modulus Kb is calculated from the porosity according to the relations between frame modulus and
porosity given by Vernik [1998].
c
εr, η, ζ , σ0, and L0 vary with the pore fluid salinity Cf, and they are calculated from their corresponding equations in
Appendix B.
fields Er and Et generated by such a horizontal force due to the electrokinetic effect. By comparing their
amplitude patterns (Figure 5b) with the data collected by Haines et al. [2007], we find even a horizontal force
cannot explain the data, either.
Haines et al. [2007] proposed that the Lorentz field is caused by the motion v of the metal hammer plate
crossing the Earth’s magnetic field B0, i.e., v × B0 (in their experiments, no Lorentz field was measured when a
plastic hammer plate was used). Furthermore, they pointed out that the aluminum cylindrical hammer plate
has more freedom to move horizontally than vertically so that the horizontal velocity of cylinder vH can be
higher than vertical one vV even though the impact on the cylinder has a smaller horizontal component than
the vertical component. As a result, the Lorentz field was proposed to be created by the horizontal motion vH
crossing with the vertical component of the Earth’s magnetic field B0z and seemed to be radiated by a
horizontal dipole with an orientation 50° west of north (i.e., the hammer plate orientation in Figure 4c) which
is perpendicular to both the directions of vH and B0z.
To evaluate their explanation of the Lorentz field, we calculate the electric fields generated due to the
motional induction effect using equation (19). The source we utilize is also a vertical force as well as a
horizontal force that is oriented 40° east of north. The horizontal force is used to generate the horizontal
motion of the hammer plate (Figure 4c). Note that the parameters used for the electrokinetic simulations
in Figures 6a–6c are for a porous medium (in Table 2) but our formulations for the motional induction
effect require an elastic medium. We then treat this porous medium as a nonporous solid, and get the
equivalent P velocity, S velocity, and density, which are 4.0 km/s, 2.5 km/s, and 2.3 g/cm3, respectively. The
conductivity and relative permittivity are chosen to be σ0 = 0.069 S/m and ε = 7.2 × 10 11 F/m, respectively.
The Earth’s magnetic field are chosen with components Bx = 2.3 × 10 5 T, By = 0, and Bz = 4 × 10 5 T, the
same value with Haines [2004]. The radial and tangential electric fields of the EM wave generated by a
vertical force are displayed in Figures 6d and 6e, from which we can see that they are direction dependent
while those resulting from the electrokinetic effect (Figure 6a) are not. The EM wave generated by the
horizontal force is also directionally dependent (Figures 6f and 6g). In Figures 5c and 5d, we plot the
amplitude patterns of the motional induction EM waves as a function of receiving position and compare
them with the Lorentz field collected by Haines et al. [2007]. It can be seen that the amplitude patterns of
Figure 6. Waveforms of the modeled EM waves arising from the electrokinetic (EK) effect received at the 12 positions in
Figure 4a: (a) Radial electric fields excited by a vertical force FV and (b) radial and (c) tangential electric fields excited by
a horizontal force FH oriented 40° east of north. Waveforms of the modeled EM waves arising from the motional induction
(MI) effect: (d) radial and (e) tangential electric fields excited by FV and (f) radial,and (g) tangential electric fields excited by
FH. In each subgraph, the waveforms are normalized by the max amplitude among the 12 signals.
the EM wave resulting from the horizontal force (Figure 5d) fit the data better than those by the vertical
force (Figure 5c). This confirms the conclusion made by Haines et al. [2007]; that is, the horizontal
motion of the cylinder in the Earth’s magnetic field are responsible for the observed field. By the way,
Figure 6 also illustrates that a mechanical source can generate observable EM wave due to the motional
induction effect.
iωsem r
eiωsem r ^
^ 0 F þ Aem1 i 1 e
^ 0 3^r^r B
^ 0 F
Eem ðrÞ ≈ Aem1 B 0 I ^r^r B IB
4πr ωsem r 2 ω2 s2em r 3 4π
iωsem r iωsem r
e i 1 e
¼ ^^
ðI r r Þ þ ^^
ðI 3r r 0 Þ Aem1 B ^ 0 F
4πr ωsem r 2 ω2 s2em r 3 4π
iωsem r iωsem r " #
e i 1 e σ 0 B0 1 ^ 0 F (47)
¼ω μ
2
ðI ^r^r Þ þ ðI 3^r^r 0 Þ 2 2 ; 2 B
4πr ωsem r 2 ω2 s2em r 3 4π ω G sem ss
|fflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflffl{zfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflffl}
p
The theoretical basis we use for modeling the electrokinetic phenomenon is Pride’s equations [Pride, 1994]
that are reviewed in Appendix B. According to the work by Gao and Hu [2010], the displacement u and the
electric field E generated by a moment tensor source in a full space are shown below:
Xsem
iωsei ωsr X sps
iωsei ωsr T
α¼ T Fα;s M^r ^r T M^r ^r þ LFα;s ^r M^r ^r
s¼ss
4πr s¼spf
4πr
Xsem
ei ωsr
þ T Fα;s 2 trðMÞ^r þ MT ^r þ 2M^r 6 ^r T M^r ^r
s¼ss
4πr
X sps
ei ωsr
þ LFα;s 2 trðMÞ^r þ MT ^r þ M^r 6 ^r T M^r ^r
s¼spf
4πr
hX
sem
ei ωsr i 1
þ T Fα;s
4π ωsr 3 ω2 s2 r 4
X
s¼ss
sps i
e i ωsr
i 1
LFα;s 3trðMÞ^r þ 3MT ^r þ 3M^r 15^r T M^r ^r ; (48)
s¼spf
4π ωsr 3 ω s r
2 2 4
where α = u, E. spf, sps, ss, and sem are the complex slownesses of the fast P wave (Pf), slow P wave (Ps), shear
wave (S), and EM wave, respectively. T Fα;s and LFα;s are the complex amplitudes of the transverse and
longitudinal components [Pride and Haartsen, 1996]. The expressions of the complex slownesses and
amplitudes are detailed in Appendix B. The magnetic field generated by the moment tensor is
(
1 X sem
ei ωsr ω2 s2 Xsem
ei ωsr iωs 1
H¼ T FE;s ½^r ðM^r Þ þ T FE;s 2 þ 3 ½ðIMÞ 3^r ðM^r Þg; (49)
iωμ s¼ss 4π r s¼ss
4π r r
where
I M ¼ δki ek ei Mjk ej ek ¼ δki Mjk ei ej ðek ek Þ ¼ Mji εijl el : (50)
Once the parameters of the porous medium and the source are given, one can calculate the displacement u,
the electric field E, and the magnetic field H at the specified position r from equations (48) and (49).
To get reasonable seismic and EM responses due to the electrokinetic effect, we follow the existing literature
and select proper parameters of the porous medium for numerical simulation. The porous medium is
assumed to be the sandstone that was used in the streaming potential experiment conducted by Jaafar et al.
[2009]. The porosity, permeability, and formation factor are ϕ = 0.19, κ0 = 70 × 10 15 (m2), and F = 17.7,
respectively. The tortuosity α∞ = 3.36 is derived from F = α∞/ϕ. The solid grain modulus and shear modulus
are chosen as Ks = 35.7 GPa and G = 14.7 GPa, respectively. The frame bulk modulus Kb is calculated from the
porosity according to the relations between frame moduli and porosity given by Vernik [1998]. The
parameters that affect the conversion between the seismic waves and EM fields are discussed in detail in
Appendix B. They are, namely, the fluid relative permittivity εr, the fluid viscosity η, the zeta potential ζ , the
rock conductivity σ0 , and the low-frequency electrokinetic coupling coefficient L0, all of which change with
the pore fluid salinity Cf . Their values are either chosen from experiment data or derived from empirical
relations and thus should be realistic. All the parameters of the porous medium are listed in Table 2.
Note that these parameters used for calculating electrokinetic wavefields are for a fluid-saturated porous
medium while the theoretical formulations derived in the present work for modeling the motional induction
effect are based on the elastodynamic theory for nonporous elastic solids. To compute the seismic and EM
wavefields arising from the motional induction effect, we treat the sandstone as a solid rock and then get the
equivalent P velocity (Vp = 4.0 km/s), S velocity (Vs = 2.5 km/s), and density (ρ = 2.3 g/m3). Then we calculate
the elastic moduli H and G from equations (15) and (14), respectively. The conductivity and dielectric
permittivity of the elastic continuum are identical to the bulk conductivity and permittivity of the porous
medium. All the parameters of the equivalent solid rock are listed in Table 1 (solid rock 2).
As shown in Figure 1b a Cartesian coordinates is used with the source being located at the origin point o
and the receiver being located at (x = 40 km, y = 40 km, z = 10 km). The source is a fault with the strike, dip,
and rake being 90∘, 60∘, and 0∘, respectively. The scalar moment is M0 = 1.59 × 1018 N m corresponding to
an Mw6.1 earthquake. The source time function is also a Ricker wavelet with central frequency of 1 Hz.
Figure 8
With Cf = 0.001 mol/L and other parameters listed in Table 2, we calculate the displacement uEK, the electric
field EEK, and the magnetic field HEK due to the electrokinetic effect by using the formulas (48) and (49).
With the parameters of the equivalent solid rock listed in Table 1, we compute the wavefields uMI, EMI,
and HMI arising from the motional induction effect by using equations (23), (24), and (36). The displacements
calculated from the two mechanisms are compared in Figure 8. As expected, there is no visual difference
between uEK and uMI. In Figure 8, we also compare the motional induction EM signals EMI and HMI (red lines)
with their electrokinetic counterparts, i.e., EEK and HEK (black lines). Each component of the electric and
magnetic fields is divided into three continuous time periods, i.e., 0 10 s, 10 s 20 s, and 20 s 30 s, in order
to illustrate the EM responses corresponding to the EM wave, the P wave, and the S wave, respectively, which
have different arrival times and amplitude scales.
In the electrograms in Figure 8, we can see three signals that are generated due to the motional induction
effect (red lines). The earliest one EMI
em is the EM wave which arrives immediately after the source originates.
The second one EMI p which has an arrival time of about t = 14 s is the coseismic electric field accompanying
the P wave. The third one which is denoted by EMI s and arrives at t = 23 s is the coseismic electric field
produced the S wave. These three signals are of different amplitudes. EMI em is on the order of 0.0001 μV/m,
smaller than EMI
p which is the coseismic electric field accompanying the P wave and is on the order of
0.01 μV/m, and much smaller than EMI em which is the coseismic electric field accompanying the S wave and
whose amplitude is as large as 20 μV/m. The electric signals resulting from the electrokinetic effect are also
plotted (black lines). We can also identify three signals, namely, EEK
em , Ep , and Es which have similar
EK EK
waveforms, same arrival times but different amplitudes with their motional induction counterparts, i.e., EMI em ,
EMI
p , and E MI
s , respectively. EEK
em is of the order of 0.01 μV/m, 100 times greater than E MI
em (0.0001 μV/m). EEK
p is of
p (0.01 μV/m). This indicates that in the geological condition
the order of 1000 μV/m, much larger than EMI
described by the parameters in Table 2 with Cf = 0.001 mol/L, the electrokinetic effect is the dominant
mechanism for producing the EM wave and the P-converted coseismic electric field. However, EEK s has an
amplitude of about 10 μV/m which is on the same order of EMI
s (20 μV/m), indicating that the two mechanisms
have comparable efficiency in converting the S wave to the electric field.
In the magnetograms in Figure 8, HMIem is the magnetic signal of the EM wave generated by the source due to
the motional induction effect while HEK
em is the one due to the electrokinetic effect. The amplitude of Hem is of
MI
the order of 0.001 pT, 100 times weaker than Hem which is of the order of 0.1 pT, indicating again that the
EK
electrokinetic effect dominates the generation of the EM wave. HMI p with amplitude of 10 pT is the coseismic
magnetic field accompanying the P wave. In contrast, the electrokinetic counterpart HEK
p is zero because the P
wave cannot produce a magnetic field due to the electrokinetic effect [Pride and Haartsen, 1996]. HMI
s and Hs
EK
are the S wave magnetic fields due to the motional induction effect and electrokinetic effect, respectively.
The former (on the order of 1 pT) is 3 orders of magnitude weaker than the latter (on the order of 1 nT),
showing that electrokinetic effect is the dominant mechanism in transforming the S wave energy into the
magnetic signals.
The former comparison between the EM fields arising from the two mechanisms is made under the condition
that the pore fluid salinity is Cf = 0.001 mol/L with the corresponding conductivity being about 7. × 10 4 S/m.
Note that the coupling term σ v × B0 in equation (2) implies that a higher conductivity will give rise to a larger
induction electric current which will generate stronger EM field. On the contrary, theoretical and experiment
works [e.g., Garambois and Dietrich, 2001; Block and Harris, 2006] have indicated that an increase in the
conductivity will cause a decrease in the EM field resulting from the electrokinetic effect. Therefore, it is
Figure 8. Comparisons between the displacements, the electric fields, and the magnetic fields calculated from the elec-
trokinetic formulations given by Gao and Hu [2010] (black lines) and the motional induction formulations derived in this
study (red lines). Each component of the electric and magnetic fields is divided into three continuous time periods, i.e.,
0 10 s, 10 s 20 s, and 20 s 30 s, in order to illustrate the electric and magnetic responses corresponding to the EM
wave, the P wave, and the S wave, respectively, which have different arrival times and amplitude scales. Note that the P
wave cannot produce a magnetic field due to the electrokinetic effect [Pride and Haartsen, 1996] so that we find that
EK EK EK
H p,x = H p,y = H p,z = 0.
necessary to consider the influence of the conductivity on each mechanism. In this study, we control the
conductivity by the pore fluid salinity as discussed in Appendix B. Letting the salinity varies from 10 5 mol/L
to 5 mol/L (Note that 5 mol/L is close to the saturated concentration of the NaCl solution at room
temperature), we have that the conductivity changes from 1.13 × 10 4 S/m to 1.4 S/m.
In order to investigate how the conductivity affects the ability of the P and S waves in producing the
coseismic electric and magnetic fields, it is convenient to study the transfer functions E/u and H/u for the
P and S waves arising from both the motional induction effect and the electrokinetic effect. According to
previous studies [Pride and Haartsen, 1996; Garambois and Dietrich, 2001; Gao and Hu, 2010], the transfer
functions E/u and H/u corresponding to the P and S waves arising from the electrokinetic effect are
iωe ρL Hs2p ρ
EK
Ep ¼ up ; (51)
eε Cs2p ρf
EK G s2s ρ=G
E ¼ iωμe ρ L jus j; (52)
s ρf s2s μeε
EK G s2s ρ=G
H ¼ iωsse ρ L jus j; (53)
s ρf s2s μeε
where eρ ¼ iη=ðωκ0 Þ. A P wave cannot generate any magnetic field due to the electrokinetic effect so that H/u
vanishes for a P wave [Pride and Haartsen, 1996; Gao and Hu, 2010]. For the motional induction effect, the
transfer functions E/u and H/u are (detailed derivation are given in Appendix C)
μσB
MI 0
Ep ≈ 2 u ; (54)
sp eεμ p
2
MI
E ≈ max 1; ss μσB0 jus j; (55)
s eεμ s2 eεμ
s
s σB
MI p 0
H ≈
p 2 u ; (56)
sp eεμ p
MI ss σB0
H ≈
s s2 eεμjus j: (57)
s
By using equations (51)–(57) and letting |up| = |us| = 0.01 m, we calculate the amplitudes of the coseismic EM
fields produced by the P and S waves due to the electrokinetic effect and the motional induction effect at
different conductivities and four different frequencies, and plot them in Figure 9.
The variation of the coseismic electric field with the conductivity at f = 0.1 Hz is displayed in Figure 9a, from
which we can see that when the conductivity increases the P-converted electric field due to the motional
induction effect EMI
p (red solid line) increases while that due to the electrokinetic effect Ep (blue solid line)
EK
decreases. EEK
p is larger than Ep at conductivities less than the transition point 0.016 S/m for f = 0.1 Hz.
MI
Figures 9b and 9c show that the transition point is augmented to 0.12 S/m and 0.86 S/m when the frequency
is increased to f = 1 Hz and f = 10 Hz, respectively. For f = 100 Hz (Figure 9d), EMI
p is always smaller than Ep ,
EK
indicating that at higher frequency the electrokinetic effect is always the dominant mechanism in converting
the P wave to the electric field in the conductivity region σ0 ≤ 1.4 S/m. Figures 9a–9d also show that for a given
frequency the S wave electric field due to the electrokinetic effect EEKs (blue dotted line) decreases with the
conductivity while that due to the motional induction effect EMI s (red dotted line) almost keeps constant.
Furthermore, EMI
s is always bigger than EEK
s regardless of the conductivity and the frequency, implying that the
motional induction effect always has a stronger ability in transferring the S wave energy into the electric signal.
Figures 9e–9h display the changes of the coseismic magnetic field with the conductivity at four different
frequencies. We find that the magnetic fields produced by the P wave (HMI MI
p ) and the S wave (Hs ) due to the
motional induction effect have comparable amplitudes. This means that the P and S waves have almost the
same efficiency in producing the magnetic field via the motional induction effect. Both HMI
p and Hs increase
MI
Figure 9. (a–d) Comparisons between the coseismic electric arising from the motional induction (MI) effect and the
electrokinetic (EK) effect under different conductivities and frequencies. EMI
p (red solid) and Es (red dotted) are the
MI
electric fields accompanying the P and S waves, respectively, due to the motional induction effect. EEK p (blue solid) and Es
EK
(blue dotted) are the ones due to the electrokinetic effect. (e–h) Comparisons between the magnetic fields arising from MI
p (red solid) and Hs (red dotted) are the magnetic
effect and the EK effect under different conductivities and frequencies. HMI MI
fields accompanying the P and S waves due to the motional induction effect. HEK s (blue dotted) is the magnetic field
accompanying the S wave due to the electrokinetic effect. There is no curve of HEKp because the P wave cannot generate any
magnetic field due to the electrokinetic effect [Pride and Haartsen, 1996; Gao and Hu, 2010].
dominates the S-to-magnetic conversion at low conductivities, while HMI s dominates at high conductivities.
The transition conductivity is 0.013 S/m at f = 0.1 Hz (Figure 9e) while it is increased to 0.078 S/m and 0.33 S/m
when the frequency is augmented to 1 Hz (Figure 9f) and 10 Hz (Figure 9g), respectively. Figure 9h shows that
HEK
s is always larger than Hs at f = 100 Hz in the conductivity region σ0 ≤ 1.4 S/m.
MI
Figure 10. Variations of the coseismic EM fields arising from the motional induction effect with the conductivity at four
different frequencies, namely, f = 0.1 Hz, 1 Hz, 10 Hz, and 100 Hz. Variations of (a) the electric field (EMI
p ) and (b) the
magnetic field (HMIp ) accompanying the P wave. Variations of (c) the electric field (Es ) and (d) the magnetic field (Hs )
MI MI
andthen it increases slowly in the high-conductivity range and seems to approach an upper limit. For
example, at f ¼ 0:1 Hz EMI
p rises linearly in the range σ0 < 0.01 S/m and slowly in the range σ0 ≥ 0.01 S/m to an
upper limit of 0.3 μV/m. EMI
p at f = 1 Hz has similar variation but with broader linear part (σ0 < 0.1 S/m) and
seems to approach a larger upper limit (about 3 μV/m). For the cases f = 10 Hz and f ¼ 100 Hz EMI p shows
linear dependence of conductivity over the range of conductivities considered in this article, i.e.,
1.13 × 10 4 S/m–1.4 S/m. At conductivities lower than 0.01 S/m the curves of EMI
p at four different frequencies
coincide with each other, indicating that in this conductivity range EMI
p is independent of the frequency.
From Figures 10b and 10d, we find that the coseismic magnetic fields that accompany the P and S waves, i.e.,
HMI
p and Hs , share similar properties with Ep . Such a dependence of the conductivity and the frequency for
MI MI
the coseismic fields EMIp , Hp , and Hs is similar to the dependence of conductivity for the magnetic field
MI MI
produced by a Rayleigh wave given by Yamazaki [2012] (see Figure 2 in his work). However, the electric field
accompanying the S wave EMI s is different, and for a given frequency, it nearly keeps constant over the range
of the conductivity shown in Figure 10c. If the frequency is augmented by a factor of 10, the value of EMI s is also
7
amplified by the same factor. For example, Es is approximately 3.2 × 10 V/m at f = 0.1 Hz, and it is amplified
MI
to 3.2 × 10 6 V/m, 3.2 × 10 5 V/m, and 3.2 × 10 4 V/m when the frequency is increased to f = 0.1 Hz,
f = 0.1 Hz, and f = 1 Hz, respectively.
The former paragraphs compared the coseismic EM fields arising from the motional induction effect and the
electrokinetic effect. We now investigate the EM waves generated by the moment tensor due to such two
mechanisms. In Figure 8 we find that the electric and magnetic fields of the EM wave caused by the motional
induction effect are on the orders of 0.0001 μV/m and 0.001 pT, respectively, while those caused by the
electrokinetic effect are on the orders of 0.01 μV/m and 0.1 pT, respectively, indicating that the electrokinetic
effect produces a stronger EM wave. This result is obtained under the condition σ0 = 7. × 10 4 S/m. Note that
increase in the conductivity will enhance the mechanoelectric conversion efficiency of the motional
induction effect but weaken that of electrokinetic effect. It is necessary to compare the EM waves caused by
those two mechanisms under other conductivity conditions.
The motional induction EM wave corresponds to the terms with amplitudes Aem1 and Aem2 in the expressions
of the electric and magnetic fields in equations (24) and (36). As is discussed in section 3.3 and illustrated in
Figure 7, |Aem1| is always larger than |Aem2| especially for low conductivities and high frequencies, and the EM
wave is mainly controlled by the terms with the amplitude Aem1. Therefore, the electric and magnetic fields of
the EM wave in equations (24) and (36) can be approximately rewritten as
iωsem iωsem r 1 eiωsem r 2 eiωsem r i 1 3
em ≈ Aem1
EMI e Eem1 þ E þ E ; (58)
4πr 4πr 2 em1
4π ωsem r 3 ω2 s2em r 4 em1
2 2 iωsem r
1 ω sem e 1 eiωsem r iωsem 1 2
HMI
em ≈ Aem1 Hem1 þ 2 þ 3 Hem1 : (59)
iωμ 4πr 4π r r
According to equations (48) and (49), the electric and magnetic fields of the EM wave resulting from the
electrokinetic effect are
iωsem ei ωsr EK;1 eiωsem r EK;2 eiωsem r i 1 EK;3
EEK ¼ T F
E þ E þ E ; (60)
em E;sem
4πr em
4πr 2 em 4π ωsem r 3 ω2 s2em r 4 em
2 2 iωsem r
1 F ω sem e EK;1 eiωsem r iωsem 1 EK;2
HEK
em ¼ T E;sem Hem þ 2 þ 3 Hem ; (61)
iωμ 4πr 4π r r
where
EK;1
Eem ¼ M^r ^r T M ^r ^r; (62)
EK;2
Eem ¼ trðMÞ ^r þ MT ^r þ 2M ^r 6 ^r T M ^r ^r ; (63)
EK;3
Eem ¼ 3trðMÞ^r þ 3MT ^r þ 3M^r 15 ^r T M ^rÞ^r ; (64)
EK;1
Hem ¼ ^rðM ^r Þ; (65)
EK;2
Hem ¼ ðIMÞ 3 ^rðM ^r Þ: (66)
1
different amplitudes in front of their respective brackets and vectors inside. Let us investigate the vector Eem1
EK;1
and its counterpart Eem . By comparing their expressions in equations (25) and (62), respectively, we can
1 EK;1 1 EK;1
approximately have Eem1 ≈Eem because the amplitudes of Eem1 and Eem should be on the same order or at
2 EK;2 3 EK;3 1
least they should be closed to each other. Similarly, we can further have Eem1 ≈Eem , Eem1 ≈Eem , Hem1
EK;1 2 EK;2
≈Hem , and Hem1 ≈Hem . As a result, dividing equations (58) by (60) and (59) by (61), respectively, we obtain
MI MI
E H jAem1 j
em em
EEK ≈ HEK ≈ F : (67)
em em T E;sem
The ratio between the strengths of the EM waves arising from the two mechanisms is proportional to and
EK MI EK
represented by jAem1 j=T FE;sem . We then plot the variations of EMI
em = Eem and Hem = Hem with the
MI EK
conductivity in Figure 11. For f = 0.1 Hz, Eem =Eem < 1 when σ0 < 0.013 S/m, indicating that at low
conductivities the electrokinetic effect produces stronger EM wave than the motional induction effect. If the
frequency is increased to f = 1 Hz and f = 10 Hz, respectively, the dominant range for the electrokinetic effect
is extended to σ0 < 0.08 S/m and σ0 < 0.78 S/m, respectively. If the frequency is augmented to as high as
100 Hz, the electrokinetic effect is always dominant over the range of conductivity considered here. It is
explicitly seen from Figure 11 that under low-conductivity and high-frequency conditions the electrokinetic
effect is the primary mechanism for the generation of the EM wave.
of the two mechanisms can result in two kinds of EM signals, i.e., the independently propagating EM wave and
the coseismic EM fields accompanying the P and S waves, which do not simply proportional to the amplitudes
of the seismic waves but depend on the type of the waves. The dissimilarities are that both the EM wave and
the coseismic EM fields arising from the motional induction effect generally differ from their electrokinetic
counterparts in the amplitudes and the dependence on the frequency as well as the conductivity. For the
coseismic EM fields, the transfer functions E/u and H/u corresponding to the P and S waves were derived and
compared with their electrokinetic counterparts. The electric field accompanying the P wave arising from the
motional induction effect EMI
p increases when the conductivity increases, while its electrokinetic counterpart Ep
EK
decreases. As shown in Figures 9a–9d, for low frequencies (f < 100 Hz) the motional induction effect dominates the
P-to-electric conversion at high conductivities. For example, at f ¼ 0:1 Hz EMI
p is larger than Ep when the
EK
conductivity is higher than the transition point 0.016 S/m. The transition point of the conductivity will shift to
0.12 S/m and 0.86 S/m when the frequency is increased to f = 1 Hz and f = 10 Hz, respectively. At frequencies higher
than 100 Hz the electrokinetic effect always dominates in the conductivity range considered in this study
(10 4 S/m–1.4 S/m). The relation between the coseismic magnetic fields accompanying the S wave arising
from the motional induction effect HMI EK
s and its electrokinetic counterpartHs (Figures 9e–9h) is similar to the relation
between Ep and Ep (Figures 9a–9d). However, the relation between the electric field accompanying the S wave
MI EK
the increase of the conductivity, while Es almost keeps unchanged over the range of the conductivity (see
MI
induction effect is always the primary mechanism in converting the S wave energy to the electric field.
One phenomenon we noticed in Figure 2 that the real data observed during the 2008 Qingchuan earthquake
shows that the P wave-generated coseismic magnetic field when it arrived at the receiver. The electrokinetic
effect seems to have certain obstacle to interpret the coseismic magnetic signals starting with the P arrival,
because it theoretically predicts no magnetic field accompanying the body P wave [Pride and Haartsen, 1996].
Consider that the instruments receiving the seismic and EM signals are usually located close to the free surface,
where the P wave can convert a reflected S wave that can generate significant magnetic field due to the
electrokinetic effect. However, the synthetic magnetic field synchronizing with the P wave has only horizontal
components and no vertical magnetic field can be generated before the S wave arrives [Ren et al., 2012]. This is
because only the SH wave can give rise to the vertical magnetic field while the SV wave only generates
horizontal one [Pride and Haartsen, 1996]. Since in a horizontally layered media the P wave is only coupled with
the SV wave, no vertical magnetic field can be generated unless the SH wave arrives. Nevertheless, we notice
that this conclusion is obtained under the condition that we use a horizontally layered geological model and
assume media are homogeneous and isotropic. Perhaps a complex geological model with heterogeneous or
anisotropic media could result in vertical magnetic field when the P wave arrives. In addition, when the seismic
waves passed the instrument it caused the shaking of the magnetometer, which might give rise to a changing
of the magnetic signal, especially in the vertical component. This needs to be examined in the future studies.
In contrast to the electrokinetic effect, the motional induction effect predicts a significant magnetic field
accompanying the P wave as shown in Figures 3 and 8. The MI effect seems to have no obstacle to interpret
the vertical coseismic magnetic field starting with the P arrival since the P wave can directly generate a
magnetic field with both horizontal and vertical components. As far as this property is concerned, the MI
effect is more likely to be the mechanism for the real EM data than the EK effect if we can confirm that the
vertical magnetic field was not caused by the shaking the of the magnetometer. However, it is still a difficulty
to exclude the electrokinetic effect at present.
Another phenomenon we noticed is that the coseismic EM fields arising from the motional induction effect
is not strictly proportional to the conductivity (Figure 10) although the coupling term σ0v × B0 in equation
(2) implies a direct proportion between the EM fields and the conductivity. In the low range of the
conductivity, EMIp , Hp , and Hs rise linearly with conductivity and do not depend on the frequency. In the
MI MI
high-conductivity range, they increase slowly and seem to approach their respective upper limits. An
increase in the frequency will extend their linear-rising part toward to high conductivities and enhance
their upper limits. This agrees with result obtained by Yamazaki [2012] about the dependence of conductivity
for the magnetic field produced by a Rayleigh wave.
The EM waves generated by a fault slip (described by a moment tensor source) due to the two mechanisms
were also compared. The result shows that the motional induction effect can generate a stronger EM wave
than the electrokinetic effect under high-conductivity and low-frequency conditions (Figure 11). Note that
high conductivity gives rise to high attenuation of the EM wave. For example, under the condition that
f = 0.1 Hz and σ0 = 0.1 S/m, the penetration depth of the EM wave is only
sffiffiffiffiffiffiffiffiffiffiffi sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
2 2
δ¼ ¼ ¼ 5:03 km: (68)
ωμσ0 ð2π0:1 Hz4π107 H=m0:1 S=m
In this situation, the EM generated by the source can only propagate for a very short distance. Although the
EM wave generated due to the motional induction effect is 10 times stronger than that due to the
electrokinetic effect (red dash-dotted line in Figure 11), it may become undetectable at a distant observation
site except that the earthquake is sufficiently large. Nevertheless, there is a possibility that the medium in the
vicinity of the earthquake source is more conductive while that out of the source region is less conductive so
that the EM generated by the source can have strong amplitude and propagate far with a low attenuation out
of the source region. Under this condition, it is reasonable to taken the motional induction effect as the
preferred candidate mechanism for the observed EM waves (e.g., the direct magnetic signals observed by
Okubo et al. [2011]). Otherwise, if the source region is known to have a low conductivity, the electrokinetic
effect should be considered prior to the motional induction effect.
A1. Displacement
To get the frequency-space response of the displacement, we apply an inverse Fourier transform to equation (12)
∫ueðkÞe
1
uðrÞ ¼ ikr
dk
ð2πÞ3
82 3 9
< =
1 4 1 1 1
kk5F0 e
′
ikr
¼ I 2 2 kk þ eikr dk
ð2πÞ3 :
∫ G k ω ss
2 2 2 ω ss H k ω sp sp ω
2 2 2 2 2 ;
h1 1
∫ ∫
1 ikðrr′ Þ 1 1 1
kkeikðrr Þ dk
′
¼ e dk I
G ð2πÞ3 k 2 ω2 s2s Gω2 s2s ð2πÞ3 k 2 ω2 s2s
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Iu1 Iu2
i
∫
1 1 1
kk eik ðrr Þ dk F0 :
′
þ
Hω2 s2p ð2πÞ3 k 2 ω2 s2 (A1)
p
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Iu3
′
We now solve the first integration in equation (A1). Let r = |r r′| and ^r ¼ rr
r ; Iu1 can be rewritten as
∫ k
1 1 ⌢
where θ⌢ denotes the angel between k and ^r . Equation (A2) can be solved in a spherical coordinates (r; ⌢
θ ; ϕ):
∞ π 2π
∫ ∫ ∫ k
1 1 ⌢
Iu1 ¼ eikr cos θ k 2 sin ⌢ ⌢ ⌢
θ dkd θ dϕ
ð2πÞ 3
00 0
2
ω ss
2 2
∞
k2 4π sinðkr Þ
∫
1
¼ dk
ð2πÞ k 3
0
2
ω ss
2 2 kr
∞
k sinðkr Þ
∫
1
¼ dk
2π2 r 0 k 2 ω2 s2s
1 iωss r
¼ e : (A3)
4πr
The final result in equation (A3) was obtained by using the Cauchy’s residual theorem to solve the integration
in the third step. Note that kk in equation (A1) actually correspond to the spatial derivatives. Therefore,
Iu2 can be rewritten as
iωss eiωss r eiωss r ω2 s2s eiωss r
Iu2 ¼ ∇∇Iu1 ¼ 2
ðI 3^r^r Þ þ 3 ðI 3^r^r Þ þ ^r^r : (A4)
r r r
The third integration in equation (A1) can be achieved by replacing ss by sp in equation (A4):
iωsp eiωsp r eiωsp r ω2 s2p eiωsp r
Iu3 ¼ ðI 3^r ^
r Þ þ ðI 3^r ^
r Þ þ ^r^r : (A5)
r2 r3 r
With Iu1, Iu2, and Iu3 being determined, we get the displacement in the frequency-space domain:
uðrÞ ¼ GFu ðrj^r ÞF0
n 1 eiωss r 1 eiωsp r
¼ ðI ^r^r Þ þ ^r^r
G 4πr H 4πr
" iωss r ! #
1 i 1 e 1 i 1 eiωsp r o
þ 2 2 2 2 2 2 ðI 3^r^r Þ F0 ; (A6)
G ωss r ω ss r 4πr H ωsp r ω sp r 4πr
where GFu ðrj^r Þ corresponds to the terms inside the brace and represents the Green’s function of the displacement.
∫
1
e
EðrÞ ¼ EðkÞeikr dk
ð2πÞ3
nh
∫
1 1 1 ′
¼ B0 eikr eikr dkI
ð2πÞ3 G k 2 ω2 s2em k 2 ω2 s2S
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Ie1
∫
1 1 1 ′
B0 2 2 kkeikr eikr dk
ð2πÞ 3
Gs 2
s ω 2 k ω 2 s 2
em k ω 2 s 2
s
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ffl}
Ie2
∫
1 1 1 ′
þ B0 kkeikr eikr dk
ð2πÞ3 Hs2p ω2 k 2 ω2 s2em k 2 ω2 s2p
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Ie3
i o
∫
1 1 1 1 ikr ikr′
3 ω 2 s2 G
kke e dk B0 F0 ω2 μσ0 : (A7)
ð2πÞ em k ω sem k ω ss
2 2 2 2 2 2
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ffl{zfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflfflffl}
Ie4
One can solve the four integrals in equation (A7) in the same way with the derivations of Iu1 and Iu2 and can
easily get that
" #
1 eiωss r 1 eiωsem r
Ie1 ¼ 2 2 þ 2 2 I; (A8)
G ω ss ω2 s2em 4πr G ω sem ω2 s2s 4πr
iωsem r
s2em 1 i 1 e 1 eiωsem r
Ie2 ¼ ð I 3 ^
r ^
r Þ ^
r ^
r
ρ ω2 s2em ω2 s2s ωsem r 2 ω2 s2em r 3 4π r 4π
iωss r
1 1 i 1 e 1 eiωss r
ðI 3^r ^
r Þ ^
r ^
r ; (A9)
G ω2 s2s ω2 s2em ωss r 2 ω2 s2s r 3 4π r 4π
iωsem r
s2 1 i 1 e 1 eiωsem r
Ie3 ¼ em 2 2 ð I 3^r ^
r Þ ^
r ^
r
ρ ω sem ω2 s2p ωsem r 2 ω2 s2em r 3 4π r 4π
" ! #
1 1 i 1 eiωsp r 1eiωsp r
ðI 3^r^r Þ ^r^r ; (A10)
H ω2 s2p ω2 s2em ωsp r 2 ω2 s2p r 3 4π r 4π
iωsem r
1 1 i 1 e 1eiωsem r
Ie4 ¼ ð I 3 ^
r ^
r Þ ^
r ^
r
G ω2 s2em ω2 s2s ωsem r ω2 s2em r 3 4π
2 r 4π
iωss r
s2s 1 1 i 1 e 1eiωss r
ðI 3^
r ^r Þ ^
r ^
r : (A11)
s2em G ω2 s2s ω2 s2em ωss r 2 ω2 s2s r 3 4π r 4π
Substituting Ie1, Ie2, Ie3, and Ie4 into equation (A7), we finally obtain the electric field
where B^ 0 ¼ B0 =B0 and B0 = |B0| are the direction vector and amplitude of the ambient Earth’s magnetic field.
Aem1, Aem2, As1, As2, and Ap are the amplitude constants and expressed as follows:
1
Aem1 ¼ ðμσ0 B0 Þ 2 ; (A13)
G sem s2s
!
1 s2em 1 1
Aem2 ¼ ðμσ0 B0 Þ ; (A14)
G s2s s2em s2s s2em s2p
s2s 1 1
As1 ¼ ðμσ0 B0 Þ ; (A15)
s2em G s2s s2em
1
As2 ¼ ðμσ0 B0 Þ 2 ; (A16)
G ss s2em
1 1
Ap ¼ ðμσ 0 B0 Þ : (A17)
H s2p s2em
In equation (A12), GFE ðrj^r Þ is the Green’s function of the electric field.
μ is the magnetic permeability of the porous medium; ρ = (1 ϕ)ρs + ϕρf is the bulk density; ρs is the solid
grain density; ρf is the pore fluid density; ϕ is the porosity; η is the fluid viscosity; ε = ε0[(εr εs)ϕ/α∞ + εs] is the
dielectric permittivity, where εf and εs are the relative permittivities of the solid and fluid phases, and ε0 is the
vacuum permittivity; and σ0, κ0, and L0 are the bulk conductivity, the permeability, and the electrokinetic
coupling coefficient, respectively. These three variables are actually frequency dependent. However, they
vary so little with frequency in the seismic wave frequency band (less than several hundred hertz) that they
are chosen as static values in this study. The expressions of σ0 and L0 are given in sections B6 and B7,
respectively. F and f are the average force densities exerted on the bulk material and fluid phase, respectively.
H, C, and M are the elastic moduli which are expressed as
H ¼ K b þ 4G=3 þ α2 M; (B7)
C ¼ αM; (B8)
M ¼ K f K s =½ϕK s þ ðα ϕ ÞK f ; (B9)
where
α ¼ 1 K b =K s : (B10)
Ks and Kf are the bulk moduli of the solid and fluid phases, respectively; Kb and G are the bulk and shear
moduli of the framework, respectively.
According to the plane-wave solution given by Pride and Haartsen [1996], there are four body waves involved
in Pride’s equations, namely, the fast P wave (Pf), the slow P wave (Ps), the S wave (S), and the EM wave. The
fast P wave is actually the P wave in elastodynamics. The slownesses of the Pf and Ps waves are expressed as
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
4eρρ ρt
2s2pf ;ps ¼ γ∓ γ þ e
ρ L 2
e
ε ; (B11)
HM C 2 ρ
where the “” corresponds to the Pf wave slowness spf while the “+” corresponds to the Ps wave sps. γ and ρt
are expressed as
ρM þ e
ρH 1 þ e ρL2 =eε 2ρf C
γ¼ ; (B12)
HM C 2
ρt ¼ ρ ρ2f =e
ρ: (B13)
The slownesses of the S and EM waves are
( 2 )1=2
ρt eρL2 ρt e
ρL2 ρ2f L2
2ss;em ¼ þ μeε 1 þ
2
± μeε 1 þ 4μ ; (B14)
G eε G eε G
where the “+” in front of radical corresponds to the S wave while the “” corresponds to the EM wave. The
complex amplitudes in the expressions of the seismoelectromagnetic wavefields in equations (48) and (49)
have been derived by Pride and Haartsen [1996]. They are
2
M spf e
ρ 1þe ρL2 =eε M
LFu;spf ¼ ; (B15)
HM C 2 s2 s2 pf ps
M s2ps e
ρ 1þe ρL2 =eε M
LFu;sps ¼ ; (B16)
HM C 2 s2ps s2pf
s2 μeε 1 þ e ρL2 =eε
T Fu;ss ¼ s 2 ; (B17)
G ss s2em
s2em μeε 1 þ e ρL2 =eε
T u;sem ¼
F
; (B18)
G s2em s2s
2
e
ρL M s ρf =C
LFE;spf ¼ iωLCu;spf ¼ iω pf ; (B19)
eε HM C 2
s2pf s2ps
2
e
ρL M s ρf =C
LFE;sps ¼ iωLCu;sps ¼ iω ps ; (B20)
eε HM C 2 s2 s2
ps pf
iωμρ L
T FE;ss ¼ iωT Cu;ss ¼ 2 f 2 ; (B21)
G ss sem
iωμρ L
T FE;sem ¼ iωT Cu;sem ¼ 2 f 2 : (B22)
G sem ss
Equation (B24) is valid in the temperature range from 273 K to 373 K. With temperature being 298 K the relative
permittivity calculated from equation (B24) varies from 78.24 at Cf = 10 5 mol/L to 36.1 at Cf = 5 mol/L.
In equation (B25) Tc is also the Celsius temperature. C m f is the molality of the pore fluid solution and can be
calculated by C mf ¼ C f =ðρf AC f =1000Þ, where ρf is the density of the fluid and A is the atomic mass of the
salt in g/mol (in the present study we choose A = 58.44 g/mol for NaCl). With a constant temperature Tc = 25∘C,
the viscosity varies from 1.9 Pa s to 3 Pa s when the salinity changes from 10 5 mol/L to 5 mol/L.
ΔV εr ε0 ζ
Cs ¼ ¼ ; (B26)
ΔP ηðσf þ 2Σs =ΛÞ
where Cs is the ratio of the measured streaming potential ΔV to the applied fluid pressure difference ΔP, σf is
the pore fluid conductivity, Σs is the specific surface conductance, and Λ is a length-scale characteristic of the
pore microstructure. 2Σs/Λ represents the electrical conductivity from surface conduction.
Figure B1. (a) Modeled zeta potential as a function of the pore fluid salinity for three pH values with an offset ζ 0 = 0.035 V.
The scattered solid squares represent the experiment data obtained from sandstones by Jaafar et al. [2009]. (b) Modeled
bulk conductivity σ0 of the porous medium with (solid line) and without (dashed line) surface conductance. (c) Variation of
the coupling coefficient L0 with the pore fluid salinity.
Theoretically, calculating the zeta potential is also available. Revil et al. [1999] suggested one model to
calculate the zeta potential [Revil and Glover, 1997, 1998]:
χ
ζ ≈ φd exp ζ ; (B27)
χd
where φd is the Stern potential, χ ζ is the distance from the shear plane to the Stern plane, and χ d is the Debye
Screen length. The Stern potential is given as
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi !
2k b T 8103 εr ε0 k b TN 10pH þ K Me C f C f þ C a þ C b þ 10pH þ 10pHpK w
φd ¼ ln p ffiffiffi : (B28)
3e 2eΓ0s K ðÞ If
Here kb is the Boltzmann’s constant, T is the absolute temperature, e is the charge on an electron, N is the
Avogadro’s constant, KMe is the binding constant for cation adsorption on quartz, Γ0s is the surface site density,
K() is the disassociation constant for dehydrogenization of silanol surface sites, Ca is the acid concentration,
and Cb is the base concentration. pKw = log(Kw), where Kw is the disassociation constant of water. If is the
ionic strength. In the present study, we assume that pH = 6 and 10 5 mol/L ≤ Cf ≤ 5 mol/L. Under this
condition, the contributions to the ionic strength from the acid and base are negligible compared with the
dissolved salt (NaCl), so that we can have If ≈ Cf [Revil et al., 1999; Glover et al., 2012]. All the symbols in
equation (B28) are described and listed in Table B1.
The Debye screening length is expressed as
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
ε0 εr k b T
χd ¼ : (B29)
2000Ne2 If
The distance from the shear plane to the Stern layer is chosen as χ ζ = 2.4 × 10 10 m, as used by Revil
et al. [1999].
Table B1. Parameters Used for Calculating the Zeta Potential and the Surface Conductance
Parameter Symbol Value or Range (Unit) Source
10
Distance of the shear plane from the Stern plane χζ 2.4 × 10 (m) Revil et al. [1999]
Debye Screen length χd 55 ~ 51.6 (mV) From equation ((A5))
Temperature T 298.15 (K)
23
Boltzmann’s constant kb 1.38 × 10 (J/K)
19
Charge on an electron e 1.602 × 10 (C)
23 1
Avogadro’s constant N 6.022 × 10 (mol )
12
Dielectric permittivity in vacuum ε0 8.854 × 10 (F/m)
pH pH 6 Glover et al. [2012]
7.5
Binding constant for cation (sodium) adsorption on quartz KMe 10 Glover et al. [2012]
8.5
Disassociation constant for dehydrogenization of silanol surface sites K() 10 Glover et al. [2012]
10 -2
Surface site density Γ0s 10 (m ) Glover et al. [2012]
5
Salinity of the pore fluid Cf 10 ~ 5 (mol/L)
Ionic strength If If ≈ Cf
15
Disassociation constant of water Kw 9.22 × 10 Glover et al. [2012]
Acid concentration Ca 0
Base concentration Cb 0
8 2 -1 -1
Ionic mobility of sodium ions βNaþ 5.20 × 10 (m s V ) Crow [1988]
7 2 -1 -1
Ionic mobility of Hydrogen ions β Hþ 3.63 × 10 (m s V ) Crow [1988]
8 2 -1 -1
Ionic mobility of chloride ions βCl 7.90 × 10 (m s V ) Crow [1988]
7 2 -1 -1
Ionic mobility of hydroxyl ions βOH- 2.05 × 10 (m s V ) Crow [1988]
9 2 -1 -1
Ionic surface mobility βs 5 × 10 (m s V ) Revil et al. [1998]
Mean grain diameter d 130 (μm) Glover et al. [2012]
It should be noted that zeta potential ζ calculated from equation (B27) has a negative value at low salinities. It
increases (become less negative) with the increase in the salinity and reaches a positive value at a high
salinity [Glover et al., 2012]. Using the parameters show in Table B1, we find that if Cf > 0.6 mol/L, ζ becomes
positive. However, positive values of ζ have not been observed in actual experiments. Experiment data
[Jaafar et al., 2009; Vinogradov et al., 2010] show that when the salinity increases ζ becomes either constant or
slightly more negative after it reaches its maximum. Glover et al. [2012] introduced a constant zeta potential
offset ζ 0 to equation (B27) and modified the zeta potential as
χ
ζ ≈ ζ 0 þ φd exp ζ : (B30)
χd
Although such an additional constant has not been supported theoretically, it can improve the fit of model to the
experiment data. Figure B1a shows the modeled zeta potential versus salinity and pH with an offset ζ 0 = 0.035 V.
The parameters used for the calculation are listed in Table B1. The scattered solid squares denote the experiment
data obtained from sandstones by Jaafar et al. [2009]. We can see that the theoretical zeta potential curve
with pH = 6 (dashed line) fits the data very well. Therefore, in this study we choose the dashed line to relate the
zeta potential to the salinity, which gives ζ = 0.0899 V at Cf = 10 5 mol/L and ζ = 0.0311 V at Cf = 5 mol/L.
Johnson et al. [1987] and Revil and Cathles [1999]. In this study we choose the relationship given by Revil and
Cathles [1999], that is,
d
Λ¼ ; (B33)
3ðF 1Þ
where d is the mean grain diameter. The surface conductance Σs is given by Revil et al. [1999]
Σs ¼ ΣEDL
s þ ΣProt
s þ ΣStern
s : (B34)
In equation (B34) ΣEDL
s is the contribution from the diffuse layer and is given by Revil and Glover [1998] as
rffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffih
2000εr ε0 k b TN
ΣEDL
s ¼ pH
BNaþ C f þ BHþ 10pH Θ1=3 1
C f þ 10
i
þ BCl C f þ BOH- 10pHpK w Θ1=3 1 ; (B35)
where,
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
ffi 10pH þ K Me C f
Θ¼ 8000εr ε0 k b TN C a þ C b þ C f þ 10pH þ 10pHpK w ; (B36)
2eΓ0s K ðÞ
and Bi = βi + 2εrε0kbT/(ηeZi) is the equivalent ionic mobilities for ion “i.” βi is the ionic mobility of ions “i”
(see Table B1) and Zi is its valence.
ΣProt
s is the proton contribution to the surface conductance, and here we choose the value given by Watillon
and De Backer [1970], that is, ΣProt
s ¼ 2:4109 S.
ΣStern
s is the conductance from the Stern layer
eβs Γ0s K Me C f
ΣStern
s ¼ pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi 2=3 ; (B37)
pH 810 εr ε0 k b TN
3
10 þ K ðÞ 2eΓ0s K ðÞ
C þ K Me C f
where
C a þ C b þ C f þ 10pH þ 10pHpK w
C ¼ 10pH þ K Me C f pffiffiffi : (B38)
If
In equation (B37), βs is the ionic surface mobility, and in this study, we use the value βs = 5 × 10 9 (m2s- 1V- 1)
given by Revil et al. [1998]. With the parameters given in Table B1, the surface conductance calculated from
equation (B34) varies from Σs = 2.43 × 10 9 S at Cf = 10 5 mol/L to Σs = 13.2 × 10 9 S at Cf = 5 mol/L.
Using equations (B23), (B31), and (B33), we calculated the bulk conductivity of the rock σ0 with F = 17.7 and
d = 130 μm and plotted it in Figure B1b. We can find that the significant contribution from the surface
conductance to the bulk conductivity at low salinities. At Cf = 10 5 mol/L, the bulk conductivity calculated
without the surface conductance (dashed line) is only 0.69 × 10 5 S/m, 1 order of magnitude smaller than
that calculated with the surface conductance (solid line), that is, 11.3 × 10 5 S/m. In this article we use the
solid line in Figure B1b to control the conductivity σ0, which gives σ0 = 11.3 × 10 5 S/m at Cf = 10 5 mol/L
and 1.4 S/m at Cf = 5 mol/L.
α∞ = 3.36, and other the parameters shown in Table B1 to determine εr, η, and ζ , we calculate the
electrokinetic coupling coefficient L0 and plot it in Figure B1c. The coupling coefficient L0 varies in the range
13.9 × 10 10 sC/kg–1.88 × 10 10 sC/kg when the fluid salinity varies between 10 5 mol/L and 5 mol/L.
E ¼ jEjeikr e^ ; (C2)
where k ¼ k k^ ¼ ωsk^ is the wave vector with k^ denoting the direction of the wave propagation and s
denoting the slownesses of the P and S waves. |u| and |E| are amplitudes. u^ and e^ are unit vectors. By
substituting equations (C1) and (C2) into the following equation:
The term u ^ 0 in equation (C7) shows that the direction of Ep is perpendicular to both the directions of
^ B
the displacement u ^ and the geomagnetic field B ^ 0 and also indicates that the amplitude of Ep depends on the
sine of the angle between u ^
^ and B 0. If u ^ 0, Ep becomes zero because u
^ is parallel to B ^ B^ 0 ¼ 0 in this situation. If
^ is perpendicular to B
u ^ 0 , we have u ^ B ^ 0 ¼ 1 and then Ep achieves its maximum amplitude. Here assuming
u ^
^ B 0 ¼ 1 we approximately have the E/u transfer function for the P wave as
μσB0
Ep ≈
s2 eεμ up : (C8)
The S wave produces a material vibration in the direction that is perpendicular to the direction of the
propagation. The electric field produced by the S wave can be written as
μσB0 2
Es ¼ j u s j u^ B^ 0 ss k^ k
^ u ^ ^0 :
B (C9)
s2s eεμ eεμ
Equation (C9) shows that the S wave electric field consists of two terms. If s2s =eεμ≪1, the first term dominates the
2
^ 0. If s =eεμ≫1, Es is determined by the second
^ B
electric field and in this situation Es is along the direction of u s
^ i.e., the direction of wave propagation. Similarly, by assuming u
term and its direction is parallel to k, ^0 ¼ 1
^ B
^ ^
and k^ k ^ B 0 ¼ 1 in equation (C9) we approximately get the E/u transfer function for the S wave
u
2
s μσB0
jEs j≈ max 1; s 2 jus j: (C10)
eεμ ss eεμ
Equation (C14) means that the direction of Hs is parallel to that of the S wave displacement. Approximately,
the H/u transfer function for the S wave is
ss σB0
jHs j≈ 2 jus j: (C15)
ss eεμ
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