| = Godeernattonal Analysig + Tndinite mo: of ferms which are Obeineat clus do de sen yotaton about a siegu Cralurt lend (o-pord) Que. Colles) Grrformexs]/ Go formations. of These Ganfsmations differ In CneEyy ¢ Srability: + To decide this enegy¢ Siebility of Grrbarmees Ie calied © Garpsmationol qnalysis- . s le for tae rortion abou ign bend! tht Enceay requinemant - much jes dan aska@d/moL wohich Is Qvatabe in Surroundigg- ~ TRL fee sotetion happens do relene Tha SiaHC RED Stain of QA Clow ' + Cpolewlt Dovidolly cishibutu its static Shain jnio various Gokerrmoations dhertfrt the Stability yncreoe 2 Rotation happens: ed with CamScanner Scanni ed with CamScanner= Bond Creal T+ iB wre aegu DIP) aM X20 Bonde of dhe Same asm Dinedsal Brey J+ Ig the angle bin any 100 bands of dhe adjecunt agoms HCH pinedsal Ge7lt = 10a" CH an a _ cl) ch = Dut do vodatiow cihedra) agg Chepges Gudinuowly but dhe band argls ahwx remains dnetant: Scanned with CamScannerTh ne mowome there ave wo types of sepulsions — . cio > ne Size & Croat: VarderXall © Nareer- Wot! Repul Dut to tee Si re Go “Texssiona! Repulsion “Taxsiona] Sisal Every type of aepukion jncrenre Potential enegfy LOhich is Golled Strain ed with CamScanner Scanni ed with CamScanner ScanniMoteentar - Representation Sard- Home _wepresevtator | 8 \ Cte CHs CH —Aip- Zp -CHs M H L2 23 : = & H 13 Hl H H H H H H H H Cts CT Noting ig Said then We Select MHL gid WL pnest Hoo Giems for Cra rsieg Saw-horse Chk -CHy-Nhe € rs 4H” +] Scanned with CamScanner Scanned with CamScanner"Neromands Preyections + By dre help of Saro-hoate "@ omc a wae tH rH —h OWS a a Scanned with CamScanner Scanned with CamScannerGoaforrmations jn Stang + CHs “cts Hy ™S ae Ge, H sage Nander Wal) Repulsion > Ecrip- >Ste4: TL dre dihedral oat is Go’ 3 suis Oo > Eclipsed Fore ‘ ” XO -28 O< DA <66 9 _SkeA fommg | B93 Bo psig, mer € Repuleion Eclipged psteggered r ny 9 >be. Tato] Repulsion > Ec pSteg: “Er Fo PSK PSteH: Re A rH H HH ct +l H vie 2 A, & she Fl - H By H ¥ H Pa Ct srpapesed Eclipsee| rl) lipsed: Srebity Sipggered psKen PEc ipsed Dut do dnt tmereve in Sioe of Jeop- YVarder wal) repulsion — Pncweos] Ry POR. TE. Inewending Scanned with CamScanner Scanned with CamScannerCHe-CHp. —CHe-CHle <> : Hg HAH Cs Hg wil + | Al Ser" BOE te Gos H. H 60 Hoy - ‘4 H te 4 Hi ry =, Bs 3 oe 8 Hg 4 He ‘CH ANTE — Ogpnally Eolipsed CaucHe 1 Fwyaabpsed (ar 2a4 Eclipsed For Soke heres. . Sh sigageree) Ut rr tao bulk Qe Seperea! by 180 = Anrtifercy 1aP eT Go = GAUCHE De Hl dhe Bulky ops ave cverlaping wit enc omer — Fuly eclipsed Scanned with CamScanner Scanned with CamScannerCoesn't+ exist: + \landernwal) vepulsion ext in all the form: Repukiony eal Gavene Peel Pulyeclipsed KH ven: Repulsion “ < “ “ _ . Toe| sepulsion Paliy eciiesed > Paetecli: >Gauche 7Anti Porentio.! Enepgy dullyecti 2 Pastecti 7 Gauche Anti Stabjuity Order duly ecii< Pashecli Partially Eclipses! >auche ? Buti ctalility pGeli < Parti Beli < Uauche o19xLG thy: Less Scanned with CamScanner Scanned with CamScanner© Dravd all the Gnfesmations of Cthelene Greate . Che -GHe (Ondi free Ager) bi oH a On goleovs Stott — al ean “at in i State: ct 3 HoH ah ad ae Se fp A Fr i Dominant: Bn gov: State © ‘ oranept apres InSovent water A) Grvfernnations Ove Siabitigesl by lnier-H-bondhe Wit Waite H-bonding Is equal So iths @mmoen g coed n't remain O Criteria of GAbility. So Anti Ptrauche 7 P-ecli rtecli Scanned with CamScanner Scanned with CamScanner®@- n- propy) Choride - es H Oe H' Chg Sn Sele - Si ~ (More free of attraction, Anti> Qavehe Pore Sieble in Solid) ei Sf Chauche >Anti (| Bex moteaed Jets Seperacted) leas Dolaa- gnotocte Supports Ifquiel sdade Ho) Hf mt ae: re ee as an OO Cr CHs » ed with CamScanner Scann ed with CamScanner ScanniQ@ What will happen to the chipotle moment if dre Solid paepyl Chloride ts heater & melted: + @B Dipole moment wil) decrease: H oe" oH ci] Br 7 G rl i H H Cl os Br Chauche Anti Te jg an Experimenta) fact» On drt bovis of oApote moment it is clecidect ed with CamScanner Scanni ed with CamScanner Scanni"2,3 -cimethy] budane > c- tc H C os cd We H chy rl Go5-S 5 th “yCHy H pede 2 e oct SON davon Gn this Special example bregt Change Sone or Resi Cue do repulsion - Stent AU CHE > nti Scanned with CamScanner Scanned with CamScanner© Crp Neg @ Ch —Op l ) bur Nm ‘ (2,8, P ec atom docit Shard ion dipate) \ T } ? | ~& well “i : H WM H Hr, 4 NMG nauche PAH > Parti €c: Pfs ec: Ons Amuene 7Poenii'r #:€c Scanned with CamScanner Scanned with CamScannerO Draws dre Gndtemens # cliscuss Stebitity— A+ 3.3- climethy! pentane ¢ HC y) H 3 ) + + 4 H \ H S 13 i H CHS H f I} 66 Ay 3/35 72,4 , ao ff Hs , SAIRBP 42 ne CMs HE” CH, HE Ch, Scanned with CamScanner Scanned with CamScanner(li) CHa -Coor) Cn-cso® | | « Che — CoH = cidlie Cte-co0?® Baule Svuccinic Acid Syabitity Sable Gauche rAnt > Pastiecl >follyecl) Anti > hauche 7 Pees — SAG] DE EOE ; Cor) aon oni ; H Cyquahe weet oT Scanned with CamScanner Scanned with CamScannerOp gene ve ae Zs -OH,f, ~ Nt, CHy, “CooH, “COOR ex OH. QR In Gauche form into motecsalar— H-bonding will be predent ° So Stabivty order iN God: Siete (hauche >? Anti 7 Past: ecli > fully eclipsedt 2 Derto jon-dipelt interaction) also (nauche form may be-stable chan Anti . pram Tony -Dipate Gtraction a Lo te . thy , Ho] Ml stebiuty Order = OH, F,Cl,Br, “Oru cre: (hauehe Anti > Part eclirfullyecli Scanned with CamScanner Scanned with CamScanner© Preclict Which will have Q greater clipote moment (2 -clichoroethane OF Cthelene Giycote: Both are In Gescous Stade C-Cl & Co bends Qre nearly Same polar So gauche Ig negrly Sane }n both ut gauche Ig) ethelene glyate pill Be More So Heth gly: > HUy2-clicheth: Scanned with CamScanner Scanned with CamScannerZ discuss the Stability Order Gbout CN bend: 2 Gh Qe Groen IEE BA 3 7274 ed with CamScanner Scanni ed with CamScanner¥ o% 109.26 Co! 49.88 Go 19-28 ) " oe f28 0-28’ oy sti 109° There Cypoalkan relewet 118 Crgte Stroln by upped Peocers yo vortouy Orrdorenators. Scanned with CamScanner Scanned with CamScanner0 Cctepsopane is ale planes 4 cen’? undesgo FUpPieg process H al De remains in @ forced eclipsed farey © C] Undegpe & Aippreg procers # Qmes gut of . occed ecb psec fore) YA 208 39 Puckere] Otaipe Doe Jo -Fuipphe4 avgye Eis0iny aN Caney out oF TAL Cclipsed Brcll TOs vanes dna stebilty: en SProte + Hi) vig Qrxe CQniduree +o be Planer Fer poactan! Pudpese OO, owe CO PKI > pL LA ed with CamScanner Scanni ed with CamScanner ScanniGasiigintiotsth Analysis of £ sreicheane + “metteral Concert CJ Plog ple repulelen An YD YVI- oF = DJ maltose — eiotleet = rah ae mol , Ss + Thy is knorin aa ving Pippiog- + Stabitity Orvler- Chair Sp Tsist boat Dy boot > pale chair Lee! Eaiiose! Cettpggereal) §— Gkeny (Eclipse) (og i) otel Noof Gefemecs 19 reer Tyree ed with CamScanner Scanni ed with CamScanner ScanniStability Order= Chair P Twist boat > Boat PHalf Choir Chair forey- OF Every Grbon there ill be dio types of bends - 9 @ Axial Bane) @ Enuictoriol Bord 1 Flipping FOP dhe verex ig up + Axial ts UP: " " Down + Arial is Daan ¥ 7 a + Afler flippleg aw axial bewmes equiteria! 3 Vice- Versa: Ines Gre keq 4 Bee Both are Sualty stable Scanned with CamScanner Scanned with CamScannert * wus upper bends Ore above te pont Cyr Ud: dower bonds Qre belan tht plant: 4 Bond pghich 1g present above bere flippirg will be Qbove (upper) acter FlippI Eg 0160 ° * Axial: Equitorial pasitians Chapéel (Orientation Chappe), Gofeguaation to)l] Not Change therefore They Qre Qnfermers, . ed with CamScanner Scanni ed with CamScannerRepulsion These. exist 1,.9-Diax lod repulsion 1 the chair fore - Thats why Chair ie de MOst Stable Gotormer OF Cycighexane : ed with CamScanner Scanni ed with CamScannerDut 40 4,3- Diario) repulsion any bulky Group Qlmays fries do sermain at equitorial position: LT H te 8 roy PP PRO? H + em HF VA (er Os tre 1,3 -Diarial repulsion jnewense Prt Keg willl increowe: Scanned with CamScanner Scanned with CamScannero-e Lo XG [rf < c-¢-C —_ = Lye Duie Bore c 1,.3-Diaxlo] sepulsion }Nerenves « A rm zy LT Onyen reduce dissencach g Ke HP Rooraup 7 = [~T* Ke >ks Scanned with CamScanner Scanned with CamScannerQt Gmpave the Hoe = CeC-€ @ ag oO Ee 5S OO yOg In Ast 2rd Ka7Kk) So vase of eflippieg 4 >2 # So due do move flipping st Is more Stable than 2nd}. ¢ So HOC of 2nd Is more than Ast Scanned with CamScanner Scanned with CamScanner= ered _foro4 : oh ari — 2 fe sph nario position: equrienies Scanned with CamScanner Scanned with CamScanner; ‘i | \| a ee Scanned with CamScanner Scanned with CamScannerTey Boer be ic lens Stable bez Exlipece forey (1) B+ is Eolipsedd forey (B Flag pate Repyiion: Cyclonen? Ore, = SPINA ~ ot tieg Pate repulsion Qn be Gnvertea! inde attraction then Boaterey vail! be Core oe 1 Pesitlon 17 boos -ferey .Braeilly Grder ~ ee ore Bea | leapt Stable > G- Ecliper! GS fg pale Qe what ig dhe mest Sb © eepuisiaw Cortaner of $9 Gycloruxane —y-clio. i £ Bendis no fo Olivo, a Boat ren ig chore orale —_— ed with CamScanner Scanni ed with CamScanner Scannivn off Same tiep = SK- FT 9 C; wae -te- AR 9 reat Sw. AR eTTrans Cenem) stede ment - Apiol “on ed with CamScanner ed with CamScanner Scanni ScanniDraw tne mest crab Gndermer of - a oF ; LL Hi Mo Hs 3 @ Men. CMe ; gy oF Ch 1) Fieping | Flipping cy is Y FZ ee 4 Scanned with CamScanner Scanned with CamScanner