Sec: ISR.IIT_*CO SC(MODEL-B) WAT-34 Date: 16.04.

23
Time: 3HRS 2018_P1 Max. Marks: 180
KEY SHEET
PHYSICS
1 CD 2 C 3 BC 4 ABD 5 ABC
6 ABC 7 2.5 8 4800 9 336 10 4
11 3 12 700 13 10 14 1 15 A
16 A 17 B 18 C

CHEMISTRY
19 AD 20 ACD 21 ABD 22 A 23 ABD

24 ABD 25 7.95 26 0.05 27 63.5 28 19.3

29 16 30 127 31 0.77 32 19 33 B

34 D 35 B 36 C

MATHEMATICS
37 AC 38 ABCD 39 ABCD 40 BC 41 BCD
2.82 or 5.19 to
42 AC 43 44 50 45 4 46
2.83 5.20
47 0.5 48 13 49 4 50 1 51 D

52 C 53 A 54 B
Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
SOLUTIONS
PHYSICS
31 5
1. l1  l2  2
2 4
2 4l
1  1 2  2
3 5
3v 5v l 6
f    1 
2l1 4l2 l2 5
3 x
2. p  p0 cos sin 300 t
2
At close end Pr  Antinode
At open end Pr  Node
(a) At X=0
p  p0 cos 00  P0 Antinode
At x=0.5 m
p  p0 cos 3   P0 Antinode
(c) At x= 0 antinode -close end.
(D) x=0 antinode-close end.
2
x  Antinode-close end.
3
3.

4. For closed pipe.

v
f  n   n  1,3,5 ……..
 4l 
v 320
For n  1, f1    80 Hz
4l 4 1

JR.IIT_*CO SC Page No: 2

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
For n  3, f3  3 f1  240 Hz
For n  5, f5  5 f1  400 Hz
 correct options are  A ,  B  &  D  .
5. Standing waves can be produced only when two similar type of waves (same frequency and speed
but amplitude may be different) travel in opposite directions.
6.

7.

 RT
8. V0 
M0
As per question
 RT  R  300

M0 MH
M 32
 T  0  300   300  4800 K
MH 2
9. When reservoir is lowered by x, let the level of water fall by y
y 7y 6x
x  y x   y
6 6 7
For x  21 cm, y1  18 cm
For x  21  49  70 cm; y2  60 cm

  e  18................  i 
4
3
 e  60................  ii 
4
 ii    i  gives

 42    84 m
2
V   f  0.84  400  336 ms 1
10. Speed of wave is property of the medium. Hence, both waves have same speed.
Since frequency of second wave is double that of the first, therefore, its wavelength will be half that
of the first.
1 2

2 1
 
11. y1  a sin  kx  t   k  
 2
 
y2  a sin  kx  t  
 3
   
y  y1  y2  a sin  kx  t   sin  kx  t   
  3 

JR.IIT_*CO SC Page No: 3

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
5
12. Velocity of the man Vm  36   10 m / s
16
Echo time  t  4 sec

 Vm  Vs 
2d V  Vs  t  700m
d  m
t 2

13.
7
14. L
4
4l 2 2 7
  ,k   
7  4L / 7 2L
x  0 is a node
 7   L 
 Ax  sin kx  a sin     a
 2L   7 
5. f  2000 Hz and   2  8  16 cm
 Speed of sound in air in the pipe is
v  f   2000  0.16  320 ms 1
320 4 80
When f '  1600 Hz;  '   m  cm
1200 15 3
 '
Length of the tube is L   2n  1   2  n  1  1
4 4
80
  2n  1 .16   2n  3 . n3
3
 16
 L   2n  1   6  1   20 cm
4 4
v 320
16. Fundamental frequency f 0    400 Hz
4 L 4  0.2
 Resonant frequencies are 400 Hz, 1200 Hz, 2800Hz……
 Answer is2800 Hz
17. Amplitude  A sin Kx;

2 x 2 l 
Kx     .
 2l 3 3

A 3

2
18. K.E is maximum after covering a phase of
  3 3T 3 2 3
   time of  
4 2 4 4 8 w 4w

JR.IIT_*CO SC Page No: 4

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
CHEMISTRY
o 
19. Metals with E value less than 0.96V will be able to reduce NO3 in aqueous solution. Therefore,

  
metals V E  1.19V , Fe E  0.04V , Hg E  0.86V
o o
  o
 will all reduce NO

3
but

Au  E o  1.40V  cannot reduce NO3 in aqueous solution.

25. We know,
it
lost during electrolysis 
2
Equivalent of Cu
96500
2  103  16  60
  1.989  10 5
96500
1.989  10 5

lost during electrolysis 

2
or mole of Cu
2
This value is 50% of the initial concentration of solution.
2  1.989  105
Thus, initial mole of CuSO4   1.989  105
2
1.989  10 5  1000
Thus, initial concentration of CuSO4 
250
CuSO4   7.95  105 M
26. As given
ZnSO4 CuSO4
Cell I: Zn Cu
C1 C2

0.06 C
E 'cell  E 0 cell  log 2
2 C1
ZnSO4 CuSO4
Cell II: Zn Cu
C1 C2
0.06 C
E 'cell  E 0 cell  log 2
2 C1
If Ecell  E 'cell then Ecell  E 'cell  0.03V and C2  0.5M
By Eq. (1) and (2) ,
0.06 C
E 0 cell  E 'cell  log 2
2 C '2
0.06 0.5
0.03  log  C '2  0.05M
2 C '2
27. Cu 2  2e  Cu
2F charge deposit 1 mole of Cu i.e., 2F of electricity deposit 63.5g mass of Cu at the cathode.
28. Q  it or Q  10  103  t ………(i)
2 H 2O  2e  H 2  2OH 
JR.IIT_*CO SC Page No: 5
Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
0.01 mole of H2 is liberated by 0.02 Faraday of charge
i.e., Q  0.02  96500 C ……… (ii)
From eq (i) and (ii),
10  103  t  0.02  96500
0.02  96500
t
 19.3  104 sec.
10  10 3

Given, Sn  aq   2e  Sn  s  ; ESn / Sn  0.140V

2  o
29. 2

G1o   nFESno 2
/ Sn

 2   0.14  F  0.28 F ……….(i)

Sn 4  aq   4e   Sn  s  ; ESno 4
/ sn
 0.010V
G2o   nFESno 4
/ Sn
 4  0.01F  0.04 F ……….(ii)

Sn 4  aq   2e   Sn 2  aq  ;  G 3o ……….(iii)
To get Eqs.(iii), subtract Eq.(i) from (ii)
So, we get
Sn 4  4e   Sn; G2o  0.04 F
Sn  Sn 2  2e  ; G1o  0.28F
_____________________________________
Sn 4  2e   Sn 2 ; G3o  G2o  G1o
 nFESno 4
/ Sn 2 
 0.04 F  0.28 F
2 FESno 4
/ Sn 2 
 0.32 F
0.32 F
ESno 4
/ Sn 2   0.16V
2F
ESno 4
/ Sn 2 
 16  10 2V
30. At anode 2 H 2O  O2  g   4 H   4e 
At cathode 2 H   2e   H 2  g 
it
Number of gram equivalent 
F
i  current passed = 0.10 A
t  time = 2 hours  2  60  60 seconds
F  Faraday constant  96500
0.10  2  60  60
 Number of gram equivalent   0.00746
96500
Number of gram equivalent = number of moles  n  factor
Number of gram equivalent
 Number of moles =
n  factor
Volume of 1 mole of ideal gas  22.7L

JR.IIT_*CO SC Page No: 6

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
Volume of O2  number of moles of O2  22.7
0.00746
  22.7  0.0423 L
4
Volume of H 2  number of moles of H 2  22.7 L
0.00746
 22.7  0.0846 L
2
Total volume   0.0423  0.0846  L  0.1269 L
 127 mL or 127cm3
31. Latimer diagram
7 4 2 0
MnO 
MnO2 


Mn2 E 
1.03V
E1o 1.68V
Mn 1.21V
o o
E2 3
4 n13
n 2 n2 2 3

E4o ? n4 7
So, n4 E4o  n1E1o  n2 E2o  n3 E3o
7 E4o  3  1.68  2  1.21  2   1.03
5.04  2.42  2.06 5.4
 E4o    0.77V
7 7
o
EMnO 
/ Mn  s 
 0.77V
4

1
32. 100 W lamp will produce 100 Js
10
 100 J  110  C  C  Coulombs
11
Therefore, total Coulomb passed in 10 h
10

 10  60  60  32727.27 C
11
2
Number of gram equivalent of Cd deposited
32727.27
  0.34
96500
112.4
Weight of Cd deposited  0.34  g  19.1g
2
33. For reaction
E o  EOo . P . glucose   ERo. P . Ag  / Ag
E o  0.05  0.8  0.75V
Now nFE o  2.303 RT log10 K
nFE 0 nE 0 2  0.75
log10 K     25.33
2.303RT 2.303RT / F 0.0592

JR.IIT_*CO SC Page No: 7

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s

34. On increasing concentration of NH 3 , the concentration of H ion decreases, thus using nernt
0.0592 2
equation, Ered  Ered  log10  H  
0

n
0
0.0592
n
 2log10 1011 
 pH  11,  H    10 11 M 
 0.0592  11  0.6512V  0.65V
0
Ered increased by a factor of 0.65 from Ered .
35. It is an electrolyte concentration cell in which the electrode with concentrated electrolyte solution
acts as cathode and second one as anode. For a concentration cell, applying Nernst’s equation,
0.059  M aqn.  cathode
Ecell  log10
n  M aqn.  anode


0.059
Ecell  log10
1.0
n 5  102
 0.076 or 76 mV
36. In this case

Ecell 
0.059
log10
1.0
1 2.5  103
 0.152V or 140 mV

MATHS
37.

38.

39.

40.

41.

JR.IIT_*CO SC Page No: 8

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
42.

43.

44.

45.

46.

47.

48.

JR.IIT_*CO SC Page No: 9

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s
49.

50.

51.& 52.

53.

54.

JR.IIT_*CO SC Page No: 10

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s

JR.IIT_*CO SC Page No: 11

Narayana IIT Academy 16-04-23_ISR.IIT_*COSC(MODEL-B)_WAT-34_Key&Sol’s

JR.IIT_*CO SC Page No: 12