Quecess Eo eee Sea AON Poy WEEKENDITEST) Sri Chaitanya IIT Academy, India AAP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELI RANCHI ‘right Choieg for the Real tlspirant ICON CENTRAL OFFICE, MADHAPUR-HYD ‘Sec: Jr.Super60- 2016 2 Date: 19-08-17 Time: 07:30 AM to 10:30 AM WAT-15 Max. Marks: 186 OCI) Name of the Student: ALT. APER-II IMPORTANT INSTRUCTIONS: 1) This booklet is your Question Paper. 2) Use the Optical Response Sheet (ORS) provided separately for anew 3) Blank spaces are provided within this booklet for rough work. 4) Write your name, roll number and sign in the space provided on the back cover of this booklet. 5) _ You are allowed to take away the Question Paper at the end of the examination. ‘OPTICAL RESPONSE SHEET: 6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression at the corresponding place on the Candidate's sheet. 7) The ORS will be collected by the invigilator at the end of th 8) Do not tamper with or mutilate the ORS. Do not use the ORS fi 9) Write your name, roll number and code of the examination center, and sign with pen in the space provided for this purpose on the ORS. De not write any of these details anywhere else on the ORS. Darken the appropriate bubble under each digit of your rell number. DARKENING THE BUBBLES ON THE ORS 10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS. 11) Darken the bubble COMPLETELY. 12), The correct way of darkening a bubble is as : 13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way. 14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or “un-darken" @ darkened bubble. 19-08-17_Jr.Super60-_WAT-15_SYLLABUS the questions MATHS: SYLLABUS COVERED FROM 14-08-17 TO 18-08-17 (WAT-15) HYSICS: SYLLABUS COVERD FROM 14-08-17 TO 18-08-2017(WAT-15) CHEMISTRY: VSEPR Theory & shapes of simple molecules, VBT and HybiSti Chaitanya IIT Academy ime: 07:30AM to 10:30 AM, 19.08-17_Jr-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P JEE-ADVANCE-2016-P2-Modol IMPORTANT INSTRUCTIONS Max Marks: 186 : F If the extension of the spring is xq at time t, then the displacement of the first block in time tis TrSuper604 space for rough work Page 3Sri Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2) WAT-15_Q.P 3 Ina boat of mass 4M and length ‘L’ on a frictionless water surface. Two men A (mass = M) B(mass = 2M) are standing on the opposite ends. Now A travels a distance L/4 relative to boat towards its centre and B moves a distance 3L/4 relative to boat and meet A. The displacement of the boat on water till A and B meet is, \ SL L 2L Aye B) zei & p) BE x ) zero OF Ne A paraboloid shaped solid object is formed by rotating on parabola y=2x* about y-axis as shown in figure. If the height of the body is ‘h’ then the position of centre of mass from origin. (Assume density to be uniform throughout). ¥) 3 vie h Bt oF pb) TrSuper604 space for rough work Page 4Sti Chaitanya IIT Academy 19.08-17, juper60-1_JEE-ADV._(2016_P2)_WAT-15_Q.P 5 A dise of radius R and mass M is placed on smooth horizontal surface as shown in figure. A light rod of length ¢ is hanged from the centre of disc and a small mass m is attached at the end as shown in figure, Now a velocity Vo is given to mass m, Find the maximum height which mass m can attain. ( Assume rod can rotate < 90°) M pian pIBM G1 m Tg Mim 2g mm 2g 2M Two solid hemispheres of radii R and R/2 with centers © and 0' respectively as shown in figure. The density of bigger hemisphere is p and that of smaller hemisphere is 2p. Taking center of bigger hemisphere is at origin and the distance between centers of two hemispheres 00" is R/10, find co-ordinates of center of mass of the system, TrSuper604 space for rough work Page 5Sti Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P (-R 21R) ) (-R 7k) (REN (2 21 3B) 2) of st) py (=8,78) \sors0 } 30°80 Gots 30°16) SECTION — II (MULTIPLE CORRECT ANSWER TYPE) This section contains 8 multiple choice questions. Each question has 4 options (A), (8), (C) and (D) for its answer, out of which ONE OR MORE than ONE option can be correct. Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases 7. An object comprises of a uniform ring of radius R and a uniform chord AB (not necessarily made of the same material) as shown, Which of the following can not be the center of mass of system x {R R\ (RR) (R R) ats (3) Gea) TrSuper604 space for rough work Page 6Sri Chaitanya IIT Academy 19.08-17, juper60-1_JEE-ADV._(2016_P2)_WAT-15_Q.P 8 Which of the following is/are correct? ‘A) If the center of mass of three particles is at rest and it is known that two of them are moving along different non- collinear lines, then the third particle must also be moving, B) If the center of mass of a system remains at rest, then the net work done by all the forces acting on the system must be zero, C) If the velocity of center of mass of a system remains zero, then the net external force acting on the system must be zero. D) If the speed of center of mass is changing, then there must be some work being done by the intemal forces on the system, Two blocks of masses m and 4m lie on a smooth horizontal surface connected with a spring in its natural length. Mass m is given initial velocity Vo as shown in figure Which of the following is true about subsequent motion? Y — m bese 4m pO =o A) Kinetic energy of mass m is maximum in ground frame and centre of mass (CM) frame simultaneously. B) Value of maximum and minimum kinetic energy is same in CM and ground frame, C) Minimum kinetic energy is zero in CM frame but non-zero in ground frame. A aan parea D) Maximum and minimum kinetic energy of m in ground frame is, respectively, zm and zero. TrSuper604 space for rough work Page 7Sri Chaitanya IIT Academy 19.08-17, juper60-1_JEE-ADV._(2016_P2)_WAT-15_Q.P 10. u Two identical buggies move one after other due to inertia (without friction) with the same velocity vy . A man of mass m rides the rear buggy. Ata certain moment the man jumps into the front buggy with a velocity u relative to his buggy. If mass of each buggy is equal to M and velocity of buggies after jumping of man are vyeay and Vfront . Then A) Ne = 19 B) yu, ©) Vjogs =p $e D) Von = ) Vpn °* remy ) Vial Two person of mass m, and m) are standing at the two ends A and B respectively, of a trolley of mass M as shown. When the person standing at A jumps from the trolley towards left with ua with respect to the trolley, then (Ground it frictionless) my, m2 AoE << L A) the trolley moves towards right B) the trolley rebounds with velocity aa mm, +) C) the trolley rebounds with velocity ar D) the centre of mass of the system consisting of two persons and trolley remains stationary TrSuper604 space for rough work Page &Sri Chaitanya IIT Academy 19.08-17, juper60-1_JEE-ADV._(2016_P2)_WAT-15_Q.P 12. Choose the correct statement(s) regarding center of mass A) If F, =0 center of mass frame is inertial frame B) Centre of mass frame is a zero momentum frame C) Kinetic energy of a system is minimum in centre of mass frame D) None of these Assuming potential energy 'U' at ground level to be zero. sctiiphee Stile $ All objects are made up of same material. Up = Potential energy of solid sphere Ug = Potential energy of solid cube UR = Potential energy of solid cone Ug = Potential energy of solid cylinder A) Us > Up B)Ug>Us — C)Up>Ug D) Us > UR TrSuper604 space for rough work Page 9Sti Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2) WAT-15_Q.P 14. Ablock of mass m is placed at rest on a smooth wedge of mass M placed at rest on a smooth horizontal surface. As the system is released A) The COM of the system remains stationary B) The COM of the system has an acceleration g vertically downward C) Momentum of the system is conserved along the horizontal direction D) Acceleration of COM vertically downward is amB u R) ma0,>0, BY) A>4>0, C)A>>4 ——D)A=4, 23. Which is correct statement As the % S-character of a hybrid orbital decreases 1) The bond angle decreases Il) Size of orbital decreases ID) The bond length increase IV) Size of orbital increase A) LIILIV B) ILIV, Cal D) All are correct 24, Shape of iF, molecule is A) Pentagonal bipyramidal B) Trigonal pyramidal ©) Tetrahedral D) Square planar TrSuper604 space for rough work Page 14Sti Chaitanya IIT Academy 19-08-17_J-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P SECTION = Il (MULTIPLE CORRECT ANSWER TYPE) This section contains 8 multiple choice questions. Each question has 4 options (A), (8), (C) and (D) for its answer, ut of which ONE OR MORE than ONE option can be correc. Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted ar 25. _ In the structure of #7,CSE, which of the following statement is /are correct. A) Two C-H bonds are in the same plane of axial S-F bonds. B) Two C-H bonds are in the same plane of equatorial S-F bonds (C)Total six atoms are in the same plane D) Equitorial $-F bonds are perpendicular to plane of x -bond 26. Identify the correct statement in the following A) Hybridisation of carbon in C,0, is SP B)N(Me), and. (SiMe,), are iso structural C) In trigonal bipyramidal arrangement lone pair of electron are usually occupied at equatorial position D) The shape of 15 is linear. TrSuper604 space for rough work Page 15Sri Chaitanya IIT Academy 19.08-17_Jr-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P 27. Which of the following statement(s) is/are a valid postulate(s) of valence bond theory? A) Overlapping orbitals have unpaired electron B) Greater is the extent of overlapping higher is the bond strength C) Greater is the orbital overlapping higher is the bond length D) Lateral overlapping of atomic orbitals results in formation of = —bond 28. Which of the following statement is (are) correct? A) In CIF, , the axial C!-F bond length is longer than equatorial C!—¥ bond length. B)In SF, F-S-F equatorial bond angle is 120° C)In [1c1,J C1-1—C1 bond angle is 90° D) There are two P"—d" bonds in SO, 29. There is a change in the hybridisation when A) NH, combines with H' B) All,combines with 7 C)NH, forms NH,” D)SiF, forms SiF;* TrSuper604 space for rough work Page 16Sti Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P 30. Which of the following orbital can form 6 -bond (Delta bond). A) de —y orbital B)dz* orbital Cary Orbital D)P orbital 31. In which compound vacant orbitals take part in hybridisation A) ACI, B)CH.Cl COBH, D)H,BO, 32. _Indentify the incorrect statement(s) amongst the following A) molecule having trigonal bipyramidal geometry and sP'd hypridisation, the d- orbital involved in hybridization is dx’ B) In SP’d hybridisation, dx*—y*,dz* sets of d-orbital is involved ©) 1 and. XeF,* have same hybridization D) Co;*and S0,are iso electronic and isostructural. SECTION ~ Il (PARAGRAPH TYPE) This section contains 2 groups of questions. Each group has 2 multiple choice questions based on @ paragraph. Each question has 4 choices A], 8), C) and D) for its answer, out of which ONLY ONE is correct Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases. Paragraph for Questions 33 and 34: The Approximate shape of a molecule can often be predicted by using what is called the valence shell Electron pair repulsion (VSEPR) model. Electrons in bonds and in lone TrSuper604 space for rough work Page 17Sti Chaitanya IIT Academy 19.08-17_Jr-Super60-l_JEE-ADV_(2016_P2)WAT-15_Q.P pairs can be thought of as charge cloud that repel one another and stay as far apart as, possible , thus causing molecules to assume specific shapes. The repulsive interactions of Electron pairs decrease in the order. Lone pair- lone pair > lone pair— bond pair > bond pair — bond pair These repulsion effect result in deviations from idealised shapes and alteration in bond angles in molecule. Among the following molecules i) xe0, ii) xe0F, iii) Xeo,F, iv) xeF, Those having different molecular geometry but same number of lone pairs on xe are, A) (),Gi) and (iii) only B) (),(Gi),Gv) only ©) (ii)(iii) and (iv) only D) (i),(ii),(iii) and iv which of the fallowing represent the isostructural. pair? A) sre and if B) clo,f, and SOF, C) se,” and xe0, D) All of the above TrSuper604 space for rough work Page 18Sri Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P Paragraph for Questions 35 and 36: Different types of bonds are present in the chemical compounds. These bonds have different strengths and bond energies associated with them. These bonds are formed in different environments associated with atoms and the compounds in which they are present which of the following will form only « bond (generally) A) s-s overlapping B) Hybrid orbital overlapping C) s-p overlapping D) All of these Shape of the molecule is decided by A) o bond B)xbond €) both « and bond D) neither « nor x-band TrSuper604 space for rough work Page 19Sri Chaitanya IIT Academy 19.08-17_Jr-Super60-l_JEE-ADV_(2016_P2)_ WAT-15_Q.P MATHEMATICS Max Marks : 62 SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 6 multiple choice questions. Each question has 4 options (A), (8), (C) and (D) for its ONLY ONE option can be correct. 1g scheme: +3 for correct answer, 0 if not attempted and 1 in al other cases. answer, out of wl Mar 37. The number of solutions of sinx = is ANG B)7 D9 38. The number of solutions of 2! +3" +4" A)2 B)I 3 Do 39. If f:R-»R isa function satisfying the property f(x+1)+f(x+3)=2 for xe R, then the period of (x) is A)3 B)2 o4 D)s 40. Let f(x)=2x(2-x);0 (1,3) be a function defined by f(x) 3| (where [. ] denotes the greatest integer function), then which of the following is/are true? “f) D) f is not bijective function AS (3) ©) f'(2)= TrSuper604 space for rough work Page 22Sti Chaitanya IIT Academy 19.08-17_Jr-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P 48. The function (: XY where f(x)=sinx+cosx+2V2 is invertible if 49. For the function f(x) =log,, (31° -4x+5) A) domain is (0,2) B) range is R ©) domain is R D) range is Joe 50. The equation |x—l|+a]=4 ae R has A) 3 distinct real roots for unique value of ‘a’ B) 4 distinct real roots for a< (~0,-4) C)2 distinct real roots for fa) <4 D) no real root for a>4 SECTION ~ Il (PARAGRAPH TYPE) This section contains 2 groups of questions. Each group has 2 multiple choice questions based on @ paragraph. Each question has 4 choices A], 8), C) and D) for its answer, out of which ONLY ONE is correct Marking scheme: rect answer, if not aHempled and -2 in all other cases. Paragraph for Questions 51 and 52: TrSuper604 space for rough work Page 23Sti Chaitanya IIT Academy 19.08-17_J-Super60-l_JEE-ADV_(2016_P2)_WAT-15_Q.P Let f(x) be a real valued continuous function such that £(0)=A:f(e+y)=F(x)f(a-y)+ f(y). (a-x)¥x,y eR then for some real values of ‘a’ 51. f(x) isa A) periodic function B) periodic function with no fundamental period ©) Not a periodic function D) increasing function 52. #(x)= A) Se B) ‘ope D) sinx 2 Paragraph for Questions 53 and 54: Consider the function f : R — (0,«)defined by f(x) =2* +2 53. f(x)is A) One-One Onto B) One-One IntoS C) Many-One Onto D) Many-One Into 54. The number of solutions of f(x)=2x+3 is AO B)I 2 D4 TrSuper604 space for rough work Page 24Sri Chaitanya IIT Academy, India "right Choieg for the Real flspirant ICON CENTRAL OFFICE, MADHAPUR-HYD Sec: JrSuper60-1 WAT-15, Di: 19-08-17 Time: 07:30 AM to 10:30 AM 2016_P2 Max.Marks: 186 KEY SHEET PHYSICS 1] A |2] 4 [3] 4 |4] ¢ Js] D 6] a | 7] scp |s] ac [9] acp fio] Be 11] ABD |[12] aBc [13] aBD |14| cp |is] 3B 16| ¢ a7] bp fis[ c CHEMISTRY 19[ A |20] B [21] c |22] B Jas] a 24] A |[25]| ac [26] acp [27] aBp |[28] acp 29] BD [30] ac [31] ac [32] acp |33| D 34] D (ssi D [se] a MATHS 37] B /38] B |39] Cc |4o] c ]4r 42 B [43] aBc [44] aB [45] BD |46 47|| apc [48] asc [49] cp [50] asco |[51 s2|| c ss] p [se] c03. 04, 05, 06. 07. tanya IT Academy 19-08-17_tr.Super60-1_JEE-Adv_(2016_P2)_WTA-15_Key & So's SOLUTIONS PHYSICS There is no friction between the blocks and «,, =sind Sunewts=Sarcn Beng mVo=(M+m)V y=. Mim From energy conservation emVir +Mgé =mgh + Mge+ Zoemyv* Amyi- 4M" meh 2 2 Wim) J mvMem—m neh 2” Mem) Centre of mass always lies b/w centre of mass of segments and always lies on ‘TrSuper601 Page 2Sri Chaitanya IIT Academy 7_rSuper60-I_JEE-Adv_(2016_P2)_WTA-15. Key & S. 08, 09. 10, 1B axis of symmetiy. Conceptual In both CM and ground frame, Kyux is there, when x is zero in spring, which occurs simultaneously. Keinm =0 (ground frame when energy is shared by spring and 4m and m will reverse direction of motion). (M+m)¥, = MV +m(V +n) A.) Fa: onthe syste (im ~ mM) in horizontal detion is eo. cere of ne of the stem remsie satocry Assia Bay Conserve ese wometue ia hizntl diction a (-u, -v)i= (aay =M)vi-0 mat, Potential energy depends on both mass and centre of gravity. ‘TrSuper601 Page 3itanya IT Academy 19-08-17_Jr.Super60-1_JEE-Adv_(2016_P2)_WTA-15_Key & So's CHEMISTRY 19. Ans: A ICI”, have a Linear structure and lone pair of electrons occupied at equatorial positions 20. Ans: Conceptual 21. Ans:e \ RloF \ oF ° Dh Ne H—Be —i1 Pr h SINGLE BOND 22. Ans: B ete“ ae“ a HO Fr Cla Higher the electronegativity of surrounding atom, lesser is the bond angle between the bonds. 23. Ans: A 24. Ans: A 25. Sol: A&C ‘TrSuper601 Page 4itanya IT Academy 19-08-17_Jr.Super60-I_JEE-Adv_(2016_P2)_WTA-15_Key & So's C-SpP* HYBRIDISATION S-sP'd HYBRIDISATION 26. Sol: A,C.D o=c 0(C,0,) V(Me),: pyramidal, Ni(SiMe,),-Trigonal planar 27. Sol: A,B,D Conceptual 28. Sol: A,C,D P 7 Cth. ai | 1698.4 i \ ur ws , a NN 0 auto VR | tse INF pip F a cl F reson 29. Sol: B,D. Net, NEE = AIH, AIH A) SP* SP’ By 7 SP? SPY ou Nh pst. 5° sP* SP SIF? SP’ 30, Sol: A&C Conceptual ‘TrSuper601 Page 5jtanya IT Academy 19-08-17_Jr.Super60-I_JEE-Adv_(2016_P2)_WTA-15_Key & So's 31 32, 33, 36. 38. Sol: A&C 1. Ei gM Ke Un a7 Ne an pS of Nef ad oa aN Sol: A, In Sp'd hybridization az*orbital is used 1,' have Sp’ hybridisation, xXer," have Sp'd Comphrensinon :1 CO} and SO, are is isostructural but not isoelectronic Ans :D S ZA xe, F HIN Pyramides square pyramides see-saw capped octa hedron Ans: d All pairs having same no of sigmas bonds and lone pair of e° ‘Comphrensinon :IT Ans:d All the orbitals are overlap along the axis Ans:a Only sigma bond decided the shape of molecule, MATHS 10 J gfe Draw the graphs of y=sinx; y= yet i Draw the graphs of y=[ ‘TrSuper601 Page 6Sri Chaitanya IIT Academy 19-08-17_Jr.Super60-I_JEE-Adv_(2016_P2)_WTA-15_Key & So's 39. f(x)=f(x+4) = period =4 40. 2 Since the graph of y= f(x) is symmetrical about the line x = 1 = graph of y= s(/(x)) and y= s(/(x)) are also symmetrical about the Tine x = 1 4 f'(s)=2"-+ar+b is injective if dise <0 a=1> b=1,2,3,4,5 =2 =3 =4 a2. replace x by a s a 2) now replace x by (+ @ =f Put raat /(0)=-1 Multi answer question 4B. (sf ())=S (FO) =2 if S(O) =P) x= (0) IAM A))=- F&F (F@)- 7) ‘TrSuper601 Page 7jtanya IIT Academy 19-08-17_Jr.Super60-I_JEE-Adv_(2016_P2)_WTA-15_Key & So's 45 46, 47. 48. 49. 50. = (x)= FF) S(n+2)-f(n41) [222 =(n+2)|n=1 = (n42)[¢ (n+1)-F(n)] 3 f(n42)=(n43)f(n+1)-(n+2) F(n) P(x)=x+3:0(x)=-x-2 Horizontal line test fails But range of /“'(x) is [1,.0), so ignore Conceptual f (x) =2sin| x- 22 (or) WBcor{ x22 Similarly y= [/2,3v2] 3x? -4x45>0 3 A<031—4x+ (5-107) =0 X is real >A>0 10" ates y2 [logy cy). If a>0 Ifa4 no root ‘TrSuper601 Page &$0-L JEE-Adv_(2016_P2)_WTA-15_Key & So's Passage type questions 51 & 52 hint f(x) => periodic constant function Passage type questions 53 & 54 hint Conceptual ‘TrSuper601 Page 9