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1. The total number of structural isomers possible for an amine with molecular
formula C4H11N is:
a) 4 b) 8 c) 5 d) 7
2. Which of the following compounds is most basic?
a) Aniline b) Cyclohexylamine
c) o-Nitroaniline d) p-Methoxyaniline
6. Hinsberg’s reagent is
a) (COOC2H5)2 b) C6H5SO2Cl
c) C6H5SO2NH2 d) CH3COCH2COOC2H5
7. Consider the basic strength of amines in aqueous solution, which one has smallest pka
value:
a) (CH3)3N b) C6H5NH2
c) (CH3)2NH d) CH3NH2
9 to13 given below consist of an Assertion (A) and the Reason (R).Use the
following key to choose the appropriate answer:
a) If both (A) and (R) are correct and (R) is the correct explanation of (A).
b) If both (A) and (R) are correct and (R) is not the correct explanation of (A).
c) If (A) is correct but (R) is in correct.
d) If (A) is incorrect but (R) is correct.
e) If both (A) and (R) are in correct.
9. (A) In a strongly acidic solutions, aniline becomes more reactive towards
electrophilic substitutions.
(R) The amino group being completely protonated in strongly acidic solutions,
the lone pair ofelectrons on the nitrogen is no longer available for resonance.
10. (A) Hinsberg test is used in the separation of 1o,2o and 3oamines.
(R) Benzene sulphonyl chloride is used as Hinsberg reagent.
11. (A) Amines are more basic than esters and ethers.
(R) Nitrogen is less electronegative than oxygen. It is in the better position to
accommodate thepositive charge on the proton.
12. (A) Aniline is less basic than aliphatic amines.
(R) Electron pair at –NH2 group of Aniline is delocalized due to mesomeric
effect.
13. (A) Benzamide on treatment with NaOH and Br2 gives Aniline.
(R) Hoffman’s Bromamide reaction is a degradation reduction.
14. Give the chemical tests to distinguish between the following pairs of
compounds:
a) Methylamine and Dimethylamine
b) Aniline and N-methylaniline
15. Complete the following reaction equations:
a) C6H5N2Cl + H3PO2 + H2O →
b) C6H5NH2 + Br2(aq) →
16. How are the following conversions carried out:
a. Aniline to P-hydroxyazobenzene
b. Ethanoic acid to methanamine
17. What is the role of HNO3 in the nitrating mixture used for nitration of benzene?
18. Give the possible explanation for each of the following:
a) Why amines are less acidic than alcohols of comparable molecular mass?
b) Why aliphatic amines are stronger bases than aromatic amines?
19. Write the names and structures of the major products in the following reactions:
a. C6H5NH2 + C6H5COCl alkali
b. C6H5N(CH3)2 + HNO2 →
c. 2,4-Dinitroaniline i.HNO2 ,ii Anisole
20. What happens when
a. Aniline is heated with conc. Sulphuric acid at 475K.
b. Aniline is oxidized with potassium dichromate in acidic controlled
conditions.
c. Aniline reacts with carbonyl chloride.
Lnit 12ORGANICCOMPOUND CONIAINING NIIROKGEN
Answers
2b 3c 4 a T5b 6b
9d 10b 11 a 12a 13 a
14. a. Carbylamine test: Methylamine being a primary amine gives this test, But N-
Foul smell
b. Carbylamine test: Aniline being a primary amine give this test, But N-
17. HNO; in the nitrating mixture is used for the nitration of benzene. This is because it
acts as base and provides the electrophile NO: ion for the nitration of benzene.
18 a. Since O is more electronegative than N, O can accommodate the
negative charge
more easily than N. As a result, the amide ion is less stable than alkoxide ion.
Hence are less acidic than alcohols of
comparable molecular mass.
b. The strength of base is determined by its ability to donate a lone pair of
electrons. In case of aromatic amines lone pair of electrons on N is in resonance
with benzene ring. This makes aromatic amines weaker bases.
19 . Benzanilide ot N- phunylhmaomidi
b. p-Nitroso-N,N-dimethyl aniline
C. 4-Methoxy-2',4'dinitroazobenzene
20 a.
CoH NH: p- SOHCH:NH:
b. CoHNH.C:Op-Benzoquinone
c. CotH NH+ COC-CH:NCO
21