Professional Documents
Culture Documents
Lectura 1
Lectura 1
Rotary Kiln
1
Introduction
2
Process Description
The causticising process, which is a part of chemical recovery at the pulp mill,
produces white liquor from green liquor. This process consumes lime, CaO, and
produces lime mud, principally CaCO3, as a by-product. The purpose of calcina-
tion is to convert the mud back into lime for reuse in the causticising. The prime
method used for calcination in the pulp industry is a rotary kiln. Conceptually, the
lime kiln, which is a large cylindrical oven, can be divided into four process zones
according to the temperature profile of the solids material and the flue gas in the
kiln. These four zones are drying of the wet mud, heating of the mud powder up to
the reaction temperature, calcining of calcium carbonate into calcium oxide, and
agglomeration of the formed fine powder into granules. The endothermic calcining
reaction (Eq. 1) starts at about 800 ·C, and the reaction heat required is 1.8 MJlkg
CaC03 decomposed.
CaC03 (s) + heat -> CaO (s) + C02 (g) (1)
At the Wisaforest mill, the lime mud is first washed and then dewatered by
means of two parallel vacuum drum filters. After the filters, the mud at about 75%