HCHEMO ACADEMY DE KIEM TRA DINH Ki THANG 4 GIAI DOAN 1/2023 Mon: HOA HQC VO CO CO BAN Nay this 29/04/2023 ‘Thdi gian kim bai: 180 phat (khdng ké thoi gian giao dé, DETHICHINA THUC 522 86m cd thai gian sean) Dé thi gbm c6 04 cau, in trong 16 trang Cfu héi Tidu dé bai Ting diém Phan trim 1 Cau tgo chat 25 25% 2 | Nhigt & Dong hoa hoe 25 25% 3 | Héa hge phan tich 25 25% 4 Hoa hoc nguyén to 25 25% Ting 100% - Chive cic bgn may man nha!! -*Hiing sé vat li: ‘Toc dg anh sang trong chan khong 10-1 ©=3,0.10'ms! Hang s6 Plank h=6,626.10J.s Dign tich nguyén 6 = 1,602.10C Hang so dign méi e0= 8,854.10? F.m-1 Khéi lugng electron me = 9,109.10" kg Khoi lugng proton mp = 1,673.10 kg Khdi lurong notron my = 1,675.10? kg Hing s6 Avogadro Na = 6.022.10% mol! Hang s6 Boltzmann k= 1.381.107 .K" ‘Hang s6 Faraday F = 96485 C.mol" ci R=8,314 LK'.mol" Hing s6 hi mol = 8,206.10? L.atm.K".mol" on vj khoi lng nguyén tir Lu = 1,6605.107" ke “Ap suat chudn p?= I bar = 105 Pa= 750.062 torr Ap suat khi quyén Pam = 101325 Pa Nhigt dé theo Celcius 0°C=273K Angstrong 1A°= 10m Nano mét Tnm = 10° m Pico mét Tpm= 10? m Electron Volt TeV =1,602.10F Pi m=3,14wpeagnofosemuns Aapes jesuioy> ue>uoury 10-2 Md ihe) ar oer] rey nd ie cs ey es a Od) '!a 4d} 11 | 8H| nv | 34 | so Ey a OT OE Ant BI) i ay | ag | as | sy | ap] ep | uz] n>] IN 69 | 34 w)/D)s | 4\is|w 224! 404 Ansty © — SNawa1z4OmavL2Ia0Rad SOVQL ¥ 1 [12 | Tong Cau 1: Thang diem [| 10 | 15 25 25% - Diem cham - Chuyén dong ciia electron 77 trong indol tuong ty hat trong ging thé tron, gay ra tinh thom, va cic trang thai “chim lugng tir” thu phat ning lrgng dudi dang vi tin higu dign ti N N Indol ~ Gia thiét nang lugng cia ede electron 7 trong hé vong thom indol tinh theo mé hinh hat trong giéng thé trén, nang hireng Es tinh theo bigu thite duéi day: = Trong d6 n la sé lgng tir chinh (n= 0, + 1, + 2, + 3,...5 h la hing sé Planck, h = 6,6261.10°F.s; m, li kh6i rong electron, me = 9,1094.10Hkg, m= 3,1416; 1(m) 8 ban kinh ciia giéng thé tron. 1. Tinh chu vi va ban kinh ehuyén dng ciia ede electron 7. + Gia thiét chu vi chuyén d6ng cia electron 7 bang chu vi giéng thé tron va bang chiéu dai mach lién hop; 46 dai lién két trung binh gitra cacbon va cachon |i 1.4 A® ; d6 dai lién két trung binh gitta cacbon va nito li 1,25 A® Balam:2. Tinh buée séng 2 (nm) ciia photon kich thich 1 electron tir mire HOMO lén mie LUMO. Biét e = 2,9979.10%(im/s). Bailam:© Q1-3 ~ Mét chat rin mau vaing X1 durge hoa tan trong dung dich axit nitric ¢6 de xtie tée nhigt 46 co, thu durge dung dich A vi khi thodit ra cé khdi Iugng phan tir gip 1,586 lan khang khi, Khi thém mot lugng Bari clorua du vao dung dich A, ta thu duge m1 gam ket tia tring X2, lo tich két tia, Dung djch sau phan img trén cho tic dyng veti mot hung due dung dich bac sunfat tgo thanh hai ket tia rn X2 va X3 tach ra khoi dung dich. Dé loc mei dung dich, nho timg gigt dung djch natri hydroxit dén khi dung djch thu duge e6 moi truong gin trung tinh thu duge m2 gam két ta miu ving X4 (77,32% khoi long Ag), + Biét m2 = 2.4m1 3. Xe din cic chat X1-X4, Bai lam:© Q1-4 ‘Ong thie phan tir ca khf trén va viét ede phuong trinh héa hoc xi ra,Q2-1 dong héa hoc - ¥ tT | 12] 13 | Tong Ciu2: ane diim | 3 7 1S 35 25% _—— ‘Diem cham - Tién hanh thi nghiém voi cae chit khi: mgt binh chita dic bigt gm hai bng dén thay tinh duge néi véi nhau boi mét van khda (ban diu van duge khéa). Mot bing c6 thé tich 3 dim?, con mt béng kia c6 thé %& tich 1 dm’. Thi nghigm duge bit du khi ~ Gia sir rang nhigt do khong d6i trong si 1. Bong dén bén trai bom day khi helium véi 4p sudt 0,40 atm, bong bén phai duryc bom day khi neon véi ap suat 0,80 atm. Tinh ap suat tong khi van mé. Bai© Q2-2 2. Trong mot thi nghigm khie, bong bén trai duge bom khi NO, edn bong bén phi bom khi Os, Ap suit cua ca hai bong déu la 100,0 torr. Khi van duge mé, NO sé phin img bat thugn nghich véi O2 tao thinh NOs, sau dé sn phim phan img nay sé& bi dimer héa thufn nghich tg0 thinh khi N2O.. Sau khi can bing dirge thiét lap, ap sudt khi tng trong binh la 70,0 bar. a. Tinh phan mol cita mdi khi 6 trong binh sau khi cic edn bing duge thiét Ip. Bai Lim: b. Tinh hing s6 can bing Kr ciia phan img dimer héa NO» Bai fam:3. Co ché ctia phan ting 2/1, +O, + 2,0 duge dé nghj nhu sau: H, —-» 2H" H’ +0, ++ ‘OH +°0" ‘O° + H, 4+ ‘OH +H" “OH + H)>—+>H,0 + H* H’ + Hip py “OH ++ OF ip phy + Biét: Phan img (5) va (6) la phan (ing vai thanh binh. a. Chi ra cée tiéu phan trung gian cia phan img va céc giai doan cia phiin img, a Q) @) 4) (5) (6) Q2-3 ‘Balam: b, Tin tc 6 tao thanh H: Bai lam:© Q2-4 . Khi ede chat phan img duge My vira dit s8 cd hn hgp nd, Tinh dp suat cia binh phan Gng khi xay ra phan tmg né theo ede hing s6 téc 6 phan img, R va T. Bai lam: 10© Q3-1 Hoa hge phan tich - ¥ i | 12 | Tong Cau3: fang digm | 10] 15 25 25% + Dim cham - Dung dich X chira 2 don acid HA (vii pKai = 6,76) va HB (pK.2 = 6,87) 6 pH = 3,75 1. Chuan d§ 10,0 mL dung dich X can 10,0 mL dung dich NaOH 0,220 (M) dén diém twong duromg a, Tinh ndng d6 ban dau cua mdi acid wong dung dich X. Bai lam: u© Q3-2 b, Tinh pHw tai diém tong duong. Bai lam: = M6t dung dich dém duge thém vio dung dich X dé git pH ciia dung dich bang 10,0 thu duge dung dich Z (coi thé tich ctia dung dich KhOng dé Khi them dung dich dém vao) 2. Tinh d@ tan ciia hydroxide M(OH): trong dung dich Z, biét ring ede anion A’ vi Bed kha ning tno phirc véi M* + Biét: - pKs(M(OH):) = 11,51 -Phite cla M® voi A’ 06 8, =2,1.10°; 05.10" .05.10° ~ Phaite ciia M* vi A 0Q3-3 IE ;O ie© Q4-1 Hoa hoc nguyén t6 : ¥ iT [12 | Tong Cau ds langdigm | 12] 13 25 25% x z Diém cham: 1. Phite (Fe(CN)6}* €6 nang lugng téch ki 394,2 ki/mol va ning lugng ghép electron la 210,3 ki‘mol. ‘Vé gian do nang hgng ctia phite [Fe(CN)sJ* va cho biét phuc la spin cao hay spin b. Hoi vai su kich thich electron tir ty dén ey thi phite [Fe(CN).]* hap thy anh sang ¢6 butte séng 7. bing bao niu Bai lam: 14© Q4-2 2. Khi nghién eu co ct han img thi ‘tir trong phire chat vudng phang ngudi ta han thdy ring téc d6 thay thé phéi tu X boi mét phdi tu Y chiu anh huong cua phéi tir Z (Z nim & vi tr trans so vbi X). Néu Z, cng hogt dng vé anh hurtmg trans thi X edng linh dng va edng 8 bj thé. S) ov PC] os fs JN Ti Ko[PtCh, viet so dé diéu ché phire chat cis va phite chit gans-[Pt(C2H4)(2-ampy)Ch] (trong dé 2-ampy i 2-aminopiridin). Biét thit ty anh hung trans cua cde phdi ti: CoHs > Ci > 2-ampy. Trong phire chat trén, nguyén tir kim logi trung tém Pt lién két vii phdi tt 2- aminopiridin qua nguyén tir nite nio? Giai thich. + Biét: Cau hinh electron ca Pt: [Xe]4f"*5d°6s! 15Q4-3 HET- Thi sinh khong duge sic dung tai ligu; Gition thi Khong gid thich gi thém. 16