MULTIPLE CHOICE QUEST! Choose the correct opti IONS 1. Simon Tra in chemist 7 (2) published (te) his Pe lic Table in 1906 (bo) Mandeleev’s published his Parca Table in 1872 and correctly predcing the properties of Ga, Se and Ge. He (b) correctly predied (7 OF U8) the properties of we Ga, Sc an Poly Satoh ae "so we as (c) based (tt..14) his Periodic Table on the increasing | correct. ‘ a7 order of atomic numbers ss (a) corrected (t/(#) the atomic mass of indium from 100 to 113 2. In the fourth period of Periodic Table there are: (c) Fourth period starts from 4gK and Q-1 (a) 16 elements in total tends up at agKr, There are 18 elements a-z (b) no representative elements (/ttp.s!s) in total inlcuding 10 (3d) elements from 3-3 (c) 18 elements in total including 10 transition 2486 t0 392. (¢) is correct. go elements : 18-5, (d)_ series of elements having ‘patialy filed 32 Ete 4M) 4¢-orbitals =F Transuranic elements (a) have been prepared in the laboratories of the world cannot be called as synthetic (2.1 = **) elements are included (tscft*) in 6th period (b) d-Block elements have (a) three series (i ) of ten elements each (b) four series of ten elements each (c) have partially filled d-orbitals (d)__afé also called inner transition elements 4. (@) Transuranle elements, from g,Np ‘onwards are synthetic, and prepared in the laboratories. Théy are in 7 period and have 5f orbital as partly filled. (2) is conect. (c) (d) _have 4f as partially filled orbitals (c) There are four series of dblock elements ie., 34, 4d, 5d and 6d but 6d has less than 10 elements and have partially fled 6c-orbitals. They are outer transition elements. (c)is correct. GROUP SIMILARITIES AND DISSIMILARITIES Liresembles ('4,=1\%+) Mg in the sense that (a) their nitrides give NH, when treated with water 5. (a) Li and Mg are hard metals, do not react with water and give simple oxides. They give NH, when their nitrides “__(0)_both are soft metals (£3) react with H,0.Periodic Classificati ion of Elements and Periodicity 8 Ws 28 8 es (6) they react with water vi (4) both give peroxides and apenas Carbonates and nitrates of Li and Mg UN + 3H, ‘U(OH) + NH Mg,N + 6H,O—* 3MaIOH2 + 2NHy ws orid? 5 a) is cored. Sree (€) They decompose as follows: U,cO, —+ U0 +€0,— (a) donot decompos: : (b) decomposed to 3¢ (22) on heating (©) decompose t give oxides and 0, ‘INO, —> 20,0+4N0, + nae (0 give CO, from carbonate and NO, | NOs) 7 IMgQ_* 2N0, * 92 7B _ +0, from nitrates * . —=*1 — Mgco, —» MgO +002 are high! 1 - even a angie 1) and do not decompose (o)sconest au The peculi ) Te a fourth group element. pees haviour (Lr Ket) Ue Li) of eno catn carbon from its family members is due to: Smallest in size, undergoes catenation (a) its very small size : hd has maximum electronegalvityi9 0) aay of etenton, its group members (1s cece ‘ (cdL2 CA ' (0) its maximum et Oo at ese ve (@)_allare tue Bree] me 8. Boron and silicon are: Ta Band Si give acidic oxides) BCly (a) semiconductors (»(#) and SICI, react with H,0. Their nitrides (b) give basic oxides react with water, But they are ‘semi- (c) give their chlorides which do not react with water conductors, S(2) scores (d)_give their nitrides which do not react with water ° 9. The reason for the difference of nitrogen form its | @_Al the first three oplions have ‘other family members are: oe corect statements when nitrogen is ae P| sge| compared wih P, As, Sb and Bl. So (a) very small size of it Me Nd spn (2s coedt. (b) high electronegatiity of ritrogen Sh. (c) d-orbital not available (ts12,%) in N-atom (d) all are true 10. F, differs from other halogens that: FE (®) Fis very_teact (a) itis less reactive than others cf electronegative and is a colourless gas. i fine ao makes exes 8 Antu a eco. So n bonding ~ ‘ eli correc. (c) its electronegativty is low ri id) itis a coloured gas__ ° (o) The pola A pte ed scot Wr be wn temp. required to .decompsoe their carbonates of TEA group elements: (a) decrease down thegroup“ ".. i “(b) 4 rease down the group. = , Gernot be predicted ( (S/ Ut) to have a definite (c) cannot trend (ui). es (4) cannot be explained by keeping in’ view the wer (sleie-t2z) of metal ion olarizin: ‘carbonates i ¥ cient goes on increasing. So (6) of 5 ot Swe: 3 VPP tte - G Sb T- dic active, highly enev @ (d)_is basic if X = Cl, Br” ’ eI 22 Ilmi Inorganic Chemistry (Manuaj) ELECTRONEGATIVITY 12, 13. Pauling scale of electronegatlvity: Te) The EN. of F is 4.00. The scag does not help to calculate the E.N, of a. and Fblock elements. E.N. values always increase from left to the right in PLT. So(c) is corect. . 1@) First three options are correct statements. In option (4) i the lectronegativty difference of the bonded atoms is 1.7, then bond is 50% jonic and not 70%. So (d) is correct option. (a) _ says that flourine has value of E.N as 3.5 (b) helps us to understand (tf) the E.N. value of d- and f-block elements (6) involves (t/=+!) the concept (427 2*) of partial ionic character of a covalent bond (d)__ the value of E.N decreases from left to the right in a period murove: ‘One of the following statements Is not correct. Point out that . (2) The partial ionic character (2° Ver” 1) of a bond is due to electronegativity difference (b) The % of ionic character can be calculated fora bond (c) The bonds which are having E.N difference more than 1.7 are said to be ionic - (4) If the E.N. difference is_1,7, then the bond has 70% ioni¢ character__“o.a\4 So'r The compound like XOH is acidic if X= Na, K is strongly basic if X= K~ is amphoteric if X ] GAL NaOH, KOH are bases and KOH is the best base, HFO Is not formed. When X= Cl or Br, then the compounds HCIO and HBrO are acidic. So (b) is correct, POLARIZATION AND POLARIZING POWER There is electrostatic force of 15. The Ee) @ (eties), of polarization (F672) involves atacton dng polarization, Cation is ee , ti ind does not undero (a) that electrostatic (< 23 Sx-/Usru.%) force of polaizaion” The vaue ‘Ot charge attraction between positive and negative centres | densities of we and -ve ions does not matter determine the extent of polarization. So (0) the concept (179 fs#) that cation is polarized by | “Sa anion {c) the concept that cation is said to be polarized (d)_ the values of charge density (3. 2+ J Gb) z cation and anion seed (2e2748 64) of ae spe eably (22 TLE Ty of a negalive ion | (@) Ave lon Is polarized Wf size Is . lepends upon: bigger, charge Is higher and pyotons in ein 0), theses the nucleons ara_less. Anyhow, the oer (b) the amaiigo charger» - number of si@uirons in the nucleus ebro) + liber of protons in the nucleus snarls Sa) cick (d) “number of néutrorjodic Classification of Elements and Periodicity 23 Perl 7 ‘Which of the following is true by considering (2x Zu.” 3) the polarizing power of positive ions for following -ve ions? @ s® Br0,° > Br0,° x (a 0,0 >No, g)_ ClO > Br > 19 ¥ fl. (9 S© Is big sized so moro polaizable, BrO is big sized, has more number of 0 afoms and so more polaizate, POS is big sie et big size of P-alom as compared fo N-alom. 1 has low charge density and ClO has maximum, Hence (c) is corect. GENERAL FEATURES OF TRANSITION ELEMENTS 18. elements from fa) scandium to zinc (b)_ lanthanium to hafnium (@) yttrium to cadmium (@)_none of these 79. Which of the following do not belong to the same The first transition series comprises (tx F ) of (a) Fist transition series is from 2,Sc to gels gla 10 ji are Af series. geY ~ 4gCd are second series Le, 4d. $0 (a) is corect. Te) cr, Mo & W belong fo group VI-B. Ni, Pd and Pt belong to VIII-B. Mn, Ru, + group? . Re do not belong fo same group Cu, Ag, (@) Cr,Mo,W —(b) Ni, Pd, Pt As beiong 0 IB. So (cjiscorech. c)_Mn,Ru,Re__(d) Cu, Ag, Au 20. Re haste ele soniguston (0) eRe has 5¢6s? configuration @) (b) S when 4 & are removed {0 form Re then © a @ three electrons remain in 6d. So option | (is correct. 2, The element between U and Bk is: (a) Sequence is 92U, gsNP, g4PU, ggAm, (a) Am (b) Pa gM, Bk. So (a) Is corec. (c)_ Th (d)_Fm 7%. dblock elements show all the following properties | (c) The characlesicproperies except, associated with transition elements are variable oxid, states, calalylic properties (2) variable oxidation states Ayes. 4) (b) catalytic properties (tz FM”) zi (0) natural radioactivity (\6.Kid..5) (@)_colour of the compounds (Ler) and colour of ons and compounds. Well tadioactiily is not essentially associated with them, So (c) is correct. @ Eu©_gm® ) Ww _yp® « ©) © —E,8 ——~O-m® TB) The electronic configuration of Lu is (Kel! f 5d 6s? and of ¥ is ... [Xe] 44 652, By loosing 368 and 268 respectively, the electronic configuration and Y© Is same, (b) is of Lu correct. a4 Imi Inorganic Chemistry (Manual) 24, ‘Atomic radil of third transition series along the | (@) Alomic radi in d-block elements do not change regularly. These values for period 7 Sd elements decrease upto alr (a) increases regularly Pidale of series and then neeieten (d)is conect. (b) decreases regularly (c) first increases and then decreases (d) first decreases and then increases ee 25. Which element of actinide serles has the highest | (@) goth has M.P = 2033°C. g4Pu = (ste) melting point? 913°C, g7U = 1408°C and g,NP = (a) Th (b) Pu 910°C. So option (a) Is correct. __{)_U (d)_Np_ - 7B. Indicate (t722) from the following which has smallest | ( They are all in ee They are lanthanides. Lu‘ is last eoue co 2 © clement in this series, so oF smallest (a) La (b) Cd size, (d) Is correct. i y® __Ww® OXIDATION STATES OF TRANSITION ELEMENTS 27. The oxidation state of U in UO® is: [° #2 ce on Pose ean 4 2 when U has lost 62” and US has salisfied +4 charges from two O-aloms. () 6 @ 3 : The remaining two *ve are there. So (c) +_| is conect. 28. The number of unpaired electrons in Fe® (Z= 26) is: | () 26Fe has configuration asad. @) 4 (o) 5 Went becomes Fe®, then vo 8 o () 6 @ 2 4s and one of 3d are removed. So 5 € are left in d. (b) is correct. 29. In the first transition series, the highest oxidation | (6) 2sMnis in the middle of the series. It has 5 unpaired electrons in 3d orbital state is exhibited (t= A>) by: and maximum values of oxidation (a) Cr ie ea b) o ; slates. (b) is correct. 30. Stable oxidation states of Zr and Nb are respectively | (6) 42" and Nb have electronic (2A): : con figuration as 5s? 4a and 5s? Sd’. (2) +3and+5 = (b) +4 and +5 When they share all the electrons of s 5 +5 and+6 — (d) +3and 43 od otis, then they can show 4 7 rom the = and +5 oxid, states. So (b) is correct. cause given below which forms’stable +4 | (6) La, «Eu, Gd can cia so | (a) gla () Ce : oxidation states. ¢gCe can have +3 and a +4 as well. So (b)is correct. | ane ee nePeriodic Classification of Elements and Periodicit 28 COLOURS OF TRANSITION METAL IONS ————— (a) Colour Ts associated with presence 32, Which of the following ions is not expected to be coloured (Poin eLiey gma ee ee (a) Mn® Abie (b) FeQ— Brow configuration 4s'30"® while Cu has () Ti® (0 Cu% Ct -4 wee a a sc we pale, 12 90 Z colour. Hence . 33. Which of the following ion is colourless in ls aqueous | («oT has wo elections in fob solution? in +4 oxidation state it has configuration, (a) Np® (b) ThO 5f° s0 is colourless. So (b) is correct. )_Am® () “Cm® 34. OutofLa®, Pr® and Nd® which is colourless? (b) Pr® is green, Nd® is red white ( Pr® () La® La® is colourless. This Is due to () nd® (d) None of these re electron in La. s corect. 35. Which of the following trivalent (Lv uw uZ)| () EO Is red, Pm© is pink and lanthanide ions is not coloured? sm® is yelow, YoO id ji¢ configuratic (e] Af", So we ne eeigiee (_Pm® @_sm® MAGNETIC PROPERTIES . 36. In first transition series, the divalent compound having | (a) Nn® has maximum nate of say st ) red electrons Le, 5, $0 it has ae magnetic moment (247 U nL J—-nLJ) — de rete anes Al : ; cored. (a) Mn (b) Fe (c)_Cu (d)_ Co ()_cu__()_co @ionie | (@) The electronic configuration of oT! 37, ‘The expected magnetic moment of Ti” ion is: a (a) 4.90 (b) 284 1s 4s?3¢°, In +3 state l has ond electron © i () 0 Aa) inidends0= VA (1=2)=VEBM ie Sole)isconect, 38. Which of the following is expected to have the least | (4) cu® has electronic configuration magnetic moment? . as 4s° 3¢°, It has only one unpaired (a) co® (0) cu® Glecton and so lsu vaie is 1.732 BM, © ne ( Mm® aa leas among the four options. 39, (@) The magne propery depends Which of the following is epee to be diamagnetic (WL S2ba2r5) Sularu* 2)? (a) CrCl, (b) Cucl, (c) ZnCl, (@) Cuso, upon unpaired electrons. Zn in ZnCl, has zero unpaired electrons, so is diamagnetic, So (c) is correct.Imi Inorganic Chemistry (Manu, a} 26 40. One of the following trivalent lanthanide ions is | (a) tu® has configuration tke] 4f) diamagnetic. Which is that? has no unpaired electron, hence | @ wWw® ne® Gamagnelc. Nd© has 3 unpses; p® (@ ™m® oP has 2 unpaired es, ggTm® ta © two unpaired electrons. So (a) is cone, LANTHANIDES AND ACTINIDES | ich of the following statement is not true? (d) 4f and-4f series have q) “ a voters are 14 elements in series, elements each, Lu and Lr aoe | (b) 5fseries has 14 elements in it. ___ | elements of two sereis. sla | (c) Lu and Lr are at the end of 4f and 5f series | written in period 6, well within te | respectively. P.T not outside it. | (4) s7la is included in 4f series and Is one of the | lanthanides, written at the bottom of periodic table. | 42. +3 oxidation state is associated with almost a ee ae yang x (a) all the members of 4f series aka | (b) only three elements of 4f series (c) only with 53Ce, sgPr and ggTb (d) all those members of 5f series which have 3 electrons in 5f orbital a 43. ite Lee of lanthanide contraction lies with which of the ®, Le irosence (a) Electrons of s7La present in 6s-orbital (b) Electrons of all members of 4f series lie in f-orbital (c) Variable oxidation states of members (4) _ionic radii of lanthanides 44, 46, ‘The property of being colour is associated with which, sets of fons of lanthanides? ( ta®,u® (b) ce®, vr® () Gi )_sm®, Dy® Which of the following statement is not true? (a) The alloys of lanthanides are very important. (b) Cerium salts are used in dyeing. (c) Sulphate of Gd is used to produce low temperature. (d) Cerium glass is used in eye lenses to improve the eye sight. {@) Sm® and Dy© show yet) colour, All other mentioned hee) are colouress ions. (a) Lanthanide do give alloys. Point out the false statement. (@) Actinides also give (a) Actinides have better tendency to form complexes than lanthanides, (b) Actinides have high nuclear charge than lanthanides. (c) Actinides are smaller in sizes than respective lanthanides, property of contraction. (d)_Lanthanides show contraction but actinides do not. :1 MULTIPLE CHOICE QUESTIONS Choose the correct option: 78 two repulsive and four When two hydrogen atoms approach each other (hc FLe-/fi) to form Hp molecule then, (a) there are two forces of attraction and four of repulsion (Jud_/@) (0) there are three attractive and three repulsive (0c) there is a compromize distance at which potential energy is at the minimum (c£7/) (@)_ at the compromise distance the potential energy is at the maximum (eieol) The form of overlap for the molecule F-F is: (a) p-porbitals by side-to-side manner (b) p-poorbitals by end-to-end manner (22817) ()_ s-porbitals (@)_s-sorbitals The first approximate wave function ( P goilgesrilsl) for H, molecule when two H atoms approach each otheris @ veya () w+, vew ov, @) w= wy, + yew, —t Quantum, mechanical treatment of Valence Bond (hr KE FS Siu? 2 us) Theory for Hp molecule shows that: _| {e) There attractive distance, the potential energy of minimum and gets is correct. forces. At the compromise bond distance, the the system is at the the stability. So (c) (b) p-orbital Is directional. A o-bond between two F-atoms is due to head-on overiapping of p-orbitals. So (b) is correct. {a) The frst approximate wave function is the multiplication of two wave functions of atoms a and b of hydrogen. They are not added or subtracted. The wave function in option (d) is second tial wave function. (a) is correc. (a) During bond formation, two atoms share their electrons and lower their energy. So they exchange thelr 3. Anyhow there Is possibilty of ionic56 Imi Inorganic Chemistry (1 Manual) (a) electrons are exchanged (J. ul) during bond | formation (b) there is no ionic character in H, (c) spins of electrons do not contribute (A bi) to lowering of energy (0) there is no need of considering the shielding effect (76236) faeall| character. When spins of wo eechan are opposite the system is sau Shielding effect contributes to fe stabilly of H. (a) is correct, 5. 8. _ In AX,E, type compounds: VALENCE SHELL ELECTRON PAIR REPULSION (VSEPR) THEORY ] According to VSEPR theory the structures of S80, gas and co,® ion: (a) are trigonal and tetrahedral respectively (b) show trigonal planar structures (c) donot have multiple bonds in both ‘species (d) differ from the geometry of BF, AXE type compounds are: (2) perfectly ( 4) trigonal planar (b) non-planar molecules (UneAyER) (©) V-shaped (d) T-shaped The bond angles of SF, and PCI, are: (a) same for both compounds (b) different from each other (c) 180° and 120° respectively (d) different but both are perfectly symmetrical lize) (a) _ there are two lone pairs and three bond pairs (b) the best example is F,©, which has a bent structure ; (c) the best example is XeF,, having angle of 120° between two bonds (d)_have three lone pairs and two bond pairs (0) $03 is perfectly trigonal planar wih three double bonds and angles of 120° hh co®, there is one double and two single bonds, but resonance makes the CO'y’ ion perfectly trigonal planar and bonds are partially double and partially single. So (b) is correct, () AXE are SnCiz, PbCI, type ‘molecules. They have one lone pait E and two bonded atoms x with one a atom A. They are V-shaped and eve one lone pair at the comer of a triangle. (is correct e ies igonal bipyramig wih free SrOleS Ff 120° and six of 90° I i piel of 90°, lis a parte Molecule, SF has one lone les in te ia bipyramide and fone pair lke PC, and i Pond angles are not So (is conect, * SYM. molecule. 9. distorted octahedral In SF, out of six electron pairs around the S-atom, 6 bond pairs and one lone pair a ee a 6 bond pairs in an iregular maa f there are 6 bond pairs in square bipyrami vay é ‘ there are 6 bond pairs and the structu corr 3Theories of Chemical Bonding 57 i close the center 10, The repulsive interactions (ZF SGs=-nd-pu) have Berean compared i 8 band the sequence: pair fp), $0 (IP — IP) rs nee (a) (bp Ip) > (Ip- bp) > (lp — ip) greater and (bp - aH} re (8) (>~1p)> Vp~bp)> (bp ~ bp) minimum, So (t) is cor a le relation depends on the nature of compounc have fogik regular 11, There are three molecules as BF, CH, and SF, Which tea anit eap tated Lied set of the molecules has regular (161) geometry? Planar, _ tetrahedral _ : on (2) BYF, and CH, (b) CH, and SF, pepe Thera ae no. ene (c)_SFyand BF, (4) _BF,, CH, and SF, " Te the A ave ellher 12 A molecule AB, consis two o bonds, two m bonds |) THe ABs tie spss have eer and one Ip in the valence shell (J? vss) of A. The thn alee pit, ots bor andre arrangement (77) of Ip as well as bonding electron | pai lies al one of the comers of tig airs is: 4 . ta square pyramidal structure BB, So(c)is correct, (b) linear (c) trigonal planar . {2)_unpredicted (ened hBs A ly IS pyramidal | @ © & @ IA element with three 13. BCI, molecule is planar balls Cl, is py cutemast & and so BC Fel wi (Ppa). The reason is that: Clbond | De perfectly trgonal with no one pai. N (a) N-Cl bond is more covalent than B — Cl bon is VA element wih fhe outermost & (b) Natom is smaller than B Three are shared by three Cl-atoms and (c} B—Clbondis more polarthanN-Clbond | ore lone pair ic there. That pair (1) BG, does not have fone par {p) on,B, but NC, | a outer just tke fit, has on one N-alom, and is pyramidal, - neva): {€) Te is VLA group element ike St 14. Which one has the octahedral shape (024 % 18 iin olsnceahd Thy So 8 (a) PF, (b) ce shared by 6F-aloms and perfecly sym, (d) Structure square bipyramide or () TeF, (9) GF, octahedral is produced, So (c) is correct. 15, The shape of XeF, is: (a) tetrahedral (b) sphere ; . 8 square planar (d) trigonal bipyramidal (¢) Xe has 8 €8 in outermost shell. Four ate shared by 4F atoms, two lone pairs ate there. They lie al on opposite sides Which pair is isostructural (= S74 i) from the following? (a) XeF,, IFS (bd) NH,, BF; () co¥,so® (4) PCL, Ick of octahedral so Qverall il is square planar. ina (a) Xef 2 ate linear species with three lone pairs and two bond Pairs. So (a) is correct, ee58 Imi Inorganic Chemistry (Man 47. Two lone palrs and two bond pairs of electrons are i S present in: . (c) fills has one fone pair, BF hay (a) NH, (b) BF, lane gal, CO, has no Fre pk id 1as two lone pairs and oe () 4,0 (@) CO, pais, So (cis caret ben ° , 18. In NO ion, the number of bond pairs and lone pairs of | (@) Nog is planar trlangular ang elctrons are respectively. shows resonance. It has no lone pair, (@) &7 (b) 14.3 Natom but 7 fone paks on thee o. ) 22 3 atoms. N has five covalent bonds wih a Js | three O-atoms, so has 5 bond pas 79. The molecule having unequal bond lengths (c)PCIg_ has trigonal bipyramice (ns aaSASo31) is: pee peel cesar lie in oe ar toms ndi (a) NF, (b) BF, thal plane. So, there Ite eae () Pcl, (@) SF, bond lengths. BF; & SFs ara sm — ‘and bond lengths are same within a molecule, So(c) is correc. 20. CO, is isostructural with: (a) HgCl, and CO; are both linear a) Hg Cl molecules SnClp and NO, ae V- 6 oo Lp (b) Sncl, shaped. CzHs has bolh carbons as ) Cc) (@)_ NO, hedral. So (a) is correct. HYBRIDIZATION AND SHAPES OF ‘SIMPLE MOLECULES 21. Strength of the bond (=3u (Ft) formed by the overlap | (6) sp? has 75% sp has 66% and $9 between two sp, sp? or sp? hybrid orbitals is in the tay SO pela order: belter the strength of a bond. So (2) § (2) sp—sp> sp?— sp*> sp?— sp° cone (b) sp? —sp?> sp?— sp?> sp—sp (©) sp*—sp?> sp?— sp?> sp—sp (d) _sp°— sp? = sp?— sp’= sp- sp 2. oe hybrid orbitals are: (a) A ona sie a) linear (b) _ pentagonal bipyramidal electrons. 3 is te pall © _hexagonal__(@)_octahedral an cn esate {OT 23. chorbital involved (ts) in sp°d hybridization is: Ce) oz a or arora 18 (@) dg_p (b) 4d, other dotilas which is dreced od oa long Zax. can easly P 12 (8) dye hybridization with 3p-orbitals. 24. corbital involved in dsp? hybridization is: () So apan a) scorer RY a day () 4, which fakes part in dsp? hybriizalo® C) da (@) ¢ ae atom in CO, molecule is: (a) sp* hybridised (b) sp? hybrid (c) spd hybridised(d) Fd varied 7 Gabon in CO, 1s sv? * makes two o and two x-bonds with atoms, So (d) is corect.Theories of Chemical Bondin 26. The hybrid state of S in 0, is similar to that of carbon in: (a) CO, (b) CH, (cy CH, (@) CH, 59 (6) 5 In $03 is sp"-hybridized as carbon In CH, But S makos three x-bonds with O-slongwith three @ bonds. C makes only one x bond with other carbon atom. In CO, and CH carbon is sp, and in CH, carbon is sp? hybridized. (jis coredt. “ZW. The central atom does not assume (LF a1) spe () Nin NO. Bin BFy and § in $03 2B. 2. 30. 3. 32, hybridization in: ‘are sp? hybridized. In PCI, the hyb. of P Is sp? and lone pair is present at one of the comers of tetrahedron. So (c) is correct. () NOS (b) BF, () PCI, @ 80, The type of hybrid orbitals used by Cl atom in cloe ionis: (@) sp (b) sp? (c) sp (d) None of these Paani acco (c) In CIOS, “Cl undergoes sp? hybridization and one of the comers of tetrahedron is occupied by lone pair. There are two m-bonds and 4a bonds. So (chis corect. The hybridization of atomic orbitals of nitrogen in NO, NOS and NH@ are respectively: (2) sp’, sp*, sp? (b)_sp*, sp, sp? (©) sp,sp*, sp? (d)_sp, sp’, sp? Bond length of ethane (|), ethene (II), acetylene (III) and benzene (IV) follows the order: (a) (1) > (il) > (Ill) > (IV) (b) (I) > (Il) > (IV) > (Ill) (c) (I) > (IV) > (Il) > (Ill) @)_ (i) > (I> (> () Which of the following statements (=tl,) are correct? (2) InBrF,, Br exhibits dsp* hybridization (b) In SiF,, Si shows sp? hybridization (©) InNH,, N exhibits sp? hybridization () In SO,, S shows sp hybridization (4) NO® has spiv-atom, NOS has sp2 Neato and in NHO, N is sp? ® hybridized. In NHg, the forth comer having lone pair accommodates H® ion to give a perfect tetrahedral structure of Jon. So (4) is correct. (€) The order of bond lengih is C-C>C=C>C-C. Butin benzene the bond length isin between single and double. So C — C (ethane) > C = C (benzene) > C = C (ethene) > C = C (ethyne). So (c) is corec. (b) Bi, has two lone pairs and three bond pairs and shows dsp’ hyb. In NH the alom of N and in SiF, the atom of Si have sp? hyb. In SO, $ is sp? hyb. and there are three o and three n-bonds, In SIF, Si is sp? hybridized and tetrahedral, So (b)is correct. In XeOF, the type of hybridization is: (@) spe (bo) sp°d? () spd (4) compound is not possible (8). Xe has 8 e in outermost shell. 1 undergoes sp'd? hyb. Four hyb. orbitals have one e~ each and share 4F atoms in a plane. One pair is shared with one O-alom to form ao & x bond. One lone pair on Xe remain as such. So (b) is Correct.33, 34, 35, 36. 37. 38. Imi Inorganic Chemistry (Manuay (a) ts — character (b) 4s — character 2 (co) 38- character (d) ts — character Which one of the following will have a tetrahedral disposition (u% 44)? (a) SO, (b) SO, () so© ( so® Resonance structures (Ufttst1<- 24 bU 2 bw) of a molecule should have: (a) identical arrangement (.27u* £1) of atoms (b) nearly the same energy content (c) the same number of paired electrons (d)__identical bonding (1 £1) The CO® ion: (@) possesses (< %) four electron pairs of equal status states around the carbon (b) has four electron pairs arranged in a tetrahedral way (c) the carbon is sp? hybridized and structure is triangular planar (d) has one double bond and two single bond so it is not perfectly (ut) triangular In PF molecule, there is: (a) hybridization of centra! P-atom is dsp? not sp'd (b) trigonal bipyramid structure but one of the bond angle is 110° 7 (c) hybridization of central P-atom is sp'd and not dsp? with trigonal bipyramide (d)__net value of dipole moment 11,2 is a monovalent ion (o/fu*»L1) (a) having bent structure (=) (b) has sp°d hybridization of iodine-ator ie structure with sp*-hybridization (c) has linear struct l ryt ff has linear structure with sp'd hybridization and one of Clatom has negative charge ym and is bent 60 ees > Tar of? hybridized orbital has 25%, 5S A sp? hybrid orbital contains: oe poharecer. In olher mn 3 nas {thot S and tho p charade 55 (2) is comect. (@) InsO©, S-undergoes sp? hyb. Twa O-alom are neutral and two tring the ~ve charge with them. Two are doutle bonds and two are single. SOM hag four resonance structures and all the bond angles and bond length are equal $0 (c)is correct. (a) The various resonance contibuing structures of a species have identical arrangement of aloms. They are not esseniially of same energy and do not have same number of x-electrons. (©) CO® is tianguiar planar species having C as sp2hyb, Two atoms are ‘neutral and one O°. The species shows liwee resonance structures and has ‘equal bond angles and o gles and bond lenglhs. So (0) Ps in grog $ p V-A elements, lis Configuration Is 352 33.145 3d orbital is orb and one s, three p andonedi o 10 give 0° but not asp? hyp, 7) re angles i 120° and 6 are 99%, fa ‘moment is zero ¢ ite (Qiscoredt Wue to symm, Structure, (4) locine is in grou outermost shell, free U has & in undergoes Spd hyb. One or 7 Orbital it remains empty, cI vb. orbital two & in il. Other Cha tes iis unpaired election. So tne "8 one of linear and three long pais ure is a" plane of trigonal bip in (@hisconect MSO siya?Theories of Chemical Bonding 39, 40. 41. IF, is an it 5 interhaloger 2 out false einen a imele compound, Pint a ie hybzton of iodine atom is sp'd? pairat 6 comer square bipyramid but with a lone « al i bond angles are perfectly 90° le structure is squar ic i pair and five bond oe a ales oO. 1 About 10s ion which of the following is not true? (a) C08 has perfect tetrahedral structure (b) ClO? has one single bond and three double bonds (c) It does not involves resonance (d) The central atom is sp? hybridized and one of O- atom comes in the form of O° Indicate (tu wl) the correct order of increasing C—O bond length in CO, co? and CO, (a) CO Nodal plane (b) a plane perpendicular to the molecular plane WO On which bisects (2) the carbon-carbon sigma bond at right angles (c)_ the molecular plane (d)_aplane parallel to the molecular plane - FE Withal ie eonrg sls ol tis re dager (Line) | Pan, = Te, © ine fo al te in a homonuclear diatomic (U7 z 721» LUA & Li) | homonuclear d-atomic molecules molecule? a5? F151 Gap,” < Map, (a) Se, and oy, (b) and Sy, So (c) is correct. () TM), andn, (d) o,,ando,, 46. The bond order (11 32{) of a molecule: (@) The definition of bond order is (a) depends upon number of electrons in atomic | No. of & in BMO — No. of & in ABMO orbitals 2 (b) depends upon the number of electrons in BMO ‘So option (4) is corret. (c) is the difference of number electrons in BMO and ABMO (d)_ is half the difference of number of electrons in BMO and ABMO_ 2 a7. If we compare (t/-16) MO pictures (U2) of H, and | (¢) MOT of H, says that there are 22"in H,®, then we come to known that: BMO, So bond orders 1. In H,©, there (@) bond order of H, is less than that of H, © is ny oe tecson w BNO, oo EO. (6) BD.EofH, is ess than that of H,° . Greater the bond order, greater te (©) B.LofH, is less than that of H,° ee tage a H,® is less stable than H,. So (c) 8 (8) _H,® is stable as compared to H, correct ; 48. How do you compare the molecular orbital pictures of Li, and Be,? (a) The number of electrons in BMO of both are different {b) The number of electrons in ABMO of both are same (©) The bond order of Li, is one while that of Be, is zero {c)_ In U, there are 2 & in outermost BMO and ABMO is vacant. Hence bord ‘order is one. In Bey there are”2 é in outer most BMO and 2” in outermost ABMO, give B.O = O. So Liz exists but Be does nol, So(c) is correc.Theories of Chemical Bondin (d) Li, does not exist but Be, does 49. The outer most molecular orbital (Mi of B (a) has four electrons ee (b) has two electrons in o-BMO (c) has two electrons in -BMO 1_(d)__has zero electron so bond order is zero 63 —————— J 1) Bas (6, ou F(ey) adm)” a5 M.O. Ten & of 2B aloms are filed upto pp, Tha outermost yp, has two &. (2) is corect 50." The distribution of electrons (= U 2/21) of Na| @ Tia dec deatuiceli tat fi molecule according to MOT is such that (2) its bond order is 3 . (b) thas triple bond, one o and two x. () ithas B.D.E as 940 kJ mot, showing it a very strong bond (d) all are correct 51. Theparamagnetic nature (20 L Cz, dure ©) of 0, is because; (a) bonding electrons are less than antibonding electrons . (b) bonding electrons are equal to antibonding electrons (c) it contains unpaired electrons (d) bonding electrons are not more than antibonding electrons One of the following molecular species has unpaired electrons(s). Which is that? @ N, (b) F, ()_ 0 (09 53. Comparison (16+) of molecular orbital pictures of N, O, and F, shows that (a) the outermost MO of N, is = (b) the outermost MO of O, is o (c) the outmost MO of F, is x* (d)_N, and F, are paramagnetic but O, is diamagnetic “i oy Fey, 2222 2 O15 Ode One Ra, = Hp, 0 +82, $080 =552- 3, one bonds o and two are x. The B.DE of Nz is 941 kJ mot, It means (a), (b) and (c) are correct statements, So(d) is tue__ (e) The MO picture of O, is pee, re? 2 2 4 Ots Os 92s O24 O2, Ry = Mpy RP, = ip, 02,2 has two unpre electrons in ABMO. So (c) is correc. (€) The comparison of MO pictures shows that No, Fz and O'” have no unpaired electrons. OP has one unpaired electron in x ABMO. 2% 2 7 2 2 (0) Nz = Gts Gig O25 O35 2p, = M2, 2 me, ; 22 e222 02 = ots Big O25 035 O29, R2p, = R2py soy "ry Mn, ect ot ot 2-2 Fa= O15 O15 O25 02s Op, Hp, = Map, The outermost MO of Ny is 6, of Opis x, Of Fp n°, Np & Fy are diamagnetic but zis paramagnetic, (c)is correct. 54. “According to MOT which of the following is non- existent (122267)? (@ The bond order of He, is zero because wo & are in oj, and two in64 Imi Inorganic Chemistry (Manual) (a) bond order of 2.5 (b) three unpaired electrons (c) diamagnetic character (@) stability (¢.1.2t) lower than O, SSS @ of @) HE ig 80"? 520, @ 0% (@) Ha oO 55. The MOT says that the species 0° possesses: (a) The M.O. of O 2 are 272 7 2 2 204 5 ts S25 O25 V2, Rp = Mp, Rip = 2 0 Np, %, 6-1 8.0.=>5-=25 Due to one unpaired , itis paramag. is more stable them O,. 56. On the basis of MO theory, the number of antibonding | (c) The MO of O© are filed as o?, set Gu) i 4 electron pas (32 L APE Lo eae 3h ON) In| CP of. ol ap ip, = nin ty, : outermost MO of O© fon is: rapt oan Tete are two AB decion (a) 4 () 3 es in agp, = 3p pairs in n2p, = n2p,. (a) is correct. (rea @ 5 y= Me 57. Which is the correct sequence (.*7) of bond order? | (b) The bond order of 0, is 2, for 0? : (a) 02> 02> 0, will be 2.5, and for 09 itwilbe = 22 (bt) 02>0,>09 = 1.5, So (b) is correct (©) 0,>09>09 @ 02>09>0, 58. Inthe molecule of CO, (@) The outermost MO of CO is 07, and (a) thetighest urconyied MO (MOL: 1/Fug Antic) | is unoccupied a5 is lower in energy is om than mp, AO of Os lower andi is due (b) 6, is higher in energy than Tp, Of carbon {oils high E.N. So (a) is correct. (c) AO of carbon are lower in energy than those of oxygen (d)_ the lower energy of AO of oxygen is due to its high .P. value as compared to carbon 59, The MO picture of HF shows that fe E Fer being highly Sj — is (a) AO of His lower in energy than 2p orbitals of F eee ee (b) there are two m MOs which have two electrons | Pad ders one. So (c's coe (c)_AOs of F are lower in energy than those of H atom (d)__the bond order in HF is not perfectly (, J) one 60. {a) The bond order of NO is more than b) _NO®>NO> Noo What is the order of N - O bond length in NO®, NO and NO°? (a No® No® > No THEORIES OF METALLIC BONDING 61. 62. Electron gas theory of metals considers (twF 23) 65 (@) Electron gas theory says that there are free electrons and electrical fn wal there are no free electrons electrical Conductivity (xi (fe- 7 conductivity is due to free mobile Sate oma (o'r ace en Se (c) that thermal conductivity (eo! Se Les 7) luster of metal is due to jumping of cannot be explained by it surface electrons In various onary (@) metalic lust (-G) is due to jumping of fee | electrons on the surface between various energy levels Valence bond theory of metals (c) VBT of metals is not able to explain the metal structure only. Crystal (a) only explains the structure of metals (b) () (d) is applicable (tv) to know the crystal structure of solids was given by Linus Pauling that outermost electrons of metal atom are fixed in crystal lattice (2. WE *) ‘According to MOT of metals (a) the bands where the electrons can move are (b) (c) called permitted bands (32-22 = ip!) permitted bands are also called Brilloin zones the level below which all energy levels are filled is termed as Fermi levels. (d)_all are correct structure can not be known. The electron are freely moving. This theory was given by L. Pauling. This theory can explain the geometries of simple and ‘complex molecules. 1a) The facts mentioned in options (a), (0) and (c) are correct according to MOT ‘of metals. So, correct option is ().CHOOSE THE CORRECT OPTION: THEORIES OF ACIDS AND BASES {b) Conjugate base is that one which 7 oo ‘ 1. [Bi(H,0),)~ is acidic in character. Its conjugate base | 1,55 iost one H© and remaining oH® (2uoLbGale Latuts,) is: is within the brackets. OH© inside the : : brackets will decrease one +ve charge (a) [Bi(H,0),OH)]© and overall charge on co-ordination On ® sphere will be +2. So correct option is (b) [Bi(H,0),(OH)] (0). (d) also has the zero charge on it, . ® but 3H20 cannot loose 3H® from the (c) [Bi(H,0),(OH),) single molecule of acid. (b) is correct. (d) _[Bi(H,0),(OH),) : 2. In the reaction (@) SbF, is always Lewis acid and SbF,+2F° ——> Sb Fe FO ig a basic in nature, In SbF,© a) we understar oy ‘i jg | the octet of Sb is disturbed. The only @) crcatol eed Sieseeal is according to Lewis | correct option is (a) in which SbF; is (b) SbF, is a Lewis base Lewis acid and F© is Lewis base. () Fis aLewis acid (d)_ the octet rule (we ¥ Zi) is obeyed by the complex ion produced 3. Inthe reactiog (@) First three oplion (a), (b) and (0) have correct statements for the given Cd +4NH, —> [ca(NH,)J© (a)__ the co-ordination number of Cd © is4 reaction, so option (d) is correct.Acid-Base Concepts 7 (b) the reaction satisfies (et. soncept of on and bases ~ (c) Cd / is a cation which has low lying empty orbitals (Urey. Lty 21) (d)_all are correct CO and propene are Lewis bases because (a) _a-bonds of CO gives lone pairs to a anion (b) o-bonds in propene are responsible (tst412 3) for this behaviour (+) (c) carbon of CO and n-bond of propene make them Lewis bases (d) alkenes cannot act as Lewis bases because their n- ) the Le electrons produce ring curent (2 A ueeAv zw Ach) 4 Which of the following is not a Lewis base? (a) cn° (b) ROH (c) AICI, (@) NH Which of the following statement (wx) is not correct regarding (3+) Lewls acids and bases? (a) NH, and H,0 both behave as Lewis bases. (b) Substances which can donate a pair of electrons are called Lewis bases. All Lewis bases are also called Bronsted bases. (c) fa Lewis bases must contain an atom with incomplete octet (Ait) Inthe reaction cad + SO, ——> CaSO, (a) CaO is acid and SO, is a base according to Usanovich concept (b) SO, acts as a base (c) the acid SO, accepts anion O abase © and 0® acts as {@) « bonds of @ compound are never donateable, so option (a) & (b) are inconect, The alkenes do not give ring current bul alkynes do. Carbon of CO has lone palr for donation and xe” of alkenes also do the same thing. So (c) is correct. () CN, R- GH and fH have lone pairs of electrons for donation, so they are Lewis bases. AICI; Is electron deficlent because octet of Al Is. not complete and is not Lewis baSe but is _| Lewis 2c {@) First three options have correct statements. So, option (d) is the choice because Lewis bases should not be electron deficient. {e) CaO is nol an acid because it gives its oxide ion. SO, is never a base due to is elton deficiency. In opin (.) OP is not acting as a base but CaO acts as a base. So option (c)is tue. (d)_CaQ acts as an acid HARD AND SOFT ACIDS AND BASES (d) Molecules or ions with greater 8. Which of the following property is not associated (tx) with hard acids? (a) They are cations (L042) of smaller sizes (b) They are mostly cations of higher charges number of valence electrons are soft bases. So option (d) is the choice, Well, in hard acids cations are of small sizes oF of higher +e charges and not easily polarized.90 (6) _ They are not easily polarizable (LuLt7z— 7) 10. 12, 13. o (d)_Ag® is a soft base and F® is a soft acid 14, (b)_BF, isnot elecon deficient species (urzzJufS 221) at diml. Inorganic Chemistry (Manuay) >= (4) These are the molecules or ions with, greater number of valence electrons (71 9121s) Which one of the following property is associated (tx), with a soft acid? (a) These are cations of large size (b) These are usually the cations of higher charge (c) These are easily polarizable (d) These are molecules or ions with larg valence electrons Hard acids are mostly | (a) _ions of alkali metals (b) ions of alkaline earth metals (c) ions of lighter transition metals as Co Cr™ etc. (d) all are true Soft acids are mostly (a) _ heavy transition metal ions (PePAs sorties) of 4d-series (b) heavy transition metal ions of Lanthanides series (©) ion of low oxidation states as Ca®, As® and H @ 9 (d) all are correct. In hard bases (a) there are donor atoms of higher electronegativity () the donor atoms are of high polarizability (c)_ the molecules have donor atoms as As, Sc etc (d)_ the species (v£2) like trialkyl phosphene is one the best example oO. oO Agl , is a stable ion but AgF 258 unstable because (@) Ag® and 21© are both soft © Ae and 21° are both hard (c) Ag? is hard acid but F° is soft base jer number of © 7, The reaction of BF, with F° to give BFO is a ) Soft acids are cations of smal size, are of higher charge. So (tis correct, Ta) First three options are cored satements for hard acid, so oplion (4) is the required choice. {@) First three statement for soft acids are correct. So option (d) is of choice, {a)_In hard bases” donor aloms are of low polarizability and high electronegativily. As and Sc are big slzed. Trilky! phosphene Is a sot base. $0 a) is corect, {@) Soft-soft combination and hard-hard combination are stable, Ag® and I are both soft so option (a) is correct. jo (a) Both BF, and FO ara base, BFsis electron deficient because octet of 8 is favourable reaction (n#L7 LL azo fhsty), (a) and is called symbiosis ‘not complete. F© being small sized has low polarizability, This reaction Is called symbiosis, So (a) Is correct.Gat Acid-Base Concepts 16. 1. __—_o_because one is hard and other is soft a is an ambident ligand (niie-Li Lutes (c) F© Is highly polaizable 91 Ue rc2telE tht 21L) because (a) itis soft base when S-atom gives its lone pair to form a complex it is hard base when N gives its lone pair to fom a complex (©) the metal ions tke Co, Ni, ca® do coordination with N-atom (d) all are correct Occurrence (tb Lt) of ores (es é) and minerals (U2) follows the HSAB concept, because (a) Mg®, ca® and Mn® occur as their oxides (o) cu®, Ag®, pr® occur as their sulphides (c) n®, Fe™ are border line cases and occur as oxides and sulphides both d) all are true () The pK, value according to Richi formula for H3PO, is around: STRENGTHS OF ACIDS AND BASES {(@) Tho statements in frst tree options ate correct, so option (4) Is of choice. fT (@) Sottsof and hard-hard combination Principle is applied to understand that which metals occur as oxides and which as sulphides. First three options have correct stalements hence option (dis correct. 18) HPO; Is a weak acd and has +e pK, Value of approximately around 3, So (b)is correct. ——l0_HI> HE > HBr> HCI a, (a) 1 (b) 3 () 5 ()_-7 The basic character of NiMe,, NH, and NF; follows (tT) the order. (a) "NF, > NH, > NMey (b) NMe, > NH, > NF; (c) NMe, > NF; > NH; (¢)_NH,>NF;>NMe, The correct order of acidic character of hydro acids of group VII is: (a) HI> HBr> HCI> HF (0) HI> HBr> HF > HCI (c) HF >HCI> HBr > HI Ky value of PO® and Aso® Is; () 2x 10-2 33x 10-3 () 2x 103,33 x 102 (b) Me group Is @ donating, while Fis highly electronegative and withdraws the € away from N-atoms. So order in option (b) is correc, (a) Acidic characters of hydroacids with electronegative elements goes on increasing down the group. So option (a) 's correct, - Teor d) HyPO, Is a stronger acid than HyAsOy. So POS Isa weak base and AsO isa strong base. Hence Kb ofMULTIPLE CHOICE QUESTIONS Choose the correct option GENERAL FEATURES OF COMPLEX COMPOUNDS Which of the rows has lowest (./7() oxidation ee euCN FracMite ey natci{co id +4Q— () KFe(cn), ‘) [Cofen ricl,’ (b) Only one Na® is outside the co- ord-sphere, so charge of complex ion is —1. CO ligand is neutral. So Co is in +1 oxid. state. In (a) Fe“, in (c) Fe and in (d) co® . (b) is correct.140 2 3. Iiml Inorganic Chemistry (Manuaj; !) Which one of the following Is not a co-ordination complex? (a) Chlorophyll (b) Haemoglobin (c). Vitamin B-12 (d) Acrylic Acid Tn which one of the following does Mn exhibit (0+) Its highest oxidation state? 6 at ¥C 4) = 2 (a) MhO, (o) Wn0® Mine B 2-2, The species in option (a), (b) and fey ‘are co-ordination complexes of Fe, 1/3 and Co, Acryli¢ acid Is simple unsaturated carboxylic acid, CH, = H — COOH. (c)s cored. | cia a {@) In Nn0® Mn Is In #7, in MoO, In #4, in MnO® Is 46 and in Mn i 42, So option (c) Is correct. 2 (2 : (c)_Mn0, (@)_WnO ‘The spectrochemical series tells 7 remical series 4, The spectro chemicla series (<7C-n=sb Suiza tal) a retet a ligand to act as, ‘aatorg 8 of ligands is: (=) 10 ,“) is Incorrect? (a) That metals possess two types of valencies primary and secondary (b) Each metal has a fixed number of secondary valencies (c) The secondary valencies are directed in space (tadsUtUs) around the central metal atom or ion (d) _ The complexes do not show isomerism ‘A compound has the emplrical formula CoCl, 4NH;. One mole of it gives one mole of AgCl on treatment with ‘AgNO, solution. NH, Is not removed with conc, H»SO,. thas structure (a) [Co(NH,), Ch). (b) [Co(NH,), Cl, Cl (c) [Co(NFsJs Cl) NHy (d)_ [Co(NH,),] Cl, The colour of an aqueous solution of CrCly varies form Wlolet (5°) to green (17) depending upon concentration. This variation (.f 4) is due to formation of ‘or weak, So option (¢) Is correct, ——— WERNER'S COORDINATION THEORY. (@) First three postulates in (a), (b) and (6) are correct about [Co(NH,),Cl,jol but It shows geometrical isomerism, So, option (d) Is choice, (8) The given compound should have ‘one lonizable chloride ion, So option (b) Is comect, Option (a) and (c) wil not give any ppl. with AgNOs, In (4) three moles f AgNO, wil be used, Morsover Co does not react wth ANH, but 6NH3. So (6) 8 correct. (d) “In options (a), (b) and (o), the ‘complex lon has different charge on It. So thelr colours are different. Hence ‘option (d) Is correct, (a) [CrH,O)JCl, (b) [Cx{H,0),CyCl, . ()_ICr(H,0),CLICI(d) allof these —~Chemistry of d-Block Elements 141 En FT amlx ote bm GND So —TTee 8. A complex of the formula [Co(NH,);B1] SO, gives a | (a) The SO© Is lonizable and gives white ppt. with BaCl, solution, and no ppt. with AgNO; solution, The structure of complex compound is: (a) {Co(NH),81© so® (b) [Co(NH,),S0,]® Br (@) ICoINH),S0J® Br© (@)_ICo(NH),soJ® white ppl. with BaCl, to give BaSOy. ‘Ag,80, Is water soluble, (b), (c) and (4) give pale yellow ppl. of AgBr with ‘AgNO, So option (a) is correct. EFFECTIVE ATOMIC NUMBER (EAN) ———_ The effective atomic number (¢_/istsye/ 20-2, Sell) (EAN.) of Fe in the complex ech (a) 26 (b) 35 Fer? () 34 () 36— ee The effective atomic rule is not obeyed (ty 2tt) in which of the following compound. . 6 3 (@) eF CN Oa 5 pene 3 a CoftNH,),cliCl, 10. 3 (©) (CsINHIC ( ) 26-2412 25 — b) VALENCE BOND THEORY OF COMPLEXES ee ee Which one of the following ‘complexes is not linear? (@) Ag(NH)® (0) AUCN? () agen? (@) NIP on ), is: iy pl “ 12. The hybridization of Niin the complex N (a). sp* (b) sp dsp? (4) dsp? The hybridizations of NI in Ni(CO), Is: (b) dsp? 8, 14.Which one of the following comp! tetrahedral geometry? (@) NINH 0) jeu © () IN(cnyg® —(@) NICU ) RULE (d) Fe has 26 e” in total. Itis in +2 oxid. state, It loses 268 and add 12 05 from 6 NO, So total no. of €8 with Fe In complex is = 26-2 + 12= 36. So option (d) is correct. (b) In (b) the total no. of & with Fe is = 2§-3+12=35. The other compounds obey the EAN tule. In(a) 26-24 12" 36 In (0) 27-3+12=36 In (d) 27-3 + 12= 36. So(b) is correct. @) A linear structure developes when species Is AB, type. (d) gives us AB, type species. In (a), (b) and (c) there is no lone pair on Ag and Au ions. (2), (b) and (c) are examples of linear shapes. (4) is correct. © Nien is a square planar complex lon, So N© undergoes dsp2 hybridization, Option (c) is corec. 7A) Ni In N(CO), [sin zer0 oxidation state, I undergoes sp? hybridization and structure of N(CO), is tetrahedral. @ x ——_()_ sp? (4) sp Opin (a) s core. Jaxes does not have | (q) in nici), Nils in +2 OS, So it undergoes dsp? hybridization and Is ‘square planar, The rest In (a), (b) and (6) are tetrahedral in shape, (d) Is correct. - ae20. 2. 22, os” Imi Inorganic Chemistry (Manual) Which one of the following is not a square planar (SdoburactetLi) complex? (a) pray® (b) Pane ® © PannyJ® (d) Fe(ons® The hybridization of Cr in (CHH,0),1© is: (a) dsp? (b) spd? ()_ dsp? (@)_sp'd Which one of the following does not have octahedral shape (J Uuivt-21)? (a) K,Fe(CN), (b) K,Co(NO,), {e) In (), Pais in +2 O.S, Wundargoes sp? hyb, and shows tetrahedral and not dsp? hyb. to give sq. planar. (d) is octahedral while (a) and (b) are square planar. (c) is correc. Ta) In he complex Gris in “9 OS. and involves two 3d, one 4s and three 4p atbitals to give octahedral shape. In (c and (d) only five ligands can attack. { is comect, (@)_In option (@), (6) and (c) Fe, Co have co-ordination six and so they are all octahedral. In option (d) Pt. has co- ord. no, as 4, so il cannot show octahedral geometry. Such complexes are either square planar or tetrahedral (c) Co(NH,),Cl, (d) ts (NH,),Cl, (d's correc. ‘The type of hybridization of Fe in the complex (FeF,)~ and magnetic moment (4/2131 He Lewsey) are: (2) d’sp?, 0.0 BM. (b) spe, 5.9 BM. (0)._sp'd?,4.9B.M.(d)_d’sp?, 5.9 BM. ‘Which one of the following octahedral comlexes is diamagnetic. (puter Ate wer ere IN (a) (oor —&) Fat, 0}1° (c) KjFe(CN), —_(d)_KyFe(CN)< The complex ion [cuNH,J@ has: (a) tetrahedral configuration (<27) with one unpaired electron (b) square planar with one unpaired electron (c)_ tetrhaedral with all electrons paired (d)__ square planar with all electrons paired Which one of the following has highest number of unpaired electrons (1 /212Zi7u44)? @) MniHos® () (FetHO.® © wiHo® @ Icott,nl® Which one of the followi 3 hybridization on the eel Ti mene (@) (coFJ — () Fe(CO), © INicN4® @) nic® (b) In Fer J®, Fe is in +3 OS. and has 6 weak ligands. Ils electrons remain unpaired and outermost dorbital take pat in hyb. Hence it is sp%d? not dsp, Greater number of unpaired electrons make ils p value as 5.9 BM. {@) In diamagnetic substances there should be no unpaired electrons. CN Is a strong field ligand. In K,[Fe(CN)e). there is no unpaired electron and is diamagnetic. (d) is corect. (®) The complex has co-ordination 4 and Cu is in + 2 0. S. Il has one Unpaited electron whose orbital do nol take part in hyb, It is dsp® hybridized and is square planar. (b)is correct {a) In option (a) Mn loses 2e~ of 4s and 5d electrons are unpaired. No. of ther options as for Fe®, ni® and CO has have less number of unpaired. (8) Fe(CO), has coord. no, 5 and s° dsp? hyb. is possible. In (a) the co-did ro. is 6 and so sp'd? hyb. is there. n () and (d) co-ordination number is 4. SO hhyb, may be sp? or dsp2, Hence option (b)is correctChemistry of d-Block Elements 143 Which one is a high spin (v!se¢»:) or outer-orbital (c) FO is a weak field ligand and 23. red electrons are thera in 3d complex? © © orbitals and is high spin complexe. (c) is (2) [Co(H,0)]™ (b) [Co(CN),} correct. (©) ICoFJ® (a) _tFe(cnys© 2, Which one of the following statements (=) Is false? | (6), The frst tree options have cont (a) Weak igands ike F©, C1© form high spin complexes | ‘'temen's. In epfon (9) CO is son igands like CN field ligand as compared to FO so (b) Strong ligands like CN© form low-spin complexes (CO), should be low spin comelex. (4) (c) (Fer JO is high spin complex is correct. (@ _Ni(CO), is high spin complex 25. The magnetic moment of CO® in tetrahedral shape is: | (¢) Co© has Sunpated electrons so (a) 4.878.M. (b) 1.73 B.M. p= V30+2) = 15 = 387 BM _(c)_ 3.87 8.M. (d)_ 5.87 B.M. (c)is correct. 26. The magnetic moment of Co® in square planar | (2) In square planar complex of co® complex is: ‘only one e~ is unpaired. So 1 value is (a) 1.73B.M. (b) 3.87 BM. Vis?) = = 1.7328 (c)_ 4.87 BM. (d) 5.87 B.M. (2)|s correct. 2. [(cHH,0},1© ion has d-electrons equal to: (b) In cat Cris in +3 0.S. and (a) 2 (b) 3 thas configuration 45° 3d! 3d! aa! 30? (c) 4 (d) 5 3d. It has 3 unpaired electrons. (b) is correct. 28. Which has highest paramagnetis (a) ja acbestj paramaznatian | meant (Se eee iyLnsir Lol epeafectiee highest number of unpaired é8. Fe has - © ® 4s%3d, In FeO 3 and has 4 (a) [Fe(H,O)) (b) [Cr{H,O)el a \ . ® ® unpaired &. No other metal ion has this (ce) (CulH,O}J© (¢) (Zn(H,0), much no of unpaired electrons. So option (a) is correct. CRYSTAL FIELD THEORY (CFT) 2%. The colour of [THH,0)_]© is due to: (€) Electronic config, of ays ~ Asad (a) presence of water molecules nn® there Is only one @ in one of d- (b) _intra-molecular vibration rb, He I ay orbitals. By absorbing (c)_ d-d transition of electrons in T® ion Cea easy ol chiar (4) d-d transition between metal atoms ¢¢-d transition of electrons and colour is shown due to this transition, 30. Which one of the following is coloured? ) mH () IsetHoJ® (©) ntHol® (a) TriH,0)1© [9 7 has two electrons in. fy crbitals. They can promote to eg and colour is shown in visible region Sc®, Zn® and T do not have any electron int otitals, So (ais corect.dimi Inorganic Chemistry (Manual) (c) In crystal field theory splitting of d- orbitals is supposed fo happen, when ligands approach the central metal alom or fon. So, shape of d-orbitals is essential to understand. The concept of shapes of d-orbitals is essential to understand, the theory of complexes by: (a) Valence bond theory (b) Molecular orbital theory (c) Crystal field theory 'd) _ Effective atomic number rule 32. There are two scales of energy to measure crystal fleld splitting. Which is true from the following? (2) Ag=10Dq — (b) 0.4 A= 6Dq (c) 0.6A)=4Dq (d) Allare true You have d‘ system. How much is the difference of energy in e, and f,, for a weak field and a strong field ligands when central ion is same?, (a) 8Dq (b) 5Dq c) 16 ‘d) 10 (a) Ao = 10 Dg, Total splitting in CFT is thought be Ag and it Is divided into 10 parts, Each part is called Dg. (c) For dé system CFSE is -6 Dq fora weak fleld ligand and Is (-16 Dq + p) for 33. a strong field ligand. (a) The value of 1 B.M is 9.27 x 10-2! 34, The value of one Bohr Magneton is: erg gauss~, (a) 9.27 x 10-7" erg g-! (b) 92.7 x 107" erg g-! (c) 5.88 x 10° erg gt (d) 5.8 x 10-2! erg g~!MULTIPLE CHOICE QUESTIONS Choose the correct option: Curie is the unit of radioactivity (Seif s.Kit) according | (®) According to ie definite of Cue he to which it is the mass of radioactive element which dala oe produces: (a) 3.7 x 108 dps (b) 3.7 x 101 dsp c)_ 45x 10% dsp (d) 45x 10% dg 2. The ratio of Curie and Rutehrford is: gc i (a) F=4.5x 10" (b) qe45 x 10" (c) g is the ratio of curie to Rutherford. 10 Itis re = 37 x 10, Hence option (c) is correct. c () FF37x 10 @) G=3.7 10! (d) a-tays are +ve, deflected to -¥¢ plate. B-rays are —ve, deflected lo ¥@ plate. y-rays have no charge so remain undeflected. (d) is correct. In Rutherford's experiment of separation ( ofa, B and y-tays, the (2) o-tays are deflected (+2) towards positive plate b)_ Brrays are deflected towards negative lateNuclear Chemistry 17; b lowards any plate “rays remain undeflected (& The mass of an c-particle is: (a) four times the mass of one amu Pp a (b) four times 0.166 x 10-% kg (c) four times that of H-atom (d) all are correct ‘Atha options (a), (0), (e) are saying the’same thing, 1 amu = 0.166 x 10-2” kg So mass of an a-particle = 4 x 0.166 x 10°77 kg = 0.664 x 10°77 kg Ax i078 kg is conect. {b) y-tays have no charge. It is the charge of hitting particle which ionizes the gaseous particle. The ratio of lonizaing power is x: B27 10000: 100: 1 So (b)is correct. (a) " Isotones have same no. of neutrons. If difference of Al-mass and ‘At. No. of both atoms is same, it means lonizing power (=3uSLt.77) of ol (a) _y-rays is more than those of B-rays (b) -rays is less than those of c-rays (c) c-rays is less than those of B-rays (d)__B-tays is more than those of «-rays 6. Two elements A and B are isotonic (Lu 7177 & 1) having atomic weight 54 and 56 respectively. if the atomic number of A is 26, then the atomic number of B | no-of neutrons are same is: : GH -26=N CAR No.of nol A=54~26= 28 a) 28 (b) 30 No. of 1 of B = §6 — 28 = 28 a 7 avo Option (a) Is corect. 78Ge is: 76-32=h 7. Anisotone of 37Ge Is: eed Oe of neutrons. fa, 4 (a) 3Se (b) 3Se isotones. 7% n (d) Ge {)_ais 7 )_a ARE (0) Isobars are the atoms of different 8. An Isobar of 29Ca is: nator | elements which have same mass (a 3A (b) Rar <¥ (pW | number but difernt At. No. So 3gCa © 2a () ca GY and gr are isobars, They have ® wert nod P=2and 18” © = 20 and 18 n= 20 and 22 7 {a) The number of neutrons in both are 9 3gAs and use are Isotones because both have 77 ~ 33 = 44 and 78 ~ 34 = 4, s0 both (2) same number of neutrons ate isotones. Option (a) is correct. {b) same number of protons 5 (C) difference of atomic mass by one unit _ ——_(@)_ difference of atomic number by one unit 8 "Uy Gr, Mal and 4Na are the isotopes with (@) odd protons and odd neutrons (b) odd neutrons and even protons (C) even protons and even neutrons (@) odd protons and even neutrons 8 (d) ji p=3° n=5, (odd p +even n) 9 oF p=9 n=10,(oddp +evenn) a Al n= 14 (odd p + even n) 2% yiNa p= 11 n=12(oddp+evenn) They all have odd prolones and even aA. imi Inorganic Chemistry (Manuaj I) ARTIFICIAL DISINTEGRATION The conversion (J) of {Al to ul by bombarding | (@),"?2 reaction has two slps. with o.-patticlees: whl + se ——> isP qh (a) was done by F. Jlolet and Iren curle iP > Sle Pos (b) emitted a neutron in the first step to give Py Option (2), (b) and (c) are al ieee (c) re a poston when ? in stabilized to give si stalements. So (d) is correct. (@)_all are true i 12. ‘The conversion ( ') of Na to Ng by deuterium in ®, Nee . Maely # > Navy artificial ((f +) transmuations involves the emission of " yg —: Aye 9 12 M2 at a A proton and a positron are emitted, on stn sommpones tol (c) proton and a neutron (d) positron and a B-particle 13. A neutrino is produced during: {a) The raed Ps ° (a) conversion of neutron to of ——> qH+_4@ + oy (neutrino) (b) conversion of proton to aon . ‘So option (a) is correct. (c) evolution of a B-particle only (d)__ combination of proton and neutron 14, Suggest the correct option to get a proton when () tNa+ tH agen (@) Lis bombarded with a-particle Tustte — “beln (b) 7'Na is bombarded with {H wen Ate (©) SLlis bombarded with 30 Hsopeen tl conect Ths Ioan n . git O—> ue (d)_,,Alis bombard with neutrons 15. The conversion of sLi to "'B with a-particles is a: ne ie 2, (a) (a,n) reaction (b) (a, y) reaction fadaonidoe a) and option ti {c)_(cp) reaction (d) (a, D) reaction a 16 ate The reaction is 16. When 9F is converted t — a et fo 5 O by proton bombardment, 8 + ‘We o— KostHe (a) (2) (p,a) reaction (b) (p,n) reaction esi ana (c) . teaction_(d) D) reaction 17, When 4g? is bombarded with a then 4g? is produced alongwith ,H. Which of the following is the intermediate (6) The reaction is 3 wet tt — 8 in this nuclear reaction? Bs Near B x is tion (¢) 5 (a) yP (b) \P So, hh Wi i (0,7) eae fa opt 3 ©) 6S (d)_None of themNuclear Chemistry 179 “48. The neutron was disco Tye Moat 18. fae ered by Chadwick In 1934 ©) pile — 4 Si+,H a 4 0,1 (2) Aland using c-patiles as projectie as Ho—s sen 9 The reaction is (b) Be and using a-particles as projectile aa 4 4) ‘ (8 + Ha —> Coop (c) Ll and using a-particles as projectile Only (b) is correct. (d) All of them are true (6) The reactions 19. 7 Fr was missing in the Mendeleev’s Perlodic Table and it was synthesized (t/ Lt) by artiicial| ‘sgRaryn —> oRargr transmutafon (L472 A) from, Bey. Phe oi or Bie 8 Ba (C)_gRa (@)_ Mo a 7 20. PU, Which is a transuranic element (Ui sib seef2z) | (@) wre at on option (a) was prepared from: BU +e) —> -eNo+ 4B option () @ au by neutron emission Tha racon woes (b) Np by electron capture process peel targ (ption (2) (©) Uby neutron bombardment (@)_Np by Bedecay 21. Binding energy per nucleon of sB(c_y» Sewer | (a) BE. for ul 0.081 x 931.5 MeV + =754515 MeV CAdv dS ug FLL) with mass defect 0.081 is 7. 75.455 MeV '= 6.85 MeV (1 amu = 931.5 MeV) as (a) 685MeV (b) 0.685 MeV 1 (c) 685MeV___(d) 6.85 MeV So, option (is correct. 2. If the mass defect of 2A Is 0.09 amu, then binding | (0) 8.E. of A= 0.09 x931.5 Mev = 83.805 MeV energy per nucleon of A is (1 amu = 931.5 MeV): (a) 931.5MeV (b) 9.315 MeV (c) 838MeV (d)_ 83.8 MeV 5 = £3805 - 9315 Mev So, option (b) is corect. 23. One of the following nuclei is unstable ( is that? (a) “Be (o) 5N ( $B () 40 Ba f= 15, This rai is very hgh for light eb light elements, so Is unstable.Iimi Inorganic Chemistry (Manual) : One amu is equal to: (a) 931.5 MeV of energy (b) 1.66 x 107” kg of mass (a) First three options (a), (b), (c) are all saying the same thing, so option (d) is correct. You can interconvert eV to J, kd and mass elc. (c) 1.492 x 10° d) _all are correct The mass defect (if uz =< of He nucleus, is 0.0303 (@), The eeseen in (a) (B) and (¢) amu. It means that, (a) _ binding energy of nucleus is 28.224 MeV (b) binding energy of nucleus is 28.224 x 10° eV (c) _ binding energy per nucleion is 7.0745 MeV (d)_ all are correct The BE. of He = 0.0903 x 931.5 MeV = 28,224 MeV +M=10° BE, = 28.224 x 10° eV BE/Nuc B = 7.05 MeV 4 The statements in (a), (b) and (c) are vrect. So (d) is correct. = Pe 6, (d) B.E. of ogFe = 0.51262 x 931.5 = The mass defect of Ste Is 0.51262 amu. The binding | 26. energy associated is: aoe ee y (a) 477.5 MeV for the whole nucleus 5-852 MeV (b) 8.52 MeV for one nucleon 4136 x 10-72) (c) 1.36 x 10°"? J for ck eet a i all aa correct ee So, option (fis comet 27. The nuclei with magic numbers (17S) are found: | () The nuclei with magic number are in (@)_insmaller quantities in nature tal A I a (b) in greater abundange in nature nuclear reactions. (b) is comet “ (c) to be most reactive in nuclear reactions (d)_to be least stable * 28. The nip ratio of nuclei having atomic mass more than {(€)_There is hardly any stable nucleus 160 are: having wp ere than 1.50, The best (@) 125orless (b) 1.25 to 1.90 range rus ove alt 208 192 . i F ()_1.49-1.50__(d)_1.70 and above grea nce 29, Th i whi Ceietyolas the stability belt (©) HPhas much more than p, then Scher f the point lies above the stability belt 5 cher Ore o The nucleus rich in protons lies below j toy catenin stability belt. (c) Is corect. () Is correct. (4) _all are correct 30. The nuclei above the stability belt gain stability by: | (a) The emission of particles increases protons, and decrease (a) emission of B-particles (b) emission of a proton (c) electron capture process (d) positron capture process neutons. So, the ratio 5 falls and nucleus becomes stable (a) s correct.nuclear Chemistry ot. (<2 L139). In this way: (a) Ne increases its n/p ratio (b) Ne decreases its n/p ratio (c) falls even below the stability belt Bs, aNe Is converted to 11Na by positron emission | (6) fate p=10,n=13 Pp ni pit = 1.09 Na p=t1,n=12 So 5 ratlo decreases and comes within the range of stability belt. (b) is correct. (d)__none of above is correct itron emission by an i lity to it by: Those isotopes which are below 32. Positron y an isotope gives Stabilty to it by: Ce ee owns poston he tie (a) moving up towards the Stability belt way protons decrease and neutrons (0) moving down towards stabiity belt ae (c) does not change n/p ratio Increase. So 5 increases and it enters (d)__moving up or down the stability belt the stability belt. (a) is correct. FISSION AND FUSION 3, What is the amount of energy released in kJ when 19 | @) to of alone in 1 g of SU = of ‘g2U%% undergoes fission in the fission reaction 6.02 10% | aq" + an! —» Fission products + Neutrons +320 235 "4 1 For one atom the energy released is pias 32010, (2) 6.55 105kJ (b) 8.20 x 107 kd For A aloms = Ax 3.20x 107" J (©) 18.60 10%kd (d) 12.75 x 10° kJ ©2010" J 8:20 10"7Kd (b) is correct. 44. What is the number of neutrons accompanying (t.s.7L-) Cae the formation of ‘Xe and {sr from the absorption (tx 4) of slow neutron by 3SU during fission Busy — Sire She oz (0) Is comect. (£2 92 @) 0 (b) 3 7p (@)_4 "The fissionable material commonly used in atomic | (a) eu undergoes fission very easily mb is: by slow neutrons. (a) is correct. (@ %u (b) 2Th () %u () Pu The enormous energy (AL 5c) due to explosion Of Hsbomb is due to: [2 fission of ttium to form helium (©) fusion of deuterium and tritium {fusion of 7H nuclt to form helium nucleus fission of uranium (0) The reacton's TH+ jH —> tHe +n + 17.06 Mev 22 tH+]H—> He +fn+3.3 MeV (b)is correct.182. ‘37. * The source of huge amount of energy in a fission reaction is: . (a) due to fast moving neutrons emitted (b) due to gain of mass in the nuclear reaction (C)_ high stability of product nuclei as compared to parent Iimi Inorganic Chemistry (Manuay (@) This the Toss of mass in fasge process, which is responsible for eloare of energy. (d) is corect. (d)__due to loss of mass in the nuclear reaction { | (8) The chain of reactions is ——— 233, 38. BU -and “aU are both fissionable (2.5 u7/u7) GU has to be synthesized by: s (a) neutron bombardment of 4, U (b) neutron bombardment of @ Th = (ejection of B-partcle from =Th (d) electron capture process (Od Sue Se i) 39, The energy liberated (torte) in the fission of one atom 235, of »2Uis: (a) 200MeV (6) 100 Mev () 931.5MeV (qd) 500.5 MeV 40, The energy in MeV ibrated in the fision of 1g of =U is: (@) 822% 107d 6.022 x 10% (oy OR A0" 200 MeV (c) equivalent to buming about 2.5 metric tons of coal (d) all are correct 41. Anuclear reaction given as: (b) Its the combination of two lighter + 7 __, Hel + ont is an example of: (@) - nuclear fission (b) nuclear fusion (c) _attificial tadioactivity (d) _ radio disint ration Point out a thermonuclear reaction Friars (ree rere Wd sf, 2): +), APT+ Het, sP% + nt 0) 4H, Hete2 ae? ©) Usp, oND™ + 09 (@) V+ cr, aC +4 nt ee EY 42> 233, i a +$e. m0 St, que ie This is a biting of one gn to “rh and emission of two P-partces, ts correct. (@) Reduced mass fr one aiom SU = 0.215 amu ~ Energy librated = 0.215 x 931.5 MeV = 200.24 MeV Hence option (a) is correct, (6) All he frst three options (ao) and (6) are correct statement and’say the ‘same thing. So option (d) is correct, Nuclei to form a heavy nucleus, so is @ fusion reaction. (b) is correct. 7 (b) The combination of 4H to give He sa fusion reaction and is a big thermo- ‘nuclear reaction. It gives a lot of energy in the form of heat. (b) Is correc.Nuclear. Chemistry Sooo ES (@) For a fusion reaction to take place, 43. 44, 45. (d) all are true 46. 47. 4B, 49, thermo-nuclear reaction because: _(c) Bubble chamber _(d)_Electrometer A fusion process (¥ ui, SE 1) is also called (a) it evolves more heat than atomic bomb (b) it only gives heat energy and no light energy (c) itis highly spontaneous (d) an atom bomb is to be exploded for fusion to take 183 first an atom bomb Is to be exploded which gives heat for fusion to start. (4) is correct, place DETECTION AND MEASUREMENT OF RADIOACTIVITY Which of the following i (a) Cyclotron is a device to accelerate following is not used for detection the charged partes, A (t601) and measurement (1) of radioactivity? (a) Cyclotron (b) Cloud chamber lonization chambers are used for: (a) measurement of intensity of radiation (b) analysis of transmutation (c) measurement of neutron-induced radioactivity Which is not true about G.M counter? (a) The tube contains 90% Ar and 10% ethanol (b) There is no use of amplifier (c) The pulse produced is 10 pv (d) A, D.C potential of 1000 V is applied Asclentilation counter does not involve (a) the passage of high energy charged particles (b) a transparent material through which the particle passes (c) the movement of electrons to higher energy levels (d) the light emitted having wave lengths of visible jion onl} In Wilson cloud chamber: (2) ions act as nuclei for condensation of charged ._ Patticle (b) there happens the ionization of air or gas there in (c) can be used to determine the momentum of charged particle RADIOACTIVE SERIES (d) all are true particles can be used as projectiles in artificial radioactivity. (a) is correct. (d)_ The statements in (a), (b) and (c) are true for ionization chamber. So, (d) Is a correct choice. (4) is correct. 1b) Anpliieris mustin GM. counter. All other statements are true in options (a), (6) and (d).(o)is comect. (@) 1 three statements in options (a), (0), (€) do involve in scientilation counter. So option (d) is correct because light emitted is not necessarily of visible region. (@) For Wilson cloud chamber the options (a), (b) and (c) are correct statements, So option (d) Is incorect. Which of the following element belongs to 4n series? | (a) “rn is ulimaely converted to (a) Pb-208 () Pb-207 (b) Bi-209 (@) Pb-206 ™'pb. itis called 4n series. Where nis simple inleger. If mass no. of all the members are divided by four then there is no remainder. (a) is correct.“85. Radio-carbon dating Bieiejge Imi Inorganic Chemistry (Manuay 184 : SO, An element A loses one o: and two B particles in three | (©) lrtones hava same Tope eins "successive stages. The resulting element will be: expats. doreases mass nc! a) Aitself (b) anisotone of A and atomic number by 2. Loss ct 2p +(e) anisotope of A(d) anisobar of A particles compensate the At. no. ang makes il sam i =, rn Po uPo > = i b) Statement in option (6) 1s 51. Which of the following statements is true? eee eaaae ahs @ Bpatt () I avanti Br abs to pros and | Pen = a “ ‘ gain of two neutrons proton, ‘ (b) In B-emission one neutron is converted into one proton 4 (©) In positron emission one neutron is converted into : ‘one proton / (@)_ In electron capture one neutron is converted into ‘one proton. 52. The emission of one B-particle: {d) The emission of one. p-partice {@) Increases the atomic mass by one unit Pomp 2 nautton fo proton and atomic (b) deci the . mass by ‘one unit number is increased by one unit, (c) decreases the atomic number by one unit (d) _incregses the atomic number by one unit 53. How many @ and B-particles are to be emitted for the | (@) Tn tis sequence of reacions aonic 2m mass is decreased fe conversion of 34 PO to gy Po? atomic number vonein hee (a) Two a-particles because emission of 28-paticles (b) One ct and three B-particles Fee a P- tnle: of lone (©) One cand one B-particle : amet _ —One ci and two B-particles ~ APPLICATIONS OF RADIOACTIVITY 54. The proper rays for radio carbon dating (4x, Fre tL eto AE) are: (2) X-rays (©) UV rays” . \ |. Radio-carbon dating fs Felated with: (@) radioactivity of (C0, - ~* (b) UV radiation of sun which atmosphere to "ic Converts nitrogen of ; : (©) decay constant ofc produced from "N (0) the fact that “\c is not emitter (b) Nirogen of atmosphere is converted to GC by cosmic rays in the upper atmosphere and “fc is. source of developing a way of rato carton dling (b) is correct. _. © 4c is not radioactive and decay constant of conversion of AN to WC does not matter a al. The amount of 6C Produced is concemed with the carbon dating of living and dead animals and tees. ‘$C is 9 emir. (6) is correctNuclear Chemistry 56. The process of rock dating (1 ¥L Seip. 4 usta) involves the study of: (2) radioactivity of U (b) radioactivity of @U (©) , formation of Pb (d) formation of 27 Pb 185 0) 78U decays to Pp and this ‘conversion Is employed for rock dating. | (a) The materials n (a), (b) and (9) are 57. He reve following is used in radiotherapy all used in radiotherapy 80 option (é) jt)? correct. (a) Radioactive Na—24 9 Bewin opse: (b) Radioactive | — 131 (c) Phosphorus-30 and cobalt-60 (d)__Allof them 58. 4Na is given in the form of 24NaCl to the patient. It | (a) Na is radioactive and help to helps locate the exact positon of a tumor or (a) to locate the exact position of a tumor or clot Ca (b) to follow the flow of blood (C) to treat the skin diseases (d)__for the treatment of cancer 59, P-32 is radioactive and (a) P.32'is a B emitter and is used for (2) B-emitter and is used for skin diseases Shin Giseases. Hence opfon (2) is (b) is very essential material of phosphorus fertilizer . (©) is used to increase the phosphorus content of our planet ———_(d) cannot be used for skin diseases 60, {b) In photosynthesis the equation of In photosynthesis the O, is released (ts GuG) by Plants. 0-18 is used as a tracer. Which information out Of following is correct in this regard? (2) 0,is released by CO, (b) 0-18 evolved is analysed by mass spectrometer (C) 0-18 used as a tracer is detected by radioactive procedure (@) ©, being released does not come from water labelled oxygens 2s flows. CO! +12H,0 —> CyH,,0" +60, +6H,0" % released does not come from CO, ~ 18 is not radioactive. 0, being cael comes from H,0. Heavy Isotope of "80 is analysed by mass spectrometer. (b) is correct.L_chRoWATOoRAPAY — ag Partition chromato. raphy is: (a) a technique j wich ue in Which mixtures of Substances bh cl are separated stalonay ha ne ween the moving solvent and a (b) nota liquid-liquid chromatography (c) not gas-liquid chromatography (d) same as adsorption chromatograph 2. Separation of com nent i era, ponents (tf fi ¥ Ur”) in paper (2) involves differential migration (‘Se AZ-L 353) (b) is not due to differences in Partition co-efficient () water acts as a Moving phase present in the cellulose of | Paton cronaogaaa- IS a iid and gas tos Chromatography and ig ferent from adsorpion yy. Hence option (2) is corect. (ais comect (@) The “separation of Components is due to different’ Ky values, and Waler acts as a stationary Phase in cellulose. Organic liquid does not act’ as a filter paper Stationary phase. Itis actually (d)__ organic liquid acts as a Stationary phase sera raion: 2) a 3. Ina adsorption Paper chromatography: (c) In adsorption (a) many solvents are allowed to flow over the unknown chromatography filter paper component is impregnated with an g the R, value cannot be measured ¢) the filter paper is impregnated (tt) with an adsorbent (d) _ the adsorbent may be a solid substance 4, The operations (Sis) involved in paper chromatography are: (a) choice of filter paper (b) choice of solvent (c) preparation of solution ; (d) all of them adsorbent. The adsorbent may not be a sold substnace. (cis correct. (@) The options (a) (oh (@ ate indicating correct aspects of operations in paper chromatography So,, option Wis conect In paper chromatography the technique is: (@) ascending — (b) descending (c) radial development (d) “allof them (d) In paper chromatography the techniques which are involved are ascending, descending and racial development. So (d) is correct option. Sada 6 Which is not locating agent (:suls_/,) in TLC, Ce) SHSOu reed ion (2) iodine only —(b)_H,SO, only * + ©) _H,SO, mixed with an oxidizing agent (4) _H,SO, mixed with ceric sulphate The preparation of chromatogram in thin layer Chromatography involves: (a) silica gel as absorbent (b) plaster of Paris as binding material i (a the separation of amino acids is done on cellulose powder oxidizing agent is used as a locating agent in thin layer chromatography. (c) is correct. (@) The statements in options (a), (0) and (c) are rue for preparation of chromatography in TLC. $0 option (d)is corel. ———_d)_all the above mentioned92 Ilmi Inorganic Chemistry (Manual) One of the following is not used as a adsorbent (LS eGo J») in column chromatography: (a) Sucrose, starch and charcoal (b) Na,80,, CaCO, and MgSO, (c) Alumina and magnesia (d) “All of them The |; is extracted from water by using a extracting solvent in ‘separating furnel. In this process, (a) CCl,is used as extracting solvent (b) the amount of |, is determined by volumetric method (ec) CCk is immisible with H,0 (d) all above are true statements (@) All the materials given in options (b), (c) and (d) are used as adsorbent, so option (Qs conect. (@) The process of extraction Of |, from waler is done by CCl, as extracting solvent. CCI, is not miscible with H,0. I, is. determined by using NaS,0, solution in volumetric analysis. So all statements In (a), (b) and (c) are correct. (0) is correct 10. The solvent extraction (U6 245 £2441) is based on-one of eee ream m following phenomenon. Indicate that: adsorption, but only on (a) Distribution of solute in two liquids distribution of solute in two (b) Absorption liquids. (a) is corect. (c)_Adsorption _(d)__None of above : : 11. A separating funnel is the most suitable (—t) apparatus for a | (¢) Separating funnel is a simplest apparatus (0 do (a) continuous extraction (M¥2.< JY) extraction. It is employed for (b) multiple extractions slngle-batch extraction. (c) (c) _ single-batch type of extraction correct. (d) counter current extraction ae eT 12. Ryvalue in paper chromatography is the value is (9) reo owt sei ea (b) rate of flow of solvent do with the rate of reaction. (c) rate of reaction (d)is correct. ¢) of distances travelled by solute and solvent — 43. The most common adsorbent (usd ie40) used in TLC is: | ©) Sica gel is. rest (a) cellulose (b) silica get TLC. + (c)_glassbeads__(d)_ alumina 14, Column chromatography is o Coleen Sree (a) ion-exchange chromatography chromatography. (b) partition chromatography . (c) adsorption chromatography . (d)__ absorption chromatogray - 15. Which of the following phenomenon in column a nore rol hvoted chromatography is not involved? in column chromatograph. It (a) Jon-exchange (b) Partition involves ion exchange, (c)_ Absorption _(d)_ Adsorption __ patttion and adsorption.