FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – IX
PAPER –2
TEST DATE: 14-05-2023

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

Section – A
1. B
8
Sol. Using symmetry equivalent resistance is R
5
2. A
1  1  2 
Sol.   1  
f1   w  R 
1  2  2 
  1   
f2   w  R 
1 1 1
 
f f1 f2
2 2  1  2 
  
R R   W 
( w )  (1  2 )
4
(1   2 ) 
3
4
22   2 
3
4
2 
3
8
1 
3
3. A
0N2 r 2 r
Sol. L


Where N is total number of turns

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 2

Let total length of wire is  0 .

2
0  2r.N . r 2 0  20
Then L   …(i)
4 4
0 2 20 d.  20
R  . 0  
A V m / d m
V is volume of the wire.
mR
20  …(ii)
d
L  m
From (i) and (ii)    0 .
R 4d

4. C
   
  R  R   3  2
3   R
Sol.    60
0 0
3R

5. A, D
Sol. 
K1  8K  25K cos2 37 2 
K1  40K K1

K 2  40K  50K cos 53 2

K 2  40K
20K
K equ  10K
m
T  2
10K
K2

6. A, B, D
Sol. Ek  5.23 eV , W = 7.52 eV
Ionization energy of H atom = 13.6 eV
(A) Energy of photon = 5.23 + 7.52 = 12.75 eV
Rhc 13.6
(B) En   2   2 eV
n n
E1(n = 1) = 13.6 eV
E2(n = 2) = 3.4 eV
E3(n = 3) = 1.51 eV
E4(n = 4) = 0.85 eV
E4 E1 = 0.85 + 13.6 = 12.75 eV
So, the transition is from 4 to 1

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 3 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

nh
(C) L 
2
4h
L1(n  4) 
2
h
L 2 (n  1) 
2
3h
L 
2

7. A, C
2
 R  I
Sol. I  Icm  m  R  cos37 
 2 
Icm
 2 2
R    2
 I0  m  cos 37    mR 2  1   C.M
 2    5 I0

2 4 9  R/2
2
 
3 25

25  mR 37° 37°
 
C
13
 mR2
15 R/2 cos37°

8. A, B, C
Sol. x = S1P  S2P
d cos = n …(i) P
xmax = d = 10
n = 10 
n = 10 dcos
from equation (i) for the 4th bright ring 
 O
10 cos  = 6 S1 S2
3 d
cos  
5
 = 53 D
wall
3 D
cos   
5 D  y2
2

9D2 + 9y2 = 25D2

8
y m
3
For dark ring path difference is
 3 5 7 9 11 13 15 17 19
, , , , , , , , , ,
2 2 2 2 2 2 2 2 2 2

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 4

9. B, C
Sol. F   BI2 dy sin  B

0I1  
y
F I2 dy  
dy
 2 
2 2  y2   y
2

4 y
3 Q
 II ydy I1 x
 012 
2 3  2  y 2 
I2
4
 II  16   I I  16 
 0 1 2 ln    0 1 2 ln  
4  9  4  9 

10. B, C
Sol. Let maximum displacement of centre of mass is h
1 1
mgh = 2kh2  k(2h)2
2 2
mg
h
3k
For the velocity centre of mass
2
mgh 1  h  1 1 3 
 2k    kh2   mv 2 
2 2 2 2 2 2 
g m
v=
3 k

Section – B

11. 8
Sol. equilibrium of elemental part dy y dy

GMrA 2 dy sin  Q
dpA 2  R/2  r
R3
3R
P 2
GMydy
 dp  
P0 3R
R3
8
39GM
P = P0 + …(i)
128R
Using Bernoulli theorem
1
P = P0  v 2 …(ii)
2
From (i) and (ii)
1 39GM
v
8 R

12. 5
Sol. vmax  A sin 
6
 1.2   = 0.4 m
2

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 5 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

T 320
v   40 m/s
 0.2
40
v = f  f =  100 Hz
0.4
 = 2f = 2(100) = 200
2 2  1  2 
 x   
 (0.4)  30  12 6
   0.50
v max  (0.25  102 )(200)sin      0.25 m/s = 25 cm/s
6 2

13. 3
Sol. E   B  r  dr r P
  r2 
  B0  1    dr  r
 2  dr
0  v = r
 3
r 
 B0   r    dr  r
 2 
0
3 O
 B0 2  0.75B0  2
4

14. 1
Sol. For the first container work done
W 1 = nRTn2 …(i)
For the second container work done
nR(T  Tf ) 
W2  T V  1  T2 V2 1 
 1  1 1 
nRT(1  21 )
W2  …(ii)
 1
W1 = W2
(   1)n2  1  21 
Hence, x + y + z = 1 + 1   +   1 = 1

15. 5
2(80)
Sol. Time of flight T   16 s
10
Let t0 is the time when ball collide with the wall. Then,
60t0 = v0(16  t0) …(i)
v0  horizontal component of velocity of ball after the collision
v2  v1 = e(u1  u2)
1
10  v0  (60  10)
2
v0 = 15 m/s …(ii)
from (i) and (ii)
16
t0 =  3.2 sec
5
So, separation = 50  3.2 = 160 m

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 6

16. 6
Sol. Equivalent resistance across AB 12R 4R
RAB = 8R
Equivalent capacitance across AB
CAB = 3C A

12R
 = (8R)(3C) = 24RC 24R 24R
B

17. 5
2S
Sol. For A, 1V   0.25 mm
8
Least count of A = 1  0.25  3 = 0.25 mm
3S
For B, 1V = = 0.6 mm
5
Least count of B = 2  0.6  3 = 0.2
Difference = 0.25  0.2 = 0.05 mm

18. 3
Sol. In case I:
4T
P  P0 
r
Now radius ‘r’ increases to ‘3r’ due to charge on the soap bubble
P1V1 = P2V2
4 4
P r 3  P2 (3r)3
3 3
P
P2 
27
In case II:
2 4T
P2  1  P0  , where 1 is final charge density (1 = /9)
20 3r
P 2 P  P0
  P0 
27 162 0 3
 2 9 
 P  P0 
 480 4 

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 7 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

Chemistry PART – II

Section – A

19. D
Sol. It is an example of anti elimination via E2 mechanism. Hence, meso gives trans alkene.

20. C
Sol. NO 2 NO 2

Na/liq.NH
3

C H OH

2 5

21. C
Sol. CrCl3  NaOH  Cr  OH 3   NaCl  soln 

H2 O2 NaOH
Hg2 NO3  2
AgNO3
Ag2 CrO 4  
 Na2 CrO4
brick red ppt. yellow solution

NH2
Hg  Hg 3

NH
 Hg2 Cl2
Cl white ppt.
Shiny black ppt.

22. A
Sol. Nodal plane in 5d orbital are
n   1 5  2 1 2

23. A, B, C, D
Sol. Br H
Br
D D
Br D
SN 2 H D E
2
  H  

H
H
H I D
D
I
I Syn e lim ination

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 8

24. A, B, C, D
Sol. H
CH CH CH3
F CH CH CH3
NH
2
  CH CH CH3
F
H
C
O C CH3 NH2 C
N(CH3)3 O C CH3
C
N(CH3)3 O C CH3

CH CH CH3
CH CH CH3

C
C CH3
O O C C CH3

NH2
ROH

CH CH CH3

C
O C H CH3
NH2

25. A, B, C
8
Sol. PQ  PNH3  4
2
 K eq I  4  4  16 cm2 Hg
26
Pz  PNH3   13
2
 K eq II  13  13  169
P  s   Q  g   NH3  g 
Cx x x B
Y  s   Z  g  NH3  g
A B B Bx
 PTotal  x  B   x  B 
Also, x  x  B   16
B  x  B   169
2
By adding  x  B   185
  x  B   13.60
 PTotal  2  x  B   27.20

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 9 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

26. A, C
200  0.9
Sol. Moles of HCl   0.18
1000
200   0.45  2 
Moles of Ba  OH2   0.18
1000
Thus, H   OH  hence no reactant is left unreacted.


r Ho   0.18  56.2 kJ mol1 
 10.116 kJ
Hcaloremeter  CP T
 450  T
Hsolution  m.s.T  400  4.184  T
Htotal  450T  1673.6T
10.116  103  2123.6T
10116
T   4.7636  4.76
2123.6
T2  4.76  21  25.76o C

27. A, B, C, D

Sol. AlCl3 .6H2 O  SOCl2   AlCl3  HCl  SO2 

Al2 O3  Coke  Cl2   AlCl3  CO 

Al  Cl2  dry    AlCl3

Al  HCl  dry, gas    AlCl3  H2 

28. B, D
Sol. Ag and Mg2 don’t give coloured bead.

Section – B

29. 2
Sol. Molality = m, molarity = M, density = d, molar mass of solute m 
1000M
m
1000 d  Mm 
1000  4.0
2.273 
1000 d  4  60
d  2.0 gm / ml

30. 2
Sol. a  2R  1.35
3a  4R
1.73
a a  1.35
2
1.35 o
a   10 A  10  10 8 cm
0.135

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 10

zm
Density  3
a  Nav
2  600
  2 gm / ml
10  10   6  10
8 23

31. 8
Sol.
B(x)

A C(y/2)
a-x-y-z

D(z/3)

d  A  dx dy dz
   
dt dt dt dt
d B  1 d C 1 d  z 
  
dt 2 dt 3 dt
 1  A   2  2  A   3  3  A 

   
  60  10 3  2 25  103  3  5  10 3
  125  10 3
1 1
tavg.    8 sec .
 125  10 3

32. 3
H 27.6  103
Sol. T   276 K  3o C
S 100

33. 2
0.059
Sol. 0.58  0.521  log102
n
n2

34. 5
Pb
Sol. Z  1
RT
b / RT  0.02

PV
50

P
PV  nRT  50
 2RT  50
RT = 25

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 11 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

 b  0.02  25  0.5
Excluded volume for 10 moles = 10 × 0.5 = 5

35. 4
Sol. Ni  4CO  Ni  CO 4 

36. 2
Sol. n n
a a n
a b a
a b
a b
M M
M
d c e c
c e
e d
d
Cis
n n
a a n
a c a
a c
a d
M M
M
d b e b
c c
e d
b

n n
a a n
b c a
b d
b d
M M
M
e d e c
c e
a a
a

Trans
6
 2
3

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AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 12

Mathematics PART – III

Section – A

37. D
2
Sol. 3  3!  6!  4  2 – 3  3!  2!  4! = 119  (3!)  4!

38. A
Sol. Let P(–1, y1), A(t1) and B(t2), then t1t2 = –1, t1 + t2 = y1
t 2  t2
If circumcentre be (h, k), then h  1 2 and k = y1
2
2 2
 2h  y1  2  locus is y = 2x – 2

39. D
Sol. At-least 2 of , ,  must be equal. So, number of elements equals 9 C2  2C1  3  9C1

40. D
10  4  30  5  60  5  100  5  180 10  30  4  60  5  100  5  180  5
Sol.  Average Marks 
20 20
 Average marks  (58.5, 91.5)

41. A, C, D
Sol. If f(x) = f(y)  x = y  f is one-one
By IVT, f is strictly increasing or strictly decreasing
But if f(x) < f(y)  x < y  x, y
 f is always strictly increasing function
Case-I: If f(x) > x  fff(x) > x (contradiction)
Case-II: If f(x) < x  fff(x) < x (contradiction)
 f(x) = x is the only solution

42. A, D
Sol. As can be seen in graph area y
3
3 
=  cos2   cos1   sin1  cos1 2
2 2
 
 a b
2 
3
c = 0, d   2
2
x
e=0 cos 2 O cos 1 sin 1 1

43. B, D
Sol. 0  Domain of R
R–1, R are not reflexive, symmetric but are transitive relations
44. A, C
Sol. f(r) is an increasing function but not differentiable at all points where sin–1(sin x) is not
differentiable
r 2
f r    r = 0, 2, 4, .....
2
Critical points don’t form a geometric progression

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 13 AITS-FT-IX (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

45. D
           
Sol. x   y  z    x  y   z if x   y  z    x  y   z
      
x, y, x  y are coplanar if x  y  0

46. B, C

Sol. Shortest distance of point from given line =

2  2 1 
3
2  
2 1 2
The given point is on angle bisector of the planes so r  = 3  2 2 
3  2 1  3

Section – B

47. 8
Sol. k = 52  100  34

48. 9
36!
4! 9  2  1 4
 4!
Sol. P
 9! 4!
52!
4
 4!
13! 4!

49. 5
3n
Sol. Sum is C2n

50. 4
Sol. xP3  xP7  xP11  .....  xP2023

51. 1
Sol. Circumcircle of GHI is S

52. 9
Sol. Square can always be inscribed in the ellipse

53. 6
Sol. Let sides be a, b, c, then A  2 ab , V = abc
3
 A 2
Using AM – GM inequality V   
6

54. 6
  
i i i
Sol. z 4
 
 1 z 6  2z3  2  0  z = 1, –1, i, –i, 2e 4 , 2e 4 , 2e 4 2

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