Parte 1 Ordem 0 1a Ordem 2a Ordem Parte 2

Medida t (s) A A-A0 ln(A) 1/A t (s) A

1 0 0.428 0 0 0 0 0.428
2 60 0.351 -0.077 -0.1983369721159 0.512554250872 60 0.384
3 120 0.338 -0.09 -0.2360773000988 0.622131283526 120 0.358
4 180 0.326 -0.102 -0.2722258142151 0.7310360644458 180 0.339
5 240 0.315 -0.113 -0.3065505567562 0.8381545764723 240 0.322
6 300 0.306 -0.122 -0.3355380936294 0.9315252580783 300 0.304
7 360 0.295 -0.133 -0.372147839242 1.0533819103437 360 0.288
8 420 0.286 -0.142 -0.4031313847619 1.1600548983727 420 0.273
9 480 0.278 -0.15 -0.4315020818912 1.2606737040274 480 0.257
10 540 0.27 -0.158 -0.4607012365834 1.3672551055729 540 0.244
11 600 0.261 -0.167 -0.4946027882591 1.4949690263902 600 0.235
12 660 0.252 -0.176 -0.5296941080704 1.6318053701231 660 0.225
13 720 0.246 -0.182 -0.5537916596494 1.7285920522757 720 0.217
14 780 0.241 -0.187 -0.5743262620911 1.8129289952302 780 0.207
15 840 0.234 -0.194 -0.6038020802241 1.9370556753734 840 0.198
16 900 0.229 -0.199 -0.6254011920276 2.0303636289434 900 0.191
17 960 0.223 -0.205 -0.6519514241217 2.1478563346046 960 0.181
18 1020 0.218 -0.21 -0.6746281327927 2.2507073651719 1020 0.174
19 1080 0.213 -0.215 -0.6978310298724 2.3583870826203 1080 0.168
20 1140 0.209 -0.219 -0.716788943617 2.4482403970845 1140 0.162
21 1200 0.203 -0.225 -0.74591721654 2.5896597762534 1200 0.156
22 1260 0.199 -0.229 -0.7658183708573 2.6886770300099 1260 0.151
23 1320 0.195 -0.233 -0.7861236370181 2.7917565300743 1320 0.146
24 1380 0.189 -0.239 -0.8173761805222 2.9545566928745 1380 0.143
25 1440 0.186 -0.242 -0.8333765218686 3.0398954878907 1440 0.137
26 1500 0.182 -0.246 -0.855116508505 3.1580568963747 1500 0.133
27 1560 0.178 -0.25 -0.8773396452897 3.2815289299591 1560 0.131
28 1620 0.175 -0.253 -0.8943372216583 3.3778371161549 1620 0.126
29 1680 0.171 -0.257 -0.9174596390791 3.5115046182434 1680 0.123
30 1740 0.168 -0.26 -0.9351592161785 3.6159323542501 1740 0.12
31 1800 0.164 -0.264 -0.95925676776 3.7611123774789 1800 0.118

εb  0.000004583 M-1

[S]0 0.1 M (Solução estoque B0, do reagente S)

[S]1 0.005 M (Concentração na mistura reacional após duas diluições: 5 mL → 50 mL, e 10 mL → 20 mL)

[S]2 0.01 M (Concentração na mistura reacional após duas diluições: 10 mL → 50 mL, e 10 mL → 20 mL)

kef(1) 0.0019 L/mol s

kef(2) 0.0035 L/mol s
n 0.8813555 Adimens. 1
k(1) 0.4 L3/mol3 s
k(2) 0.4 L3/mol3 s

Ambas 2 ordem, m=2

 Ordem 0 1a Ordem 2a Ordem
A-A0 ln(A) 1/A
Parte 1: Ordem 0 versus t(s
0 0 0 -0.3
f(x) = − 0.000111787634408602 x − 0.084520161290
-0.044 -0.10848064299407 0.267718068535825 -0.25 R² = 0.908069079030279
-0.07 -0.1785902091811 0.456847491254634
-0.089 -0.23312308820135 0.61340390924379
-0.2

Ordem 0
-0.106 -0.28457165003739 0.76914146398096 -0.15
-0.124 -0.34209549417558 0.953025086079685
-0.1
-0.14 -0.39616271544585 1.13577362409138
-0.155 -0.44965140039684 1.32655506487282 -0.05
-0.171 -0.51004711068658 1.55460198552675 0 200 400 600 800 1000 1200 1
0
-0.184 -0.5619549702886 1.76191205760686
-0.193 -0.59953768143764 1.91887055080533
t(s)

-0.203 -0.64302279337738 2.1079958463136

-0.211 -0.67922584204134 2.27184633274474
-0.221 -0.72640440231643 2.49446927626529
Parte 1: Ordem 1 versus t(s
-0.23 -0.77085616488726 2.71405645237421
-1.2
-0.237 -0.80684976753517 2.89915349611
-0.247 -0.86062616431597 3.1884132803222 -1
f(x) = − 0.000450040505596382 x − 0.192586442553
-0.254 -0.90006789636727 3.41067783865077 R² = 0.970869678881695
-0.8
-0.26 -0.93515921617854 3.61593235425011
Ordem 1

-0.266 -0.97152686034941 3.836390908042 -0.6

-0.272 -1.00926718833226 4.07380781212557
-0.4
-0.277 -1.04184335876687 4.28606795816055
-0.282 -1.07551657387346 4.51286647036231 -0.2
-0.285 -1.09627856532189 4.65655839487615 0 200 400 600 800 1000 1200 1
0
-0.291 -1.13914226975367 4.96282147486186
t(s)
-0.295 -1.16877406736004 5.18234839435036
-0.297 -1.18392587238065 5.2971391881287
-0.302 -1.22284128863032 5.6000593383771
-0.305 -1.24693884020938 5.79363270268217
Parte 1: Ordem 2 versus t(
-0.308 -1.27163145279975 5.99688473520249
-0.31 -1.28843857111613 6.1381276730556
4
3.5 f(x) = 0.00188794061547598 x + 0.335956374752006
R² = 0.995625104632026
3
2.5
Ordem 2

10 mL → 20 mL) 2
e 10 mL → 20 mL) 1.5
1
0.5
0
0 200 400 600 800 1000 1200 1
t(s)
 1
0.5
0
0 200 400 600 800 1000 1200 1
t(s)
em 0 versus t(s) Parte 2: Ordem 0 versus t(s)
-0.35
f(x) = − 0.000150396505376344 x − 0.0784818548387096
02 x − 0.0845201612903225 -0.3 R² = 0.910088724719134

-0.25

Ordem 0
-0.2

-0.15

-0.1

-0.05
00 1000 1200 1400 1600 1800 2000 0 200 400 600 800 1000 1200 1400 1600 1800 2000
0

t(s) t(s)

dem 1 versus t(s) Parte 2: Ordem 1 versus t(s)

-1.4
f(x) = − 0.000690863800294417 x − 0.142821035178836
-1.2 R² = 0.981904413936606
82 x − 0.192586442553376
-1
Ordem 1

-0.8

-0.6

-0.4

-0.2
00 1000 1200 1400 1600 1800 2000 0 200 400 600 800 1000 1200 1400 1600 1800 2000
0
t(s) t(s)

dem 2 versus t(s) Parte 2: Ordem 2 versus t(s)

7

x + 0.335956374752006 6
f(x) = 0.00345808516156276 x − 0.0865637670434589
R² = 0.998502818803022
5

4
Ordem 2

0
00 1000 1200 1400 1600 1800 2000 0 200 400 600 800 1000 1200 1400 1600 1800 2000

t(s) t(s)
 1

0
00 1000 1200 1400 1600 1800 2000 0 200 400 600 800 1000 1200 1400 1600 1800 2000

t(s) t(s)
1800 2000

1800 2000

1800 2000
1800 2000