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Phase Test 2 (Solutions)
Phase Test 2 (Solutions)
Pleas e read the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
SANKALP2224 A&B LOT
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
1. This question paper contains Three Parts.
2. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
3. Each section is further divided into two parts: Part – A & C
4. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
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website: www.fiitjee.com.
SANKALP2224 A&B LOT-(Ph-2)-Paper-1-PCM(000000.1)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
(A) I1 + I2 A B
2
(B) I3 + I4
(C) I1 + I3
(D) I1 + I2 + I3 + I4
1. A, B, C
2. Suppose a horizontal force F is applied at the top most point of a rigid body lie on horizontal surface
of radius R and mass M.
(B) Force of friction will be forward for Solid sphere and Hollow sphere
2. A, B, D
3. A particle of mass m is projected with a velocity V making an angle of 45 with the horizontal. The
magnitude of the angular momentum of the projectile about the point of projection when the particle is
at its maximum height h is,
(A) zero
3
(B) mV /( 4 2 g)
3
(C) mV /( 2 g)
(D) m 2gh3
3. B, D
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SANKALP2224 A&B LOT-(Ph-2)-Paper-1-PCM(000000.1)-3
4. In which of the following cases the centre of mass of a rod is certainly not at its centre?
(C) The density decreases from left to right upto the centre and then increases.
(D) The density increases from left to right upto the centre and then decreases.
4. A, B
5. A, B, D
6. Rod can rotate about hinge point ‘P’. A particle of mass ‘m’ collide with the P
rod and stick with it as shown in the figure. Then,
m
3v0
(A) Angular velocity of rod is . m
4 v0
v0
(B) Angular velocity of rod is .
3v 0
(C) Velocity of centre of mass rod is .
8
9v 0
(D) Velocity of combined centre of mass of system is
16
6. A, C, D
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SANKALP2224 A&B LOT-(Ph-2)-Paper-1-PCM(000000.1)-4
7. A, B
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
(A) |U|=K=|T|
(B) K = | T | = | 2U |
(C) 2K = | T | = | U |
(D) K = | T | = |1/2 U |
8. D
0 r
(A)
2g
0 r
(B)
3g
0 r
(C)
g
3 0 r
(D)
2 g
9. B
10. A hollow sphere rolls without slipping down a plane inclined at an angle of 30° to the horizontal. Its
linear acceleration will be
5
(A) g
14
2g
(B)
3
g
(C)
2
10. D
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SANKALP2224 A&B LOT-(Ph-2)-Paper-1-PCM(000000.1)-5
11. Two masses of 1 gm and 4 gm are moving with equal kinetic energies. The ratio of the magnitudes of
their linear momenta is
(A) 4 : 1
(B) 2 :1
(C) 1 : 2
(D) 1 : 16
11. C
12. The centre of a wheel rolling on a plane surface moves with a speed v 0. A particle on the rim of the
wheel at the same level as the centre will be moving at speed
(A) zero
(B) v0
(C) 2 v0
(D) 2v 0
12. C
13. A ball is dropped from a height of 1m. It coefficient of restitution between the surface and the ball is
0.6, the ball rebounds to a height of
(A) 0.6 m
(B) 0.4 m
(C) 0.16 m
(D) 0.36 m
13. D
This section contains 05 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the OMR is to be bubbled.
1. The period of rotation of the earth so as to make any object weight-less on its equator is 12k minutes.
Find the value of k.
1. 7
2. A uniform wheel of radius R = 4 m is set into rotation about its axis at an angular speed = 3 rad/s.
This rotating wheel is now placed on a rough horizontal surface with its axis horizontal. Because of
friction at the contact, the wheel accelerates forward and its rotation decelerates till the wheel starts
pure rolling on the surface. Find the linear speed (in m/s) of the wheel after its starts pure rolling.
2. 4
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SANKALP2224 A&B LOT-(Ph-2)-Paper-1-PCM(000000.1)-6
3. A ball is moving with velocity 2 m/s towards a heavy wall moving towards 2 m/s 1 m/s
the ball with speed 1 m/s as shown in figure. Assuming collision to be
elastic, find the speed of ball immediately after the collision (in m/s).
3. 4
4. A dog of mass 10 kg chases a rabbit running with a speed of 7 km/hr and mass 2 kg with a speed of
13 km/hr along a straight line. The speed of the centre of mass of the dog rabbit system is 5n km/hr.
Find the value of n.
4. 2
5. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m and its
-7 2
cross-sectional area is 4.9 10 m . If the mass is pulled a little in the vertically downward direction
and released, it performs simple harmonic motion of angular frequency 140 rad s1. If the Young’s
modulus of the material of the wire is n 109 Nm-2, the value of n is
5. 4
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eSANKALP22224A&B-(Ph-2)-Paper-1-PCM()-2
SECTION – I : CHEMISTRY
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1.
For the reaction: A g
B g C g
K p at 500o C 1.8 10 4
K p at 600o C 6.4 10 6
Then it can definitely be said
(A) The formation of B and C from A is exothermic
(B) The formation of B and C from A is endothermic
(C) Increase of pressure would shift the equilibrium towards left
(D) Decrease the temperature would accelerate the formation of B and C
2. The solubility of a sparingly soluble salt Ax By in water at 25°C is 1.4 × 10–4 M. The solubility product
is 1.1 × 10 –11 , the possibilities are.
(A) x = 1, y = 2 (B) x = 2, y = 1
(C) x = 1, y = 3 (D) x =3, y = 1
3. Which of the following statement(s) is/are correct for the given reaction?
4A B 2C 2D
(A) The rate of disappearance of B is one-fourth the rate of disappearance of A
(B) The rate of appearance of C is half the rate of disappearance of B
(C) The rates of formation of C and D are equal
(D) The rate of formation of D is half the rate of disappearance of A
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eSANKALP22224A&B-(Ph-2)-Paper-1-PCM()-3
(A) Br (B) Br
Cl
(C) Cl Cl (D) Cl
6. Arrhenius equation is represented as: k AeEa /RT . Which of the following options is/are correct?
(A) Graph plotted between k and 1/T is a straight line
(B) Graph plotted between log k and 1/T is a straight line with a positive slope
(C) Intercept of the graph between log k and 1/T = logA
(D) Slope of the graph between log k and 1/T = 2.303Ea/R
7. In the reaction A 2B 3C D , which of the following expressions will describe change in the
concentration of various species as a function of time?
d C dA 3d D d C
(A) 3 (B)
dt dt dt dt
3d B 2d C 2d B d A
(C) (D)
dt dt dt dt
8.
The equilibrium constant KC for the reaction SO 2(g) NO2(g
SO3()g) NO(g) is 16. If 1 mole each
of all four gases is taken in 1 dm 3 vessel the equilibrium concentration of NO would be
(A) 0.04 (B) 0.6 M
(C) 4.4 M (D) 1.6 M
9. The solubility product (Ksp) of AgCl is 1.8 10 10 . Precipitation of AgCl will occur only when equal
volumes of solution of
(A) 104 M Ag and 10 4 M Cl are mixed (B) 107 M Ag and 10 7 M Cl are mixed
(C) 105 M Ag and 10 5 M Cl are mixed (D) 1010 M Ag and 1010 M Cl are mixed
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eSANKALP22224A&B-(Ph-2)-Paper-1-PCM()-4
NO 2 Cl Me OMe
11. An endothermic reaction with high enthalpy for the reaction is given by the diagram:
Potential Energy
Potential Energy
(A) R
(B) R
P
P
Potential Energy
P
P
(C) (D)
R R
HO
OH
(A) 2 (B) 4
(C) 8 (D) 16
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eSANKALP22224A&B-(Ph-2)-Paper-1-PCM()-5
OH
(A) (B)
H3C N
H3C
N N OH
(C) (D)
HO N
H3C OH
1. NH4 COONH2 s 2NH3 g CO2 g . If equilibrium pressure is 3 atm for the above reaction;
calculate Kp.
2. For the hypothetical reactions, the equilibrium constant (K) values are given:
A B; K1 1
B C; K 2 2
C D; K 3 4
The equilibrium constant (K) for the reaction A D is
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eSANKALP22224A&B-(Ph-2)-Paper-1-PCM()-6
ANSWERS
CHEMISTRY (SECTION–II)
1. A, C, D 2. A, B 3. A, C, D 4. B, D
5. A, B, C 6. C 7. A, B, C 8. D
13. C 1. 4 2. 8 3. 2
4. 6 5. 9
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-2
S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
2 2 2 2
1. The curves x + y + 6x – 24y + 72 = 0 and x – y + 6x + 16y – 46 = 0 intersect in four points P, Q, R
and S lying on a parabola. Let A be the focus of the parabola, then
(A) AP + AQ + AR + AS = 20 (B) AP + AQ + AR + AS = 40
(C) vertex of the parabola is at (–3, 1) (D) coordinates of A are (–3, 1)
M110902
1. B, C
2 2
The points of intersection P, Q, R, S lie on 2x + 12x – 8y + 26 = 0 i.e. (x + 3) = 4(y – 1)
So vertex (–3, 1), focus (–3, 2)
2
Points of intersection also lie on y – 20y + 59 = 0
sum of two of the ordinates = 20
AP + AQ + AR + AS = 40.
M110101
2. B, C
If x a, then |x a| = x a, and the equation becomes
x2 2ax a2 = 0 x a 1 2
a < 0 a 1 2 a hence x a 1 2 cannot be the solution.
x a 1 2 a is the solution, which is positive.
Again if x < a, then |x a| = (x a) and the equation becomes
x2 + 2ax 5a2 = 0 x 1 6 a
Again as a < 0, a 1 6 0 a , hence x a 1 6 cannot be solution
x a 1 6 a is the solution, which is negative
M110101
3. A, B, C
a1/3 + b1/3 = (a + b)1/3 is true
when either a = 0 or b = 0 or a + b = 0
3
x = 0, , 1.
2
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-3
4. The point represented by the complex number 2 i is rotated about the origin through an angle .
2
The new position of the point is
(A) 1 + 2i (B) 1 2i
(C) 1 2i (D) 2 + i
M110306
4. A, B
If the rotation is clockwise, the desired number = i(2 i) = 1 2i.
If the rotation is counterclockwise, the desired number = i(2 i) = 1 + 2i.
M110305
1994 1995
5. If (1) is a cube root of unity, then the value of + is
2
(A) (B)
3 4
(C) (D)
M110305
5. A, D
1994 + 1995 = 1994(1 + )
= 1994 (2) = 1996 = = 4.
ab
6. For any three unequal numbers a, b and c, equals to
bc
b a
(A) if a, b, c are in A.P. (B) if a, b, c are in G.P.
c b
a
(C) if a, b, c are in H.P. (D) none of these
c
M110501
6. B, C
If a, b, c are in A.P., then a b = b c
ab b
1
bc c
a b 1
If a, b, c are in G.P., then say
b c r
a 1
1 1
ab b 1 a
Now r
bc c 1 r r b
1
b
1 1 1 1 a b ab a
Next if a, b, c are in H.P., then .
b a c b b c bc c
7. Let a1, a2, a3, …, an are in G.P. such that 3a1 + 7a2 + 3a3 – 4a5 = 0, then common ratio of G.P can be
3
(A) 2 (B)
2
5 1
(C) (D) –
2 2
M110502
7. B, D
Given 3a1 + 7a2 + 3a3 – 4a5 = 0
7(a1 + a2 + a3) = 4(a1 + a3 + a5)
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-4
2 2 4
7(1 + r + r ) = 4(1 + r + r )
2
7 = 4(r – r + 1)
2
4r – 4r + 1 = 4
2
(2r – 1) = 4
2r – 1 = 2
3 1
r= , .
2 2
PART – A: (Single Correct Answer Type)
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
8 4 8
(A) , (B) ,
5 5 5
8 8 4
(C) , 0 , (D) ,
5 5 5
M110202
8. C
log 2 4 5x 2
4 5x 4
4 5x 4 or4 5x 4
5x 0 or 8 5x
8
x 0 or x
5
8
. solution set x , 0 ,
5
9. If a, b, c are in GP, then the equations ax2 + 2bx + c = 0 and dx2 + 2ex + f = 0 have a common
root if d/a, e/b, f/c are in
(A) AP (B) GP
(C) HP (D) None of these
M110102
9. A
Since a, b, c are in G.P.
b2 – ac = 0
4(b2 – ac) = 0
which shows that ax2 + 2bx + c = 0
as equal roots
2b
+= = b/a
a
Hence, -b/a must also be a root of
dx2 + 2ex + f = 0
d(-b/a)2 + 2e(-b/a) + f = 0
d b 2 2e b 2 f b 2
0
a a b a c a
2
b = ac
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-5
d 2e f d e f
Hence, 0 , , are in A.P.
a b c a b c
2
10. Three normal are drawn from point (5, 0) to parabola y = 4x. The centriod of the triangle formed by
feet of these three normals is
1 1
(A) , (B) (5, 0)
2 2
(C) (2, 0) (D) (0, 2)
M110905
10. C
Normal from any point
y = mx – 2am – am3
a=1
y = mx – 2m – m3
Now it passes through (5, 0)
3
So, 0 = 5m – 2m – m
Or, m[m2 – 3] = 0 m = 0, 3
2 2
Point of contact of normal and parabola (am , –2am) (m , –2m)
So, point (0, 0), (3, –2 3 ), (3, 2 3 )
So, centroid = (2, 0).
11. The centre of square ABCD is at z = 0. A is z1, then the centroid of ABC is
z1
(A) z1 (cos i sin ) (B) cos i sin
3 2 2
(C) z1 cos i sin (D) none of these
2 2
M110307
11. B
OA = OB = OC C(z3) B(z2)
Let B (z2) and C(z3)
z 2 0 OB i / 2
e z2 = iz1
z1 0 OA
z3 0 OC i z =0
e z3 = –z1
z1 0 OA
z z 2 z3 z (1 i 1) z1
centroid = 1 = 1 i
3 3 3
z1 D A(z1)
If B is the point D, then centroid = – i
3
z1
centroid cos i sin
3 2 2
12. Let <an> be an arithmetic sequence whose first term is 1 and <bn> be geometric sequence whose first
term is 2. If the common ratio of geometric sequence is half the common difference of arithmetic
sequence, then the minimum value of (a4b1 + a3b2 + 2a1b3) is equal to
25 3
(A) (B)
12 2
25 3
(C) – (D)
12 2
M110501
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-6
12. C
2
7 25
a4b1 + a3b2 + 2a1b3 = 3 d , where d is common difference of A.P.
6 12
M121502
13. C
2
2
S.D =
n
n
n(n 1)(2n 1) n2 (n 1)2
n n 6n 4n2
2(n 1)(2n 1) 3(n 1)2 n2 1
= .
12 12
14. The number of real roots of the equation (x – 1)2 + (x – 2)2 + (x – 3)2 = 0 is
M110101
14. 0
(x – 1)2 + (x – 2)2 + (x – 3)2 =0 3x2 – 15x + 14 = 0
Discriminant = 225 –168 = 57
M110903
15. 2
a 4
c= = 2.
m 2
3 i 3 i
16. arg is equal to
2i 2i
M110303
16. 0
3 i 3 i 6 5i i 2 6 5i i 2 10
arg arg = arg 0
2i 2i 5 5
an b n
17. The value of n, for which is A.M between a and b is
a n 1 b n1
M110501
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SANKALP 2123 AB-LOT-Ph-II-Paper-1-PCM(100495.1)-7
17. 1
an b n ab
for n = 1, , which is AM between a and b.
a n 1 b n1 2
2 2 2 2 2 2
18. If a > 0, b > 0, c > 0 and the minimum value of a(b + c ) + b(c + a ) + c(a + b ) is abc, then is
M110506
18. 6
Using AM G.M
1
ab 2 ac 2 bc 2 ba2 ca2 cb2
6
ab2 .ac 2 .bc 2 .ba2 .ca2 .cb2
6
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FIITJEE INTERNAL TEST
PHYSICS, CHEMISTRY & MATHEMATICS
CPT–1 CODE: 000000.1 PAPER–2
Time Allotted: 3 Hours Maximum Marks: 183
Pleas e read the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
SANKALP2224 A&B LOT
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each section is further divided into one part: Part – A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All One Part.
Part–A (01 – 07) contains 07 multiple choice questions which have one or more than one correct answer.
Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Part–A (08 – 14) contains 07 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Part–A (15 – 18) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer
and 0 mark for a wrong answer.
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1.
Consider a body of mass 1.0 kg at rest at the origin at time t = 0. A force F t ˆi ˆj is applied on
the body, where 1.0Ns1 and 1.0N. The torque acting on the body about the origin at time t =
1.0 s is . Which of the following statements is (are) true?
1
(A) Nm
3
(B) The torque is in the direction of the unit vector + k̂
1 ˆ
(C) The velocity of the body at t 1s is v
2
i 2jˆ ms 1
1
(D) The magnitude of displacement of the body at t 1 s is m
6
1. A, C
2. A particle of mass 5 gm is placed in a potential field. Its value is given by (5x 2 + 10) joule/kg. Then,
Choose the correct option(s)
10 5
(B) Its frequency is
2. A, B
3. When springs are connected in parallel with a mass m, which of the following relations hold good?
(Symbols have their usual meanings)
(A) Keq = K1 + K2
1 1 1
(C) 2
T T12 T22
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-3
3. A, B, C, D
(B) 4 cos2 t
4 A, B, C
5. A body is performing linear SHM. If the displacement, acceleration and the corresponding velocity of
the body are y, ‘a’ and v, respectively, which of the following graphs is/are correct?
(A) v
2 (B) v
O 2 O a
a
(C) 2 (D) v
y
O
a
O 2
a
5. A, B, C, D
(D) disc
6. A, D
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-4
0m
7. A metre stick oscillates as a compound pendulum about a horizontal axis through
A 0.2 m
A. Then
0.5 m
(A) the length of an equivalent simple pendulum is 0.58 m.
B 0.8 m
(B) the period of oscillation about A and B is same. 1m
7. A, B, C
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
8. The linear density of rod of length L is given by = Bx2 where B is a constant. Then the co-ordinates
of centre of mass are
3L
(A) 4 ,0
3L
(B) 0, 4
4L
(C) 3 ,0
0,4L
(D) 3
8. A
9. The position of a particle is given by : r ˆi 2ˆj kˆ
and momentum P 3iˆ 4ˆj 2kˆ .
The angular momentum is perpendicular to :
(A) X-axis
(B) Y-axis
(C) Z-axis
9. A
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-5
10. The centre of mass of a half disc shown is at C while O is the centre.
Thus OC is
C R
(A) R/2 O
(B) 2R/
4R
(C)
3
10. C
11. The system shown in the figure is in equilibrium. If now M is given a d/2 d/2
slight vertical displacement, what will be the time period of resulting
oscillations? k
30 30
M
(A) 2
k
M
M
(B) 2
3k
3M
(C) 2
k
2M
(D) 2
k
11. B
12. A block of mass M is attached with the springs as shown. If the block
k
is slightly displaced, the time period of SHM for the block shown in k
M
the figure will be k
=0
m
(A) 2
9k
m
(B) 2
k
4 m
(C)
3 k
m
(D)
2k
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-6
12. C
13. A thin rod of linear mass density at right angle at its mid point (C) and A
fixed to points A and B such that it can rotate about an axis passing
through AB. The moment of inertia about an axis passing through AB is /2
45
90
3 C
(A) 45 /2
6 2
B
3
(B)
2 2
3
(C)
4
3
(D)
2
13. A
14. An earth satellite is moved from one stable circular orbit to a farther stable circular orbit. Which one of
the following quantities increase?
14. B
m
Three particles, each of mass m, are situated at the vertices of an equilateral
A
triangle of side length a. The only forces acting on the particles are their mutual
gravitational forces. It is desired that each particle moves in a circle while
maintaining the original mutual separation a.
Then answer the following questions. 60
C B
m m
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-7
2
3Gm
(A)
a2
2Gm2
(B)
a2
2 3Gm2
(C)
a2
3Gm2
(D)
2a2
15. A
Gm
(A)
a
Gm
(B) 2
a
Gm
(C) 3
a
Gm
(D) 4
a
16. A
17. If t1 and t2 are the time taken by ball of mass 1 kg and 2 kg respectively to reach at the bottom most
point vertically below then
(A) t1 > t2
(B) t1 = t2
(C) t1 < t2
17. B
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SANKALP2224 A&B LOT-(Ph-2)-Paper-2-PCM(000000.1)-8
(A) 7 m/s
2 20
(B) m/s
3
5 20
(C) m/s
3
(D) 20 m/s
18. C
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-2
SECTION – I : CHEMISTRY
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
1. For the reaction C s CO2 g 2CO g , which of the following statements is/are correct?
(A) The equilibrium shifts in the forward direction if the volume is increased
(B) The equilibrium shifts in the forward direction if inert gas is added keeping volume constant
(C) The equilibrium shifts in the forward direction if more of CO 2 is added
(D) The equilibrium shifts in the backward direction if pressure is increased
CH CH OH O O
(A) (B)
O O
(C) O (D) O
4. Which of the following reactions at equilibrium in the gaseous phase would be affected by an
increase in pressure?
1
(A) N2 O 4
2NO2
(B) CO O2
CO2
2
(C) N2 O 2
2NO
(D) 2NO2
2NO O2
6. An acid indicator HIn has K a 3 105 , the acid form is red and basic form is blue. Which is/are
correct?
[log 3 = 0.477]
(A) pH = 5 when indicator is 75% red (B) pH = 4.05 when indicator is 75% red
(C) pH = 5 when indicator is 75% blue (D) pH = 4.05 when indicator is 75% blue
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-3
8. The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at
-4 -1 -1 14 -1
25 C is 3.010 s , 104.4 kJ mol and 610 s respectively. The value of the rate constant as
T is
(A) 2.01018s-1 (B) 6.01014 s-1
(C) infinity (D) 3.61030 s-1
CH CH2
(A) 8 (B) 16
(C) 32 (D) 64
10. A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the
presence of a catalyst at the same rate with same frequency factor, the temperature required 400
K. What is the activation energy of the reaction, if the catalyst lowers the activation energy barrier
by 16 kJ/mol?
(A) 100 kJ/mol (B) 80 kJ/mol
(C) 60 kJ/mol (D) None of these
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-4
(P)
(Q) (R) O (S)
(A) R > Q > P > S (B) Q > R > P > S
(C) S > R > Q > P (D) Q > P > R > S
(A) (B)
(C) (D)
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-5
15. Calculate the pH of the mixture, when 50 ml of 0.10 M NH4 OH and 50 ml of 0.05 M HCl are
mixed together. Given : pK b 4.7447
(A) 4.7447 (B) 7.0
(C) 9.2553 (D) 12.3979
16. Calculate pH of mixture, when 50 ml of 0.05 M NaOH and 50 ml of 0.10 M CH3 COOH is mixed
together. Given : pK a 4.7447
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-6
Presence of chiral center is not an essential condition to show optical isomerism. Essential condition is,
compound should show non-superimposable mirror image.
Allenes do not contain chiral center but show optical isomerism when different groups are attached on
double bonded carbons.
Biphenyls also shown optical isomerism when both rings are perpendicular to each other and any ring
should not contain plane of symmetry.
H Cl CH 3
H OH
(C) (D)
H OH
C2H5
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eSANKALP2224A&B-(Ph-2)-Paper-2-PCM()-7
ANSWERS
CHEMISTRY (SECTION–II)
1. A, C, D 2. A, B 3. B, D 4. A, B, D
5. B, D 6. B, C 7. B, C, D 8. B
17. A 18. D
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-2
S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. If two distinct chords of a parabola y2 = 4ax, passing through (a, 2a) are bisected on the line x + y =1,
then length of the latus-rectum can be
(A) 2 (B) 1
(C) 4 (D) 5
M110902
1. A, B
Any point on the line x +y =1 can be taken (t, 1 - t)
equation of the chord, with this as mid-point is
2
y(1- t) – 2a(x + t) = (1 – t) – 4a t, it passes through (a, 2a)
so t2 – 2t + 2a2 – 2a +1 = 0, this should have 2 distinct real roots so a2 – a< 0, 0< a< 1, so length of
latus-rectum < 4 .
2. A, B
As a circle can intersect a parabola in four points, so
quadrilateral may be cyclic. The diagonals of the
quadrilateral may be equal as the quadrilateral may be an
isosceles trapezium.
A rectangle cannot be inscribed in a parabola.
So (C) is wrong.
3. The set S of all real x for which (x2 – x + 1)x – 1 < 1 contains
(A) (– 5, – 1) (B) (– 1, 1)
(C) (– 1, 0) (D) (– 3, 1)
M110202
3. A, C
2
1 3
Here x2 – x + 1 = x 0 x R
2 4
gives (x2 – x + 1)x – 1 < 1
taking log both sides
(x – 1)log10(x2 – x + 1) < 0
Case I: x – 1 > 0, log10(x2 – x + 1) < 0
i.e. x – 1 > 0 and 0 < x < 1 no solution.
Case II: x – 1 < 0 and log10(x2 – x + 1) > 0
x < 1 and x > 1 or x < 0
x < 0.
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-3
M110303
4. B, C, D
Let |z1| = |z2| = r z1 = r (cos + isin)
and z2 = r cos isin
z1z2 = r2 i , which is purely imaginary
z1+z2 = r [(cos + sin)+ i (cos + sin) ]
2 2 2
(z1 +z2) = r (2i ( cos + sin)) which is purely imaginary .
-1 -1
Also arg(z1 ) + arg(z2 ) = -/2 .
2z i
5. If z = x + iy then the equation = m represents a circle when
z 1
(A) m = 1/2 (B) m = 1
(C) m = 2 (D) m = 3
M110307
5. A, B, D
Let z = x + iy
2z i 2 2
m 4x2 y 1 m x 1 y2 4x2 + (y –1)2 = m2 {(x +1)2 + y2}
z 1
If m = 2 then only x2 gets cancelled.
Locus represents a circle for any other value of m
6. In a G.P. the product of the first four terms is 4 and the second term is the reciprocal of the fourth
term. The sum of infinite terms of the G.P is
(A) 8 (B) –8/3
(C) 8/3 (D) 8
M110502
6. A, B, C, D
a, ar, ar2, ar3
Product of terms = a ar ar2(ar3) = 4
a4r6 = 4 …(i)
1
and ar = 3
ar
a2r4 = 1 …(ii)
4 8
ar =1
4r2 = 1
1
r=
2
a2 = 16
a = 4.
2 3
7. If a, a 2, a 10 be three consecutive terms of G.P., then the fourth term is
(A) 0 (B) 6
729
(C) (D) 54
16
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-4
M110502
7. C, D
The given equation can be written as
2 2 2
8. If and are the roots of the equation, 2x –3x –6 =0, then equation whose roots are +2, +2
is
(A) 4x2+ 49x +118 = 0 (B) 4x2- 49x +118 = 0
2 2
(C) 4x - 49x –118 = 0 (D) x - 49x +118 = 0
M110103
8. B
+ = 3/2 , = -6/2 = -3
49
S = 2 +2 +4 = (+)2 -2 +4 =
4
118
P = 2 2 +2 (2 +2) +4 = 2 2 +4 +2 [( +)2 -2 ] = .
4
49 118
Therefore, the equation is x2 - x 0
4 4
4x2 – 49x +118 = 0
M110101
9. A
Let f(x) = ax2 + bx + c. Since f(x) has no real zeroes, either f(x) > 0 or f (x) < 0 for all x R . since f(0)
= c < 0, we get f(x) < 0 for all x R . Therefore, a < 0 as the parabola y = f(x) must open downward.
Obviously f(1), f(1) and f(2) < 0.
10. If ‘a’ and ‘c’ are the segments of a focal chord of a parabola and b the semi-latus rectum, then
(A) a, b, c are in A. P. (B) a, b, c are in G. P.
(C) a, b, c are in H. P (D) none of these
M110902
10. C
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-5
2
(At , 2At)
a= ( At 2 A )(2At) 2 = A(1 + t2) (A, 2A)
2 a
A 2A A 2
c= 2 A 2 (1 t )
t t t c (A, 0)
b = 2A b
(A/t2, -2A/t)
2A 2 2A 2 (1 t 2 ) 2 (A, -2A)
(1 t 2 )
2ac t2 t2
so, 2
=b
ac A 2 2 A (1 t ) 2
(1 t ) A (1 t ) (1 t )
t2 t2
2ac
b=
ac
1
11. The maximum distance from the origin of co-ordinates to the point z satisfying the equation z =a,
z
is
1 2 1 2
(A) a 1 a (B) a 2 a
2 2
1 2
(C) a 4 a (D) none of these
2
M110302
11. C
1 1 1 1
We have |z| = z z
z z z z
1
|z| a + |z|2 – a|z| –1 0
|z|
a a2 4 a a2 4
|z| .
2 2
12. Consider an infinite geometric series with first term a and common ratio r. if its sum is 4 and the
3
second term is , then
4
7 3 3
(A) a = , r = (B) a = 2, r =
4 7 8
3 1 1
(C) a = , r = (D) a = 3, r =
2 2 4
M110502
12. D
Let G.P is a, ar, ar2 ……
3 a
ar = & =4
4 1 r
1 3
16r2 –16r + 3 = 0 r = ,
4 4
1 3
if r = , then a = 3 and if r = , then a = 1
4 4
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-6
13. In a group of students, mean weight of boys is 80 kg and mean weight of girls is 50 kg. If the mean
weight of all the students taken together is 60 kg, then the ratio of number of boys to that of girls is
(A) 2 : 1 (B) 1 : 2
(C) 2 : 3 (D) none of these
M121501
13. B
Let the number of boys be n1 and that of girls be n2, then
80n1 50n 2
60 = 60n1 + 60n2 = 80n1 + 50n2
n1 n2
10n2 = 20n1 n1 : n2 :: 1 : 2.
x 1
14. The values of ‘x’ satisfying the inequality
x 2 4x 3 1 log 5
5 x
8x 2x 2 6 1 0
are,
(A) (, 1] [3, ) (B) [1, 3]
(C) {1, 3} (D) {1}
M110202
14. D
1
(x 3)(x 1) 1 log 5 x
x
2(1 x)(x 3) 1 0
If we find the domain of above inequation
then (x – 3) (x – 1) 0 also (1 – x) (x – 3) 0
(, 1] [3, ) (x – 1) (x – 3) 0
1x3
Now possible values of x is 1 and 3 but only x = 1 is satisfying the inequality.
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Let m, n be the roots of the equation x2 + qx + r = 0 and let s, t be the roots of the equation
x2 + bx + c = 0.
m s
15. If , then
n t
(A) r2c = qb2 (B) r2b = qc2
(C) rb2 = cq2 (D) rc2 = bq2
15. C
M110903
M110903
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SANKALP 2123 AB-LOT-Ph-II-Paper-2-PCM(100496.1)-7
16. D
m s mn st mn st
15–16. Since ,
n t mn st 2
m n 4mn s t 2 4st
q b
q2(b2 – 4c) = b2(q2 – 4r)
2 2
q 4r b 4c
2 2
cq = rb .
For mn = st
2 2 2 2 2 2
q – b = (m + n) – (s + t) = (m – n) – (s – t)
= [m – n – (s – t)][(m – n) + (s – t)]
= [(m + t) – (n + s)][(m + s) – (n + t)]
With m = r, rq = bc, s + n = – q, sn = r and s + t = – b, st = c
nc rt
n – t = b – q and r or –t=b–q
t c
i.e. t(r – c) = bc – cq = rq – cq = (r – c)q t = q n = b
2
and hence n, t are the roots of x – (b + q)x + bq = 0.
1
Let Sr, r N, denote the sum of an infinite GP whose first term is 2r 1 and common ratio . Let
2r.
n n
1
Vn
r 1
Sr and Qn S S
r 1 r r 1
.
Vn
17. lim equals
n2 n
(A) 0 (B) 1
(C) 1 (D) 2
M110505
17. C
n n
Vn S
r 1
r 2 r n n 1
r 1
Vn n 1
lim 2
lim 1
n n n n
18. B
(i) Vn = n (n + 1) V1 < V2 < V3 < .....
Statement 2 is true
n n n
1 1 1 1 1 1 1 1
(ii) Qn S S
r 1 r r 1
4 r r 1
r 1
4 r r 1 4 1 n 1
r 1
Q1 < Q2 < Q3 < ……….
Statement 1 is false
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