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Chapter 6 (Unit Operations of Chemical Engineering Seventh Edition)
Chapter 6 (Unit Operations of Chemical Engineering Seventh Edition)
The Mach number, denoted by Ma, is defined as the ratio of u, the speed of the fluid,
to a, the speed of sound in the fluid under conditions of flow
Ma= (6.1)
By speed of the fluid is meant the magnitude of the relative velocity between the
fuid and a solid bounding the fiuid or immersed in it, whether the solid is consid-
ered to be stationary and the fluid fiowing past it or the fluid is assumed to be sta-
tionary and the solid moving through it. The former siluation is the more common
in chemical engineering, and the later is of great importance in aeronautics, for the
moion of missiles, rockets, and other solid bodies through the atmosphere. By def
initionthe Mach number is unity when the speed of fluid equals that of sound in the
Same fluid at the pressure and temperature of the fluid. Flow is called subsonic,
133
134 SECTION 11 Fluid Mechanics
to whether the
Mach number is less than
Sonic, or supersonic according unity, a
near unity, or greater than unity, respectively. 1ne most interesting probleo
where Mach numbers in
compressible flow lie in the high-velocity range, a
Total-energy balance
Consider a Huid in steady How
velocity andu, enthalpy H, through system, entering at a with
u+d( (6.4)
In the light of the assumptions, this equationis simplificd by omitting the potential
energy terms, noting that a, = a,= 1.0, u = V, and restricting the friction to wall
shear. Equation (6.5) then becomes
+a5+dhy, =0 (6.6)
From Eq. (5.7), with D =
4rH
fdL
dhs2 TH (6.7)
Eliminating dhs, from Eqs. (6.6) and (6.7) gives the form of the mechanical energyy
equation suitable for treatment of compressible flow:
+ +ufdl
2 rH
=0 (6.8)
Velocity of sound
The velocity of sound through a continuous material medium, also called the
acoustical velocity, is the velocity of a very small compression-rarefaction wave
moving adiabatically and frictionlessly through the medium. Thermodynamically.
the motion of a sound wave is a constant-entropy, or
isentropic, process. The mag-
nitude of the acoustical velocity in any medium is shown in physics texts to be
where the
a-/), (6.9)
p-RT (6.10)
where R = molar gas law constant, 8,314 J/kg mol K forp in N/m* and T inK or
T'in °R
1,545 ft 1b,/lb mol forp in lb,/in.* and
M= molecular weight
The gas may be either pure or a mixture, but if it is not pure, the composition should
not change. Equation (6.10) may be writen logarithmicaly and then differentiated
toggive
(6.11)
Since the specific heat c, is assumed to be independent of temperature, the
enthalpy of the gas at temperature 7'is
H =
Ho + Cp(T To -
(6.12)
where H =
enthalpy per unit mass at
temperatureT
Ho = enthalpy at arbitrary temperature Io
dH = Cp dT
(6.13)
Acoustic velocity and Mach number of ideal gas. For ideal gas,
an an isentrope
path follows the equations
PP = const (6.14)
Tp- ?)= Const (6.15)
where y is the rati0 of
C,, the specific heat at constant eciic
heat at constant volume. For an
ideal gas, pressure, to C, ne
>P
Y Cp (6.16)
Cp- R/M
Since, by assumplion, C, Is
The independent of
temperature,
quantity so are c, and
Eq. (6.14), (dp/dP)s
form
Can be
calculated by Y.
of
giving dilferentiating
rentiating the
he logarithmic
log
dp
0 and
CUAPTER O: Flow ol
Compressible Fluids 137
a-- (6.17)
Ma* =
.18)
YP TR/M
The asterisk condition
The state of the fluid moving at its acoustic
processes of compressible-fluid flow. The condition where u=a and Ma =
velocity is important in some
I is
called the asterisk condition, and the pressure, temperature, density, and enthalpy
are denoted by
p, T'P, and H' at this state.
Stagnation temperature
The stagnation
temperature of a high-speed
fluid is defined as the
temperature
the ffuid would atta:n were it
brought lo rest adiabatically without the development
of shaft work. The relation between the actual fluid
temperature, the actual fiuid
velocity, and the stagnation temperature is tound by using the total-energy equa-
tion (6.3) and the enthalpy equation (6.12). Let station in
a
Eq. (6.3) refer to the
state of the flowing gas at temperature 7 and enthalpy H, and station b
state 0 in Eq. (6.12) to the stagnation condition. Stagnation is denotedand
by the sub- reference
Scnpt s. Then u, = 4, the velocity of the gas, and H, = ", 0. Since the process is
adiabatic and Q= 0, Eq. (6.3) becomes
H,-H = Ho-H (6.19)
Eliminating Ho - H from Eq. (6.19) by using Eq. (6.12) gives, for the stagnation
temperature 1,
T, =T+ 2 (6.20)
The stagnation enthalpy H, is defined by the equation
H, = H +
(6.21)
Equation (6.3) can be written
where , a and H,b are the stagnation enthalpies at states a and b, respectively. For
an adiabatic process, Q=0, 7sa Isb and the stagnation temperature is constant.
138 SECTION I1: Fluid Mechanics
Convergen
Secion
Divergent section -
Reservoir Receiver
(o Flow
Thermal insulolion
1senlropic section
TL
Thermal insulation
Reservoir
Isenlropic section Receiver
Friction section-
Sothermal
Heating jacket
FIGURE 6.1
() Isentrepic now
low. (c) Isotnernal n
a
comvergenl-divergent
iricton low. nozzle. (b) Adiabatic iric
CHAPTEk 6: Flow of Compressible Fluids 139
From the reservoir the gas is assumed to flow, without friction loss at the
entrance, into and through a pipe. The gas leaves the pipe at defhnite temperature,
velocity, and pressure and goes into an exhaust receiver, in which the pressure may
be independently controlled at a constant value less than the reservoir pressure.
Within the pipe any one of the following processes may occur:
1. Isentropic expansion. In this process the cross-sectional area of the conduit must
change, and the process is described as one of variable area. Because the process
is adiabatic, the stagnation temperature does not change in the conduit. Such a
process is shown diagrammatically in Fig. 6.la.
2. Adiabatic friction flow through a pipe of constant cross section. This process is
reversible, and the entropy of the gas increases; but as shown by Eq. (6.22),
since Q=0, the stagnation temperature is constant throughout the conduit. This
A conduit suitable for isentropic flow is called a nozzle. As shown in Fig. 6.1a, a
complete nozzle consists of a convergent section and a divergent section joined by
a throat, which is a short length where the wall of the conduit is parallel with the
axis of the nozzle. For some applications, a nozzle may consist of a divergent
section only, and the throat connects directly with the receiver. The configuration of
an actual nozzle is controlled by the designer, who fixes the relation between , the
cross-sectional area, and L, the length of the nozzle measured from the entrance.
Nozzles are designed to minimize wall friction and to suppress boundary layer
separation. The convergent section is rounded and can be short, since separation
does not occur in a converging channel. To suppress separation in the divergent
section, the diverging angle is made small, and this section is therefore relatively
long. The nozzle entrance is sufficiently large relative to the throat to permit the
velocity at the entrance to be taken as zero, and the temperature and pressure at the
entrance to be assumed equal to those in the reservoir.
Generalized treatments, including general heat transfer to and from the gas, injection of gas into the
conauit, variations in specinc heal and molecular weight, chemical reaclions, the drag of internal
bodies, and change of phase, are given in Refs. I and 3.
II: Fluid Mechanics
140 SECT1ON
section is to
ncrease the velocity and.
The purpose of the convergent decreas
the pressure of the gas. At
low Mach
numberS
tne process conforms essentiallse the
for incompressible flow [Eq. (4.67)]. In the conver
Bernoulli relation Sec.
usual sonic at the throat. Mach
tion flow is always subsonic,
but it may become number
in a convergent nozzle. In the diveroen
greater than unity cannot be generated
tion, the flow may be subsonic or supersonic.
The purpose divergent se
of the
section
differs shaply in the two situations. In subsonic now the purpose of the section ic t
reduce the velocity and regain pressure, in accordance with the Bernoulli equation
An important application of these nozzles is the measurement of fiuid flow, which ie
discussed in Chap. 8. In supersonic flow, the usual purpose of the divergent section
is to obtain Mach numbers greater than unity ror use in jet engines, equipment used
to produce very fine sprays, or experimental equipment such as wind tunnels.
Flow through a given nozzle is controlled by fixing the reservoir and receiver
pressures. For a given flow through a specine nozzle, a unique pressure exists at
each point along the axis of the nozzle. The relation is
conveniently shown as a plot
of p/po versus L, where
Po is the reservoir pressure and p the pressure at point L.
Figure 6.2 shows how the pressure ratio varies with distance and how changes in
receiver pressure at constant reservoir
pressure affect the pressure distribution. The
pressures at the throat and in the receiver are denoted by
P, and P, respectively.
Ifp,
and po are equal, no flow occurs and the
pressure distribution is represented
by line aa. If the receiver pressure is
Occurs and a
slightly below the reservoir
pressure, flow
pressure distribution such that shown
as
by line abc is
Pressure recovery in the established.
convergent section is shown
by line bc. The maximum
velocity occurs at the
throat. If the receiver
and the velocity pressure is further reduced, the flow rale
at the throat
throughout the nozzle increase. A
limit is attained when the velocity
becomes sonic. This case is shown
and Ma =
1. The ratio by line ade, where p, = P,
p'/po is called the critical
r Flow is subsonic at all other pressure ratio and is denoted Dy
points on line ade.
PilPo
PlPo
FIGURE 6.2 -
Variation ol
pressure ralo with
distance from
nozzle inlet.
CHAPTER 6: Flow of Compresible Fluids 141
1.0
Pressure ratio, P/Po
FIGURE 6.3
Mass flow rate through nozzle.
As the receiver pressure is decreased from that of point d to that of point e, the
mass flow rate through the nozzle increases. The fiow rate is not affected by reduc
tion of pressure below that coresponding to critical flow. Figure 6.3 shows how
mass flow rate varies with the pressure ratio p,/Po- The flow rate attains its maxi-
mum at point A, which is reached when the pressure ratio in the throat is reduced to
its critical value. Further reduction in pressure p, does not change the flow rate.
The reason for this is as follows: When the velocity in the throat is sonic and the
cross-sectional area of the conduit is constant, sound waves cannot move upstream
into the throat and the gas in the throat has no way of receiving a message from down-
stream. Further reduction of the receiver pressure cannot be transmitted to the throat.
f the receiver pressure is reduced to the level shown by point f in Fig. 6.2, the
pressure distribution is represented by the continuous line adghf. This line is unique
tor a given gas and nozzle. Only along the path dghf is supersonic flow possible. If
the receiver pressure is reduced below that of point, for to
example,
pressure at the end of the nozzle remains at that of point f and fow through the
point &, the
nozzle remains unchanged. On issuing from the nozzle into the receiver the gas suf-
ers a sudden pressure drop from that of point f to that of point k. The pressure
cnange is accompanied by wave phenomena in the receiver. If the receiver pressure
is held at a level between
points e and f, pressure distribution curves of the type
dsg'i and dhkj are found. Sections dg and represent isentropic supersonic flow.
The sudden pressure jumps 88 and hi' represent shock waves, where the flow
changes suddenly from supersonic to subsonic. Shocks are thermodynamically irre-
versible and are accompanied by an increase in entropy in accordance with the
Second law of thermodynamics. Curves g'i and Hj represent subsonic Rows in which
ordinary pressure recovery is taking place.
The area below line adghf is not accessible to any kind of adiabatic flow.
Isentropic flow is confined to the subsonic area aded'a and the single line dghf.
The qualitative discussions of Figs. 6.2 and 6.3 apply to the flow of any com-
pressible fuid. Quantitative relations are most casily found for ideal gas flow.
142 SECTION I: Fluid Mechanics
flow
Equations for isentropic
the flow of ideal gas through n0zz/lee ar
The phenomena occurring in
derivable from the basic equations
given earlier in this ode
Scribed by equations chapter.
Change in gas properties during flow. The density and temperature pathe of the
gas through any isentropic flow are given by Eqs. (0.14) and (6.15). The constannts
(6.23)
To
p-/Y 1-1/Y
Po
(6.24)
These
equations apply to both frictionless subsonic and supersonic flow, but they
must not be used across a shock front.
f)--
Integrating and substituting the limits yield,
Po p
after
p
rearrangement,
(6.26)
AMach number form of
u from Eq. (6.26) into the firstEq. (6.26) of
is convenient. It
is derived by
stitution from Eq. (6.23). This equality Eq. (6.18) and eliminating subsnu
gives p/P% Dy s
(6.27)
Solved explicitly for the
pressure ratio, Eq.
(6.27) becomes
Po
+I(y (6.28)
1)/2Ma?)1/(1-1/
-
The
criticul pressure ratio,
ing p tor p and 1.0 for Ma: denoted by r,, isfound from Eq. (6.28) by stitut-
Su
2 -1/y»
For air at 300 K, (6.29
y ==14 and r, =
0.528.
CHAPTER 6: Flow of Compressible Fluids 143
Gp - ( )1-I/y
(6.30)
(6.32)
Ma-1)= (6.33)
Equation (6.33) shows that for subsonic flow, where Ma «1, the velocity
increases with decreasing cross section (converging conduit) and decreases with
increasing eross section (diverging conduit). This corresponds to the usual situa-
tion of incompressible fow. Lines abc, ade, g'î., and j of Fig. 6.2 represent
examples. For supersonic flow, where Ma > 1, the velocity increases with in-
creasing cross section, as in the diverging section of the nozzle. This conforms to
ine dghf of Fig. 6.2. The apparent anomaly of supersonic flow is a result of the
variation in density and velocity along an isentropic path. Since the mass flow
rate is the same at all points in the nozzle, by continuity the cross-sectional area
of the nozzle must vary inversely with the mass velocity up. The velocity steadily
increaseswith Mach number, and the density decreases. However, at Ma = 1, the
value of Ggoes through a maximum. In the subsonic regime the velocity increases
faster than the density decreases, the mass velocity increases, and S decreases.
In the supersonic regime, the increase in velocity is overcome by a sharper de-
crease in density, the mass velocity decreases, and S increases to accommodate the
total mass flow. This behavior of G is demonstrated by studying the first and sec-
ond derivatives of Eq. (6.30) in the usual manner for investigating maxima and
minima.
144 SECTION II: Fluid Mechanics
Solution
(a) The pressure at the throat is calculated from Eq. (6.28):
0.036
1)/2]0.8310-1714)
20 (1 +[1.4
P= 13.12 atm
From Eq. (6.10), since R = 82.056 x 107 atm.m°/kg mol K,
20x 29
82.056 12.72
x 10-3 x 555.6 kg/m° (0.795 lb/ft)
Substituting Po/ Po from Eq. (6.10) into Eq. (6.26) gives, for the velocity in the throat,
-/Y
2y RTo
Mg--)
=
I.1175v1.01325 x 10 =
355.7 m/s (1, 167 fi/s)
The density at the throat is, from
Eq. (6.23),
PP =
12.72x 0.6564 =9.41 kg/m' (0.587 Ib/ft)
The mass velocity at the throat is
G, =
u,P = 355.7 x 9.41 =
3348
kg/m* (686 Ib/fts s) .s .
=
555.6 x
0.656-/4 =
492.5 K (886.5"R)
(b) From Eq. (6.29)
/1
r )
0.528 P 20 x 0.528 = 10.56 atm
CIAPTER 6: Flow of Compressible Fluids 145
T 463 K (833.4"R)
From Eq. (6.23)
- -()
=12.72 x 0.528/14 = 8.06 kg/m' (0.5031b/te°)
From Eq. (6.30)
1/1.4
1,738=|E*1.4X 12.72 x 20 x 1.01325 x 10
0.4
-1/14
JG)
()-( 0.1294
Pr 0.0939
Po
Flow through straight pipes of constant cross section is adiabatic when heat trans-
fer through the pipe wall is negligible. Although there is usually some heat trans-
fer, adiabatic flow is often a good approximation to actual conditions. The process
Is shown diagrammatically in Fig. 6.15. The typical situation is a long insulated
146 SECTION I1: Fluid Mechanics
This arises from the integration Eq. (6.8). of In adiabatic friction flow, the
SL/#
temperature of the gas changes. The viscosity also varies, and the Reynolds number
and friction factor are not actually constant. In gas flow, however, the effect of
temperature on viscosity is small, and thc effect of Reynolds number on the friction
factor fis still less. Also, unless the Mach number is nearly unity, the temperature
change is small. It is satisfactory to use an average value for f as a constant in cal-
culations. If necessary, f can be evaluated at the two ends of the conduit and an
arithmetic average used as a constant.
Friction factos insupersonie fow are not well established. Apparently, they are
approximately one-half those in subsonic flow for the same Reynolds number.
In all the integrated equations in the next section, it is assumed that the entrance
to the conduit is rounded to form an
isentropic convergent nozzle. If supersonic
flow in the conduit is required, the entrance nozzle must
include a divergent section
to generate a Mach number greater than 1.
It is desired to obtain
integrated form of this equation. The
an
form is one
containing the
Mach number as most useful integral
the dependent variable and the ction
parameter as an
friC
inated from Exy. independent
variable. To
(6.34) accomplish this, the density factor
is
du /u are found from using
Eq. (6.18), and
Eqs. (6.2) and relationships between Ma, dpll
eliminated by using Eqs. (6.4), (6.I3), (6.I1). Quantity dT /T, when it appe
and (6.18). The
results are
dp +(y- 1)Ma? dMa
1+1 1)/2|Ma Ma (6.35)
Also
du p 42 a
4 Ma (6.36)
CHAPTER 6: Flow of Compressible Fluids 147
Substitution from Eqs. (6.35) and (6.36) into Ey. (6.34) and rearrangement give the
tinal differential equalion
2(1 Ma ) dMa
THyMa'{1 +I(y -1)/2]Ma°) (6.37)
Formal integration of Eq. (6.37) between an entrance station a and exit station b
gives
JLd- H JMa,
2(1 Ma) dMa
yMa'il +[( - 1)/2]Ma*}
-L)
H TH
wheref is the arithmetic average value of the terminal friction factors, (Ja + S)/2,
and L = Lb-La.
The temperature ratio is calculated from Eq. (6.20), noting that 7oa Tob: so
40)
From Eq. (6.40) and the temperature form of Eq. (6.18) for the Mach number of an
ideal gas,
yRTgMa, TYRT,Maj
Ta t2MCp (6.41)
From Eq. (6.16)
2MCp
R 42)
Substituting c,M/R from Eq. (6.42) into Eq. (6.41) and solving for the temperature
ratio give
T + -1)/2]Mag (6.43)
T 1+I(y -1)/2]Ma
148 SECTION I1: Fluid Mechanics
conduit as station a and identifying station bas the asterisk condition, where
Ma 1.0. Then the length L,-L, represents the maximum length of conduit that
can be used for a fixed value of Ma, This length is denoted by Lmax Équation (6.38)
then gives
Corresponding equations for p/p', T/T', and p/p* are found from Eqs. (6.39),
(6.43), and (6.44).
Mass velocity
To calculate the
Reynolds number for evaluating the friction factor, the mass
velocity is needed. From Eq. (6.18) and the definition ofG
Ma=pu)
|0.052 1
241 +1(1.4-1)/210.05
(1.4 + 1)0.05 1 =280
CHAPTRR 6: Flow
oT Compressible lFluids 149
)The pressure at the end of thie iscntropic nozzle p, is given by Eq. (6.28):
0 20
+I(1.4 - 1)/210.0521.4/(14-1) 1.0016 20 atm
The pressure, tempernture, and density change in lhe nozzlc arc negligible, and except
for lnear velocity, the reservoir conditions also pertain to the
pipc entrance. From
Example 6.1, the density of air at 20 atm and 1,000°R is 0.795 1b/f*. The acoustic
velocity is, from Eq. (6.17), including 8, in the numerator,
a 14 x 32.174 x
1,000 = 1,550 ft/s (472.4 m/s)
The velocity at the entrance of the pipe is
20 0.05
M2
P=0.913 atm
The mass velocity through the entire pipe is
G=0.795
a = u' =
x 77.5 =
0.0435u
1416 ft/s (431.6 m/s)
= 61.61 lb/ftt s (300.8 kg/n-s)
Since the exit velocity is sonic, «" also be calculated from
can
Eq. (6.17) using
T=T° = 834°R (463.3 K):
834
a=u=550 1000 =1,416ft/s (431.6m/s)
(C) Using Eq. (6.45) withf Lmon/rH = 400 gives
directly.
Multiplying Eq. (6.8) by p gives
dL
o dp +pu du + UJ
2rH
(6.47)
Since pu G , u du = - (Gp*) dp, and p= Mp/(RT), Eq. (6.47) can be written
P-P= 2n Pb
(l,- L,)| (6.49)
TH
where r is the hydraulic radius of the
pipe or channel.
The density
ratio Pal Ps may be used in place of p,/P, in Eq. (6.49). Equ
tion (6.49) can also be used when the
Then, in place of 7, an arithmetic temperature change over the conduit 1s Sia
average
adiabatic flow at low Mach numbers temperature may be used. For exampl
(below about 0.3) follows the
closely. equau
D =
0.075 m
TH 0.075
4 0.01875 m
= 0.0174 cP
(App. 8) =
1.74 x
10 kg/m-s
273
288 3.31 kg/m?
A=.07527
4 .00442 m
HAPTER 6: Flow o[ Compressible Fluids 151
0.000 15 x = 0.00061
D 0.075
S= 0.0044 (Fig. 5.10)
Let (Pa + Ph)/2 = p, so
PaPb )
where p. =2.7 aum
M=29
L= 70 m
R= 82.056 x 10-* m° atm/kg mol K (Table 1.2)
T=15+273 = 288 K
1.982 x 29 x 101,325
=
1.264 atm abs or 0.264 atm gauge
-)
In these equations Q/nm is the heat Now into the gas in joules per kilogram.
(6.51)
SYMBOLS
Area, m* or ft
or ft/s; ag,
at pipe entrance
Acoustic velocity in fluid, m/s at constant pressure; c, at constans
heat, J/g. °C or Btu/lb. F;C
Specific
volume
D Diameter, m or ft
dimensionless; J, at station a, f, at station b:
Fanning friction facto,
f. average value
Mass velocity, kg/m*. s or lb/ft s; G,, in receiver; G,, at throat; G', value
G
when Ma = 1.0; Gmax, maximum value
Gravitational acceleration, m/s* or ft/ss
32.174 ft 1b/lb, s
Newton's law proportionality factor,
Enthalpy, J/g or Btu/lb; H, at station a; Hy, at station b; H, stagnation
value; Hsa H,, at stations a and b; Ho, at reference temperature; H", value
when Ma = 1.0
Greek Letters
Subscripts
AS statio
At stationb
Isentropic flow
Stagnation value
Reference value, reservoir conditions
PROBLEMS
6.1. For the inlet conditions of Example 6.2, what is the maximum length of pipe that
may be used if the pipe is 2 in. in diameter? What is it for the inlet conditions of
Example 6.32
6.3. A divergent-convergent nozzle has the proportions shown in Table 6. 1. Air (y= 1.40,
M=29.0) enters the nozzle from a reservoir in which the pressure is 20 atm abs and the
emperature 1s 3 0 K. Fiot t e pressure, the temperalure, and the Mach number versus
the length of the noZzle when (a) the fHow rate is a maximum without shock and with
subsonic discharge and (b) the tlow is isentropic and the discharge is supersonic.
TABLE .1
G.4. A standard I-in. Schedule 40 horizontal steel pipe is used to conduct chlorine gas. The
gas enlers the pipe through a rounded entrance at a pressure of 6 atm abs, a temperature
ol 120C, and a velocity of 35 m/s. (a) What is the maximum possible length of the
154 SECTION 11: Fluid Mechanics
6.6. Calculate the stagnation temperature for air flowing at 200"C and 1.5 atm if the veloc-
ity is 0.9 of the sonic velocity.
6.7. Air enters a 25-mm (1-in.) Schedule 40 steel pipe at 350 K and p =5x 10° N/m2. The
velocity is 120 m/s. Assuming flow is adiabatic, for what length of pipe would the air
leave at sonic velocity ?
REFERENCES
1. Cambel, A. B. Handbook
1961, pp. 8-5 to 8-12.
of Fluid Dynamics. Ed. V. L. Streeter. New York: McGraw-Hil,
2. Cambel,
A. B., and B. H. Jennings.
Gas Dynamics, Ncw York:
3.
p 85-8S6. McGraw-Hill, 1998,
Shapiro, A. H., and W. R. Hawthorne. J. Appl. Mech. 14: A-317 (1947).