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To cite this article: G. M. Ayoub & L. Malaeb (2012) Developments in Solar Still Desalination
Systems: A Critical Review, Critical Reviews in Environmental Science and Technology, 42:19,
2078-2112, DOI: 10.1080/10643389.2011.574104
Download by: [American University of Beirut] Date: 14 April 2016, At: 02:29
Critical Reviews in Environmental Science and Technology, 42:2078–2112, 2012
Copyright © Taylor & Francis Group, LLC
ISSN: 1064-3389 print / 1547-6537 online
DOI: 10.1080/10643389.2011.574104
1. INTRODUCTION
Two challenges relentlessly face humanity today: (a) fresh water is a fi-
nite resource seriously impacted by pollution; (b) fossil fuels are also finite
and their use in fuel-based desalination aggravates environmental pollution
problems. Technologies such as multistage flash, multiple effect, vapor com-
pression, reverse osmosis, ion exchange, electrodialysis, phase exchange,
and solvent extraction are heavy energy consumers often requiring complex
controls and bulky processes (Abu-Arabi and Venkat Reddy, 2005; Fath,
1998; Muller-Holst et al., 1999).
2078
Developments in Solar Still Desalination Systems 2079
heated and evaporates, and the vapor condenses as it hits the roof and
trickles down reaching a channel, which transmits the flow into a collection
container. The stills can have various forms, shapes, and cover materials
and their operation requires little maintenance besides regularly flushing the
basin to remove accumulated salts. As with other desalination processes, the
resulting brine remains to induce a negative environmental impact. How-
ever, such brine could prove to be an important source of metals that may
be used in various industrial applications (Ayoub et al., 2000). Disposal meth-
ods currently practiced include surface water discharge, disposal to sewers,
deep-well disposal, land application, evaporation ponds, brine concentra-
tors, and spray-drying to solids or crystallizers (i.e., zero discharge option;
Fath, 1998). Discharging brine in turbulent hydrodynamic conditions such as
water bodies featuring waves, currents, and supercritical flows and using dif-
fusers to reduce salinity through mixing and dilution are often recommended
(Medeazza, 2005). Salts recovery (Jegatheesan et al., 2009) may also be an
option to utilize the large mass of concentrated salt components. The ma-
jor waste stream produced by solar stills is not characterized by intentionally
added process chemicals, as is the case with other desalination technologies.
Rather, the concentrate reflects the raw water characteristics, which is of the
same composition but at a more concentrated level (Fath, 1998).
Although environmental impact assessment procedures have been pro-
posed, technical solutions, codes, and standards are still in their early phases
(Medeazza, 2005). The environmental concerns primarily center on the con-
tamination of surface and ground waters, underlying soil, and drinking water
aquifers. Mitigation methods include additional processing to remove or di-
lute any chemicals of concern, use of noncorrosive and nontoxic materials,
use of diffusers, and continuous blending of cleaning wastes and concentrate
or separate disposal of cleaning wastes and concentrates.
The main limitation of solar stills is their low productivity compared with
conventional desalination processes, and this has been the focus of intensive
research. The operating efficiency is low due to main two shortages: the first
Developments in Solar Still Desalination Systems 2081
is the rejection to the atmosphere of the latent heat of condensation and the
second is the difficulty in raising evaporation temperature and decreasing
condensation temperature as heating, evaporation, and condensation take
place in one container (He and Yan, 2009). Table 1 presents typical daily
yields for the conventional basin-type still. The yield is usually measured in
liters per unit area per day. Important factors, however, are masked in this
measurement method, which does not reflect the influence of parameters
that directly affect the yield such as available insolation and sunshine hours
in the geographical area where the still is installed.
A major concern in increasing the amount of distillate produced is to
maintain economic feasibility and simplicity in construction, operation, and
maintenance. In this article we present a critical review of the research
work conducted on solar stills development. Important parameters that af-
fect the still productivity include the use of absorbing materials and wicks,
cover cooling, cover slope, still design, brine depth, inlet water flow, and
initial brine temperature. Studies addressing each parameter of concern are
grouped together and results are compared. Novelty in design and newly in-
troduced features and their impact on output are then presented. Modeling
efforts of flow circulation within the still and methods to estimate internal
heat transfer coefficients are discussed next. Finally, costs of solar stills are
presented and future research needs are outlined.
Several parameters affect the performance of a solar still. These include the
presence of a dye or absorbing material, cover cooling by air or water flow,
cover slope, still design, geographical position, water depth, inlet water flow,
and initial brine temperature. Research investigations on these influencing
factors are discussed in this section.
2082 G. M. Ayoub and L. Malaeb
from as low as 7% for red carmoisine (Rajvanshi, 1981), as high as 60% for
black dyes (Akash et al., 1998), and as high as 96% for sponges and fins (Vel-
murugan et al., 2008c). An accurate comparison of the effects of different ab-
sorbers in these studies is difficult, however, due to the large variation in the
experimental conditions of each study. Such conditions include geographi-
cal location, time of the year, particular still design and construction material
used, brine depth, water temperature, and other site-specific factors. Aybar
et al. (2005) tested an inclined flat solar absorber plate with a black cloth or
a black fleece and showed that the black wick still produced 2–3 times more
water than a bare plate still. The collected data in this study, however, was
limited to a two-week period and tests were performed over 7 hr per day.
According to Murugavel et al. (2008), rubber is the best material to
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Where r2 is the best root mean square value. These correlations, however,
should be used with care given the assumptions and limitations that they
were derived for and that are stated previously. Further calibration of the
proposed equations may be necessary and the degree of their validity to
similar stills that have not been included in their derivation is unknown.
with wind speed up to a certain value between 8 and 10 m/s for winter
and summer conditions, respectively. This value was independent of the still
shape and brine heat capacity, and the wind was more effective in summer
and for higher water masses. Similarly, Fath and Ghazy (2002) reported that
increasing the air flow rate up to 0.5 m3/s increases productivity with no
further improvement obtained with air flowing beyond this rate. Tiwari and
Rao (1984) reported that the daily distillate production is almost doubled for
stills with water flowing over glass cover at a uniform velocity. On the other
hand, Fath and Hosny (2002) found that glass cover cooling by wet cloth for
1-, 2-, and 6-hr intervals had no effect on productivity and that continuous
cooling is needed to release a significant amount of condensation energy.
No effect on productivity was noted in their study for wind speed in the
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The effects of using different shapes (Figure 1) and having multibasins have
also been studied. In multiple-effect basin stills, the floor of the upper com-
partment acts as the condensing surface of the lower compartment. As a
result, efficiency is greater than that of a single-basin still typically by 35%
or more but the cost and complexity are higher (Qiblawey, 2008). Table 3
summarizes the results of different studies conducted on cover slope and
still geometry.
FIGURE 1. Spherical solar still (left) and double-basin still (right) (Color figure available
online).
still and a 10% increase in yield when water is flowing over the cover (Dhi-
man and Tiwari, 1990; Kumar and Anand, 1992; Sodha et al., 1981b). Tanaka
et al. (1981) showed that the performance of a tilted-wick still is superior to
the conventional still with an increase in productivity by about 20–50%. The
wick basin type solar still designed by Minasian and Al-Karaghouli (1995) in-
creased productivity by 85% while that studied by Velmurugan et al. (2008a)
gave a 29.6% increase compared with 15% and 45.5% when using sponges
and fins, respectively. Analytical expressions for the thermal efficiency of
evaporative heat loss and heat transfer in these types of stills have also been
derived (Janarthanan et al., 2005; Shukla and Sorayan, 2005).
Effect of Maximum of 0.36 l/hr obtained for two stages Obikane and Al-Bilbisi
multistages Reverse wind direction reduces efficiency by (2009)
22% while forward wind direction increases
efficiency by 6%.
Effect of (i) 0.8 L/hr for optimal conditions Obikane et al. (2009)
multistages (ii) Triangular shaped multistage still have
1.4–1.5 times more productivity than those
that are rectangular.
Regenerative Similar to a double-effect still: 70% more Abu-Arabi and Zurigat
still productive than the conventional still (2005)
Vertical still Low efficiency of 18.6–33.19% was attributed Boukar and Harmim
to high vapor and condensation heat (2005)
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TABLE 4. Effect of brine depth (modified from Khalifa and Hamood, 2009b)
Variation in Decrease in
brine depth Type of still productivity (%) Reference
2, 4, 8, 12, 16, Single sloped, 30◦ 25%; the yield became Tiwari and Tiwari (2007)
and 18 cm constant for depths
>10 cm
2–3.5 cm Single sloped, 32◦ 26% Badran (2007)
1.5–4 cm Single and double 9% Al-Hayek and Badran
sloped (2005)
3–6 cm Single sloped, 15◦ 29% Nafey et al. (2002)
2–30 cm Double sloped 14% Al-Hinai et al. (2002a)
3–6 cm Double sloped, 15◦ 13.5% Akash et al. (2000)
2–7 cm Single sloped, 32◦ 14% Nafey et al. (2000)
2–5 cm Single sloped, 8–13◦ 11% Kamal (1988)
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Murugavel et al. (2008) reported that for deep basins, water depth is in-
versely proportional to productivity during daylight but the reverse is true
for overnight production. Also, Tripathi and Tiwari (2005) reported that more
yield is obtained during offshine hours as compared to daytime for higher
water depths due to storage effects. As for continuous saline water feeding,
lower mass flow rates were found to produce more output (Aybar et al.,
2005).
A simple passive solar still can produce from 1–4 l/m2/day (Table 1) depend-
ing on location, water depth, time of the year, tilt angle, construction, and
insulation material and solar radiation. According to Khalifa and Hamood
(2009a), solar radiation I (MJ/m2/day) has the highest impact on productivity
and they correlated them as follows:
FIGURE 2. Still with passive condenser: (a) purging and (b) natural circulation (Color figure
available online).
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Main Findings
Type of Still of the Research Productivity Basic Features Reference
Separate evaporation Optimizing energy efficiency and 40 l/m2 product water 15 patented interconnected Koning and Thiesen
and condensation approaching the limit of day in day out for elements enhance each (2005)
chambers freshwater output. optimized version others’ performance and
productivity.
Built-in additional Most influential factors are solar 8 l/d/m2 base area (55% Built-in finned condenser tilted Fath and Hosny
condenser and intensity, insulation, basin mass, more than the to be parallel to sun rays (2002)
enhanced evaporation evaporation surface area and reference) and enhanced evaporation
condenser inner reflectivity. using black dyes.
Still with a radiative A delay in response to thermal Maximum condensation The radiative panel, storage Haddad et al. (2000)
cooling system capacity advances the time at is 2 L in 10 hr. tank, and still are designed
which maximum productivity so that the tank is able to
occurs. Productivity increases condense all vapor
with solar radiation but produced during daylight.
efficiency decreases due to
increased thermal losses.
Inverted absorber solar About double the output of the An optimum value for The evaporative heat loss is a Tiwari and Suneja
still conventional still. yield is reached for strong function of (1998, 1999)
seven basins. temperature.
Still with additional Efficiency increased by 45% A condenser in the shaded Fath (1998)
condenser compared to conventional still. region of the still.
Double-condensing Significant enhancement in 35–77% higher output Suneja and Tiwari
chamber still output due to vapor pressure than that of (1997)
difference between the two conventional solar
condensing chambers. still.
Simple basin still with 2–3 l/m2/day Passively cooled condenser Fatani et al. (1994)
condenser placed on the still roof.
Simple basin still with Efficiency = 71% 7.1 l/m2/day Condenser placed under the Lessing (1990)
condenser energy collecting area.
Multiple solar still with a 20% higher yield than the simple 15–25% higher than the Excess vapor is condensed on Reddy et al. (1983);
condenser wick still but under cloudy and noncondenser-type the additional surface and Tiwari et al. (1984)
arrangement low intensity conditions both still. reduces heat load on the
stills show similar performance. cover.
Simple basin still with Efficiency = 42% 4.5 l/m2/day Passively cooled condenser Chandra et al. (1980)
2089
condenser placed inside the still.
2090 G. M. Ayoub and L. Malaeb
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FIGURE 3. Solar still coupled with flat-plate collector (Color figure available online).
than simple passive stills. Table 6 summarizes the basic features and findings
of studies conducted on solar stills that are coupled to external heat collec-
tors and/or reflectors (Figures 3 and 4). Although the increase in productivity
can be significant in some cases, most studies do not show the additional
costs entailed by the proposed design. Similarly, system feasibility and jus-
tifications for increased area requirements and complexities in maintenance
and operation are often not included.
Main findings
Type of still of the research Productivity Basic features Reference
Air-blown tilted wick A major part of the enthalpy of 1 l/m2/hr for double Heat and mass transfer is Aboabboud et al.
double-chamber with the hot saturated air entering glass cover based on the flow rate of (2009)
heat recycling the lower chamber was saturated air pumped in.
recycled.
Tilted wick still with an Optimal reflector’s inclination 15–27% more output An inclined external reflector Tanaka and Nakatake
inclined reflector was 15◦ from the vertical than still with vertical to increase the productivity (2009a)
reflector of a tilted-wick still.
Tilted wick still with a Optimum still orientation is 41% more yield than the The still is rotated once a day Tanaka and Nakatake
vertical flat plate obtained for the equinox and simple basin type at southing of the sun. (2009b)
reflector solstice days.
Vertical multiple-effect Productivity increases by Productivity is 9–17% No contamination contrary to Tanaka and Nakatake
diffusion type solar increasing partition area and higher for optimum inclined wick stills, which (2007)
still, coupled with a the number of partitions and by collector angles than get soaked and where
heat-pipe solar decreasing the saline water the fixed ones partitions deform due to
collector feed rate and the thickness of protruding fibers from
diffusion gaps between wicks.
partitions.
Asymmetrical still with 20% more output than a Use of mirrors on the inside Al-Hayek and Badran
mirrors symmetric greenhouse walls (2004)
still
Coupling with storage Coupling with a hot water storage Thermal coupling with a Productivity is a linear Mathioulakis and
tank and external heat tank leads to a constant tank can double the function of solar radiation Belessiotis (2003)
sources production rate. productivity. and the average values of air
temperatures of previous
days.
(Continued on next page)
2091
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2092
TABLE 6. Studies on solar stills with collectors and reflectors (Continued)
Main findings
Type of still of the research Productivity Basic features Reference
Still augmented with A double effect arrangement did 2.19 l/m2 versus 3.13 An asymmetric inverted Smyth et al. (2002)
reflector and not improve output. l/m2 for the passive convection suppression
concentrator still circular reflector.
Solar still with stored Efficiency improved by Storing energy during the day Abdel-Rahim, (2001)
excess solar energy 28% and condensing the vapor
inside copper tubes held at
a lower temperature.
Four-effect diffusion still Different modes and 8.7 l/m2/h with energy Two units: A hot storage tank, Rheinlander and
configurations of heat recovery, input of 2.0 kW/m2 coupled to a solar collector, Graeter (2001)
and natural or forced and the distillation unit.
convection in the four
distillation chambers.
A thermal desalination Numerical simulation results and 25 l/m2/day for 4.8 kW A solar collector and a Schwarzer et al. (2001)
unit with a heat experimental data for the unit h/m2/day solar desalination tower of six
recovery system are presented. radiation stages with water circulation.
Still with concentrator Yield increase by 22% External trough type Zaki et al. (1992)
concentrator.
Solar still integrated with Forced circulation mode gives 30–35% increase in yield Using a thermosiphon mode Yadav (1991)
a flat-plate collector 5–10% higher yield than of operation.
thermo-siphon mode.
Single-basin solar still Best performance is for forced 24% higher yield than Disconnecting the collector Rai and Tiwari (1983);
coupled with a circulation and blackened jute for a simple during off-sunshine hours Tiwari (1985); Rai et al.
flat-plate collector cloth floating over the basin single-basin solar still. increases yield. (1990)
water and a small quantity of
black dye.
Developments in Solar Still Desalination Systems 2093
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flow to eliminate scaling and stagnation with the suction of humid air to
remove condensation on the internal cover. An elongated shape of the still
was built to prolong retention time and accumulate heat so as to evaporate
more of the brackish water before being discharged. The exiting brine is
collected and rerouted to a heat exchanger in countercurrent flow with
the seawater entering the still, gradually increasing the solution’s thermal
energy. Evaporating water is routed in copper tubes drawn by cold salty
solution entering the system. Vapor in copper tubes is liquefied and the
liquefaction’s energy is given back to the cold salty solution. The reported
net output of the system was 5.3–5.8 l/m2/day and was expected to increase
if the still is operated in tropical areas. Kemp (2009) described another novel
still, which uses convoluted tubes, operates on 95–100% renewable energy,
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has very low environmental impact, has minimal operating and maintenance
costs, and is scalable. For the tested conditions, productivity varied between
7 and 9 l/m2/day.
hc L
Nu = = C · (Gr · Pr)n (5)
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K
The Prandtl number expresses the ratio of viscous to thermal diffusion rates
and is only a function of the fluid and the fluid state:
µCp
Pr = (6)
K
The Grashof number Gr approximates the ratio of the buoyancy force to the
viscous force acting on a fluid:
gβρ 2 L3 T
Gr = (7)
µ2
Farid, 1995). Adhikari et al. (1990) considered the influence of the charac-
teristic space of stills but ignored the fact that the relationship between the
evaporative and free convective heat transfer coefficients will change with
temperature. Kumar and Tiwari (1996) developed a thermal model for so-
lar distillation units based on linear regression analysis to determine these
coefficients for different Grashof number ranges without the limitations of
Dunkle’s model. They used the following relation:
mew
= C(Ra)n = C(Gr · Pr)n (13)
R
Which can be written in the form:
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y = mx + Co (14)
Where:
K 3600
R = 0.016273(Pw − Pg ) (15)
d hfg
The following relation for the evaporation rate of solar stills could be devel-
oped and verified by experimenting on a multistage stacked tray solar still
(Hongfei et al., 2002):
hc
me = (ρw − ρg ) (17)
ρf Cpaf Le(1−n)
Koffi et al. (2009) modeled a solar still using an implicit numerical scheme,
the Diabolo-Sablier algorithm. The amount of distilled water generated highly
depended on the ambient temperature. It was noted that further experiments
with the particular conditions and simulated device are needed before sound
conclusions can be made. Tsilingiris et al. (2009) modeled solar stills with
the relaxation of some simplifying assumptions in Dunkle’s model and the
use of a modified form for the Grashof number in order to account for the
difference in water vapor content, which is lighter than dry air between two
regions of humid air mixture:
∗ gL3 ρg
Gr = 2 −1 (18)
ν ρs
2098 G. M. Ayoub and L. Malaeb
Where ρ s and ρ g refer to the saturated mixture density at the free brine
surface and the top condensing plate at temperatures Ts and Tg , respec-
tively. This expression is further simplified assuming ideal gas behavior and
a similar form to that of Dunkle’s relation for the convective heat transfer is
obtained with the numerical multipliers being 5.5% lower due to the con-
sideration of humid air thermophysical properties. The expression used for
the evaporative heat transfer assumes that the saturated vapor pressure at
the water surface and the cover is negligible compared to barometric pres-
sure and is valid for an average still temperature of around 50◦ C. Jubran
et al. (2000) modeled a three-stage still with an expansion nozzle and heat
recovery systems. They used a corrected latent heat of vaporization at the
condensation surface temperature Ts as presented by Cengel (1998):
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Other researchers have treated the still as a black box and correlated the
incidence solar radiation with the distillate quantity produced during daytime
operation (Mathioulakis et al., 1999; Voropoulos et al., 2004):
The value of a solar still is ultimately judged on the basis of its economy
(Arjunan et al., 2009). Solar stills are characterized by their high initial costs
and low annual operating costs. If P is the initial investment in the system, i
the interest rate, n the number of useful years, and S the salvage value, then
the system annual cost is determined as (Arjunan et al., 2009, Kumar and
Tiwari, 2009):
i(1 + i)n
First Annual Cost = P (25)
(1 + i)n − 1
i
Annual Salvage Cost = S (26)
(1 + i)n − 1
Although research on improving the still productivity are abound, few have
fully addressed the economical aspects. Mukherjee and Tiwari (1986) ana-
lyzed the costs of different types of stills and concluded that roof type con-
crete solar distillation plants are the best choice for large-scale plants. Kumar
and Tiwari (2009) presented a complete life-cycle cost of a single-slope hy-
brid active solar still and estimated its energy payback time as 4.7 years
compared with 2.9 years for a passive still. The cost of distilled water varies
considerably depending on the system design and the year of investigation.
Reported values vary from $30/m3 for a large-size plant for pyramid-shaped
still (Fath et al., 2003), to $20/m3 for a large size plant (Ghoneyem and
Ileri, 1997), to $16.3/m3 for a cluster of 250 simple stills (Al-Hinai, 2002b),
to $2.4/m3 for 50m3 production using porous basin stills (Madani and Zaki,
1995) and down to $0.66/m3 for a system using the novel still described by
Kemp (2009). From this trend, it can be seen that further research can lead
to a water production cost that competes with other technologies. Larger
systems will help decrease the overhead costs of auxiliary components
(Arjunan et al., 2009). Kabeel et al. (2010) performed a cost analysis for differ-
ent still configurations and some of their results are shown in Table 7 along
with cost and productivity data from other studies. Table 7 also presents
cost data for small-scale reverse osmosis systems for comparison. It should
be emphasized that an accurate comparison in terms of desalination costs
and production is difficult. The prices and material performances depend
greatly on the place and year of the project implementation (Charcosset,
2009). It should be noted, however, that the production rate for solar stills
is proportional to the area of the still, which means that the cost per unit of
water produced is nearly the same, regardless of the installation size, which
makes them more attractive for small-sized applications. This is in contrast
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2100
TABLE 7. Cost and productivity data for solar stills and renewable-energy RO
to fresh water supplies and to other desalination methods, where the capital
cost of equipment per unit of capacity decreases as the capacity increases
(Kalogirou, 2005).
also invaluable for better prediction of the still performance and for system
optimization. Promoting solar distillation further requires focusing research
efforts on improving existing technology to lower costs and developing more
compact installations that reduce land use. Of key importance are material
optimization, system reliability, design sustainability and longer life span, use
of hybrid systems, and the combination of the effectiveness of individual de-
velopments into one integrated system. Such improvements need to address
the enhancement of thermal storage and insulation, increasing the surface
area available for evaporation, incorporating thermo-optical properties of
the condensing covers, and developing novel geometrical setups to add to
the benefits of this old system from today’s high-tech developments. The
introduced modifications, however, should not defy the basic advantages
of the solar still in being simple, low cost, easy to handle, and requiring
little maintenance. The use of solar panels, collectors, ponds, condensers,
and other productivity-enhancing devices requires considerable space and
thus developing more compact systems with low cost is a main challenge.
Battery storage may be necessary to account for the intermittent nature of
solar radiation but this storage is only practical for small-scale plants, due to
the cost of batteries. The maturity of the introduced technologies should
also take into account the low level of infrastructure, often characteriz-
ing places with severe water stress and that lend themselves to solar stills
application.
Finally, the solar still remains to be the basic technique for the inexpen-
sive production of water and is a low-tech method that can be easily adopted
by local rural people. With the growing global oil crisis, the need for alter-
natives to conventional desalination plants based on fossil fuels grows. The
use of solar stills has so far been restricted to small-scale systems due to
their relatively low thermal efficiency and production rate compared with
the large areas required. They tend to be competitive, however, with other
renewable-desalination technologies in small-scale production due to their
relatively low cost and simplicity. Enhancing solar stills in order to eradicate
their limitations can therefore provide a means to attain self-reliance and
2102 G. M. Ayoub and L. Malaeb
is another issue. The brine produced by solar stills may also be of less en-
vironmental impact than that produced by other desalination technologies
since it is free from the chemicals, antiscalants, and cleaning waste streams
that constitute a necessary part in operating other desalination systems.
ACKNOWLEDGMENTS
The authors would like to acknowledge the Lebanese National Council for
Scientific Research and the Middle East Desalination Research Center, Oman,
for financially supporting this work.
NOMENCLATURE
Sc Schmidt number = Dν
Sh Sherwood number = 0.15(Gr × Sc)1/3
T Temperature, K
Ta Ambient temperature, K
y Daily productivity of the still, kg/m2/d
β Expansion factor
Difference
εeff Effective emissivity
εw Emissivity of water
εg Emissivity of cover
µ Dynamic viscosity
ν Kinematic viscosity
ρ Density
ρv Density of partial pressure of vapor
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