CN 102491917 A (19) HE A RAE RAPA “p (12) SERB SASS (10) RERZS7HS CN 102491917 A (43) FRB AL 2012. 06.13 (21) IRS 201110402504. 2 (22) IRE 2011. 12.07 CRRA dR TARE bh 100048 Jk UTTER RLM LL Sb RAE (72) RBA i HE SKE Fe MT (61) Int. cl 0070 233/36 (2008. 01) 0070 231/12(2006. 01) 0070 69/96 (2006. 01) C070 68/06(2006. 01) 0076 51/41 (2006. 01) 0070 53/10(2006. 01) 0076 59/08(2006. 01) BOIF 17/22 (2006. 01) BOIF 17/18(2006. 01) AOIN 37/20(2008. 01) AIP 100(2006. 01) ARG 2 WA MIR 2 GA) RRB LAE eA te a IN = IR rail ar OE RE SE 8) HE BLE Ae er OM MBNA OE AR ERY ee A HEIN HE, HY AeA Ac Be ESE A i Ae eo AE = Me Hi AA a ech AR A ae 3 PI FABRA — FP Hs OL PT S| APR HOLA DT ACRE PE A IEE 3 UL, AG SEAR ER LID, AE MIR DRT ib FO Fa HE LB MY ae (2a UN I Pe he WME RE AU HT AEE BS.CN to2ag1917 A RHE RK FH 2K 1, TRIS DERE PE Fe be AEE BE CE A TA — FRR SCAT 2 — FP GUL Be SE = PP eR SAC (Hk) AEE BSE EAL DEE PE = th JET PE EA, i 5 AEF CE EE he I PEN PS eS ILA CH R——C—NH—(CH,)s—N*—CH, * Av CH, SRE ERY Cy ~ Coy HAM ER AS HA EL EBS EY A REE, I EIR, AL ee, Bi BAR, HRT HEAR 5 Ay CH,CO, HCO, , HCOO , CH,COO , FLA@HE . J5 EEMRAR 52 ARAL T/A HSO, NO, HPO, . ON. 2. HARASS LTA S-2E TTT HEFL, SURRIEZE TRY Cy ~ Coy MANE AOA EB SCARE I REE HEE, AL FOR, aR, LRT EE 6 SAAB AEA 1 TANS Ze HS THIAL, HURP ETE TA” 4 CHCO, HCO, sHCOO .CH,COO FLREGHR EER Sek PRGA TJ RAR HSO, NO, HPO, . OH A, RAUBER 1 GAS ZR TB TE i 5 HOARE GE CE T° Ee DADA = eh OP BAR FG PE AE SBT — PA EE WR FATT Bee LS — FRE SUBEAUARAR EG 1 1 ~ 5 21, BOSE 80 ~ 250°C, BEET TA 4 ~ 15 sib, BEE FEA) 0. 5 ~ 4, OMPax, FTV PUGHEE PAE — FF EASA AL AS 90% BRINE AU a 2 THAT cE BE FR — FFP, AEH A) BS EE Sah J FE UG HCP AE = RR TE BENE Fs ° omy ° cus | CH Hy 5 PRAYER 1 (OTA Len TE HA 5 OR GE CEP THAR SEE Bc A ALITTLE ECD 3S PE RGR FN Re RR Cd) CEPA TDG IER PATE A FMS AIR Ci) HPRAR EGAN 1 0.5 ~ Lot 3, BE OA AE 10 ~ 60°C, KE MEAT TA] 2 ~ Th, HACKS 90%. RBM Ks ° CHs I R—C—NH—(CH;—=N_ + CHAOCO;CH; —> ems ‘CH; + CHyCOs CH: i g CHs R-C—NH~(CH;);“N—CH- CHjCOs +HA—> R- —C—NH—(CHz)z—N*CHy, + Av +CH;OH; ba CHy ib 6, BRAY BER 1 POTEAU -AE MSG TE HUY td a» FONE GE CE tl TAL A TE ZS WE TARE ATE ZN 7. HUB BOAEER 1 PAHO PEA HOE REIN GE SOR ECE Pp ee SE = SASOBCHER TRG He (PKOL2-CHCO,) + Are Sie REN ATE = TEAR Al BH (PKOL2-HCO,) bh eed 2CN to2ag1917 A RHE RK FH 22H UCI = FE FH RH (PROL2-HCOO) . F—Aoc SAVER Bee = FFE ZR BE (PKOL2-CH,COO) . oh Be We A PE SP SE FL Be (PKOL2-CH,CHOHCOO) 742 25°C F ili FP ABE Pe BE 9 FO 2.24% 107 ~ 2. 24% 10 "mol /L., $e FE AI HLH 28. 15 ~ 33. 69mN/m. BARA CAUSES 1 OTSA TTS EHUD EME, SCARS ELE PTGS Bh A A VELA BAY BE 8 AU a FIO AS 5 TCA Pe i PR OT A 4URLER. PKOL2-CH,CO,, PKOL2-HCO,, PKOL2-HCOO PF ME HH SMU (2A — (BE, ALP ASSL Ue [40d ERE]. PKOL2-CH,COO, PKOL2-CH,CHONCOO x 4 #440 UH (EY 8H SE.CN 102491917 A eH AR PREC S Mia MARE PSB ah SRE BEM AT Coon] Ax Az HN: A Fi ay I he A Ca We AR eh HACE ET iE» SEL PAHO FED iy WG A — Ae We — A cE YT eI TER PS ie. AS Se ST ee AE ER eS CH) AIC BO FH EEA Cs Ms Ht OR He A eae» HL SEAR TT ME AE EE TA Jk HALE A SUK HRA Cooo2] fet LAE HAAR NASA SACS EA ARE AB AE TEAR ee AR ANE AE AG et BS PA ST SCARE 5 eR FUE SUA ke, LC EIS As FB RE A RT 9 SP AT O02 — FG A PIAS OH PS FL TAD HEA 2 Coons] Axe WML ik AAS RRR SSEE H]AA BEA SILA Be ACE AN ED EE VD VRS FY 28 C6, A RF EO A, SAT OS RES BREE SATB 4 FFE UI ISIN EAD HR HA BNP, BA AU PALE VERA ACALAR, GH NaBr NaCl ij SEG IE 1G eR FFE 9 SURI, DG AE 7) A, SE i FE UBC PE PAE ETT PAE L.A Sh, MRR SC a Pe a 5G EHR PTE Ue Fe A BL DG A AL SRNL RAS Coos] A Az HA ES A LAI Ay EER TATE — FPR ARR RRIF a EU ll 4 TA Be Ex ANA BOE AE: TE lh PET ED HP CR PEAT HEE Looms] A Az MEY BALA he A te By a UD RP eh Ss AA sta [0008] R——C—NH— (CH,)s [0007] FRY ROY Cy ~ Cop MLA ASA EL EBS RE PRM EE, ER, AS PQ, GHD, BURP EAE + [0008] A 4 CH,CO, . HCO, , HCO”, CH,COO FL ARH. FI HERRHL 37 LMR. TPH. HSO, NOs s HPO, Ol. fooos] ALAA HART a a PER AS RIA Coovo) Ax BY FTA 1 RG BD eA Ss PAE ee yi 3 I I Ss FP A 4CN to2ag1917 A eH 2K AUBERT LEPESANT BSE, RR TAIT Hs OE ee DE — EB ME a HL 5 1 1, SMBERE 80 ~ 250°C, RAVINIA) 4 ~ 15 i}, RMEFE I 0. 5 ~ 4. OMPa, GH ERRTE SEF BE ABU ALS 90.6 » BRIN Cet A EE ASL BR — FEUD pS Jee FS AEF SPI = PE TBR LR [0011] 9 CH ° chy R—C—NH—(CHy)s—N + CHOCO;CHy —* R—C—NH—(CH,),—N—CHy + CH;COS" CH; CH; Coon] Far SA8 fy SACs Bg BS he A 0) A wk ARG GW de GS AR Pe 5k (Ci) PERRET 2 HR i EDGR PE FRE BR FP he Sj Ac PR CBR) TARA EL Lt 0.5 ~ 12 3, RAE 10 ~ 60°C, KEANE) 2 ~ Th, HEALS 90%. MVR [0013] ° cH, i Gite R-C—NH~(CH2)3-N—CH3 + CH;COS +HA—> R—C—NH— (CHa) NCH - AX 4#CH,OH cH, CHs Coors] ile OT ALATA TE, CREATE AAS TE, CSE. PW ETA BS FP WEG TG he} A Iie AE (PELL) FUL (FA 2) (FAL 3) GES RUT b> the Coons) fara Ay AES ENT 3S RE le Ze TK PEE 9» Pe TE =F SADA Ta BE (PKOL2-CH,CO,) Foe Ses ERR ALAS — SE RR SLB (PKOL2-HCO,) fed UII ME SF ET RHE (PROL2-HCOO) .— Are SE NMEA SE = PIE Ze (PKOL2-CH,COO) , fe BOG HE PL HE = FTL FL Pe (PKOL2-CH,CHOHCOO) #E 25°C F 22 THI 9K Ay ~ Hee HE a AR CPA)» ELH Ay UA FP MSC Be ATE 99 2. 24 107 ~ 2.24 10*mol /L, TKD 28, 15 ~ 33. 69mN/m. Coons) Far AS Hs AE ENE SS PRE le ah A AS TE MUG RE Oy LOmg/ml. tS TERPS FRR Phe CAR BS TA GAL AS ER A 2 [0017] 1185-400 FH FE (mm), they CREWE rm RMT tee 28.6 11.0 13.2 W2 32.0 124 125, 13.3, Geaarkoi coment 7 79 109 na [oo18]CN 102491917 A eH 3/4 PKO12-CHsCOO 347 23.0 189 33.7) PKO12-CH;CHOHCOO- 38.1 23.3 19.7 339 FAL 19 204 18.5 20.3 Coons] fii Ar wR Mks He 3a) he eh Ae yw HAL HY BS ee A A Ay I PS PR PETAL See (6 EAGER TR BF AL SAL He. PROL2-CH,CO,. PKOL2-1ICO,,, PROL2-HCOO Xf PS Ee at hil (2A) AR, A PLS he SMM FH] 2 PKOL2-CH,COO, PKOL2-CH,CHOHCOO Xf 4 Piva Hd (OLA, ARE AR AR Coozo] A AE ARYL RA PSL = AS AE BP] A Ly A i eT PD eRe ET LT ‘PES PELE» AA ALR AR RTI 5 A REI TRF TAT RIT, HE TP PSE RORY IR A» RAG TPM LAA AB 2 ORS FETT PSEA Cooat] ft eRe WRN (oo22] fl 2 ree DBR AQ PE BS ASS (oo2s] fl 3 ree WIR AQ PE DBS ALS [0024] [#4 425°C PKOL2-CH,CO, PKOL2-HCO, ,PKO1 2-HCO0, PKO12-CH,CO0,PKO12-CH,CHOHCOO PRUTTK Hy BHM EAL 6 RET a ABTHAK (0025) Seif 1 [ooze] PUR} se REM AITE— PEALE 28. 4g AU TAR 18q, TEE MA Bie FRE SBF 150°C, HAE LNY 10h, PUI) 1. MPa RIVE AR RB A Da Py REPENS EE ETAL AS BEA PB, HR 9 HJ a» PBR AS BA ARIAL Bh soe EET 3 = PERG PARI 32. 60 (oo27] — Seitifal 2 [0028] Hk eA WE SAE—PAALNR 42. Gy AIMEE PAK 18q, SEIMEI RE, IA Si) BR SE, BES FLL 170°C BEE IY 12h, SALE 1. AMPA. SHUG AREAS EA FAI Hy Fs MSCS ADD 5 AES HALLO PE — ARH 9} BS J A AAR BT Soe EN SE = PE HK 31. dg (002s) Sitifal 3 [00s] BRIDE AS / 1 J Ue INCI 3 — PR BUI 36. 9g ALMA INE 18¢. CNMI Dn ABR, SARTRE 160°C, BPERIS 10h, SEALE A) 1. SWPao SQ BELA IG ERY Bl FEE ANE II A EP AE Ee eS ATL RA — IS, CU A JE a BINS / 1) Ae REPT 3: = PET FG PE CIAL 43, Le (oos1] Sif 4 [0032] IR ERE REE PE Me AR PAG Og, GEL, On Ae ey, 150°C, HEME Sh, SAE A 1. 2MPas KOA EI ARYe HAE SE AD Fa NCBA A HELE FALTER A WH — FF RHR Gb ol» PER A BACAR 6CN 102491917 A eH 4A FE 6b ERTS SP I PG 15. 60 HR — ERENT ES TG M3. 75g ALLA 0. 6g, IABP AT TU REI 35 CHEN 4h, KM AUR SS PAUL ih, ABT — ee I PE = HE ZR IAL 3. 36g. Coosa] Se itefal 5 [0034] eI EET — PA 16g AURA PNG 9g, FRAPS, Mn Ae SEP, BURFI 160°C, BEEF BENE 10h, SEAN FRAY 1. SMP BREEN AC It ERY 2 EA FD Da MBE 2 EE FLATTER HS RGF FT, IRS a Je at » PER A BO BACAR [5 8b eR PTE SP I PG 16. Ag. PUR eM BS PETG WK 4g ALL O. 7g, IMA BU EL EE BEI AO'CHEPE RS Sh. ATAU BREE HUFF FBI — eA IE = PE ZR IAB 3. Ag Coos] Seitefal 6 [0036] PSH 28g + — se RELI — PRE WAT 27 BRA PM, Zee Hat A Be SEP, BURT 160°C, BUFF BENE 12h, SALARY 1. OMPa ROLE ERM aN EA PD Wa MCB AID 2 HEE FALTER — FR, HR SP a J at» PR AS BF AAR FB ERR TUE = RI DANE 30. 70 PRR eT = DR TG M3. 75g ALFLAG Le. INA BURA ES REI 35°C RAE BNE dh BAT AC BRAS HUFF RS hs 3B EER PE = PE ZR GIA 3. 37gCN 102491917 A i om oH Mt 12K i } pes ee ChacnacncH oMCnAcEKANEH CHCOO eect tren egCN 102491917 A i om oH Mt 2/2 A rH f YorNr-t) = PKOT2CH,CO, | © PKOIZHCO, | | prorncoo | + PRorecHeoo | + PROZ-CH.CHOHEOG 40 3s 30 as DSO tgofermot") fea