640 Appendix B Table B44 Antoine Equation Constants? Logs Example: The vap loEi0 Peary Compound Acetaldebyde ‘Acetic acid ‘Acetic acid® ‘Acetic anhydride Acetone ‘Acrylic acid Ammonia" Aniline Benzene n-Butane i-Butane Butanol 2-Butanol Butene Butyrie aid arbon disullide Carbon tetrachloride Chlorobenzene Chlorobenzene* Chlorobenzene* Chloroform Chloroferm* Cyclohexane Cyelohexanol n-Decane Decene 1,-Dichloroethane 12-Dichloroethane Dichloromethane Diethyl ether Diethyl ketone Diethylene glycol Dimethyl ether Dimethylamine NN-Dimethyltormamide 1u-Dioxane Ethanol Ethanolamine Euthyl acetate Ethylacetate” Ethyl chloride Ethylbenzene ae r re P'inmmHg, Tin“C nessure of acetaklehyde at 25°C is determined as follows: 600.017 25 1 291.809 > Pisol25'O) = 10°" = 902mm Hy (25°C) Formula CHO GH, CHO, CaO CHO CHO, NH, caLN Cae n-CiFho 1-CMo CHO CiHicO CH CHO, cs, cc, Cac Gua GHC CHC, cul, Gin GH:0 n-CioHle, CyoElan HAC, Gud LC, CiHeO CHO CAHioO: CHO GHN GENO CHO; 8.00552 Range (’C) 0210344 298 to 1265 01036 62.8 to 139.4 = 12910553 20.0 t0 700 83 10 60 102.6 to 1852 145 10 809 18.010 -0.3 85.110 - 89.20 1287 724 to 1071 11510 -39 20.0 1500 3.610799 14.1 10760 62.00 131.7 Ord 4210 230 10410 603 30 to 150 19910816 93.7 to 160.7 945 to 1751 868 to L716 =38810 176 30810994 40.0 1040 60,8 10 19.9 $65 to 1113 1300 10 243.0 “78210 -249 =7181069 30.00.99 200 to 105.0 19610934 65.4 t0 170.9 15610758 20 to 150 55910 56.5 t0 1371 6 2.9551 A 8.00552 7.38782 718807 74948 7am 5.65208 7.554665, 732010 6.39272 632485 6.78866 7.36365 720131 653101 871019 6.98279 6.87926 6.97808 7.10690 6.92508 6.95465 6.90328 6.8094) 6.25530 6.95707 6.95433 6.97702 7.02530 7.40916 6.92082 7.02529 1.63665 6.97603 7.08212 6.92796 7asiss 811200 7.45680 720179 7.09808, 6.98647 6.95650 zB 1600.07, 153,313 1416.7 aatamis 1210595 648.629 1002711 assis 1208531, 943.453 899.617 1305.198, 157.000, 810.261 2433.04, 1169.110 1212001 1431.053 1500.0 4413.12 170.966 1163.03 1206.00), 912.866 1503.568 3497527 1174022 aam.as4 1325.938, 1064.066 1310281 1939359 389.264 960:242 400.869 1554679 1592.864 1577.670 1244951 1238710 10300007 193.543 c 291.809 222.309 225 qo9s17 229.664 154.683 247.885 206.089 219.888 239.711 241.942 3407 168.279 228.066 255.189 241,593 226.409 21750 2240 2160 226.232 214 223.148 109.196 194.738 197.056 229.060 222.997 252.616 228.799 214.192 162.714 241.957 221.667 196.434 240.337 226.184 173.368 217881 2170 238612 213.091 “Adapted from T Bovblik, V. Fred, and E. Hla, The Vapour Pressures of Pure Substances, Beever, Ansterdam, 1973 1rmasked with an asesse(*), constants ate ftom Lange's Handbook of Chemis, 5th Eeitio, Handbook Publishers Inc, Sandusky, OH, 1956 (continued)Table B.4 (Continued) Compound Ethylene glycol Ethylene oxide 12-Fthylenediamine Formaldehyde Formic acid Glycerol n-Heplane i Heptane 1Hieptene n-Hexane i-Hexane L-Hexene Hydrogen Cyanide Methanol Methanol* Methyl acetate ‘Methyl bromide Methyl chloride ‘Methyl ethyl Ketone ‘Methyl isobutyl ketone Methyl methacrylate ‘Methylamine ‘Methyleyclohexane ‘Naphthalene Nitzobenzene Nitromethane n-Nonane 1-Nonene n-Octane i-Octane 1-Octene n-Pentane i-Pentane 1-Pentanol 1-Pentene Phenol 1-Propanol 2-Propanol Propionic acid Propylene oxide Pyridine Siyrene Toluene 1,,1-Ttichloroethane 1,12-Trichloroethane ‘Trichloroethylene Vinyl acetate Water? Water* m-Xylene o-Xylene p-Xylene Formula CHO, GHO GHN: HCHO CHO; CHO, nC 1-H CHa n-CThe 1CHyy Cathy HEN cH,OH CHO CHO; CH,Br cana cao CcHGNO; CHANO, n-CiH Ole nC iC CH CTs 1-CHy GH,0 CH CaO GHO HO CHO, CHO GHN CH CH GHGs Gul CLO, 0 HO m-CaEy Hie City Range (0) 50.0 02000 0310318 265 to L174 1094 © -223 37.410 1007 183.3 to 2604 25910993 18510909 21.6 0.945 13010695 1281061, 15910643 16.410 46.2 14910837 200 140 1810558, 7001036 7501050 428 (0884 21.7 0 1162 3920892 83.1 10-62. 25.6 to 1018. 80.310 179.5 134.1 to 210.6 55710 1364 0301518 665 w 147.9 52.9 to 1266 417 0 iss 449 t0 122.2 13310368 16310286 747 10 1560 12810307 1072 to 181.8 602 to 1046 52310893 724 w 1283 24210348 67.310 1529 2990 1448 35310 1115 5.410 169) 50,0 0 113.7 17810865 2180720 dt060 60 t0 150, 592 te 140.0 635 to Mds.4 583 t0 139.3 Physical Property Tables A 8.09083 8.69016 716871 719578 758178 6.16501 6.90253 6.37689 691381 6.88555, 6.36839 6.36880 752823 8.08097 7.87863, 7.06524 7.09084 709349 7.06356 sei, 8.40919 7.33690 6.32827 7.03358, 71562 7.28166 693764 69stIT 691874 688814 6.93637 684471 6.73457 7.18246 63268 7.13301 774016 7.74021 7423 ols 7oans 7.06623 6.95805 s6u34d 695185 651827 721010 8.10765 7.96681 7.00646 7o01sd 6.98820 B 2088.936 2005.79 136.235, 970.595 1699.173, 1036-056 1267.828, 1238.22, 1265.120, 175817 1151401 154.646 1399.49 1582271 1473.11 1157630, 1086.06 948.582 1261.339 1168-408 2050-467 1011532 1273673, 1756.328, 1746.58 1406.937 1430.459 1437.86, 1351.756 1319529 1355.79 1060.793 992.019 1287-625, 1083.206 1516790, 437.686 1399517 A733. 1086.36 1373 799 1507434 1346.73, 2136.621 114410 1018-603, 1296.130, 1750 286 168.210 1460.183, 1476393, 451.792 c 203.454 334.765 194.366 2aga4 260:714 28.097 216.823 219.783, 220051 224867 28477 226.006 260,418 239.706 2300 219.726 24ao14 289.336, 221.969 11998 274.369 233.286 221723, 208 842 201.783, 227.600 201.808 205.814 209.100 211.625 213022 Bisa 229.568 161.330 233.348 1743954 198.463 197527 217724 228.594 214979 214985 219.693, 302.769 209.197 192.731 226.655 235.000 228,000 214827 oa