yuiz 1 Test Form A July 7, 2014 ly CHEM 1C —B.Kunkel QUIZ1 S2014 INSTRUCTIONS: Bubble in Form A on your Parscore Form Write your perm number and bubble in your perm number (7 digits only) Completely fill bubbles / answers > There are six questions. Each question is worth 4 points. It is to your benefit to SHOW ALL YOUR WORK ON THE QUIZ and CIRCLE YOUR ANSWERS. Turn in the Seantron form only. Keep the quiz so you can check your work and your answers later. The answers to the quiz. will be posted on our course web page. NOTE: No hats with caps allowed. No notes or calculators allowed. Cell phones and all other electronic devices must be turned off and put away. 1. What is the molecular geometry and polarity of the SO2 molecule using VSEPR theory? Electronegativities: S (2.5), 0 (3.5) A) linear, nonpolar B) linear, polar ) bent, nonpolar D) bent, polar E) none of the above 2. Use Lewis structures to predict the bond order for a carbon-oxygen bond in carbonate ion, CO;””. A)2 B) 43 Ql D) 32 E) more than one of the above 3. For which of the following molecules and ions does the central atom have sp hybridization: NO", Os, and Is? A) NO," only B) Os only C) Ir only D) Os and I5~ E) I; and NO,* 1” 8A 7 2 4 7] He JA_2A 1.008 BA 4A 5a 6a | 4003, 34 spe |7[s po] 2} | Be p|c|n|o|F | Ne coun [9.012 1081 | 12.01 |xa01| 16.00 | 1900| 2038 3 [ate B]u | as, iw [a7 [a E 3]Na | Mg al} si |p| os Ja] ar & “|azooimaso] 3 4 5 6 7 tat __ 22 | 26.98) 28.09 |30:57| 52007 | 35.05 | a995 3 [o [aya] [als] w]e psi] | a] ]ast a [as] a sfx | ca} se} mi | v | cel ata | Fe | co | Ni | cu| zm | Ga | Ge | As| Se | Bef kr [38.10 40.08] 4486) 478 | soe |5200) 56:94 [35:5 |55.93 [se 65.5 | 65.9 | 69:72 7261 [ra92| 7m | v9.00 | 93.40Quiz 1 Test Form A July 7, 2014 4, What is the molecular geometry around a central atom that is sp'd hybridized and has one lone pair of eletrons? A) trigonal bipyramidal B) trigonal pyramidal ) none of the above 5. Which of the following has the highest bond order? A) OF B) 0." ©) 0; D) 02" E) The bond order in all these species is the same. 6. Consider the image of a molecular orbital in a homonuclear diatomic molecule below. This molecular orbital was formed by combining a 2p orbital from each atom. What is the energy of this molecular orbital, compared to the energy of a 2p orbital on one of the separate atoms? A) higher B) lower C) the same D) not enough information End of Quiz ANSWERS: 1.D 4D 5D 6B 1A sa 1 2 H 7] He aA_2A 3.008 3A 4a sa 6a | 400 sys a af | te s}e [xl o | F | xe 50 oa ast 1201 |sa.r| x600 | 19.00 2038 3 [ufo a yu pis} ie |] E al Na | ay afs |e] 's | a] ae Eigse) sss 6 7 8 9 at _a2_| 26981 2809 [a07] sz | s5as| 995 ~) | a; zl Bpals pez p=ys pa || tal ss pas] 36 aie [ea] x] m |v |e] mm | re [co | Ni | cu | an | Ga| Ge | as| se | te | ke 3310] 40.09 4496] «728 so [spon] su [ss [sas lon Joss | 5.30 | e872] 7251 [rasa] 7596 | aso | 5380Quiz 1 Test Form A July 6, 01s CHEM 1C - B.Kunkel QUIZL $2015 INSTRUCTIONS: Bubble in Form A on your Parscore Form Write your perm number and bubble in your perm number (7 digits only) Completely fill bubbles / answers There are six questions. Fach question is worth 4 points. It is to your benefit to SHOW ALL YOUR WORK ON THE QUIZ and CIRCLE YOUR ANSWERS. Tarn in the Parscore form only. Keep the quiz so you can check your work and your answers later. The answers to the quiz. will be posted on our course web page. NOTE: No hats with caps allowed, No notes or calculators allowed. Cell phones and all other electronic devices must be turned off and put away. 1. A compound, XFs, is 52.44% X by mass. What is the molecular geometry of XF.? A) tetrahedral B) square planar ©) square pyramidal D) see-saw E) none of the above 2. Which of the following characteristics apply to S03? 1. polar bonds 2. nonpolar molecule 3. linear molecular shape 4. Sulfur is sp hybridized A) L only, B) Land 2 ©) 3and4 D) 1,2,and3 E) 1,2,3,and4 3. How many atoms in this structure are sp* hybridized? Lone pairs are not drawn in, A)2 B) 3 4 D) 5 E) none of the above More Questions —_Quiz 1 Test Form A July 6, 2015 4. Of the following, which molecule has the smallest bond angle? A) CBry B) H30 ©) CO, D) NH E) more than one of the above have the same smallest bond angle 5. Which of the following is paramagnetic? A) N: B) B, Q Gt D) FY E) At least two of these are paramagnetic: 6. According to molecular orbital theory, which of the following lists ranks the oxygen species in terms of increasing bond order? D) OF <0" <0; E) none of the above End of Quiz ANSWERS:LB 2A 3.C 4B SE 6BQuiz 1 Test Form A April 11, 2014 CHEM IC —B.Kunkel QUIZI ‘Sp2014 INSTRUCTIONS: Bubble in Form A on your Parscore Form Write your perm number and bubble in your perm number (7 digits only) Completely fill bubbles / answers yp There are six questions. Bach question is worth 4 points. It is to your benefit to SHOW ALL YOUR WORK ON THE QUIZ and CIRCLE YOUR ANSWERS. Turn in the Seantron form only. Keep the quiz so you can check your work and your answers later. The answers to the quiz will be posted on our course web page. NOTE: No hats with caps allowed. No notes or calculators allowed, Cell phones and all other electronic devices must be turned off and put away. L. Consider the following molecule. Lone pairs are not drawn in. ° I =CH-C—CH)—C=N ita eesti cts Specify the hybridization of each carbon atom (in mumerie order: C-1_C-2 C-3 C4 C-5), A) spy ssp’ sp’ sp) sp" B) sp’ sp’ sp’ sp sp C) sp, sp SR SPL Sp. D) sp? sp? sp? sp sp E) sp’ sp’ sp’ sp’ sp Hy 2. Predict the molecular geometry and polarity of PFs. The electronegativity of P is 2.19 and the electronegativity of F is 4.00. A) trigonal planar, polar B) trigonal planar, nonpolar C) trigonal pyramidal, polar D) trigonal pyramidal, nonpolar E) tetrahedral, polar 3. Consider a molecule with three atoms, the molecule cannot be linear if the hybridization of the central atom is, : A) sp, B) sp? C) sp* D) sp’or sp* E) sp’d or spd? aa 8A, 7 2 H 7] Me 3A 24 1.008, 3a 4a sa oa | 2.003 37s 3] 6]7|s >3 | i a} ui | te Bi} cin] o |e] ne 6041 |9012| 1081] 1261 |1201| 16.00 | 1900 | 2038 nm | wa [as] a6 pa | ae ala | mg aj si |r| s | a] ar Er) EE) wm aT) |My | Te Tm le sel | v || Mm | Fe | co | ni | co 39.10 4008] 2496] 4738] sass [5200] 5494 [55.95 [5093 |5s.60 [e355 2698| 2809 |s097| 3207 | 3545 | 3995 es Ga| Ge | as] Se | te | ke 6372| 7261 |7490| 7a96 |7990| 93.80 BoekeQuiz Test Form A April 11, 2014 4, How many of the following molecules and ions are linear? NCh CH: SCN CS: SO» a4 B) 2 ©3 D)1 Ho 5. Of the following, which molecule has the smallest bond angle? A) CHa B) CLO ©) NOs D) COs E) more than one of the above have the smallest bond angle 6. Which statement about the ammonia molecule is true? The clectronegativity of N is 3.04 and His 2.1 A) The N—H bonds are polar, but the molecule is non-polar. B) The molecule has both three g- and one x-bond. C) The H—N—H bond angles are greater than or equal to 109.5 degrees. D) The nitrogen atom uses sp* hybrid orbitals for o-bonding. E) More than one of the above statements are true. End of Quiz ANSWERS:LE 2.C 3D 4B 5.B 6DQuiz 1 Test Form A April 8, 2016 (CHEM IC — B.Kunkel QUIZ1 ‘Sp2016 INSTRUCTIONS: Bubble in Form A on your Parscore Form Write your perm number and bubble in your perm number (7 digits only) Completely fill bubbles / answers jp ill There are six questions. Each question is worth 4 points. Itis to your benefit to SHOW ALL YOUR WORK ON THE QUIZ and CIRCLE YOUR ANSWERS. Turn in the Scantron form only. Keep the quiz so you can check your work and your answers later. The answers to the quiz will be posted on our course web page. NO’ io hats with caps allowed. No notes or calculators allowed. Cell phones and all other electronic devices must be turned off and put away. 1. An. AX3 molecule has an electronic geometry of trigonal bipyramidal. How many lone pairs are on the central atom? Ayo BI C2 D)3 E) none of the above 2. How many of the following molecules are polar? PCs IFs SO: XeFs Ayl B)2 O3 D)4 E)0 3. Consider the image of a molecular orbital in a homonuclear diatomic molecule below. This molecular orbital was formed by combining a 2p orbital from each atom. What is the designation of this new molecular orbital? A) Tp B) Top C) 62 D) 6°» E) None of the aboveQuiz 1 Test Form A April 8, 2016 4, How many atoms in the following molecule are sp” hybridized? Note: Jone pairs are not drawn in. Lod 4 ©. C, H A)10 NF Neo Bs i | o6 ¢ ca D)12 a E) none of the above | 4 ° 5. Which of the following is paramagnetic? A) Fo B) Ni ©) D) Be E) more than one of the above are paramagnetic 6. Order the following in order of INCREASING bond strength. LooONr IL os? im G IV. Net A) [<< I CO; + 2H,0 a) Carbon goes from sp hybridization to sp hybridization b) Carbon goes from d’sp” hybridization to sp” hybridization ©) Carbon goes from sp* hybridization to sp hybridization d) Carbon goes from sp’ hybridization to sp hybridization e) The hybridization of carbon does not change during this reaction 5) {4 pts) Which of the following is polar: a) BF b) co; NCI d) none of these e) more than one of these 6) (3 pts) Consider the following molecule: Hef! aces Hac N All atoms in this molecule must lie within the same plane. a) True b) False Answers: ae 2yA 3)8 4D sc OryQuid Sample Quiz ¢ Instructions: No hats or hoods allowed. No books or notes allowed. No calculators. Cell phones, iPods, headsets/headphanes, and any other electronic devices must be turned off and put away. There are a total of 2 pages (6 questions} on the quiz. Not every question is worth the same number of points~-point values are indicated for each question. You may work out the problems and write your answers on this quiz; however, you must completely fil in the appropriate bubble(s) on your ParSCORE form. Turn in the ParSCORE form ONLY. You may keep your quiz if you want. The answers to the quiz will be posted on our course web page. 1) (4 pts) According to VSEPR theory, which of the following will have tetrahedral electronic geometry? a) Ns b) Ste c) CH, d) Both (a) and (c) have tetrahedral electronic geometry e) Choices (a), (o), and (c) all have tetrahedral electronic geometry 2). (3 pts) Determine the number of «and x bonds in the following molecule: H H i rd co H Cy N a) 4a,2n b) 40,30 co) 6a,20 d) 4G,50 e) 60,37 3) (3 pts) Identify the hybridization for Xe and F in the molecule XeF,. xe F a) | sp sp b) | asp sp Cae di | sp" sp e) dsp’ sp4) a) b) 4) e 5) a) b) p) a) co) a) 4) 3 d) e) (4 pts) How many of the following molecules are nonpolar: NH, CH,O, BFs, SFsCl {4 pts) Determine which of the following will decrease the bond order in the molecule Nz ‘Adding an electron Removing an electron Either adding an electron or removing an electron will decrease the bond order Neither adding an electron nor removing an electron will decrease the bond order (3 pts) Determine the C-0-N bond angle (labeled a”) in the following molecule: HO 1 ut H-C-O-N-O TN Hs 180° Less than 180° but greater than 120° 120° 109.5" Less than 109.5° Answers: yo aye ajc 4yB syc ee