AIITS 2224 PT I JEEM Sol

FIITJEE
ALL INDIA INTEGRATED TEST SERIES

PART TEST – I
JEE (Main)-2024
TEST DATE: 03-12-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. C
Sol. Let x = length, then
 X  L and dx   L 
x
By principle of dimensional homogeneity    dimensionless
a 
 a   x   L 
By substituting dimensions of each quantity on both sides we get
L
 Ln
2
L
 n0
2. C
3
Sol. Volume  a3   7.203   373.715 m3
In significant figures, the volume of cube will be 373.7 m 3 because the side of the cube has four
significant figures.
3. B
   
Sol. a b  c  d
   
ac  bd
Subtracting (2) from (1), we get
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AIITS-PT-I-PCM(Sol.)-JEE(Main)/2024 2
       
 a  b    a  c   c  d  b  d
     
 a  b  c    c  b   d
     
 a  b  c    b  c   d
      
 a  b  c   b  c   d  0
       
 a  b  c   d  b  c   d  0
    
  a  d   b  c   0
   
So,  a  d and b  c  are parallel
4. B

 dr
Sol. v  a sin  t  î  a cos  t  ˆj  bkˆ
dt

v  a 2 2  b2
The distance moved by the particle in one full turn of helix is given by
 2 2 2
s vT a   b2

5. C
Sol. v 2A  2g  h  x  and v B2  u2  2gx
Since v A  vB
 u2  2gx  2gh  2gx
 u2  2gh
 u  2gh
6. A
Sol. Considering the vertical motion, if t be the time taken by the particle to go form A to B, then
1
h  gt 2
2
2h
 t
g
During this time the particle must make an integral number of rotations (say n).
Now, considering the horizontal motion, then
ut   2r  n
u 2h
 n
2r g
7. D
d
Sol. centre 
dt
d  1
circumference     centre
dt  2  2
 centre  2circumference
 centre  4rads 1
Now v  Rcentre  (2)(4)  8ms 1
3 AIITS-PT-I-PCM(Sol.)-JEE(Main)/2024
8. B
Sol. Let AC = x and BE = y. Then
B
A C
E
D
BE  AE 2   2
2
2
x
 y     2
2
2
  x  dx 
dy
 2y       0
 dt  2  dt 
dy 1  x   dx 
    
dt 2  2y   dt 
When the rhombus is a square, then x = 2y
1 v
 vB  v C 
2 2
9. C
Sol. mg  sin    cos    2mg  sin    cos  
 tan   3
 tan   3 tan 
   tan 
10. B
Sol. kx = 2mg
By Law of Conservation of Energy
1
Mgx  kx 2
2
 kx  2Mg
 2mg  2Mg
 Mm
11. D
Sol. Net pulling force on the system is Mg + mg – mg or simply Mg. Total mass being pulled is M +
2m. hence acceleration of system is
Mg
a
M  2m
kx
a
M
Mg
Now since a < g, there should be an upward force on M so that its acceleration becomes less
than g. Hence for any value of M spring will be elongated.
12. C
Sol. Impulse is the area under F-T graph, as well as the change in momentum. So,
1
mu  Area  F0 T
2
2mu
 F0 
T
13. D

Sol. Since, F -is a constant force, so work done will not depend on path
 2, 2, 2   
 W   F  d
 0, 0, 0 
 2, 2, 2 
 W   2iˆ  5ˆj  kˆ    dxiˆ  dyjˆ  dzkˆ 
 0, 0, 0 
 2, 2, 2 
 W   2dx  5dy  dz 
 0, 0, 0 
 2, 2, 2 
 W   2x  5y  z   16 J
 0, 0, 0 
14. B
h1 h
Sol. The centre of gravity of liquid in the first column is and that in the second column is 2 .
2 2
Let Initial Potential energy be Ui
h  h 
 Ui   Ah1  g  1    Ah2  g  2 
2  2
1
 Ui  ag h12  h22
2
 
h1  h2
When the water column in the two equivalizes then equivalent height is and the centre of
2
h1  h2
gravity in both the columns is . If Uf be the final potential energy of liquid in both the
4
columns then
  h  h2   h1  h2  
Uf  2  A  1   g
  2   4  
1 2
 Uf  Ag  h1  h2 
4
Since work done is equal to the decrease in potential energy,

So,
W  Ui  Uf
2
 h  h2 
 W  A g  1 
 2 
15. C
Sol. Since 

dW  F  dr, where

dr   dx  î   dy  ˆj
 dW  k  ydx  xdy 
 dW  kd  xy  d  xy   xdy  ydx
 a, a 
 W   dW  k  d(xy)
 0, 0 
 a, a
 W  k  xy  (0, 0)
 W  ka2  0
 W  ka2
16. A
Sol. x = Elongation is spring due to mass 10 kg
mg 10  10
x   1m
k 100
1
WF   100 (3)2  (1)2   10  10  2  200 J
2
17. D
Sol. At maximum extension, velocity of both the blocks will be same Let v be the common velocity of
the blocks (towards right). By Law of Conservation of Linear Momentum, we get
6(2)  3( 1)  (3  6)v
 v  1 ms 1
If x be the maximum extension in the spring, then by Law of Conservation of Mechanical Energy,
we get
1 1 1 1
(3)(1)2  (6)(2)2  (200)x 2  (9)(1)2
2 2 2 2
 3  24  200x 2  9
18
 x
200
 x  0.3m
 x  30 cm
18. A
 
Sol. In the figure let v12 = velocity of ball w.r.t wedge before collision and v12 = velocity of ball w.r.t
wedge after collision, which must be in vertically upward direction as shown.

M 
v 12  v 12
 
v1
30o
 O
N  v2
o
30
 
In Elastic collision v12 v '12 will make equal angle (say  ) with the normal to the place. We can
show that   300
 MON  300
v2
Now,  cot 300  3
v1
19. C

Sol. The angular momentum of a body L -may be expressed as the sum of two parts,
(A) one arising from the motion of the centre of mass of the body and
(B) the other from the motion of the body with respect to its centre of mass.
   
i.e. L total  L C.M.  rC.M.  p
   
 L total  L C.M.  M  rC.M.  v C.M. 
For this problem
1
L C.M.  I  MR2  and
2
 
M  rC.M.  v C.M.   MRv CM  MR R 
 
 M  rC.M.  v C.M.   MR 2 
1 3
 L total  MR 2   MR2   MR2 .
2 2
20. B
Sol. The rod will rotate about A. Therefore by low of conservation of Mechanical Energy, we get
 Decrease in   Increase in Rotation 
   
 Gravitational    Kinetic Energy 
 Potential Energy   about A 
   
 1
 mg    IA 2
2 2
   1  m  2
2
 mg     
2 2 3 
3g
 2  ...(1)

 A
vc C
Centripetal force on CM of rod in this position in
 3mg
FC  m   2  towards A
2 2
Let F be the force exerted by the hinge on the rod upwards, then
F  mg  maC  FC
3mg
 F  mg 
2
5
 F mg
2
5
So, the force exerted by the rod on the hinge is mg, downwards.
2
SECTION – B
21. 5
Sol. Initial and final positions are shown in the figure. By Law of Conservation of Energy, we have
 Loss in GPE   Loss in GPE   Gain in RKE of 
    ....(1)
 of m   of CM of disc   mass+disc 
m
R 5R/4
C 3R/4 R/4
R/4
P Q P Q
3R/4 C 5R/4
 R
Loss in gravitational potential energy of mass m is

 5R  5mgR
mg  2  
 4  2
Loss is gravitational potential energy of CM of disc is
 R  mgR
mg  2   
 4 2
Therefore, total decrease in gravitational potential energy of system is
5mgR mgR
U    3mgR ….(2)
2 2
1
Gain in rotational kinetic energy of system (mass + disc) is K  I2
2
Where I is the moment of inertial of system (disc + mass) about axis PQ
 I = moment of inertial of disc + moment of inertial of mass
2 2
 mR 2 R    5R 
I  m     m 
 4  4    4 

15mR2
 I
8
1  15mR2  2
 K    ...(3)
2 8 
Substituting (2) and (3) in (1), we get
1  15mR2  2
3mgR   
2 8 
16g
 
5R
Therefore, linear speed of particle at its lowest point is
 5R  5R 16g
v  
 4  4 5R
 v  5gR
 x5
22. 9
2  2 
Sol. I  2  MR2   2  MR2  Md2 
5  5 
8
 I  MR2  2md2
5
2
8  5 
 I    0.5     2(0.5)(4)(2) 104
5  2  
   
5 
 I    8   10 4
5 
4
 I  9  10
 N9
23. 6
v
Sol. mv cos   mv cos   m  m 
2
2mv cos   mv
1
 cos  
2
   600
v
 2m
m
m v/2

Just after
Impact
v
Just Before
Impact
So, angle between the two before collision is
   2  1200

  60
20
24. 4
Sol. String becomes taut when A moves upwards by a distance  under influence of gravity. Let v1 be
the velocity of A at this moment, then
2
v12   10g   2g  8g
 v1  8g
Let v 2 be the common velocities of both A and B, just after string becomes taut. Then from Law
of Conservation of Linear Momentum, we have
A V1 A V2 A V2
  
V2 V2
B B B
m 8g  m  0    m  m  v 2
v1 8gl
 v2  
2 2
Both particles return to their original height with the same speed v 2 and the string becomes loose
as soon as B strikes the ground and the speed v with which A strikes the ground is,
8g
v 2  v 22  2g   2g
4
 v 2  4g
 v  2 g  4g
 x4
25. 2
Sol. Since Wnc  Wext  U  K
Let the block move down the incline through a distance x, then
1 1
fx cos 1800   0  kx 2   mgx sin    mv 2
2 2
1 2 1
   k mgcos   x  kx  mgx sin   mv 2
2 2
Fs
N
mg
 1  1  6  v 2
 v2  4
 v  2ms 1 x
x sin
26. 2
Sol. Speed of each particle at angle  using Law of conservation of Energy is
v  2gh, where h  R 1  cos  
 v  2gR 1  cos  
Also, at angle , we have
mv 2
N  mgcos  
R
 N  mgcos   2mg 1  cos  
 N  2mg  3mgcos  ...(1)
When the tube just breaks its contact with the ground then
2Ncos   Mg
Substituting the value of N from (1), we get
4mgcos   6mgcos2   Mg
Substituting,   600 , we get
3mg
2mg   Mg
2
m
 2
M
27. 6
Sol. AC = 0.5 m, BC = 0.3 m
 AB  0.4m
A
T

T

B F
C
8N
Let BAC  . Then

AB 0.4 4 BC 0.3 3
cos     and sin    
AC 0.5 5 AC 0.5 5
We observe that the object is in equilibrium under three concurrent forces. So, applying Lami’s
theorem, we get
F 8 T
 

sin 180   0
 
sin 90   0
 sin900
F 8
  T
sin  cos 
8 8
 T   10 N and
cos  4 / 5
3
 8   
8 sin   5   6N
F 
cos  4
 
5
28. 5
Sol. 100 
mv 2  4  v

2
 
r 1
 v  5ms 1
Now, 5   k g t  v  at
5
 t 5s
 0.110 
29. 8
Sol. The angular speed is
v 2
   8rads1
r 0.25
30. 4
Sol. From the diagram, we observe that
  
rP  rFields  rBall …(1)


where rP  46iˆ  28ˆj m  …(2)
Let fielder run for the ball making an angle  with the horizontal. Then


rFielder  5t cos  î  sin ˆj 
…(3)
y
INTERCEPTION
PONT

rFlelder
 
rBall
P

rP
x
(0, 0) O
where t is the time taken by the fielder to go from point P to the interception point which equals
the time taken by the ball to go from the origin to the interception point with a velocity of
 
7.5iˆ  10ˆj ms1 . So


rBall  7.5tiˆ  10tjˆ  …(4)
Substituting (2), (3) and (4) in (1), we get
 46  5t cos  î   28  5t sin   ˆj   7.5t  î  10t  ˆj

 46  5t cos   7.5t ...(5)
28  5t sin   10t ...(6)
From (5) and (6), we get
7.5t  46 10t  28
cos   and sin  
5t 5t
Since, cos2   sin2   1
2 2
 7.5t  46   10t  28 
     1
 5t   5t 
Solving to get
116
t  4s or t  s
21
So, the shortest time for interception is
t=4s
Chemistry PART – B
SECTION – A
31. C
Sol. According to molarity equation M3  V1  V2   M1V1  M2 V2 , we have
 480  1.5  520  1.2 
M3   1.344M
1000
32. D
Sol. Molarity of solution is defined as
Number of moles of urea
M  1000
Volume of solution in mL
Now, number of moles of urea
Given mass of urea 120
= 
Molar mass of urea 60
Also, density of solution
= Mass of solution/Volume of solution ….(1)
Where mass of solution = mass of urea + mass of water
= 120 + 1000 = 1120 g
Substituting values in Eq. (1), we get
1120 1120
1.15   Volume   973.9 mL
Volume 1.15
Therefore,
120 / 60
M=  1000  2.05M
973.9
33. C
Sol. van der Waals equation is
 a 
 p  2   V  b   RT
 V 
but it is given that b = 0. So, the equation reduces to
 a  a
 p  2  V  RT  pV    RT
 V  V
Comparing it with a straight line equation we get slope as -a. Calculating the slope, we get
24.6  20.1
 1.5  a  1.5
3.0  0
34. C
a
Sol. Ease of liquefaction 
b
For easily liquefiable gas, more should be the value of a and less should be the value of b.
For ethane, a = 5.49, b = 0.638 and for Cl2, a = 6.49, b = 0.562.
35. C
Sol. The electronic configurations are
C2  1s 2  * 1s 2 2s2  * 2s 2 2p2x  2Py2
C2  1s2  * 1s2 2s2  * 2s2 2p2x  2p1y
The election has been removed form bonding molecular orbital, so the bond order decreases.
In NO  NO 
NO  1s2  * 1s 2 2s2  * 2s 2 2p2z 2p2x  2p2y  * 2p1x   * 2p0y
NO+ = 1s2  * 1s2 2s2  * 2s2 2p2z 2p2x  2p2y
The electron has been removed form antibonding orbital, so bond order increases and nature
changes from paramagnetic to diamagnetic.
36. A
 1
Sol. Hybridization =    V  M  c  a where V is the number of valence electrons around central
 2
atom, M is the number of monovalent groups attached, c is the charge on cation and a is the
charge on anion.
1
For NO3 , hybridization  5  0  0  1  3, that is, sp2.
2
1
For NO2 , hybridization =  5  0  1  0  2, that is, sp.
2
1
For NH4 , hybridization =  5  4  1  0   4 , that is, sp3.
2
37. B
Sol. Cl2 is a gas at 298 K while Br2 is a liquid.
38. C
Sol. This is because according to Hess’ law, the enthalpy change does not depend upon the path
followed.
39. C
Sol. The reaction can be rearranged and summed to obtain the resultant reaction as
 1 
2NH3  N2  3H2  
 K1 
3 3
3H2  O2  3H2 O K 3 
2
N2  O2  2NO K 2
5
2NH3  O2  2NO  3H2O
2
3
K 2 K 3 
The equilibrium constant is
K1
40. D
Sol. The reaction can be expressed as
CO2  g  C  2CO  g 
Initial pressure p 0
Pressure at equilibrium p - x 2x
Total pressure at equilibrium = 0.8 atm (given)
Total pressure at equilibrium = p  x  2x  p  x
Also, since Pressure  Moles,
p  x  0.8, p  0.5
Solving, we get x = 0.3. Now,
p2CO
Kp 
pCO2
where pCO2  p  x  0.5  0.3  0.2 atm and pCO  2x  2  0.3  0.6 . therefore,
0.6  0.6
Kp   1.8atm
0.2
41. C
Sol. The reaction involved is
AgIO3  s   Ag  IO3
Let S be the solubility product of AgIO3, then
K sp   Ag  IO3 
or 1.0  108  S2  S  10 4 mol L1
100
or S  10 4  283   283  105
1000
= 2.83  103 g per100 mL
42. A
Sol. The reaction can be expressed as
X  2Y
Initial moles 1 0
Moles at equilibrium 1  x  2x
For reaction (I), let the total pressure be equal to p. The total number of moles in reaction
1  x  2x  1  x.
For reaction (II), let the total pressure be equal to p’. The total number of moles in reaction
 1  x  x  x  1 x .
2
 2x 
 1 x p  2
Therefore, K p 1     4px and
 1  x  1  x2
 p
 1 x 
 x  x 
 p '  p'  2
K p2  
1  x  1  x   p' x
 1 x 
p'  1  x2

 1 x 
K p1 1
Given that the ratio of  , therefore,
K p2 9
 4p2 x 2 
 2 
K p1 1  1  x  4p
  
K p2 9  p' x 2 2 p'
 1  x 2 
 
p 1
or 
p' 36
43. A
Sol. The reactions involved are
2KMnO4  2KOH  2K 2MnO4  H2O  O
2K 2MnO 4  2H2 O  2MnO2  4KOH  20
2KMnO4  H2 O  2MnO2  2KOH  3 O 
KI   O  KIO3
2KMnO4  KI  H2O  2KOH  2MnO2  KIO3
44. C
Sol. According to the reaction P4  NaOH  3H2O  PH3  3NaH2PO2
Oxidation state of phosphorus in P4 is zero while in PH3 it is -3 and in NaH2PO2, it is +1. This
shows that this is a type of disproportionation reaction because there is an increase as well as
decrease in the oxidation state of phosphorus.
45. D
Sol. For a zero order reaction, t 1 

 A where [A] is the initial concentration. So, k 
 A  2
 1.
2
2k 2t 1 2 1
2
Also, for zero order reaction,
x  0.50  0.25 
k t  0.25 h
t 1
46. B
Sol. Using the expression of rate constant for first order reaction, we have
2.303  A 0
k log
t  A t
Given that t = 40 min, [A]0 = 0.1 M and [A] = 0.025 M.
Therefore,
2.303 0.1
k log  0.03465min1
40 0.025
Now, Rate = k  A  (for first order reaction) = 0.03465  0.01  3.47  104 Mmin1 .
47. B
Sol. The increasing order of atomic radii is as follow:
Ga  Al  In  Tl
The atomic radius generally increases on moving down a group in the periodic table. As an
anomaly, the atomic radius of Ga is less than that of aluminium because of poor shielding of
nuclear charge by 10, 3d electrons. As a result, the outer shell electrons are held more firmly by
the nucleus and contraction of radius is observed. This concentration is also called d-block
contraction. The size of Tl is similarly affected by 14, 4f electrons (lanthanoid contraction) and the
atomic radius of Tl is almost similar in size to In.
48. B
Sol. The probability of finding an electron of hydrogen atom in a spherical shell of infinitesimal
thickness, dr, at a distance r from the nucleus, with volume dV  42 dr is
P   2  dV   2  4r 2 dr  R2  r  4r 2 dr
2
Here R (r) is the radial density function.
For 1s subshell, n = 1, l = 0 and n - l - 1 =0. Therefore, number of radial and angular nodes = 0,
Thus, the plot of radial probability P  R2  r  4r 2 versus r is as follows.
P
49. D
Sol. Applying combined gas law (for both initial and final states)
(Initial moles) n1 = n2 (Final moles)
pi V pi  V pf  V p f  V
  
RT1 RT1 RT2 RT1
V  pi pi  V  p f p f 
     
R  T1 T1  R  T2 T1 
2pi  1 1
 pf   
T1 T
 2 T1
2pi  T  T2 
 pf  1 
T1  T1T2 
 T2 
pf  2pi  
 T1  T2 
Hence, the correct option is D.
50. C
1
Sol. In 50 mins, conc. of H2 O2  of initial conc.
4
Therefore, 2  t f /2  50min  t1/2  25min
0.693
As t1/2 
k
Rate = k H2O2  (given that it is a first order reaction)
0.693
Rate  H2O2    0.05
25
= 1.386  103 molmin1
2H2O2  2H2 O  O2
1 d H2O2  1 d H2 O dO2 
  
2 dt 2 dt dt
1  2 2
d H O d  2
O
 
2 dt dt
d  O2 
1
 1.386  103  6.93  10 4 molmin1

dt 2
Hence, the correct option is C.
SECTION – B
51. 24
Sol. Given that, 3M  2N  M3N2
Let a is at. wt. of metal
  3a  28  g M3N2 has metal = 3a
3a  100
 100g M3N2 has metal =
 3a  28 
3a  100
  72
 3a  28 
 a  24
52. 38
Sol.  M  NO3 n  M2  SO4 n
 Eq.of M NO3 n  Eq. of M2  SO4 n
1 0.86

a 62 a 96
 
n 1 n 2
Where, a is at. wt. of metal and n is its valency
a
 E
n
1 0.86

E  62 E  48
 E  38
53. 24
Sol. The frequency of emitted X-rays is given by
v  a Z  b
(according to Mosley’s law, where a and b are characteristic constants)
c
or  a Z  b (where c is velocity of light)

c
thus, for 26Fe  Z  26    a  26  b  …..(1)
1
c
For 19 K  Z  19    a 19  b  …..(2)
2
2 26  b
By Eqs. (1) and (2) 
1 19  b
1  1.931 108 cm,  2  3.737  108 cm
3.737  10 8 26  b
8

1.931 10 19  b
26  b
1.39 
19  b
or 26.41  1.39b  26  b or b  1.05 …..(3)
By Eqs. (i) and (3)

3.0  1010
 a  26  1.05 
1.931 108
 a  5  107
Now, if   2.289  108 cm, then
3.0  1010
 5  107  Z  1.05 
2.289  108
 Z = 24 ( Z is integer)
Therefore, atomic no, of element is 24 and so it is chromium.
54. 79
Sol. Given H  H  e; IE1  13.6 eV

He  He  e; IE1  24.6 eV
We have to determine the values of
He2  e  He ; H  a
He  e  He; H  b
He2  2e  He; H   a  b 
The IE1 of He  IE1H  22  13.6  4  54.4eV
 a  54.4 eV
Also for He  e  He; IE1  24.6 eV
 b  24.6 eV
Thus, Total energy given out  a  b  54.4   24.6 
= - 79 eV
55. 99
Sol. Redox changes are:
Fe  Fe2  2e (in H2SO4)
2 3
Fe  Fe e (with K2Cr2O7)
6e  Cr26 
 2Cr 3
Meq. of Fe2+ in 20 mL = Meq. of K 2 Cr2 O7

1
1 = 30 
30
2+
 Meq. of Fe of valence factor one in 100 mL
1 100
= 5
20
 Meq. of Fe2+ of valence factor two in 100 mL
= 5  2  10
2+
 Meq. of Fe = Meq. of Fe
w
 1000  10
M/2
w
  1000  10
56
2
56  10
 w  0.28g
2  1000
0.28
 % of in wire =  100  99.0%
0.2828
56. 54
Sol.  A t   A 0  eK1t
Bt  B0  e K t 2
 A t  K K t  A t
 e 1 2
If 4
Bt Bt
or  K 2  K1   t  In 4
In4 1.386
 t   54 minute
K 2  K1 0.693 0.693

18 54
 A t 1
 is not possible because B decays fastly.
Bt 4
57. 2
Sol. XA  D  C
a a
a 1   
x x
a2  2  2  a2  x
 KC  x
 x
 a 1    
2 2
x 2 1    k.V 2  x
V x  
 V 
Since,  is independent of a  2  x  0  x  2
58. 315
Sol. When the balloons are filled with He, the pressure in the cylinder will gradually decrease, and as
the pressure in the cylinder becomes equal to that in the balloon, He gas in the cylinder at 1.1
atm will not be available for filling the balloons. Thus, the number of moles of He available from
the cylinder to fill the balloons (n) is given by
n = number of moles at 15 atm - number of moles at 1.1 atm
15  75 1.1 75
Or n    pV  nRT 
RT RT
1042.50
Or n  .
RT
The number of moles of He required to fill one balloon (n’) is given by
1.1 3
n' 
RT
n
number of balloons that can be filled =  315.90  315.
n'
59. 2
Sol. M  OH x will ionize as
M  OHx  M x  xOH
10 4 x 10 4
x
 K sp  M x  OH 
x

 104  x  10 
4
 4  10 12
By inspection, we can find that the relation will hold good when x = 2.
60. 5
Sol. 20 ml of 0.2 M NaOH would react with 20 ml of 0.2 M acetic acid.
30  0.2 6
[Acid] = 30 ml of 0.2 M present in 70 ml =  mole
70 70
20  0.2 4
[Salt] = 20 ml of 0.2 M present in 70 ml =  mole
70 70
pK a   log1.8  10 5  4.74
pH  pK a  log
Salt   4.74  log 4  70
 Acid 70 6
pH  4.74  log0.66  4.74  0.18  4.56
To make a solution of pH = 4.74, [Acid] = [Salt]
So 25 ml of 0.2 M NaOH must be added to 50 ml of 0.2 M acetic acid.
Additional volume of NaOH to be added = 25 - 20 = 5 ml.
Mathematics PART – C
SECTION – A
61. A
1
Sol. m1  2; m2   ; quadratic is 2m2  5m  2  0 .
2
62. B
Sol. mb > 0
 m  0 and b > 0 or m < 0 and b < 0
Hence possible lines are as shown  x-intercept cannot be +ve.
y y
m  0, b  0 m  0, b  0
In both the cases x intercept cannot be +ve.
63. D
Sol. R (a, b) lies on 9x  7y  4  0
R (a, b)
G (h, k)
P (2, 5) Q (40, –11)
  4  9a  
 R  a,
  , centroid of PQR   h, k 
 7 
2 4 a 6a
h  ……….. (i)
 3  3
5  11 
 4  9a 
7 46  9a
k  ………. (ii)
3 73
From eqns. (i) and (ii), we get
  21k  46 
Equating a, 3h  6 
9
8
 27h  21k  54  46  0 or locus is 9x  7y  0
3
This line is parallel to N.
64. B
Sol. Homogenise and put coefficient of xy = 0.
65. A
Sol. R  r  x  GB when x = PB
A
3 3
G
R
P 3
B C
3 cm
 1 
3 r  x  2 3 R  3 3. 3  3 
 
x  3  r  PB
r 1
Now, sin30o  
3 r 2
2r  3  r
1
r
3
66. C
Sol. Solving y = 7x + 5 and the circle x 2  y2  1
y
 3 4
A , 
 5 5
O x
C
 4 3
B , 
 5 5
 3 4  4 3
A   ,  and B   ,  
 5 5  5 5
4
mOA  
3
3
mOB 
4
Hence, AOD  90o

 ACB   tan1 1
4
67. C
1
Sol. y  mx 
m
or m2 h  mk  1  0
k 1
m1  m2  ; m1m2 
h h

Given 1  2 
4
m1  m2
 1
1  m1m2
k 1
  1
h h
 y  x 1
68. C
Sol. Clearly, both the lines passes through (-a, b) which is a point lying on the directrix of the parabola.
Thus,
m1m2 = -1.
Because tangents drawn from any point on the directrix are always mutually perpendicular.
69. C
Sol. y 2  4a2x, 4a  2p  0
x1  at12 , y1  2at1
at12 ,2at1
A  x1 y1 
S
B  x2 y2 
at 22 , 2at 2
x 2  at 22 , y 2  2at 2
and t1 t 2  1
4a2 t1t 2
Ratio   4
a2 t12 t 22
70. A
2 a2  ab b
Sol.   1
3 a 2 a
 1  1  e2
8
 e2 
9
2 2
e
3
71. A
Sol. Directrix : x = 0
1
e
2
Focus = (3, 0)
2 1
  x  3  y2  .x
2
2 1 2
  x  3  y2  .x
4
2
 4  x  3   4y 2  x 2
 3x2  24x  4y 2  36  0
2
 3  x  4   4y 2  12
2
 x  4 y2
  1 ….(i)
4 3
 a  2 ; b  3 ; centre (4, 0)
2
 Auxiliary circle is  x  4   y 2  4
72. C
Sol. PS1  PS2  2a
3 2  4 2  2a
 2a  7 2
P(0, 0)
S1 S2
(3, 3) (-4, 4)
Also 2ae = S1S2 = 1  49  5 2

2ae 5 2 5
   e
2a 7 2 7
 (C)
73. B
Sol. Given hyperbolas are conjugate and the quadrilateral formed by their foci is a square.
y
(0,be2)
x
(ae1,0) O (be1,0)
(0,be2)
x2 y2 x2 y2
Now   1 and   1
a2 b2 a2 b2
2
2 b2
e  1 2 ; 2 a2
e  1 2 ; ee2 2

a 2
 b2  ;
1 2 1 2
a b a 2b 2
a2  b2
e1 e2 
ab
A
 2ae1  2be2   2abe e 

2ab a2  b2 
1 2
2 ab
74. A
Sol. Curve is rectangular hyperbola.
y

P n, n2  1 
x–y=0
(0, 1)
x
O
(0, 1)
n  n2  1
Perpendicular distance, dn 
2
n
lim  n  dn   lim
n n 
2
 n2  1  n 
n 1 1
 lim 
n  2
2 n 1  n 2 2
75. D
y2 x 2
Sol.  1
1 1
16 9
Locus will be the auxiliary circle
0, 1/4
0, -1/4
1
x2  y2 
16
76. A
Sol. As, D2  0, so both roots must be common
 Both the equations are identical
a b c
Hence,  
1 2 3
So,         6
77. C
Sol. We have x 2  y 2  24x  26y  122  13 2  0
2 2
  x  12    y  13   0
 x  12, y  13
So, only one ordered pair (x, y) satisfy the given equation.
78. B
Sol. Cleary, the discriminants of the given quadratic equation are:
D1  p 2  12q, D2  r 2  4q and D3  s2  8q
 D1  D2  D3  p2  r 2  s2  0  As, p, q,r, s  R 
 At least one of D1,D2 ,D3 in non – negative
Hence, the equation has at least two real roots.
79. C
 1  1 
Sol.  x   5   x   1  8  0
 x  x 
1
Let x   t
x
Now, (t -5) (t + 1) + 8 =0
 t 2  4t  5  8  0
 t 2  4t  3  0
 t = 1 or t = 3
1
But x   1 (rejected)
x
1
So, x   3
x
2
 x  3x  1  0
D >  Two distinct and real roots.
80. D
Sol. f  x   x 2   a2  7  x  15a
 f  2  0
 
 4  2 a2  7  15a  0
2
 2a  15a  18  0
  a  6   2a  3   0
3 
 a   ,6
2 
SECTION – B
81. 3
3x  6y
Sol. We have  1 ………. (i)
k
2x 2  2xy  3y 2  1  0 ………. (ii)
Now, homogenizing eq. (ii) with the help of eq. (i), we get
2
 3x  6y 
2x 2  2xy  3y 2    0
 k 
2
 
 k 2 2x 2  3x  3y 2   3x  6y   0
y
2x2  2xy  3y2  1
3x  6y  k
x
O
Now, coefficient of x 2 + coefficient of y2 = 0

  2k 2  9    3k 2  36   0
 5k 2  45
 k2  9
 k  3 or  3
82. 5
Sol. The point  sec ,cosec  lies outside the circle
x 2  y2  3  0
 As sec 2
  
  cosec 2   3  1  tan2   1  cot 2   3 
2
 1   tan   cot    2
2
 1   tan   cot    0 
Now, minimum distance
2 2
  sec   0    cosec  0   3
 sec 2   cosec 2   3
2
 4   tan   cot    3
(Minimum is attained when tan   cot  )
 2 3  a b (given)
So, a = 2, b = 3
Hence, (a + b) = 5
83. 2
x2 y2
Sol. Any point on the parabola y 2  4ax is  at 2 , 2at  . Equation of chord of the ellipse   1,
2a 2 a2
whose mid – point is  at 2 , 2at  .
x. at 2 y.2at a2 t 4 4a2 t 2
 2  
2a2 a 2a2 a2
3
 tx  4y  at  8at  t  0 
 a2 
As it passes through  11a,  
 4 
 a2 
 11at  4    at 3  8at
 4 
 at  3at  a2  0
3
 t 3  3t  a  0  a  0  …(i)
Now, three chords of the ellipse will be bisected by the parabola if the equation (i) has three real
and distinct roots.
Let f  t   t 3  3t  a
f '  t   3t 2  3  0
 t  1
So, f(1) f(-1) < 0
 a   2,2 
But a  0, so a   2,0    0, 2 
 Number of integral values of a = 2
84. 2
x  y   
Sol. cos  sin  sin
a 2 b 2 2
 
(-ae, 0) (ae, 0)
 
If passes through (d, 0)

  da
tan tan  …(i)
2 2 da
  da
Similarly tan tan  ….(ii)
2 2 da
85. 16
2 2
Sol.  x  2   3y  1  1
(Converting the given expression)
2
2  1
 x  2  9y    1 (This is the equation of ellipse)
 3
2
  1
 y   
2   3 
Standard form is  x  2   1
1
9
2
1 Y
Let x  2  X, y   Y; X2  1
3  1
 
9
1
Let X  cos ; Y  sin 
3
Now E  4x  9y
 1
or E  4  X  2   9  Y    4X  9Y  11
 3 
 4 cos   3 sin   11
Emax  11  5  16
86. 25
Sol. Equation of N is
hx  ky  h2  k 2
Compare with the normal are Q
ax by
  a2  b2
sec  tan 
2x y
i,e.,  5
sec  tan 
x2 y 2
 1
4 1
a = 2; b = 1
 h,k 
N
x
O
h. sec  h2  k 2
 k tan  
2 5
sec  

2 h2  k 2 
5h
h  k2
2
tan  
5k
2 2

2
4 h k2
 
h 2
 k2  1
25 25h2 25k 2
2
4
h 2
 k2
 4 1
 2  2 1
20 h k 
 k  25    
87. 45
 b2 
Sol. P  ae, 
 a 
xx yy
T : 21  21  1
a b
2
xae yb
 2 1
a2 b a
ex y
 1
a a
y  b2 
P  ae, 
 a 
T S G x
O a   ae,0  e 2
x 1,0 
 ,0 
e 
Put y = 0 get
a 
T   ,0
e 
a2 x b2 y
N:   a2  b2
ae y1
Put y = 0 to get
e  a2  b2 
G   ae3 ,0 
a

G : ae3 ,0 
 a  b2 1
Area =  ae3   . .
 e a 2

e 4

 1 b2
2e
12
Now, e2  1  4
4
 e  2 and b 2  12
15.12
Area =  45
2.2
88. 3
x2  x  7
Sol. y
x2
2
 x  x 1  y   7  2y  0
D0
2
1  y   4  7  2y   0
2
1  y  2y  28  8y  0
y 2  6y  27  0
 y  9  y  3   0
 Minimum positive integral value is 3.
89. 4
2
Sol. y 2  5y  2
 x  1 3
2
y  5y  0
0y5
 y  1,2,3,4.
90. 4
Sol. Given a + b + c = 1; ab +bc +ca = 2
abc = 3
Now, a + bc = 1- b –c + bc
 1  b   c 1  b   1  b  1  c 
a a
Hence, 
a  bc 1  b  1  c 

AIITS 2224 PT I JEEM Sol

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FIITJEE

ALL INDIA INTEGRATED TEST SERIES

ANSWERS, HINTS & SOLUTIONS

Since work done is equal to the decrease in potential energy,

Centripetal force on CM of rod in this position in

Loss in gravitational potential energy of mass m is

Let BAC  . Then

 46  5t cos  ˆi   28  5t sin   ˆj   7.5t  ˆi  10t  ˆj

Sol. For a zero order reaction, t 1 

By Eqs. (i) and (3)

Meq. of Fe2+ in 20 mL = Meq. of K 2 Cr2 O7

P (2, 5) Q (40, –11)

Also 2ae = S1S2 = 1  49  5 2

2x2  2xy  3y2  1

Now, coefficient of x 2 + coefficient of y2 = 0

If passes through (d, 0)

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