Ses is 4o be extracted fiom veal by meena eh bentene using orbaucus vounley cave. nh wachaobinn units The war is copected to treat 4, reall hy. The untreated real conkeins s6o kg dl and 0 bg benzene The selvent ued containe Ue by al and S90 by benzene The eohausled selid ave do cakon 65 hy Q wnentracted al. Fad the number §) shages deg uored calohon caapsttion| o Yor [OE LOS | ory phe o ° ea Fi A wale = wafees ot ooo k & Selaher ‘Retained fe oat oe Loe Tosa] osgs Defoe Le aac stove Ef he mreal _wetteaked meat ember, tove Fal ses bal | Bearers = 30 bly “Feed ail iy nscale he leaded C6) = sertghy, solver CA) = 30 bl, fnsdubles Cn) = tevo bs[h toh ee 8) oll im mesh tole leabed = —C [ tnsclabtes = oil 5 Ate ot des Ce = 0 3505 ai > Bb, = _ise Ate Sep acs Ne = 8.53 Fos Ate 219s lhfe lenehtey sleak ar K sso by coodinckes 4 et Move, CMm, por) oe bo pee Fj + Po benzene ce ty rae Ae A > sae bs (yy) 3 & +2 Soe ob We 7 Se he 7 OF ce ey eon (= AR ORE Mra = 2 ee Fae nage ot gua Fe ey Bight End ae i Sef (ge leaded SOO BOs G Tote) Ray it 4 eH na aun pt Peas Se En 7" 0 Bory Teck 6 Eee Par, Solute G belene Locale rom Buy ine = WH ; [gem Exh ab & Oe as he | Sens Ben, : de . , @ SR : wap Dp eae, Leb G LO fre bess )1 solids Cunderflan ) co se & = leee Caw undefons = Rin feed) ae 0. Se oe ASE oso by ‘pac’. sR Seb we pe USA Ry = 8 fewcere ladbene ne bese tn Kook ia selene A sgt BA Solvent a Aw — g ea Re hin 2 equ yp Bin B30 Adie Aik sam EW Sfo ee “be Al wha. = “hh testa ssh. epee bs al | by Sle - bg 9) eae 2 % Slpe = > ee aa we AO Bm (hee dy Noy ree usta dhe abet alspe- fe whi of H-D tye, 88): * (@.1099 , 1-44) Drew o Stroy Lech col - ~e_toalesnee - eee gh im wed al tested = Gil iw Solids 4 al iw Leck sla, Dol ww lechaln ce Tertlh SIT LA = i A Vatarcee ann oh cake toleuk subs op Sha S404 to~ us} ~ 169 Aiw Leach iheRa wl p parcone 7 Sem 21Gb 8ST: e) x, = BY 2 oe a 8Problem 3: T000kg of an aqueous solution containing 35 mass % trimethylamine(TMA) and 6S mass % water, is to be extracted using benzene as solvent. A three stage cross current extractor scheme is suggested. The amounts of solvent (98% benzene, 2% TMA) to be used in successive stages are 815kg, 950kg and 2625kg. Determine the fraction of the solute removed if the stages arc ideal, The composition of the raffinate and the extract (two phases) as well as the tie line data are given below (water: A, benzene: B, and TMA: C). Water [xo [0.004 [0.006 [0.01 [0.02 [0.03 [0.036 [0.07 rich [xe [005 [0.10 [015 [020 (035 /03 [0.35 phase Benzene [ys [0.95__[0.90_|osa [078 [071 [063 [050 [0.26 rich [ye [005 [0.10 [015 [0.20 ]0.25 [030 [03s [0.40 phase Tieline [xe [004 [0.083 [013 [0215 [0393 data ye [0.035 [0.068 [0.09 [0.145 [0.31 Solution: 05 Tie line Equilibrium eurve oo 02S “ ‘The problem is solve using right triangular co-ordinates F=1000kg, xr=035 Stage I: S1=815kg, ys=0.02 i Easy Mi = 1000+ 815 =1815ke Xowi= (Fae + Ss) (F+S1)=(1000%035 + 815x002)(1815)= 0.202 ig BoeThe point F (x90, .35) and S (yo=0.98, yo~0.02) are located on the diagram. Point Mi is located on the line FS (xs11=0.202). The tie line is drawn. Extremities of the tie line give raffinate and extract phase composition of stage 1 in equilibrium. From graph m= 024 yi= 0.166 Mixon = Rixi + Enyi 1815*0.202 = Rix0,24 + (1815 ~ Ri)*0.166 Ri = 882.97kg Fi = 932.03kg Slage 2: Ratfinate from stage (Ri) is fed to stage 2 S2= 950kg, ys= 002 Ma= Ri + Sy= (882.974950)kg= 1832.97kg Maxwa = Rixi + Says 1832.97 xyta = 882.97%0.24 +950%0.02 Xo = 0.126 ‘The compo: ion of the solvent to the second stage being the same as that to the first, it is represented by the same point S. Line RyS is joined and point Mz (xwz2 = 0.126) is located. The tic line ReE2 is drawn through the point Mz. From graph x2= 0.15, y2= 0.105 Mx = Raxa + Bay 1832,97%0,126 = Rox0.15 + (1832.97 ~ Ra)*0.105, 855,39kg and E2 = 977.58kg a Stage 3: Stage 3 receives R: $= 2625kg Ms = (855.39 + 2625)kg = 3480.39kg 95.39ky as feed Maxya = Rax2 + Says 3480.39 xys = 855.39*0.15 + 2625*0.02 ngs =0.052 Locate Ms (xws= 0.052) on RaS and draw tie-line through Msto meet the equilibrium curve at the point Rs and Es. X3=0.06 and ys = 0.051 Mixne = Raxs +Bays 3480.39%0.052 = Rsx0.0596 + (3480.39 ~ R3)»0. OS Rs=541.39kg and E;=2939kg 20Total amount of trimethylamine (TMA) leaving the stages y+ Baye + Bays = 932.03*0.166 + 977.58%0.105 + 2939x0.051 = 407.3kg Total amount of TMA entering with solvent = (S) + $2 $3) ys (815 +950 + 2625) « 0.02 = 87.8kg Net amount of TMA removed = (407.3 ~ 87.8) kee =319.5kg, Total amount of solute in the feed = 1000 x 0.35 = 350kg Fraction of TMA removed = (319.5/350 )*100 = 91.3% ea Differential Extractions: Continuous countercurrent Multistage Extraction Envelope Il Envelope f Er Ss Exact Solvent Extract and raffinate streams flow from stage to stage in countercurrent and provide {wo final products, Raffinate, Rye end extract Ei.For@ given degree of separation, this type of operation requires. Rewer stages for a given amount of solvent or loss solvent for a fixed umber of stages than cross current method Total material balance over the entire plant (Envelope 1): Solute balance: FxrtSy,= Mxw=Eiyr+Rwoxne Ey-FoS-Rw Where 4 is a stream obtained by removing a mass F of the feed from first stage extract Ey or by removing a mass Ryn of the last singe rafTinate from solvent S, 20ey Ks Cp} co Ce 7 concentrottinn g tofute im & etvibution wgprcient - Cem ‘emo ry - LA salute in & = hele he Ne 7 vst pocbions 6 solute . : iN EA a fesp eed: ee bation Jf ficvie acid (Perid): — basis - Sectte 7 Ot oe serie acid in feed - = Oe eA 8 (G- A detank fl Pleric acid Benn oot Exivook - : & \ rome 002-5 Renzene x fier add qed i—> Fir) fh Rouat) Ly ormafy P- te = or wy 1 med f in feed Cpe = ooh nf ut a Yoteet BS 2 ce celmag Soe oo X46 “aly v 0. so" coner$} fiaia acid Ratginete edeviey_ tee” fxr = eck. Te eh lo eet AR evo = Ex oo > Ke 0 0246 got 4 is pore’ ® OF 0 829b OIF» 7 aa Core = ie liewee a Arsrvon Deneote Aad. . Got de ’ bebe firerie acidl 2 a @ see now \ BN “ant d Hers odd OF ia ants J fierie cud im fad L b-Or-» UO ye 10 Os yo SF. = Fo fe eee co ps0 by HWrelinerviater ps0 — 4 Y Lats: tro be ae weed Bock ) & tpn i } oa owhde g Neohne fa fed . N Ooo y Bye > He j-0-0} 7 My nN bs Amak § ovighal sebserh rseder ey by iw feed = tse (tore) Ao = leas befe entracion 5 Nookine = twit A) aicobae extracted ant 1{) Aichue bn ae (Fe) de and Qo nich mM feed = (.f. aor = 0 Ol Vo = Ke. o-oo} 4 4 I-Ap Arca 4 vsdvent = hy 2 ow FCI AD = ise (too) = Ges be, oweunt wih ertvaded = Aol % - *i) 1 ! y 8 3X) en ve wbhained Grom egher rclachiomtls ? - ye oe EX SD Y = 0988 x, Mate) bel Oa Fe bh eh +e F & i 8.4, poicotisa Gohane = Syed fre bests. fe AvXo 5 Ao Kt BY, Crs Wicetne) ee ay ee by s a nicakinn extvacted = Ay [0 -¥5) =} ont nice ean J. enbacho = O82 agg 2 Sur. A >apsara = — Date ee LH poicetine - weotey coln 1]. nic Sse by of ____ | cent — Levosene + —~ 95 _ \ Lev by F_ aw — — Te cat > ey B, isos 7 few seve J extvactiow = t fh eeWachon = preety Nose oxhaded o 10 Riesbine infec | ateoKe iw feed = 1 - Is bs feed 5 It nicehne + | a a4 bg wetey 9 A: { feed Sebenk. SUP anwrounk 9g Riche on pented = aloha. eee val | 1 | hicatie 1 feed — Ne tiee bob inate anther i = Ax,- Ax, ~pesehOps; Date: } | exes Cove tuk- eg tin Cane: —|epetey bn te Jey a Al, = SS oer I ~ O06 — 4 % — S ereuT i ys ono 2B GE rash eg eo ate =O : ie a aie ale eubadet = Ay ge =apscra Date:__. +b | Repent _| fe 2 _eWactiy uy iwi _¥ = She Nee See Slege 1 ds F = 1 by =A = 49 given & =o a Mg = ~% 2-195 so Q tee = - 148 ye = Ter L \ ® a : T i Slope = =14 Ze | Zot = <== a : % a r — 1 — Seo cone =O. See Fe [8 sheds aot innCode No: A36F2 oie BVRAJU INSTITUTE OF TECHNOLOGY, NARSAPUR (UGC - AUTONOMOUS) JIL B.Tech II Semester Regular/Supplementary Examinations, July/Aug 2022 MASS TRANSFER OPERATIONS ~IT (Chemical Engineering) Time: 3 Hours Max Marks: 70 Answer any 5 (Five) questions. All questions carry equal marks Marks Bloom Level Derive Rayleigh’s equation for differential distillation for binary mixtures? ™ 3 b) A Liquid mixture containing 60 mol% n-heptane and 40 mole% n-octane are subjected to differentially distillate at atmospheric : pressure, with 60 mole% of liquid is distilled ™ 4 ‘Compute the composition of composited distillate? yg ey x 1.0 0.655 0.487. 0.312 0.152 0 1.0 0.810 0.674 0.492 0.279 0 Explain steam distillation. Discuss the advantages and disadvantages of steam = 14M L3 distillation? {A liquid mixture of benzene toluene isto be divi ns. factionating zotumen at 101.3 kpa pressure, The feed of 100 kg mol/h is liquid and it contains 45 mole % ‘and the remaining (olucne and enters at 327.6 K, A distillate containing 95 mole benzene and 5% toluene and the bottoms containing 10 mole % benzene 14M 4 ‘and 90 mole % folluene are to be obtained. The reflux ratio is 4:1. q=1. Caleulate the number of theoretical trays required. Constant relative volatility a= 2.5 Derive the q-line equation and discuss the slopes of q-line with different feed aM 13 conditions? Derive the equation for calculation of height of packing in Packed Dis 14M 13 Column? ( Derive the operating line equation for cross current extraction and also give 14M 13 equation for slope for the case of two immiscible liquids in counter current multistage extraction. How to estimate total number stages required for the «se of continuous counter 14M Ls current extraction with reflux?(with neat sketch for equilibrium diagram)? Write about Freundlich isotherm and its applications for single stage adsorption. 14M La co col col col co2 coz cos co4 cos C06