Standand Enthalpies of Formation & Standard Entropies of Common Compounds Siitnce State MS Suton state AMF — eo | ee Ag aq. 105.79, 727 cr aq —167.080 56.5, AgCl s -127.01 96.2 clo, aq 128.10 182.0 AgBr s 1004 071 : 0 238 MNO, $124 1409 fe -umT si at : 0 (283 errs A aq Sed 3017 nT 88 Aich sro oT a 4848 —a96 ALO, 8165700 153426 Bo : 0 6s 1686 984 Bach = -8886 1287 $B 668 BaCOy, s 1216.3) 112.1 8 79.5 120.9 Ba(NOs)2 ss 992 2M s —T714A (107.6 Bao 3-385 70d aa 88535 138 Ba(OH)2 s 998.2 12 g 202.7 Bas, $1832 1992 4 m3 Br : 0 ima . 1067 ¢ . 0 sr ‘ sr cont -issd 216 ‘ Mb cho, 6 ats aon t 108 cg 1862 « ooo Ci, = 42087 as f -3520 1986 Cig 45232188 a -68003 912 Ci = -BAT a8 02311808 City 10382589 e279 1737 chon 723871268 zo) 2065 CaOH = ¢ amt 1607 é 1 1886 co © 083 1st aq 140 385 CO eH 2136 a 8891318 co,? aq -675.23 —56.9 © -285.830 69.9 Ca A 0 414 21895 1887 Cat? aq -343.0 53.1 aq 1302.6 90.4 Coch S758 TOK m6 57 CaCO, $1069) 829 é 3160 CaO =63402 08 . > CalOHy $9801 8B ened 0079103 CaSO, $141 1067 ca : ons ca? aq 75.92 -73.2 Cich = —3015 L183 Cio’ 5 -a5835 548 “The siadard eatzopy ofthe H*(eg) ion is defined to be 0Substance State AH; = Substance State Alp & inet) (ate) (GS) ete r aq 3678 113 Sree eee OraaoH hb 5 0 1161 Nio ss -239.7 380 K 8 0 64 one aq —230.015 108 Ke aq 252.14 102.5 oO, 5 0 2050 KBr 5 3938 95.9 Py 5 0 1644 Kal 5 826 PCy g -2870 SILT KCI; os 3.1 PCs g ~8749 3645 KOO, = s 43281510 PO; aq -10774 KNOy s 4946 1330 Pb s 0 Mg 5 0 327 Pb? aq 092 105 Mg"? aq -407.0 =138.1 PoBy = ss -278.7 161.5 MCh = -s——6413 896 PDC, s 8694 1360 MgCO; s -10958 65.7 PbO s 2190 66.5 MgO s 601.60 26.9 PbO. Ss -2T4 686 Mg(OH), 5 9245 63.2 8 5 0 318 MgSO, s 12819916 SO, gs -20081 2481 Mn s 820 SOs 5 -395.7 256.7 Mn‘? aq 73.6 SO? aq 909384 20.1 MnO 5 597 Sr aq HBL 14 Mn02 5 53.0 Si s 0 188 Nz 5 1915, SiO. s 9107418 Nis g 45.94 1923 Sn s 516 aq 133.26 1134 Sn*? aq -It4 aq 1046 123.0 Sn02 5 523, aq 206.85 1464 mn 5 416 £4506 121.2 ant aq =15339 112.1 s 34 6 Zuly s 2080 161.1 5 -3656 151.1 210 s 85046 43.6 5 +902 2107 ZnS ss -206.0 57.7 g +832 2400 5 $9.2 3042 5 0 m2 aq 240.34 59.0 8 721 s -8736 515 Ss 156 4S650 APPENDIX A, Table A.1_ The Standard Gibbs Free Energy Changes for Several Reactions Reaction aed ange, 2AQ) + 4Oz9) = AG2O}s) 30,540 + 66.11 T (298-463 Alyy = [Allo wero) 43,100 - 32.26 T 2Aly + 150 yy)= ALO 11687200 + 2088 T 99-2027 Cy) + 20 xig) = CO) 111,700 - 8765 T 298-2000 Gy) + Og) = COnp) 394,100 - 0.84 T (298-2000 202,800 9.96 T 773-2000 Cigy) + 2Haig) = CHa) 91,040 + 110.7 T ‘773-2000 Gage) = [Cle wr ina 22,600 - 42.26 T 620, + €0,,, = CACO,,, =168.400 + 144 T 449-1150 2Ca0)p) + SiO.) = 2Ca0-Si0..) 118,800 - 11.30 T 298-2400 €00,,, + $04g, = COS, -227860 + 165.3T 298-1230 20r) + 1809) = CO 1,110,100 + 2473 T 298-1793 20 + ny = CH,0,, “162,200 +6924 298-1956 2Ouy) + 20 ny = CuO) 188,300 + 88.48 T 1356-1509 20s) + Sri) = CurS,,) 131,800 + 30.79 T 708-1356 AF, + Gyn = FOC 29,040 2603 T 299-1000 BFE) + Cign = FesCray 11,234- 1100 T 1000-1137 Fei.) + 4029) 263,700 + 64.35 T 298-1644 F0,) + 40x) 256,000 + 53.68 T 1808-2000 BFE.) + 20,9) = FeOus) 1.102,200 + 3074 T 298-1808 Fe) + Sag) = FSi) 150,200 + 52.55 T 412-1179 Hag) +Gkg, = 2H 108.200 - 12.807 298-2000 Hag) + laig) = 2Hligy 8,970 - 1765 T 298-2000 Hag) + 4029 247,500 + 55.85 T 298-2000 “160.200 + 2072T Uy, + 8, -299,900 + 42.09 1280-2000 May # Gly, = 600,200 + 12143 T 997-1958 Mg,,) +20.) =MQO,,) -729,600 + 204 T 1363-2200 2Mg0,,, + SIO,,,, = MQ-SiO,,,, 67,200 + 4.31T 298-2171 MQ0,,) + COaig) = MGCOy.) 117,600 + 170 T 298-1000 MgO j,) + ALOxs) = MQO-ALLOs5) ~35,560 - 2.09 T 298-1698 \ 289,000 + 76.82 T 208-1517 Nag) + SHaey 87,090 + 25.8 Tin T+ 31.77 298-2000 2Niy, + One 471,200 + 172 T 208-1726 2Nig) + Ong = 2NIO,, 506,180 + 192.2 T 1726-2200 0g =1070~587T Poy Oa, “208.700 + 9175.7 600-1158 Poy, + 4Ony “181,200 + 68.03 F 1158-1808 (Continued)652 APPENDIX A, Table A.2. The Constant Pressure Molar Heat Capacities of Various Substances (c, bree dmote-k). Substance 2 bx oxo? RangeK Remark 9 aie ests A wo - = 1254-1600 Ala 2oe7 1208 298-960(7,) Ay ne 933-1600 0, 1066 1778-2853 296-2825(7,) Ba, #732 166701282 208-648 Bay, 569 8033 648-1003 B20 5290 495-820 298-2206(7,) Baro, veus ast 1016 296-1800 Socom on 3898148 296-1100 -1738 x ‘or Cort peas 044-3163 100-4000 Cnn ei 1922 619 298-1200 co Zar 410-046 298-2500 co, 4a 908 ase 298-2500 ca, ar 18 208-716 zarx ‘ere cay 09s ais Tie-m15 cad 4os2 451 695 2oe-at77 caro, aaa 569-2799 298-1530 Ce 2843 987-368 296-2190T,) 01.0, 11957 930-1565 298-1800 Cy zee 68 2986-13564.) Fon wi G17 — aan ta/te64 1000 Fe 247 ads “1e7-1664 Fen “80 1809-1873 1.0, 0 071 039 298-2500 on 296 418167 298-2000 2MgO2A,0,5S0, 626.24 9121-20083 296-1738(7,) u wer 4 298-2500 SiN, Tose 987 298-900 SO sega 4389 100-602 298-847 7 2209 1046 — 298-1155 Tram 7519 MAT 1820 298-1800 Zia ae7 tes 296-1196 Zn, m2 4ek ‘130-2128 20a 6962 753 14082081478 ZOry, mae 1478-2950(7,)APPENDIX A, 653 ‘TABLE A.3: THE STANDARD MOLAR HEATS OF FORMATION AND MOLAR ENTROPIES OF VARIOUS SUBSTANCES AT 298 K Example: For the re =1,675,700 5 which is thus the standard molar heat of formation of Al,O, at 298 K. The molar entropy of Al,O, at 298 K is $0.9 J/K. By convention, the standard molar enthalpies of elements in their standard states at 298 K are assigned the value of zero. Table AS. The Standard Molar Heats of Formation and Molar Entropies of Various. Substances at 298 K ‘Substance Hid Star K 10, =1675,700 509 8a - 24 B20 548,100 Ta Bato, 1,653,100 1079 Coyne - 573 Gon, 1,900 243 cH. 74,800 1863 co 110,500 1975 co, 883,500 2137 ca = 416 a0 634,800 38.1 catio, 1,680,500 37 3Ca0.A1,0598i0, 6,646,900 2414 C20-A} 0, $i0, 3.299.200 1448 20-A,0, 2810, 4223.70 2025 2Ca0-A1,0; SiO; 3,989,400 198.3, 1,0, =1,134,700 aia H.04) 241,800 2329 Ne - 1915 0, - 205.1 SiO, 910,900 415: SiN, 744,809 113.0 T — 307 To 643,000 347 T,0, 1,521,000 m2 T40, 2459000 129.4 To, ~844,000 50.6 2 — 39.0 504APPENDIX A 6st ‘TableA.1 (Continued) The Standard Gibbs Free Energy Changes for Several Reactions Reaction Range, K PLO, + S055) + Ong 401,200 + 2818 T 298-1158 P08, POly, + Clay PCliy, 95,000 - 794 Tin T+ 205.2 288-1000 8g) + Ong) = SOs) 961,700 + 76.68 718-2000 Si Ong) = SiOz 907,100 + 175 T 298-1685 35x) + BN) = SN 723,800 + 315.1 T 298-1685 Sn) + Clip) = SAC, 333,000 + 11847 520-025, $054) + YOng) = S05 94,600 + 89.37 T 298-2000 Up) # Gig) = UC, 102,900 + 5.02 T 1408-2500 2Up + 8C p= UC 236,800 +25.1 T 1408-2500 Up) #20 9) = UC 115,900 + 10.9 7 1808-2500 Vn + 40ry =VO,, 424,700 + 80.04 T 298-2000 Zn) +1404) = 200, 460,200 + 198 T 1243-1973, Note: Standard states are noted by eubscript. ‘TABLE A.2: THE CONSTANT-PRESSURE MOLAR, HEAT CAPACITIES OF VARIOUS SUBSTANCES ‘The constant-pressure molar heat capacities are presented as cp atbT +eT? UK cpt bT HoT? +47? WK ‘and Table A.2 includes the ranges of temperature in which the expressions are valid. Example: For Ag in the range 298-1234 K, 6) = 2130+8.54x10°T +L S1x10°T UK nd for graphite in the range 298-1100 K, 1143894107 L48x10°T ~17.38%10°T? IKAPPENDIX Standard-State Thermodynamic Properties at 25°C and 1 Bar* Adin 7m oy — Hi 4G; Suan Com Ki mot! kim? Jmol J mol" Ag*(ag) 105.56 77.09 728 Brig) M884 82396 175022 20.786 Br (ag) 12155-10397 824 = 141.8 Beal) 0 0 152231 75.689 Brita) 30.907 3.110 245.468, 36.02 C(eraphite) ° ° 5740 8527 diamond) 1.897 2.900 2377 outs Ce) 716682 671257158096 20.838 CE Aa) 928, -879 261.61 61.09 Cys) 7481-3072 186.264 35.309) Cle) =110525 137168 197.674 29.116 COae) 393509 304359 213.74 37.1 OF (ag) “67714-52781 369 6347 619.2 258.60 46.82 22673 209.20 20094 43.93 52.26 68.15 21956 43.56 8468-3282 229.60 52.63 27169-17878 160.7 1146 =1s40s -11259 266.38 6439 CHe =0385 -2337 27002 731 Cathie) 8293 1297 26931 81.67 Cyelohexene(2) (C.F) =5.36 1070 310386 105.02 eev-Glucose(e) (CHO, —12744 910.1 2121 2188 Suctose(c) (Cj:H::0y)) 2221.7 — 15438 360.2 425.5 CHYCH,),,COOH() “8908-3145 4352 460.7 CaCO\Ccaleite) 120692 1128.79 929 81.88 CaCO (aragonite) 120713 1127.75 887 81.25 Ca0K6) 63509 60403, 39.75 4280 Cs) 121679 105.680 165.198 21840 cr (ag) 167.189 131.228, 56.5 = 1364 Che) 0 0 223.066 33.907 Cute) 0 0 33.150 24435, CuP(aa) oan 63.49 996 Fe) 0 0 202.78 31.30 Fete) 0 ° 27.28 25.10 Fe'*(ag) 485 -47-3159 Hw) 217965 203247 118.713 20.784 Way ° ° ° HL) 0 130.684 28.824 HD) -1464 143.801 29.196 De) 0 144.960 29.196 Hrs) =33.45 198.695 29.142 HCl) 95.299 186,908 29.12 HF) -273.2 173.779 29.133Albin Comm Substance as KJ mol Jmol Hse) 294.1 328.1 238.97 43.68 1,00) -285.8390 —237.129 69.91 75.291 H.0) ~241818 228572 188.825, 33577 1.0.0) 18778-12035) 1096 8911 HS) 2063 33.56 205.79 3423, K (ag) 252.38 —283.27 1025 218 Kcl(e) 436.747 409.14 8259 5130 Mg) 0 o 32.68 2489 Ma) 147.70 113.10 138.650 20.786 MgO(e) 601.70 ~369.44 26.94 375 Ne) 472.704 455.563 153.298 20.786 Nig) 0 o 191.61 29.125 Nie) 46.11 16.45 19245 35.06 NH.CH,COOH(e) =52810 368.44 103.51 99.20 Nowe) 90.28 8655 210.761 29844 NOx2) 3318 S13 240.06 37.20 NOj(aq) -20736 © 11125, 1464 86.6 N08) 9.16 97.89 304.29 71.28 Nate) 107.32 76761 153.712, 20.786 Na“(ag) =240.12. -261.905 59.0 464 Nace) 41153-38438 72.13 50.50 0) 249.170 231.731 161.055, 21912 O48) 0 ° 205.138 29.355 1 (ag) 229.994 -187244 10.78 —148.5 PCIe) -2870 -2678 311.78 7184 PChig) -3749 3080 364.58 11280 80,(@) 296830 300.194 248.22 3987 Silg) 455.6 an 167.97 22251 SiC(B, cubic) 653 =628 1661 26.86 Si0,(quartz) 910.94 856.64 4184 4443, Sn(gray) 2.09 013 aad 28.77 Snwhite) 0 0 51.35 2699 S03 (ag) 909.27 74453, 20.1 =293, “Data obtained mainly by conversion from values in D, D, Wagman et a, Selected Values of Chemical ‘Thermodynamic Properties, Natl. Bur Stand. Tech. Notes 270-3, 270-4, 270-5, 270-6, 270-7, and 270-8, Washington, 1968-1981, The molality-scale standard state is wed for solutesA Fundamental Physical Constants and Conversion Factors Physical Constants Avogadro's number y= 60221415 x10” Rest mass ofthe electron 1m = 9.109826 x 10" (ks) Elementary charge = 160217653 € Plank’ const 11 = 66260693.) 8.314313 (mol K) 1.98727 amo! K) 12.0589 (ce atmol K) 0.820589 (tmnt K) 3806505 10°? (tm K) Ges constant Boltzmann's constant (k= /Ny) Conversion Factors 1 m= 100em= 1000 mm = 10 jm = 10° am Volume 11 1000 ml = 1000 cm = 10 my! Temperature T= TK ~ 273.15 (99)(TF ~ 32) Pressure 1 atm = 101325 Pa = 0.101325 MPa = 0.06805 psi Energy 14= 1 Nm= 4.184 cal = 9.8699 ce atm = 0,0098699 1 tm Him: & yseful method fr converting energy units sto multiply bythe aio of two K-values that contain the units tobe converted, Source: From Lide, DR. Ea, CRC Handbook of Chemistry and Physice, 71st, Boca Raton, FL, 1991. 559566 System Ag-Au Ag-Gu Au-Cu Cr-Fe Cun cata Mo-W Zs-Nb Phase Fee Liq Fcc Liq Fcc Liq Bcc FCC FCC Liq FCC Hex Bec Liq Bec Hex a» mob) = 15599 = 16402 33819 17535 = 168314 197088 220500) 10833 8048 12049 42804 sou 2441 bby (W/mol kK) Lia 812 454 304 100 Thermodynamics in Materials Science a, W/mob) 3019) by W/mol K) =u a; W/mol) ‘by W/mol K) Source: Chang, A., WinPhad Software, Compatherm, Madison, WI, 1998, With permission564 ‘Thermodynamics in Materials Science Element Transformation as; ang rs feo «or so as 8 2020 8 1786 R fee 2002 96 183 se “400 w 708 s dat ness 28 502 ime 2873 1 59 w hex “tee iss 36 a2 bee 1983 86 167 ve 3588 20 mo v orth eg oa 30 2 teag— 108 46 an cubic 1 140s 6s 92 ise 700 ” ais v bee“ 2183 tos 20 me 3680 nat 4863 w beet 3093 Bs 500 Ss ses i) 4 Zs sept 3 10s 13 ve nso 969 1183 2 hep = tee 1136 3a 39 bee 2128 ss Iss Ise ‘00 fy 781 7, tansformation temperature (K); AS, entropy ofthe transformation (Vinol Ky; AH, enthalpy ofthe transformation (Amol) Source: Kubaschewki, 0., Alcock, C-B., and Spencer, RJ, Materials Thermochemistry. 6th ed, Pergamon Press, Oxford, 1993,C Element As al Au ce © cv Fe HE i Mg Mo Phase Transformations for the Elements Transformation h feo Ins feo—1 “2 fee—1 Ime hex Ime hex AS, 92 042 4 los 94 9.4 92 Mi 104 958 07 92 (130) aI lie 98. los os os 16 109 184 100 29 19 ur 96 130 92 937 Bs 1 100 lis any na asta 07 2005 126 2d 25 62 os 162 4164 124 16 83 305.6 09 os. bs a412 56 2690 59 72 5608 26.1 6110 8S 4 30.1 215 m2 3752 Continued 563562 ‘Thermodynamics in Materials Science cam natine & ar AW d/molK) Element AN (gin/mob a bx ex dxt0% Ae "7 lor 868 2130 854 131 = al 1B 2698 3138 1640, 3.0 2075 Aw 19597 314671347 ~ 289 1096 cw 6 2011 912 bar 619 = co ” 58.98 18.12 24 ~042 ~ 008 cu » 63.546 3029 wor 32 947 Fe 6 55.85 Dre 7232, 290 25.08 Hy ' 1.009 231 333 = = Ht n 17858 244 7683 = = Mg 2 242 28 li92 ous = N 7 14.008: 3042 254 -297 — Ni 2% se71 nat a8 3s — oO: 8 16000 9.96 418 167 = P> 2 2072 2438 2m — — PB ® 159.09 24.09 502 -050 = ea) 247 4 — si u 28.086 2393 2 ~a4 = wi 2 4790 24.98 657 163 134 vu 2 23803 25.10 2.38 = 23.68 Zo ” 6538 238 tos — — zs 0 9122 288 895 ~oor = AN, atomic number; A WL atomic weight (gio , volume coeficient of thermal expansion (K) 8, volume coeiient of compressibility (atm) '; V8, molar volume ofthe solid at 298 K and 1 atm {cc/mol}; V', molar volume of the liquid at 298 K and | atm (cc/mol); Sox absolute entropy of the ‘element inits stable phase form at 298 K and 1 atm (mol K); CT), heat capaciy at constant pressure (01K) ‘Notes: The value of eis the number inthe table x10". The vale of ithe umber the table 10-7, ‘Sources: From Kubaschewki,O., Alcock, CB. and Spencer, RJ., Materials Thermochemistry, 6th ed Pergamon Press, Oxford, 1993; Reynolds, CL, Paugham, K.A.,and Barker, RE. J. Chom. Phys, $9, 2943, 1973, Reynolds, CL. and Barker, RE, J. Chem Phys, 61,2564, 1974‘Compound Carbides BC CnC. cscs Crs Fac Hic sic Tac Tic uc Uc vc, wc we Hydrides AIH CHa) Nitrides AN BN FeN GaN Noa NbN TaN Properties of Selected Compounds Gy =as ors 5 4 ar Shoe -aH’, U/ml) WmolkK) Kol) a KIO eT dx 10 m1 522192 4498 6121 683.25 20920 — 1086 . 2010 2389 2M 3807 = 884 3.26 2590 2824 = 1086 2018368, = Ss 395 oS ee 16s 4259 87 "1661-126 816 64 938 - 23 4330 816 ~795 = 390 13.59 126 8.70 439 rss. 1510 1280 = oss 69.08 ast = 816 30751088 — ua 4349 802 103 300 459 . — 1863. Ras 76.60 14s - 179 2008 OG 2192 ot 5083 = = 310 76.1 m0 4937 =3386 = 1927 495 M2 186 6.89 637 1270 38 5.65 = 202 sis 3226 268 7.91 48 252.3 4121 at 21.76 = 1356 11079344 = S 293 1096, 38.07 9.00 . = ws 283.1 han 2 — 39 2364 336 259 e = 14 ma m0 7657.1 S Continued 367B Element As Al Au cw) AN a 13 ” 2 Properties of Selected Elements AWt (gm/mob) 07808 26.98 196.97 ron 58.98 03.546 55385 1.009 i788 2432 14.008 5871 16.000 2072 159.09 eu) 28.086 97.90 23803 6538 9122 a xt08 “- 37 70s 8 213 si 36 1dGas 18 w ldGas 40 TdGas 37 2 16s 2 ” 93 1% Properti px vs (atm) (cc/mob) 90 1027 2 9.99 i 021 S 342 56 oe 109 710 a6 B97 6.00 TdGas = 2 in74 35 9.10 3 1200 = 1064 es 1249 6 9.16 — 1406 ‘of the Stable Form at 298 K ve (cc/mob, nse ust 113s 159 798 196, 16.07 1529 143 19.40 103 147 116s 1330 9.98 sz Sioa Wmol 426 283 975 24 300 331 273 106 BS lis 209 208.1 648 aus Iss 307 502 416 390 ContinuedF Interfacial Energies of Selected Elements Element ow ” * Ag 926 100 . Al 865, 10) 93 A ay (1370) 1 Bi 316 6530) 61 cs 686 = a cu 1360) 1700) ” Fe 1880 (1870) 208 Ga 708 = a Ni 1822 (2040) 235 me 1865 1900) Si 20 = = w 2500 2300) - 0°, surfce tension of liqu-vapo interce at the meting poie (mN/m); 9° surface fee energy of -y, surfuce free solid-vapor interface at the melting point (lin? = eral ergy of soid-liguid ieface atthe melting point (min? ergfen. Sources: Prom Lie, D.R. Ed, CRC Handbookof Chemistry and Phsics, Tita. Boca Rata, FL, Murr, LE, Interfacial Phenomena in Metals and Alloys, Addison-Wesley, Reading, MA, 197 569568 Thermodynamics in Materials Science Gm =a+ 00+ 5 +ar ~ aH, ‘Wimol Compound —immol ky KYmol) XT! xIOF dx 108 TaN ais 22300 sz) om 1 on es ae | ee Oxides ALOs s09 1os7 nd 0s co iis ust 40 06 co; 2187 BBS Ahk 600 530 a a C004 nas 9100 407872828387 uo s9 12 $820 RT = 89 cu0 26 W946 NSS “TE 289 Feass0 1 230087 BT 200 Fe.0) a4 a ae es Feds 1509) tokens 200 2 Ho 9 258 TS © 1887 ne 033 Mso 269 ols 8) NwO 460 oo oe NWO; sis = ce NbOs 173 99s WIT ABE 308 Nio 380 278887231628 Sis a4 90834690 EST 1008 Tio MT ei ie TO m2 i090 aD 23aB = Tis 19 mas. Ok 24oT es TO: 506 a v0: 70 oso 8033 GTR HST uo, sai 4104 356273544 540 Us05 225 3548 6A IH v0, 962 me oe ¥0 992 1905062 0k 30 2x0 36 a ee ee ae 20; sod loos 6062783 ys absolute entropy of compound at 298 K (mol K); AFF enthalpy of formation of compound at 298K (Ki/mol} a ftstheat capacity coeiient mol K) , second heat capacity coefficient (mol K"); 6 third heat capacity coefficient (1 K/mol; d, fourth heat capacity coefficient (Jmol K°). [Notes The negative of AHS is reported in the table. The value of Dis able value x 10™* The value of is table value 10°, The value of disable value x 10-°. Source: From Kubaschewki, 0, Aleock, CB, and Spencer, RJ, Materials Thermochemistry, 6th ed, Pergamon Press, Oxford, 198,568 ‘Thermodynamics in Materials Science Gm =a4 ors S +47 Sip AH ‘mol Compound —imolK) Kimo) SCIOTO OF TaN a8 aa ssa7 an . uN as me 557348 = vides ALO, tos? dae co. mos a) co: was aid ok Se C00 a7 50 oak m1 CoO. goo wars 1728 aor cu.0 m2 5202397 aa cu 1696S 299 Fes ao 4887 = Fo; ms eT = Feo, tier 5s mm = = H00) mse sah = = © ais 30007 os Mo ws 3 47 297g am nso 61300877 4s i957 sh me mer mek S723 tak 90834690 ST = sor 4218067 1009 3aD2Issk = 24591 0} 2407 = ouo | 7aa8 as = oso x03 678 = 4510435627 ast = Is 229 = 138 9330108 = 1950 oe a0 = 26 305 ako 0 = sos Ns 7883, = 5s. absolute entropy of compound a1 298 K (mol K); Aq enthalpy of formation of compoundat 298 K (Ki/mol} a fstheat capacity coefficient mol K);, second heat capacity coefficient mol K°}; 6 third heat capacity coefficient J K/moh fourth heat capacity coefficient Vol ‘Notes: The negative of Aff. is reported in the table. The value of b is table value x 10"%, The value of ¢ is table value 10°. The vale of dis table value x 10-* Source: From Kubaschewki, 0, Alcock, CB. and Spencer, RJ., Materials Thermochemistry, 6 ed Pergamon Press, Oxford, 1993