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INTERMEDIATE COMMON EXAMINATION BOARD

Time: 3.90p,, QUESTION paANK 2018.19

— CHEMISTRY. pyRST YEAR Marks: 60
= SECTION. » J 10%2«2)

" Answer nl} the following questions,

2 ha is Boltzman's constant? Give ns value?

a Chm im ross velocity? "

4 Nrich gas Wituses faster emaong N, D,CH, gases? Why? +

. flow niany imes methane diffuses fase \han 80,7 '

Sate Dalon's law of partial pressures?

: Give tha values of univarsg 92% CUNSIANL'R' in different unite?

“Al Thu emperical formula of n compound CHO. Its molecular woight is 80. Calcutate
the
Malacular formula ofthe compounds? ‘ a k
S on ’ ei; Many number of meles of glucose present in 540 grams of glucosa?’
S \ re! . al arg disproportonation reactions Qmva an example? X
3 . Wht ara Comproportianation reactions give an example? ’
EB 1. Assign oxidation number to the undertined cioments In each of the following
species?
© 2KMnO, ub) H,S.0, .
12, Determine the oxidation number of oxygen in OF, and O F,?
12 What is Dronstend basa? Give an example? - :
& 14 What 1s Levd's acid 2 Give an example? | .
ov 15 What is onic product of vaner (KL)? Give its value at room lomperature?

46 Define Hard water and soft water? — (Hydaoqen awd a Corn panda)
1} Wille the uses of Na, CO?
y 18. Give the importance of Na*, K+ tons in biology?
~

19. Give the importance af Mg? Ca'ticas in blology?

c, )20 Wty gypsum is added to cement? Name two man made sillcates? :
Give tna Importance of plaster of pairs?. » Cw
What is syngas (or) synthelic gas (or) vater gas? !

Pp Diamond has high covalent nature ¢ven though it has high melling point -
explian?
NY 24 What Is producer gas? ’ ) x Js .
25, What is allotrophy? Give diifarent crystalline allotropes or carbon?
4 5:23 “What are BOD, COD? : -
i? 27. Wrile any two adverse olfocts of Acid rains? )

28" Whal is groen house effect? How is global warming taking place?

29.- Write IUPAC names of 2 i

i : a) CH3-CH2-CH2-CH=CH, b) AWN
3
3
Write the structures of (a) 2,3 - dlamethyl butane b)2-methyl but-1-ene,
¢) 2.3,3,4 tetramethyl heptane d) 3,4 - dimethyl hexane
: Answer Any six of the following questions.

73 »
! " Explain ihe hybridization Involved hc aera : )
3 i i 6F, molocula. :
: in the hybridization involved in 6F, a
: - rn by ris bond? Explain different lypes of Hydrogen bonds with prompt ~ =
nd i z i,. ©, molecules and calculate Ihe respective bon
‘ ! der? Give the MOEG of H,, O, |
at. Ahal is bond or . :
. arders? / 2s i
Ss. wie tha posiulates of kinetic a_i of gases? ihe
. Win ) oe
Deducs (a) Boyles law (b) Charle ui ik a praia i 4
Deduce (n) Graham's law (b) Dallon's law fre 1 H+

Derive an expression for kinetlc energy of gus molacules?

"Calculate the emparical formula of 8 compound having reoritage compasilion (K) =
20 57

chremium (Cr) = 35,38, Oxygen (0) ® 30.07 (Glvon (he atomic weights aro K. Cram O
as

39,52 & 16).

A carbon compound Containg, 14.5% Carbon, 1.8% Hydrogen, 4.46% Chlorine, 19.24% Oxy
gon calculate the emperical formula of the compound.

Balanca the following redox reaction by ion-alectron method.

Cr,0F +80, — Cr "+50!" {in acidic solution)

Balance (he following redox reacyon by lon electron method.

MnO; +50, — Mn® + HS0; (in acidic solution)

Explain extonsive and intensive propertios.

Dofine haat capacity ? What are C, & C, ? Show thal C,-C, = R

State and explain tha Hess's [aw of constant heal summation.

Derivo the relation batween Kp & Ke for (hé following equilibrium reaction
Nyy +3H,,, = 2NH,

_ What is conjugate acid base pair? Give an example?«e *

State ve-chatlier's principle and apply it to the synthesis of ammonia i Habor's
process?

Write a few lines on the utility. hydregen as a fuel?

Wiito the chemical reaction to justify that hydrogen Permdde can fecution as an
oxidising as

well as redusing agent? - . .

Explain with sutable examples, the following. ) § Cd
I) electron-deficient i) elactron-praclse and if) electron-rich hybrides.

Explain boran bead test with a suitable examplo

. Write any two preparation methods for Diberana? Explain. -— its roact with the
(allowing :

a) Corben moriexide (CO) b} Ammonia (NH,)

Answer any Two of the following questions, 2X8=ib
Pe are quantum numbers 7 How aro the quantum numbers n, I and ml lc at 7 Explain

e significance of these quantum numbers?

hick are (he postulates of Bohr's model or hydrogon atom? Discuss the importance af
this

madel to explain various series of line spectrain hydrogen atom.

Wile an essay on s,p.d.f blocks?

What is periodic property? How the following properties vary in a'group and a pond}
Explaln
2) Electron ain ethaplhy (EA)

1) Alomic radius
3) Electro negativity (EN) 4) lonisation ethalphy (IE)
Define IE, and |E,. Wh / is IE, > IE, for a given atom? Discuss the factors that
effect IE of an

element?
What do you understand by hydridisation? Explain different types ol hybridisation
involving s
Ceraraical’ borolin )

and p orbitals ?
a) Write the corresponding equallons for the following reactions and name the
preductsA B,C (9
49,010 o (refer V+o 2 Sage) ih aualion bork

CaC, 0) A —tD ana LN

~ b)Wike ihe carrespording equations for the i reaction and name the products A B.C
(‘Yegea Ito 2 Sage) ia quuxlion bade

Ethyleno Tam A WKH pM,

* Write any two methods of preparalion of Acetylene. Explain how It Is reacts with

a)H ,0 b) 0,:

Describe (he any two methods of preparation of lide, E Explain how It is reacts
wills (he

folloving compounds. (TH 162 .

b) Hypohalous acld

5) 0,
c) Cold, dite kasi KMnO, d) Sa 0, " high pressures

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