Safety Data Sheet HEMPEL'S SILVIUM 51570 © HEMPEL ‘Conforms te Regulation (EC) No, 1907/2006 (REACH), Annex I, a5 amended by Regulation (EL) No. 20151830 Europe SECTION 1: Identification of the substance/mixture and of the company/undertaking 4.4 Product identifier Product name HEMPEL'S SILVIUM 51670 Product identity 5187019000 Product type aluminium paint 4.2 Relevant identified uses of the substance or mixture and uses advised against Fiala of application buldings . metal industry, ships and shipyards, Identified uses [eustrial applications, Professional applications, Used by spraying 4.3 Details ofthe supplier of the safety data sheet 4.4 Emergency telephone number Company details HEMPEL A'S Emergency telephone number (wth hours of operation) Lndtotegérdsvej 91 2X-2800 os. Lyngby “+45 45 99 28 00 (08.00. 17.00) ae ee See section 4 First id measures. hempel@hempelcom Date ofissue 8 September 2017 Date of previous issue 16 June 2017. ‘SECTION 2: Hazards identification 2.4 Classification of the substance or mixture Product defintion Mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Flam. Lig. 3, H228 FLAMMABLE LIQUIDS - Category 3 STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 STOTRE 1.4372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM) - Category 2 See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements = %6o6 Signal word Hazard statements 226 - Flammable liquid and vapor. 936 - May cause drowsiness or dizziness. 1372 - Causes damage to organs through prolonged or repeated exposure. 411 = Tox to aquatic fe wih long lasing eect. Precautionary statements Prevention ‘Do not breathe gas, vapor or spray. In case of inadequate ventilation wear respiratory protection. Keep ‘away from heal, hol surfaces, sparks, open flames and other ignition sources. No smoking. Response Get medical attention if you feel unwell In case of fire: Use alcchobresistant foam to extinguish Storage Réep cool Hazardous ingredients white spit ‘Supplemental label elements: Contains 2-butanone oxime and cobalt(2+) salts of C&-19 branched fatty acids. May produce an ‘lege reaction, Repeated exposure may cause skin dryness or cracking, Special packaging requirements Containers o be ited wit chid- Rt applicable resistant fastenings “Tactile warring of danger: (Wot applicable.Safety Data Sheet HEMPEL'S SILVIUM 51570 © HEMPEL SECTION lazards identification Other hazards which do not result None known. oe SECTION ;omposition/information on ingredients 2 uicuree ee a reo esis Tamer nae i Sere, yorae Ss seereista SEBEL canaenn Semmens ean eens Saree severriptaperdam, [peacee stauesias |xsao | Atte’ Tes + eo ioc eaee frov nee Sree Hera scas noise tie Secon REACH #:01-2119455851-35 | 21-53 Flam. Lig. 3, H226 5 ey Settee iors hss aoe tr Salar = pccnnoionosnese [a Aes > |m easte fecioei nae Sees sos Ete, eum So a anon oa Sera ay |2-butanone oxime REACH #:01-2119539477-28 | <1 ‘Acute Tox. 4, H312 - 1) ee Sito sh EE no secs anonayaim cere | EE posal’ as SF oc ts ommaaimis | Sra Snes al Srnec SEE a naamene “There are no addtional ingredients present which, within the current knowledge ofthe supplier and in the concentrations a Gaseited 26 hazardous to heath arte anvaranment and hence require reporting inthis section Type [1] Substance classed with a health or environmental hazard {2] Substance with a workplace exposure limit. see section 8 {B) Substance meets the criteria for PBT according to Regulation (EC) No, 1907/2006, Annex Xi [4] Substance mosis the citi fot vPVB according o Regulation (EC) No. 1807/2006, Annex XI [p] Substance ot equivalent eoncem [61 Adaitonal dsosure due to company policy SECTION 4: First aid measures cable, are 4.1 Description of first aid measures, General: In all cases of doubt, or when symptoms persist, seek metical attention. Never give anything by mouth to an unconscious person. It breathing is regular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate treatment (fst ai). Eye contact: CCheck for and remove any contact lenses. Immediately flush eyes wit plenty of water for atleast 15 ‘minutes, occasionally ting the upper and lower eyelis. In all cases of doubt, or when symptoms: persist, seek medical attention. Inhalation Remove to fresh air. Keep person warm and at rest. Ifnot breathing f breathing is irregular or it respiratory arrest occurs, provide artical respiration or oxygen by trained personnel, Give nothing by ‘mouth. If Unconscious, place in recovery position and seek medical advice. Skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Oo NOT use solvents or thinners. Ingestion It swallowed, seek medical advice immediately and show this container or label. Keep person warm ‘and at rest. Do nat induce vomiting unless directed to do so by medical personnel, Lower the head so ‘hat vomit wil not re-enter the mouth and throatSafety Data Sheet cone SILVIUM 51570 © HEMPEL SECTION irst aid measures Protection offistaiders No action shal be taken involving any personal risk or without sutable training. Ifit is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing ‘apparatus, It may be dangerous to the person providing ld to give moutheto-moutn resuscitation, 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact, No known sgnfcant fects rical hazards. Innatation Can cause central ners system (CNS) depression. May cause Growsiess or dizziness. sin contac No known significant efector rica hazards Ingestion Can cause central nervous system (CNS) depression. Overexposure signsleymptoms eye contact, No specie data. Inhalation ‘Adverse symptoms may nue he flowing feasacne Crowsinessfaique trconelusness stn contact No specfe data Ingestion No specie data 43 Indication of any immediate medical attention and special treatment needed [Notes to physician ‘Treat symptomatically. Contact poison trestment specialist immediately i large quantities have been ingested or inhaled ‘Specie treatments (No specific treatment. SECTION 5: Firefighting measures 51 Extinguishing media Extinguishing media Recommended: alcohol resistant foam, CO>, powders, water spray. Not to be used: waterjet. 15.2 Special hazards arising from the substance or mixture Hazards from the substance er Flammable liquid and vapor. Runoff to sewer may create fi or explosion hazard. In fre or it heated, rmodure = a pressure increase will occur and the container may burst, with the risk ofa subsequent explosion. ‘This material is tome to aquatic fe with long lasting effects. Fire water contaminated with this materi ‘must be contained and prevented from being discharged to any waterway. sewer or drain. Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides 5.3 Advice for firefighters ‘Promptly isolate the scene by removing all persons from the vicinity ofthe incident i there is a fire, No action shall be taken involving any personal isk or without suitable training. Fite wil produce denee black smoke. Exposure to decomposition products may cause a heath hazard. Cool closed containers exposed to fire with water. Do not release runoff from fre to drains or watercourses. Firesighters should \Wear appropriate protective equipment and sel-contained breathing apparatus (SCBA) with a full face-piece operated in postive pressure ‘mode. Clothing for freighters (neluding helmets, protective boots and gloves) conforming to European standard EN 4689 wil provide a basic level of protection for chemical incidents. SECTION 6: Accidental release measures 6.4 Personal precautions, protective equipment and emergency procedures, ‘Avoid all direct contact withthe spilled material, Exclude sources of ignition and be aware of explosion hazard. Venbilate the area. Avoid ‘breathing vapor or mist, Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk oF without suitable training, the product contaminates lakes, rivers, or sewers, inform the appropriate authorties in accordance with local regulations. 6.2 Environmental precautions of spilled material and runoff and contact with sol, waterways, drains and sewers. inform the relevant authorties ifthe faterernie cn re ith Water neil dina material Maw be harmful tothe environment itSafety Data Sheet HEMPEL'S SILVIUM 51570 © HEMPEL SECTION 6: Accidental release measures 6.3 Methods and materials for containment and cleaning up ‘Sop leak it without risk, Move containers from spil area, Approach release from upwind, Prevent entry into sewers, water courses, basements or confined areas, Wash spilages info an efiuent treatment plant or proceed as follows. Contain and collect spilage with non- Combustible, absorbent material e.g. sand, earth, vermiculte or diatomaceous earth and place in container for disposal according to local Tegulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilled product, 6.4 Referance to other sections ‘See Section 1 for emergency contact information ‘See Section 8 for information on appropriate personal protective equipment. ‘See Section 13 for addtional waste treatment information. SECTION 7: Handling and storage 7.4 Precautions for safe handling Vapors are heavier than air and may spread along flors. Vapors may form explosive miures with ar. Prevent the creation of flammable or ‘explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should be used only in areas trom which all naked lights and other sources of ignition have been excluded. Electrical equipment ‘should be protected tothe appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving Container with bonding strap. No sparking tools should be used. ‘Avoid inhalation of vapour, dust an spray mist, Avoid contact wih skin and eyes. Eatin, drinking and smoking should be prohibited in area here this material is handled, stored and processed, Appropriate personal protective equipment see Section 8. Always keep in containers ‘made from the same material as the orginal one. 7.2 Conditions for safe storage, including any incompatbilities, ‘Store in accordance with local regulations. Store in a cool, welLventilated area away trom incompatible materials and ignition sources, Keep out of the reach of children. Keep away trom: Oniizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized ‘access. Containers that are opened must be carefully resealed and Kept upright to prevert leakage, 7.3 Specific end use(s) ‘See separate Product Data Sheet for recommendations or industrial sector specific solutions. SECTION 8: Exposure controlsipersonal protection, ‘8.1 Control parameters Productingredient name Exposure limit values white pit EU OEL (Europe). (ACGIH) TWA:25 ppm 8 houre. (ACGIH) TWA: 143 mgin 8 hours. solvent naphtha (petroleum) ight arom EU OEL (Europe). "TWA. 120 mine 8 hours. Form TWA. 25 ppm 8 hours. Form solvent naphtha (petcleun), light arom, EU OEL (Europe). "WA. 120 mgin? 8 hours. Form: ‘TWA 25 ppm 8 hours. Ferm: Recommended monitoring procedures Ie this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness ofthe ventiation or ather control measures andior the necessity to use respiratory protective equipment Reference should be made to montoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide forthe application and use of procedures forthe assessment of exposure {0 chemical and biological agents) European Standard EN 482 (Workplace atmospheres. - General requirements forthe performance of procedures for the measurement of chemical agents) Reference to national qudance documents for methods fr the determination of hazardous substances wil also be required. Derived effect levels No DNELS/DMELs availble, Predicted effect concentrations, No PNECs availableSafety Data Sheet HEMPEL'S SILVIUM 51570 HEMPEL SECTION 6: Exposure controlsipersonal protection range sfee vertiaton by ozal exhaust verlon ané gos general vettton oeep te arbre concn of vapors st fonet possible and below tei respective threshold imt value. Ensue that eyewash stations and safety showers are proximal tothe work: station location. Individual protection measures General Gloves must be wom for all work that may resul in soling. Apron/coveralsfprtective clothing must be ‘worn when soiing is so great that regular work clothes do not adequately protect skin against contact \mith the product. Bafety eyewear should be used when there s a likelihood of exposure. e000 Hygiene measures Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, Using lavatory, and atthe end of day. Eyetface protection Safety eyewear complying with an approved standard should be used when a isk assessment indicates this is necessary to avoid exposure to quid splashes, mists, gases or dusts. If contacts possible, the following protection should be wom, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Hand protection \Wear chemicabresistant gloves (tested to EN374) in combination wth ‘basic’ employee training. The {ualty of the chemicab resistant protective gloves must be chosen as a function ofthe specific workplace concentrations ané quantity of hazardous substances. Since the actual work situation is unknown. Supplier of gloves shuld be contacted inorder to find the ‘appropriate type. Below listed glove(s) should be regarded as generic advce: Recommended: Silver Shield / Barer / 4H gloves, nitnle rubber. plyvny! alcohol (PVA), Viton® ‘Short term exposure: neoprene rubber, buty rubber, natural rubber (latex, polyvinyl chloride (PVC) ‘Body protection Personal protective equipment for the body should be s the rigks involved handling this product. Wear suitable protective clothing, Always wear protective clothing when spraying. Respiratory protection Use a propery fitted, ar purtying or alr-fed respirator complying with an approved standard if @ risk ‘assessment indicates ths is necessary, Respirator selection must be based on known or anticipated txposure levels, the hazards ofthe product and the safe working mits ofthe selectee resprctor. If working areas have inufcient ventiation: When the product is applied by means that will nt generate ‘an 2eracal such af, brush or roller wea half or totally covering mask equipped with gas fiter of type A, nen grinding use paticle fier of type P. When the product is applied by spraying and for continuous Dr prolonged work always wear an al-fad respirator e.g. hood with supply of fresh or compresses sir oF 2 full face, powered air punfying iter. e sure to use an approvedicertiied respirator or equivelent. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply withthe requirements of environmental protection legislation, In some cases, fume scrubbers, fiters or engineering modifications to the process equipment will be necessary 10 Feduce emissions to acceptable levels. ‘SECTION 9: Physical and chemical properties sted based on the task being performed and ‘94 Information on basic physical and chemical properties Physical state Liquia Color aluminium Odor Solvent-ike PH “Testing not relevant or not possible due to nature ofthe product. Melting pointireezing point -49°C This is based on data forthe following ingredient: white spint Bolling pointbaling range Testing nat relevant or not possible due to nature ofthe produc. Flash point (Closed cup: 38°C (100.4°F) Evaporation rate ‘esting not relevant or not possible due to nature ofthe product Flammability Flammable in the presence ofthe folowing materials or conditions: open flames, sparks and static discharge, heat and oxicizing materials. ‘Sightly flammable inthe presence of the following materials or conditions: reducing materials and akkalis, Lower and upper explosive 08-76 vol % ‘flammable itsSafety Data Sheet © HEMPEL SECTION 11: Toxicological information Productingredent name Rew Species Dove Exposure |FBvert napa erteuny, git EOD haan Vapor Rat Sas a shore L050 Derma avo 2160 mao - L050 Oral Rat 8400 mg/kg Pe scvent raph (peteum), fight LCSD Inhalation Vapor Rat 6193 mpi? urs 1.050 Dermal Rabbit a1so mgs . LBs ovat Rat a2 mana 7 strene LeS0inataton Gas. ot 2770 pom fours cso inhalaon Vapor Rat Ffaodmgme [4 hours Lg0 Oral 2es0 mag - 2-buanane oxime LOs0 Dermat {ot mo - Lbs0 ra S30 mo Fe Acute tonieity estimates Route ME vabe Tie fou egnean cas or az azar Inritation/Gorrosion Productingreiont name Reale Species | Seow Exposure |Falent naphiha pete) Faht | Eyes Mid tant Rabe fat ors 100 maces ent naphtha (petroleum), ight | Eyes - Mild irritant Rabbit - |24 hours 100 microliters Respiratory -Mid ita abit - f styrene Eyes Moveate rant astit 2 Je hours 100 matigrams 2 bstanone oxime Eyes. Severe tant abit 2 footers Mutagenic effects, ‘No know signa elects o tical hazard ‘carcinogenicity ‘No known sgnifcant effets octal hazards Reproductive toxicity ‘No known significant efecto ica hazards Teratogenic effects ‘Ne know sgnifcant elects octal hazar ‘specific target organ toxicity (single exposure} Productingredient name Categary | Route of exposure Target organs rae a Caegoy? TN appeable, | Nave efegs Seven naphtha (petreum), gh arom. Gagan 3 Neeseeteatle, | Resprotry wat intatn and Nero hes 1.2¢¢:rimetyfbenzene Category 3 Not applicable. —_ | Respiratory vactiitaton Specie target organ toxicity (repeated exposure) Productingrediont name Category | Route of exposure Taree ogame rae it Caisson? Trhalabon cena pervous ater (ONS) rene Eategory Notdetermined —_| heating ogame Aspiration hazard Productingredient name Result ie pt TASPIRATION HAZARD - Category 1 ‘ven naphtha (petlou, ht rom. ASPIRATION HAZARD - Category | Information on the ikely routes of exposure Routes oferty anticipates: Oral, Dermal, Inhalation. Potential chronle health effects Productingredint name] Carcinagenic feds | Witagenic eects | Developmental effects | Feri effectsSafety Data Sheet HEMPEL!'S SILVIUM 51570 © HEMPEL SECTION 44: Toxicological information Sensitization Contains 2-butanone oxime, cobat(2) sas of C6-19 branched faty aids. May produce an allersic ‘eatin ther information No addtional known significant effects or erica hazards SECTION 12: Ecological information 424 Toxicity 1 not allow to enter drains of watercourses. Tovc to aquatic fe with fong lasting effect. Productlngredient name Result ‘Species Eiposure [Paventnapha (etcleumy, it | Aete E050 10 woh ase Poeudokrchnerioa subeapiata [86 hours rom geen algae) ‘auto E050 6.14 mo Daphnia Daphnia magna 48 pours ‘ate LC80 9.22 mat Frch Oncommchus mys (rainbow | hours ‘wut sokentnaphina pevsleun).toht | Acte E050 28 mot ‘Agoe- Pacudokrchnetilasubcaptata [96 hours arom {green algae) ‘outs £080 6.14 mat [Bapina= Daphnia magna 48 hours ‘este L680 9.22 mot Pat" Oncomynanus mies (ainbow [86 hours rout) strene ‘Acate £050 33 mg Fresh water [Agee Pseudokrnerilasubcaptata. {96 hours Chronle NOEC 53 Yat Freshwater [AgaePseudosrctmerila subeapfata_ [96 hows 42.2 Persistence and degradabilty Productingredient name Test Result ‘Dose | _trovalum -soivetnaphiva petleur). fant |= [70%-Resaly- 28 do FE F Scivent naphtha (perleum),Fobt | - 270 %-Readly- 28 days - - Productingredient name ‘Aquatic hatte Photolsis Blodegradabiity atventnepie (pave), want |= F Rena Fokent naphta pebsleun) taht |- |. Realy 412.3 Bioaccumulative potential Productingredient name Bor Potentat Palventnaphe petteur), ight rem 10-2500 ah elven naphtha (pevaleum), Fgh arm. : 402500 om styrene 038 1349 ow z2utanone oxime os 25-58 ow 124 Mobility in soil Soiietrpaion coeidet No iran dla ete ce database, (Ke) Mobitty [No known data avaliable in our database. 42.5 Results of PBT and vPVB assessment Par ‘Not applicable we ‘Not applicable, 12 Other adverse effects [No known significant effects or crtical hazards.PT. MEGANTARA UTAMA RAYA Se te eoagrs sven re sie | PREJOB __ ACTIVITY _ ABSENSI | [wo | —_ NAMA sasxray | ) es 1 | beat A i fe | 2 | rant an a |__| surat Ween » UE ; | ca tae ‘Bheay = | 5. Ole Ghavan ene gd f/ | o._| Mowat Wel 6 Ban | twee ele | = __| 3 | Pret _Relectje 8 L 8 Wan Soout Maaber | _ / 10 | 10. a | i“ “