240 Master The NCERT CHEMISTRY Vol-II 18. Compounds of type MAyXe¥e, MAQX@¥Z, MAQXYZL. MABXYZL, M(AA),, M(AA)o Xp shows optical isomerism 14, lonisation isomerism arises when complex compounds wth same molecular formula give diferent ions in solution, 15, Linkage isomerism arises wien a complex contains & monodentate igand with more than one donor atoms, 46, Coordination isomerism arises when there is exchange of ligands between complex cation and complex anion 17, Hydrate fsomoriem arisor whon difront numbor of water molecules present in the coordination sphere. 18, Valence Bond Theory (VET) According to valence bond Uneany CVT), eel io rr et re iets of ligands can use (n~ }ns, np, nd orbitals for hybricisaton to yield square planar, tetrahedral or ‘ectahedral geometry. These hybridised then overlap wth ligand orbitals which can donate an electron pair for bonding. 19, Acomplex compound may be nner orbital complex or outer ctbital complex depending upon whether d-orbitas ofthe inner shel or outer shel are involved in hybridisation. Imer ‘orbital complex is generally high spin complex while outer ‘orbital complex is generally high spin complex 20. If no unpaired electron is present. the complexis, diamagnetic. f unpaired slectronisisfare present, complexis peremagnetic and its magnetic momeit = Jk +2) where, nis the number of unpaired elect¥ons present, 21. Crystal Feld Theory tis more appropriate theory than VBT- Recording to G*.under the influence of igand fe, dogeneracy of he dt-bitalis destroyed and it spits ito two or more energy eves 22. The extent of aplting dapends onthe strength of ligand. A strong igand causes greater sping while @ weak ligand causes smar sping 23. The diference of eneray between the two sts of dforoial (in octahedral complexes) = caled crystal fed piiting energy (CFSE) or 8. The magnitude of, depende upon the nature of the ligand 24, The iereasnglotder of 4, s given below: 4B eSteSCN"< Cl < F< OH woocet c,c001 Sy a—e, wo0c coon oocet, ease © Neth 100CCH io ‘CH,COOH 000 nove nef oy ln on Ne coon bs, nooo?” 17. Among the properties (4) reducing, (B) oxidising, (C) complexing, the et of properties shown by CN" ion towards metal species is (@) BandC (0) AandC (0) A, Band () A and B 18. Coonination number (CN) ofa metal ion in a complex can be defined as (@) umber of ligand donor atoms (©) number of ligand donor atoms to which the metal is ininootly bonded (6) number of ligand donor stoms to which the metal is dliretly bonded (4) None of the above 19, The most stable system for a chelate is (a) five fused eyclic system (@) four fused eyele sytem (6) thre fused eyelie system (4) so fused eyeli system 20. A ligand can also be reganded 88 (a) Bronsted base (0) Brosised acid (©) Lewisbase {@, Lewis acid 21. Coordination nusiber of Pt and Ni in [PxCl, > and [NICU ),]* eno respective (@) 4and6 (ands, (©) 4and4 (a) Gand 89. Inthe comply ins, [EAC0,)5]> and [Cofen), {he coordination number of Fe and Co is 6. Why? tigams (b) Because C,0}- and ethane-,2-diamine are amibidentate Tigands| (©) Decause CO} and ethane-I 2iamine are polydentate Vigands (@) None of the above 29. The coordination number of a central metal atom in a complex is determined by (@) the number ofigands around a metal ion bonded by o-bonds (©) the number of igands around a metal ion bonded by ebonds (6) the number ofigands round metal on bonded by and x bonds both (@) the number f only anon ins bonded othe meta on 24, A chelating agent has tw0lor more than two donor ‘toms to bind t asingle metal ion. Which of the following re chelating agents? 1. Oxalawo 1, Glycinao 1M Bthane-12-tiaine 111, Tiosutphato Choose the corret option (@) Land ul ©) ttt (0) ltttand iv (@ Litandv 25. Coordination number of Fe in [Fe(CN),]* and [Fe(CN),}* are respectively Aan (©) 6and6 (9) 6and3 (Gana 26, In the complex K,[Fe(CN) 9 identify the coordination sphere and the counterion (@) K" coordination spheres [FA{CN),]™ counterion (©) (FeICN) J coordination sphere; K* counter ion {©) (© coontination sphere; K* counterion {@) None of thesbove 21, The oxidation number ofthe central atom ina complex is defined as the charge it would carry (@) all se Tgands are removed alongwith the electron rs that are donated by the cena atom (0) ial the ligands are removed along withthe eletron pir that are shared with the central torn (6) ifallthe ligands are removed from th central metal tom (@) all he cloctrons pairsare shared with the conta stom. 28. The oxidation state of Fe in the brown ring complex [Fe(H1,0); NO]SO, is @3 wo wa 29. A complex compound in which the oxidation number ofa metal is 200, is, {@) [Ni(CO),] (©) (PUNt, IC, (0) KFACN.1 (@) KAlPACN1 80. The pair ofcompounds having metals in their highest oxidation states is {@) [Mn0,1°, Cr04Cl, (©) Mn0p, FeCl, or (6) Nich F>,(CoCLT (IFAENI GF ICANT?81. ‘The equation which is balanced and represents the correct product (5) is (GEE Main 2014) (@) Lis0+ 2KCI — 2Lic1+K,0 (0) [CoCKNH,)g}* + 5H" —> Co? + SNH) + CI (© (Me(H,O,F* + (EDTA) = OH, [Mg (EDTA + 64,0 (@) C80, + 4KCN —+ K,[C{CN)]+ K,80, TopicBd CHAPTER 9 : Coordination Compounds 243 82, [Co(NH,},]"* and [Co(NH,),C1,]" are the examples of {@)homoleptc complexes (b) hteroleptc complexes {© [Co(NHI,)” homolepticcomples; [ANH ),C1]" teteoleplc complex (@)[Co(NtH,)}” hotereleptic compe (CAN, homolepte comple Nomenclature of Coordination Compounds ‘38. Which of the following statement is incorrect for ‘nomenclature of coordination compounds? {@) The cation i named first in both positively and negatively charged coordination entities (6) The ligands are named in an alphabetical order before the name of central atomvion (6) Names of anionic ligands with electron (@) Prefixes mono, di, tr et, are used to indicate the numberof the individual ligands in coordination 34, The neutral licands NH,. CO and NO respectively are named is (a) amaine, carbonyl and nittosyl () amino, carbonyl and nico (6) amine, eurboxyl and ntrito (@) amine, carboxyl and nitzosyl If the complex jon is anion, the name or the metal ends with the sufix-ate, for eationie complex ion, (2) the moral is named same asthe element () the name ofthe metal ends with tho sfx até (6) the metal is named ends with the suffix =O (@) None ofthe above ‘86. Name the compound [Co(en) Cl, ];80, (@) dichloroothylenediamminecobal (i) sulphate (6) dichlorbisethylesediamminecobalt It) sulphate (6) 2-bisdichloroethylenedianminecobal (Il) sulphate (@) dichlorobisethvlesediammnecobalt (1) sulphate ‘87. Which among the following will be named as dlibromidobis (ethylenediammine) chromium (III) 35, bromide 7 (AIEEE 2012) (@)[Citen),] Bs (6) [Crem Br JBe (o[xembs 1 (2) [Cx(em)Be Be ‘88, Identify the false statement, (@) Molecular formula of tetraamminediaguacobalt (Il) blonde is [Co{NH, (HO). C | (©) [PCC1:(en), INO, ) isthe molecular formula of Sichloico bis (ethane-1,2-diammine) platinum (IV) sieate (©) Molecular formula of ron (ID) hexacyanoferate (I) is Fea{Fe(CN},s () eoaspex name stars with meta, it isananionie complex 89, In the given compound [Pi(NH }Cl(NHL ) (CH )}CL Identify the metal (4), counter ion and ligands (C). (ASCE BPC NH (b) A> Pt; B-> CC NH,,CLNHL and CH, (©) A> Pe BCL CNH, CL (@) tetrmammineaquacobalt chloride (6) tetraamminediaquacobal (ID chloride (c) tetraamminediaquacobalt (IV) chloride (4) None ofthe above 41. The IUPAC name ofthe complex [Co(NH, ) Cl, |Clis {@) tetraammine dichlorocobat (IT) chloride (b) tetraammine dicloroeobalt (IV) chloride (6) tetraammine dichlorocobal (I) chloride (@) dichloro tetraammine cobalt(II) chloride 42, Ammonia gas does not evolve from the complex FeCl, -4NH, but it gives white precipitate with aqueous solution of AgNO. Coordination number of central metal ion in above complex is six Give IUPAC name of the complex. (@) Ammonium tichlora triamamine iron (LI) (b) Tetraammine ion (Il) chloride (6) Dichlorotetraammine ferzate (I) chloride (4) Dictlorotetraammine iron (I) chloride244 — Master The NCERT CHEMISTRY Vol-II 43, The IUPAC name of compound K{FeCN) :NO]is (@) pentacyanonitrosypotassium ferrate (I) (©) potassiumeyanopentanitrosy erate (I) (6) potasiumpentacyanonitrosylferate (ID) (4) potassiampentacyanonitrosyl erat (II) 44, The IUPAC name of [Ni(PPh, 12Cls]is (a) bis-dicloro (riphenylphosphine) nickel (I) (©) dichiorobis (triphenyiphosphine) nickel (11) (6) elettorouiptenyiplosphine uckel (1D (€) tciptenylphosphine nickel (I) dichloride 45. According to IUPAC nomenclature sodium nitroprusside is named as (@) sodium pentaeyanonitrosylferate (II) () sodium pentaeyanonitrosy erate (II) (6) sodium nitoferieyanide (@) sodium nivoferroeyanide 46, IUPAC name of Na[Co(NO, ), is (@) sodium hexantritocobaltate (11) () sodium hexanito cobatat (HD) (6) sodium hexantritocobalat (11) (4) sodium eobalinicite 11) 47. Write the formula for coordination compound diamminecilver () dieyanoargontate (), (@) [AQ(NH,)o]IABICN)g}(b) [AR(NH )ILARIEN] (€} [AQINEL )sITAGICNY,] (A TABCNH ) HARIEN)T 48, Write the formula for coordination compound, named as tris (cthane-1,2-diammine) cobalt (IIT) sulphate {@) [Co(Ht,N CH, CH, NH); ($0y)s (©) (Co(Hl,NCH,CH.NH,),]80, (6) [Co(FNCH,CH.NH, ). (50, )p )3}S0u). Topic] 49, Wit the IUPAC name of K,[20(OH) }- (@) Poiassium tetranquazincate (1D) () Potassium tetrahyroxidorinete (I) (6) Potassium teranquazincate (11) (@) Potassium tetrahydeoxiderincate (1) 550. In{Co(H, NCH,CH,NHs)) (SO, the coun ©) CHAN @) Gh’ ONY @ 80; BA. The name of the complex [AIOM) (1130), 180, is (2) dihydroxoteushydridealumisium (1) sulphate () termaquadiydroyalumiur (Ht) sulphate (6) tetcaaguadiydosyaluesinium (1V) sulphate (@) None ofthe above 52, What isthe IUPAC name of Hg[Co(SCN) 4]? () Meroury tetahioeyanaio cobalt (I) (by Mercury tetrathioeyanato cobalt (I) (©) Mereurytesahioeyanato cobalt (1) (@), Mereuryttracyanato cobaltate (I) 53. Write the formula for the coordination compund Aichloridobis ethane-1,2-liamine) plain (IV) nitrate (@) [PICLA(Ens]INO4}s—() [PICT(NO, Ja }end (ey TPueMgINO, ICL, (d) None ofthese Ba, The IUPAC name of coordination compound K [ANC,04) lis (@) potassium trsalatoaluminate (ID) (b) potassium hexacarbonyluminae (tt) (6) trioxalato aluminium I potassium (6) potassium trixalato aluminate (1) 55. Write the IUPAC name ofthe coordination compound FeglFeCN) 6] (@) Iron () hexaeyanidoferat (I) (6) Iron (il) hexaeyanierete (11) (6) Iron (t) hexaeyanoferate (I) {@) from (1) hoxasyanoivon 1) Isomerism in Coordination Compounds 156. Choose the oddone Out (a) solvate isomerisan {e) tonisationisomensm 57, Identify the geometrical isomers of Pr{(NH;)sCls] {) optical somerism ch, th cy, Ni § aha, yw Por cy, UN ay cl Man! Mn, () coordination isomerism ‘Choose the correct option (@) Tad Tt () Mand tt (6) Vand It (@) Wand 1 58. Which type of isomerism arises when bidentate ligands (L-L) are present in complexes of formmula [aes =2)2)? (a) Optical isomerism () Geometrical isomerism (6) Linkage isomerism (@) Solvate isomerism159. The existence of two different coloured complexes withthe composition [Co(NHs),Cla is due to (Cost steMT 2012) (0) nization isomerism (©) inkage isomerism (© geometrical isomerism {ey cvoraination somes 60. Which one amongst the following, exhibit sseomettical isomerism? (@) [Co(NH,),BISO, (©) [CoeEDTAE (© fenseny, 7 (@) [PUNH,),Ch} 1. Identify the facial (fac) and meridional (mer) isomers from the following Nth Nil on oN NO; oe Pm, Onn my ON NO, NO; Nit, 4 B Ome ae Ui Om haw fe mer 662, Which one ofthe following hasan optical isomer ? (ca ethylenediamine) (AIEEE 200 (a) (Za(enyNH, yP* (oy {Coren) (6) [CoM O)(en)P* (arte 663, The correct statement onthe isomerism asociated with the following complex ins IER Main 2016) 1 [NiG10),NEG P* 1 [NiGI,0),(NE, ) UL. {NiO}; (NE 3 F* (@) Land show geomet andopticl isomerism Man say oly pa usa (©) ll and Il stowonly geonetieal isomerism (@) and I show geometrical and optical isomerism 64, Ina coordination entity ofthe type [PIC (en). F*, optical activity is shown by (@ only ester (©) only ran-somer (6) both ls and rans-somers (@) None the above CHAPTER 9 : Coordination Compounds 245 ie fe iT : a ac Qe ween Sc oN : : 7 a a as Ne cw Ske <3 ‘ Se Norn a nih € D Inthe ab rc ent thc nd trans-isomers (@) efisomers = B,C; rans-somers = 4, D () civ isomers = 4, D; transisomers = B, C (6) eivisomers> 4, 8; ransisomers = C, D (4) elvisomers = 4, C:sranisomers = B, D 66. The eomplex, [Pu(py\(NH, )BrCI] will have how many geometrical isomers? (CBSE ALPMET 2012) 2 3 or oo G7. Which of the following coordination compounds \would exhibit optical isomerism? {@) Pentaamminentrocobal (Il) odie () Diamminedinitroptatinurn (1) (6) trans-dicyanobis (ethylenediamine) (4) Tris-(thylenediamine) cobalt (Il) bromide 68, Which type of Ligand is contained in linkage (@) Unidentate () Bidentate (6) Polydentate (@) Ambiente 69. Coordination isomerism arises (@) when the counterion i a complex sats tsel'a potential ligand (©) from the interchange of igands between cationic and anionic elites of different metal ions present in a complex (6) Both (a) and (b) are correct. (@) None ofthe above 7. The complexes [Co(NH, )g]CH(CN),Jand [CFENH)¢]ICo{CN) ] ae the examples of which type of isomerism? (CBSE AIPM 2012) {@) Geometical nomerim (©) Linkage isomerism {6)lonsation isomerism {) Coordination isomerism246 — Master The NCERT CHEMISTRY Vol-II ‘71. The pair of (Co(SO, (NH; ); JCland [CoCINHS 180, constitutes (@) optical isomers” () linkage ames (© coontnton omens (2) fenton omen 772. (Co(NH,),80, Br and [Co(NH)5Be}SO, are (9) lnk emer (©) ionisation mers (3) eoertnation isomers (@) solvate isomers Topic "78. Which one of the following comploxee shows optical isomerism? (GEE Main 2016) (2) cis-[Cofen),, Ct (©) rans-[Cofen):C12]C1 (©)[CONT,),C13 IC} (@ [CoH ),C1} Bonding in Coordination Compounds 7A. Which one ofthe following is an outer orbital ‘complex and exhibits paramagnetic behaviour? (CBSE ALeMT 2012) r (b)[ZoINHs)6P* Dal (&){Co(Nt),” Red precipitate is obtained when ethanol solution of dimethylalyoxime is added to ammoniacal Ni(I). ‘Which of the following statements is not true? (CASE AIPM 2010) [Newt (oy[cut . ou WC—C=N* Dimethylglyoxime = I HYe—C=N, (@) Red complex has a square planar geometry (©) Complex has symmetrical H-bonding (6) Red complex has a tetrahedral geometry (@) Dimethyglyoxime functions as bidentate ligand 76. The d-electon configuration of Cr*) Mu? Fe™ and Co are d*,d°,d® and d” respectively. Which cone ofthe following will exhiitminimum paramagnetic behaviour? (Atomie number of Cr =24 Ma 5 Fe = 26, Co=27) (CBSE ALPMT 2011) (Cr, ()[Mn, 4° (©) [Fe(H,O), (a) [Co(H,O),P* ‘77. Which of the following complex ions is diamagnetic innature? (CBSE APM 2011) (@)[CoF,P Nic Onien,t (@)[CuCF 78, [Ni(CN),*[MnBr,]** and (CoF, ™, geometry, hybridisation and magnetic moment of the ions respectively, are (@) toxahedra, square planar, octahedral ap .dip?,sp'd? :5.9,0,49 (©) texts, suse planar, octahedral Aphis P20, 59,49 (6) Squye planaAerabedrl octahedral Op ap dsp #59,49,0 (@) square pay, abel oetabedal ops spit £0,89, 49 17. The parhaving the same magnetic moment is {atomic number, Cr=24, Mn =25, Fe=26 and €o=27| GEE Main 2016) {o){cat10),F* na reat.o,F (Uy ouatO,P ams CALOKE™ ()(CoCLF* and [FettLO},F* (@) [Cr(H,O),]"* and (CoC, 80. For d* ions, the number of possible pattems of electron distribution arises is (a) wo (tse © for © tive 81. For d‘ions, the fourth electron enters one ofthe ey ont giving the configuration fe, when ) a.>P ) a,

(MocH,0),}"* and A, of (Ti(H1,O),)"* > [Mo(H1,0),7* (A, of (CHO), * > [Mo(HH,0),* and A, of [Ti(H;0)gP” <[Mo(H1,0),]°" (@) 4, of (Cr(H,0),* < [Mo(H;0}, ‘and A, of [Ti(Hj0),]" > [TH(H,0),}"* '85. Which of the following complex ion is not expected to absorb visible light? (CSE ALPMFT 2010) ¢b)[NW(CN), > (LFe(H0),P* £86. When concentrated HC is added to an aqueous solution of CoC its colour changes from reddish pink to deep blue. Which complex ion gives blue colour in this reaction? (GEE Main 2015) @ [CoC (by [CoC (©)[CoC, J" (€)[Co(H,O),]" ‘87. Crystal ficld stabilisation eneray for high spin d* (LCN gP* ‘octahedral complex is (CBSE ALPMT 2010) (@)-D6a, ()-18a, (o)-16a, +P @-12a, 88, Atomic number of Ma, Fe and Co are 25, 2 respectively. Which ofthe following inner o ‘octahedral complex ions are diamagnetic? 1. [Co(NH, Jg]" TL [Mn(CN)]” UL. [Fe{CN), 1" IV AFeEN) Choose the correct option, (@) Hand I (tana (©) Land (@) Mad 189, A magnetic moment oF HT BM wil be shown by one among the Follow (CBSE AtPMrT 2012) «(coat 4p HEME (TiC, (a [Coch $90. The acahedral camps ofa metal ion M2 with four monodentate Hizands LL, l3 and Ly absor’ ‘wavelengths inthe region of red, eren, yellow and blue, spectively. Tho increasing ondor of lisand strength ofthe four ligands is (SEET 2016) @u} (©) [AUCN), and [Ag(CN); (4) SEEN and AuCM 118. In photography, the use of Na,S,0. (a) for converting AgBr into Az,SO, (b) for converting AgBr into soluble thiosulphate complex (©) for converting AgBr into silver thiosulphate (d) in reduction of Ag metal from gE SH,Ois CHAPTER 9 : Coordination Compounds 249 110, The oxcoes of eoppor and iron aro removed by chelating ligands (@) disferioxime-B () D-penicillamine (6) disfersioxime-B and D-penicillamine respectively (4) D-penicillamine and disferioxime -B respectively 120. For lead-poisoning, the antidote used is (@) white ofan exe, (0) cisplatin (6) nickel (@) EDTA Special Format Questions I. More Than One Correet Option 121. A bridging ligand possesses (@) polydentate nature (©) two or more donor centres (6) the tendeney to got itzlfatached to two metal fons (A) cmly one dentate site 122, Diethylene tiamine are (@) chelating agent () polydentate gan (6) tridentate ligand (@) nota ligand 123. A ligand having an unshared pair of eleetorns may, bea (@) neutral molecule (©) positively charged ion {) negatively charged fon (@) group containing a lone pair of eleetons 1124. The oxidation number of meta atom are zero in @NKCO), ()F(CO), (NalCACOYI (arcact 125, Which ofthe flloying Wo not have square planar geometry? fay [CoelP 8) [Fee onicn? (ore, 128, Which of he flowing me for Haan etal complex? (2 Lares te ligand the more sable is he met gad compl (6) Highly charged ligand forms stronger bonds (6) Larger the permanent dipole moment of igan, the more stable the bond (@) Greater the ionisation potential of central metal, the stronger the bond 127, Which ions are not paramagnetic (@) Ni(II” (VINICOI {@)[CotNH,),)"* (@[NUCN)F 128, Which is true in ease of (NCO), ? (6) Hybridisation of Nis p° (b) Tetraedral shape (©) Diamagnetic (4) Square planae 129. Which of he following pars do not represent linkage @ [CuNH, ), PCH, Jand (PUNE, ),}ICWCI,) (b[P4CPPH, (NCS), and (PACPPh, (SCN); ] {©) [CNH ]JNO,SO, and [Co¢NH,),S0,]NO, (@IPICL,¢NII Bx and [PB (NH) Ils 180, Which complex is dsp hybridised? (@)[Co¢NH, 1 (){Fe{CN) ()LCWNI I” (6) None of the above IL, Statements Based Questions ‘Type I = Directions (Q. Nos. 131-132) In the following questions, a Statement I is followed by a corresponding Statement Il, Of the following Statements, choose the correct one. (@) Both Statement Land Statement II are correct and Statement Il is the correct explanation of Statement (0) Bos Suteont Tail Sateen ate worsen bul Statement IT isnot the correct explanation of Statement I (©) Statement 1s eorect but Statement Is incorrect. (@) Statement 1s incorrect but Statement I is correct.