IPUC- CHEMISTRY PASSING PACKAGE

Chapter 1 :Some Basic Concepts of Chemistry

1. Problems Empirical and molecular formula-4M
2. Dalton’s atomic theory(3 Postulates)-3M
a. Law of conservation of mass
B.Law of definite proportions
C.Avogadro’s law
D.Gay Lussac’s law of combining volumes.
3. Molarity, Molality, Mole fraction- definition,formula, numerical.
4. Classification of mixtures with an example each.
5. Density: formula,S.I units
6. Calculation of molecular formula.(Tabular column)

Chapter 2 :Structure of an Atom

1. Any two limitations of Rutherford’s model.
2. Bohr’s atomic model-Any 3 Postulates
3. Any two limitations of Bohr’s model.
4. Heisenberg’s uncertainty principle- statement ,mathematical formula
5. De broglie’s- statement ,mathematical formula
6. Significance of 4 quantum numbers(1 point each)
7. Pauli’s ,Aufbau’s and Hund’s rule of maximum multiplicity- statements

Chapter 3 :Classification of elements and periodicity in properties

1. Mendeleev’s periodic law,Modern periodic law,
2. Definition,Variation along period and group: Atomic size,Ionic size,Ionization
enthalpy,Electronegativity,Electron affinity.
3. Isoelectronic species: Definition, example.
4. Short note on s,p,d and f block elements(1 point each)
5. Reasons for anomalous behaviour of 2nd period elements
6. Diagonal relationship -Explanation with 1 example.

Chapter 4 : Chemical bonding and Molecular structure

1. Octet rule and its limitations(Any two)
2. VSEPR theory postulates(any 3)
3. Account for the shape of Water, Ammonia based on VSEPR theory.
4. VBT theory postulates(any 3)
5. MOT postulates(any 3),Energy level diagram,Electronic configuration, magnetism and bond order.
6. Differences between sigma and pi bond
7. Differences between BMO and ABMO
8. Dipole moment-Definition,Units
9. sp(BeCl2 example), sp2(BCl3), sp3(CH4) hybridization
10. Intermolecular and intramolecular hydrogen bonding -Definition and 1 example each

Chapter 5 : States of matter

1. Postulates of kinetic molecular theory of gases.(Any four)
2. Law and mathematical expression(Boyles law,Charles law,Gay-Lussacs law,Avogadro’s law)
3. Ideal gas equation Derivation and numericals
4. Vanderwaal’s equation for n moles of the gas.
5. Surface tension,coefficient of Viscosity -Definition units
6. Critical temperature,critical pressure -Definition
7. Conditions for deviation of gases from ideal behaviour.
Chapter 6 : Thermodynamics
1. Definitions and examples: Isolated system, Adiabatic process, Isothermal process,Extensive
,Intensive properties,entropy
2. Statement and mathematical expression 1st,2nd and 3rd law of thermodynamics
3. Thermochemical equation -Definition and one example.
4. Hess law statement and one example (no need to remember the enthalpy values ,u can write x,y,z…..)
5. Write Gibbs equation and mention the terms.
6. Born haber cycle for NaCl.
7. Bomb calorimeter.

Chapter 7 : Equilibrium
1. Homogeneous and heterogeneous equilibrium with one example
2. Le Chatelier's principle: Definition,Effect of change in pressure ,temp and conc taking formation of
NH3 and as an example.
3. Predicting the extent and direction of reaction in terms of Kc and Qc.
4. definition-pH,Common ion effect,Acidic and basic Buffer,solubility product (with an
example each)
5. pH+pOH = 14.Prove.
6. ΔH=ΔU+ΔngRT
7. Definition, one example:Arrhenius acid ,base, Bronsted -Lowry acid base,Lewis acid ,base.
8. Kc and Kp expression for a reaction at equilibrium.

Chapter 8 :Redox Reactions

1. Balancing of redox reaction(4 equations from textbook and 1 from class notes)
2. Identifying oxidation ,reduction ,Oxidizing agent and reducing agent in the given reaction.
3. Definition of oxidation ,reduction,oxidant and reductant(according to electron transfer method,increase
or decrease of oxidation numbers).

Chapter 12: Some Basic principles and techniques

1. Chain,Positional, Functional,Metamerism, Isomerism with one example each.
2. Differences between Inductive ,mesomeric ,electromeric effect(any two differences)
3. Definition and an example each: Nucleophile,electrophile,free
radical,carbocation,carbanion,homolysis,heterolysis.
4. Kjeldahls method, dumas method, carius method ,Leibig’s method.(formula,explanation,diagram)
Chapter 13: Hydrocarbons
1. Wurtz reaction with example.
2. Kolbe’s electrolysis for preparation of ethane.
3. Free radical chlorination of methane -mechanism.
4. chlorination,Nitration ,friedel craft’s alkylation and acylation electrophilic substitution mechanism -
benzene
5. Markovinkoff’s rule ,
6. Mechanism for addition of HBr to propene.
7. State Huckel’s rule.
8. Newmann projection -eclipsed and staggered conformation for ethane.
9. Geometrical isomers of but-2-ene(cis and trans)
Chapter 10,11:s and p block elements
1. Solvays process of preparing Na2CO3,
2. Preparation of NaOH in Castner kellner cell
3. Allotropic forms of carbon(diamond,graphite and fullerene)-3 differences
4. Preparation of plaster of paris.