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(CHEM) Chapter 11.5 - Carboxylic Acids
(CHEM) Chapter 11.5 - Carboxylic Acids
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TOPIC 11.5:
CARBOXYLIC ACIDS
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THE ABOUT
ANALYSIS EXAM
• Understand how esterification works and the
conditions needed
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KEY CONCEPT
CARBOXYLIC ACIDS
HOMOLOGOUS SERIES
FUNCTIONAL GROUP
GENERAL FORMULA
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HCOOH
Methanoic 1 HCOOH CARBOXYLIC ACIDS
acid
Carboxylic acids have a general formula: CnH2n+1COOH.
Functional group
Ethanoic acid 2 CH3COOH CH3COOH
Carboxylic acids contain the -COOH functional group
(carboxyl group).
Isomerism
Propanoic acid 3 C2H5COOH
Carboxylic acid molecules that contain at least four carbon
atoms will display isomerism.
CH3CH2COOH
Isomers have the same molecular formula and similar
chemical properties.
4
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KEY CONCEPT
CARBOXYLIC ACIDS
PHYSICAL PROPERTIES
PRODUCTION OF ETHANOIC ACID
ESTERIFICATION
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PHYSICAL PROPERTIES
Physical property Reasoning
As the number of carbon atoms in the carboxylic acids increases, the melting and boiling points of carboxylic
acids increases as well.
As the number of carbon atoms in a carboxylic acid increases, the size of the molecules are bigger and have
Melting and boiling points
stronger intermolecular forces of attraction between each other. As such, more heat energy is needed to
overcome the intermolecular forces of attraction between the carboxylic acid molecules. Hence, larger carboxylic acid
containing more carbon atoms will have higher melting and boiling points.
As the number of carbon atoms in the carboxylic acid increases, the volatility of carboxylic acid decreases.
(similar to m.p. & b.p.)
Volatility With a higher relative molecular mass, there would be stronger intermolecular forces of attraction between
the carboxylic acid molecules. As such, more heat energy is needed to overcome the intermolecular forces of
attraction between the carboxylic acid molecules.
As the number of carbon atoms in the carboxylic acid increases, the density of carboxylic acid increases.
Density
As the number of carbon atoms in the carboxylic acid increases, the viscosity of carboxylic acid decreases.
(more difficult to flow)
Viscosity
Carboxylic acids with longer hydrocarbon chains flow less easily as they tend to get stuck together.
As the number of carbon atoms in the carboxylic acid increases, the flammability of alcohols decreases. (more
Flammability difficult to burn)
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Carboxylic acids are soluble in water, but as the number of carbon atoms increases, solubility in water decreases.
Solubility
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1) Oxidation of alcohol
C2H5OH (aq) + O2 (g) CH3COOH (aq) + H2O (l)
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WEAK ACID Carboxylic acids are weak acids and will be able to react with reactive
metals, bases and carbonates.
The name of the salt formed would be based on the carboxylic acid
Carboxylic acids are weak acids as they only partially dissociate in that is used and ends with ‘-ate’.
water to release a low concentration of H+ ions.
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1) Esterification
Condensation
POLYMER
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Polymerisation
(elimination of water)
LONG CHAIN
ALKANE
SUGAR
H2 gas Addition C6H12O6 → 2 C2H5OH + 2 CO2
(For Haber process) Polymerisation
Catalytic Cracking (High temp &
pressure) Fermentation
(Al2O3 & SiO2, 600 °C)
(37°C, yeast & no O2)
Oxidation O
ALKANE Hydrogenation
ALKENE ALCOHOL CARBOXYLIC ACID
C-C (200 °C & nickel) C=C -OH -COOH
Substitution Bromination
(UV light) (Test for C=C bonds)
Esterification
Prefix (warm, sulfuric acid)
CH4 (g) + Br2 (g) → CH3Br (g) + HBr (g)
C2H4 (g) + Br2 (aq) → C2H4Br2 (aq)
Meth- 1
Eth- 2
Prop- 3
But- 4
ESTER + H2O
Pent- 5 -COO- ALL ORGANIC COMPOUNDS
Hex- 6 Complete Combustion
Hep- 7 X + O2 (g) → CO2 (g) + 2H2O (l)
Oct- 8
Non- 9 Incomplete Combustion
Dec- 10 X + O2 (g) → CO (g) + 2H2O (l)
Try it yourself! (TYS Question)
Answer:
Try it yourself! (TYS Question)
Answer:
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