LABORATORIO DE CRISTAL VIOLETA

Comprobación de la Ley de Lambert Beer con curva de calibración

0
ml CV T A 1 2 3 4 5 6 7 8 9 10
2 90.3 -1.95568775
-0.5
4 67.8 -1.83122969
6 56 -1.74818803

Absorbancia
8 46 -1.66275783 -1
10 34.8 -1.54157924
-1.5

-2

-2.5
ml de CV

Por lo que se demuestra la Ley de Lambert Beer para este rango

Primera cinética

# 10 ml cristal violeta en 50 ml de solución.

# 4 ml Na OH en 50 ml de solución.
Primera cinética
Tiempo(min) Transmit. Absorbancia ln(A)
0
1.51666667 0.401 0.39685563 -0.924182723 1 2 3 4 5 6 7 8 9 10
2 0.416 0.38090667 -0.965200896 -0.2
3 0.433 0.3635121 -1.011942685
-0.4
4 0.454 0.34294415 -1.070187681
5 0.476 0.32239305 -1.131983834 -0.6
6 0.499 0.30189945 -1.19766125
ln(A)

-0.8
7 0.523 0.28149831 -1.267628831
8 0.547 0.26201267 -1.339362404 -1 f(x) = − 0.0651458344609075 x − 0.81845
R² = 0.997191489000533
9 0.57 0.24412514 -1.410074299 -1.2
10 0.593 0.22694531 -1.48304623
-1.4

ks'= 0.0651 -1.6

Tiempo(min)

Segunda cinética
0
0 2 4 6 8 10

-0.5
 0
# 10 ml cristal violeta en 50 ml de solución. 0 2 4 6 8 10
# 8 ml Na OH en 50 ml de solución. -0.5
Segunda cinetica
Tiempo(min) Transmit. Absorbancia ln (A)
-1 f(x) = − 0.123217379308333 x − 0.787
0.9 0.406 0.39147397 -0.937836263 R² = 0.996660299537435

ln (A)
2 0.443 0.35359627 -1.039599486
3 0.48 0.31875876 -1.143320692 -1.5
4 0.522 0.2823295 -1.264680461
5 0.561 0.25103714 -1.382154388 -2
6 0.601 0.22112553 -1.509024739
7 0.638 0.19517932 -1.633836547 -2.5
8 0.675 0.17069623 -1.767869752
Tiempo(min)
9 0.71 0.14874165 -1.905544362
10 0.744 0.12842706 -2.052394128

ks'' 0.1232

Tercera cinética
0
# 10 ml cristal violeta en 50 ml de solución. 0 2 4 6 8 10
-0.2
# 2 ml KNO3 [KNO3]= 0.02 -0.4
# 8 ml Na OH en 50 ml de solución.
-0.6
Tercera cinética
-0.8
ln (A)
Tiempo(min) Transmit. Absorbancia ln (A)
-1 f(x) = − 0.105932319528758 x − 0.798
1.12 0.408 0.38933984 -0.9433027
R² = 0.997935710049802
3 0.468 0.32975415 -1.109407911 -1.2
4 0.503 0.29843201 -1.209213128 -1.4
5 0.539 0.26841123 -1.315235016 -1.6
6 0.575 0.24033216 -1.425733332 -1.8
7 0.608 0.21609642 -1.532030579 -2
8 0.641 0.19314197 -1.644329762
Tiempo(min)
9 0.671 0.17327748 -1.75286104
10 0.703 0.15304467 -1.877025407

ks'''= 0.1059

Cuarta cinética

# 10 ml crista[KNO3]= 0.06
# 6 ml KNO3
# 8 ml Na OH en 50 ml de solución.
Cuarta cinetica 0
Tiempo(min) Transmit. Absorbancia Ln (A) 0 2 4 6 8 10
-0.2
1 0.395 0.4034029 -0.907819454
-0.4
2 0.426 0.3705904 -0.992657867
-0.6
-0.8
Ln (A)

-1 f(x) = − 0.0898230463355267 x − 0.81

 0
0 2 4 6 8 10
-0.2
-0.4

3 0.457 0.3400838 -1.078563221 -0.6

4 0.487 0.31247104 -1.16324349 -0.8

Ln (A)
5 0.518 0.28567024 -1.252917139 -1 f(x) = − 0.0898230463355267 x − 0.81
6 0.549 0.26042766 -1.34543017 R² = 0.999475442671669
-1.2
7 0.577 0.23882419 -1.432027618
8 0.607 0.21681131 -1.528727848 -1.4
9 0.637 0.19586057 -1.630352262 -1.6
10 0.659 0.18111459 -1.708625379
-1.8
Tiempo (min)

ks''''= 0.0898

Quinta cinética 0
0 2 4 6 8 10
-0.2
# 10 ml cristal violeta en 50 ml de solución.
-0.4
# 10 ml KNO3
# 8 ml Na OH en 50 ml de solución. -0.6
-0.8

ln(A)
quinta cinetica -1 f(x) = − 0.0770390859583505 x − 0.85
Tiempo(min) Transmit. Absorbancia ln(A) R² = 0.999811278872629
-1.2
1.08333333 0.409 0.38827669 -0.94603707
2 0.432 0.36451625 -1.009184138 -1.4
3 0.461 0.33629907 -1.089754412 -1.6
4 0.488 0.31158018 -1.166098581 -1.8
5 0.514 0.28903688 -1.241200983
Tiempo (min)
6 0.54 0.26760624 -1.318238632
7 0.564 0.2487209 -1.391423911
8 0.59 0.22914799 -1.473387247
9 0.615 0.21112488 -1.555305452
10 0.637 0.19586057 -1.630352262

ks'''''= 0.077

Obtención del orden de la reacción:

Orden de la reacción= m+n

m 0.92027281
Orden de la reaccion= 1.92027281

Determinación de k2 sin efecto iónico

k2 10.4794858
Efecto salino log k2 exp
k2''' 9.00793461 0.95462522
k2'''' 7.63845635 0.8830056
k2'''' 6.54967861 0.81621999

log k°= 1.02033997

solucion logk2 S S^1/2 g(s) k2 teórico
1 1.02033997 0.004 0.063245553 0.05948349 10.4794858
2 1.02033997 0.008 0.089442719 0.08209952 10.4794858
3 0.87441407 0.028 0.167332005 0.14334568 7.48883162
4 0.80978426 0.068 0.260768096 0.20683272 6.45333577
5 0.76854071 0.108 0.328633535 0.24734701 5.86868385

0.95 f(x) = − 1.31287238094566 x + 1.14610847797256

R² = 0.98866174486564 Por lo tanto el valor de A experi
0.9
log k2 exp

0.85
A=
Column C e%=
0.8 Linear (Column C)

0.75

0.7
0.12 0.14 0.16 0.18 0.2 0.22 0.24 0.26
g(s)
4 5 6 7 8 9 10 11

A
Linear (A)

ml de CV

4 5 6 7 8 9 10 11

ln(A)
0.0651458344609075 x − 0.818459125677097Linear (ln(A))
97191489000533

Tiempo(min)

4 6 8 10 12
 4 6 8 10 12

− 0.123217379308333 x − 0.787162669251826
.996660299537435
ln (A)
Linear (ln (A))

Tiempo(min)

4 6 8 10 12

= − 0.105932319528758 x − 0.798001562396084
0.997935710049802 ln (A)
Linear (ln (A))

Tiempo(min)

4 6 8 10 12

Ln (A)
− 0.0898230463355267 x − 0.810009690063724
 4 6 8 10 12

Ln (A)
− 0.0898230463355267 x − 0.810009690063724
0.999475442671669 Linear (Ln (A))

Tiempo (min)

4 6 8 10 12

ln(A)
= − 0.0770390859583505 x − 0.857741303639037
0.999811278872629 Linear (ln(A))

Tiempo (min)
or lo tanto el valor de A experimental

0.65645
28.9685658