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J Coal 2017 05 012
J Coal 2017 05 012
PII: S0166-5162(17)30188-X
DOI: doi: 10.1016/j.coal.2017.05.012
Reference: COGEL 2839
To appear in: International Journal of Coal Geology
Received date: 6 March 2017
Revised date: 18 May 2017
Accepted date: 20 May 2017
Please cite this article as: Ahmed Abdulhamid A. Mahmoud, Salaheldin Elkatatny,
Mohamed Mahmoud, Mohamed Omar, Abdulazeez Abdulraheem, Abdulwahab Ali ,
Determination of the total organic carbon (TOC) based on conventional well logs using
artificial neural network. The address for the corresponding author was captured as
affiliation for all authors. Please check if appropriate. Cogel(2017), doi: 10.1016/
j.coal.2017.05.012
This is a PDF file of an unedited manuscript that has been accepted for publication. As
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College of P etroleum and Geosciences, King Fahd University of P etroleum & Minerals, 31261 Dhahran, Saudi Arabia.
*Corresponding Author Email Address: elkatatny@kfupm.edu.sa
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Keywords
Abstract
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Total organic carbon (TOC) is the measure of the amount of carbon available in an
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organic compound and is often used as an essential factor for unconventional shale
resources evaluation. Previous models for TOC determination based on density log
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data considered the presence of organic matter is proportional to the formation bulk
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density. Also model those based on: resistivity log, sonic, or density logs as well as
the formation level of maturity (LOM) were used to determine the TOC. These
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models assumed linear relation between resistivity and porosity logs. Previous
TOC for Barnett and Devonian shale formations based on conventional logs using
artificial neural network (ANN). Core TOC data (442 data points) and well logs
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(resistivity, gamma ray, sonic transit time, and bulk density) from Barnett shale were
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used to develop the ANN model. For the first time an empirical correlation for TOC
was developed based on the weights and biases of the ANN model. The developed
The developed ANN model predicted the TOC based on conventional well-log data
with high accuracy. The average absolute deviation (AAD) and coefficient of
determination (R2 ) for the predicted TOC compared with the measured TOC for
Barnett shale are 0.91wt% and 0.93, respectively. The developed model outperformed
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the previous available models in estimating TOC for Devonian shale as well with
AAD of 0.99 wt% and R2 of 0.89 compared to AAD of 1.16 wt% or more and R2 of
0.65 or less for the available correlations. The developed empirical correlation was
used to estimate the TOC with high accuracy for Barnett shale and Devonian shale
formations.
The developed correlation will help the geological and reservoir engineers predict the
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TOC using well logs without the need to measure TOC in the laboratory.
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1. Introduction
rock. The ability of producing un-expelled hydrocarbon from source rocks (tight oil
and shale gas) was extended recently after the improvements in both horizontal
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of bulk rock permeability (Lee et al., 2011). A major shift in the global energy
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advances evidenced by the rapid advances of unconventional resources in North
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America (Aguilera and Radetzki, 2013). Shale exploration and development
activities in other continents was inspired after the economic success in North
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America (Jia et al., 2012; Jinliang et al., 2012; Zou et al., 2014).
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Because of the limitation of the required data and physical tools, the potential of the
unconventional shale resource is still poorly quantified. Since the evaluation process
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measurement of TOC from core samples in the laboratory is accurate but it is costly
and time consuming. On the other hand, the current practice of TOC estimation based
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on bulk density log alone or based on the conventional sonic (or density) logs and
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resistivity log using empirical correlations is fast but not accurate enough due to the
Currently two proven techniques of estimating TOC from well-log data are used;
these methods are: the Schmoker density log based technique (Schmoker, 1980,
Schmoker correlation was developed for Devonian shale formation, Eq. 1, based on
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pyrite, and organic matter). He considered the total density of the formation as a
function of the densities and fractional volumes of these four components, and setting
the pyrite, organic matter and matrix densities of 5.0, 1.0, and 2.69 g/cm3 ,
respectively. The pyrite volume was assumed to increase linearly with the increase of
Based on these assumptions, Sckmoker derived Eq. 1 to calculate the organic content
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in volume percent. TOC in wt% can be obtained by converting the volume to weight
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percent. There is a well-established correlation between wt% and volume percent for
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Devonian shale (Schmoker, 1979). The author concluded that this method was
Where TOC is the total organic carbon, ρ B is the formation density in absence of
Schmoker model was then refined in Bakken shale formation, Eq. 2. The relation of
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pyrite-organic matter volumes, which was originally developed for Devonian shale,
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correlation (Eq. 2) for Bakken formation (upper and lower members) was derived by
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assuming constant porosity and pore fluid density profiles. Then by considering the
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organic matter density of 1.01 g/cm3 , a matrix density of 2.68 g/cm3 and organic
matter content to organic carbon content ratio of 1.3, the relation was simplified, Eq.
3 (Schmoker and Hester, 1983). The authors compared the results of fifty nine
laboratory measurements from thirty nine wells in Bakken shale with organic content
ranging from 6 to 20 wt% with those of Eq. 3 and found that Eq. 3 yielded good
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TOC wt % 154.497
57.261
Eq. 3
Where ρo is the organic matter density (g/cm3 ), ρmi is the volume-weighted average
density of grain and pore fluid (g/cm3 ), R is the ratio of weight-percent organic matter
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The major disadvantage of Schmoker method is that it assumes the formation bulk
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density and porosity are constant, and any change in the bulk density is due to
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presence or absence of low density organic kerogen.
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Passey et al. (1990) proposed ∆logR method for estimating the TOC content which is
now the widely used method. In this technique, the separation between the properly
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scaled porosity indicator log (e.g sonic transit time curve) and deep resistivity reading
separation caused by the organic-rich rocks is related to: the effect of the low density
and low velocity of kerogen on the porosity logs and the responds of the resistivity
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Where ΔlogR is the resistivity porosity logs separation, R and Δt are the target
formation resistivity (ohmm), and sonic transient time (µs/ft), respectively, Rbaseline
and Δtbaseline are the base formation resistivity (ohmm) and base sonic transit time
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∆logR technique has two major drawbacks: the first one is the assumption that the
rock composition, texture, and compaction do not change, this method may lead to
incorrect estimation of the target shale. Since in reality the composition and texture of
the organic rich shale extremely vary for different resource play (Rokosh et al.,
2010). The second drawback is the limited ranges of applicability for sonic transit
time and resistivity for this method because of the assumption of 1:50 linear
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relationship (constant slope of 0.02, Eq. 4) between the porosity and logarithmic
resistivity logs. The use of LOM is another weakness of ∆logR technique since LOM
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is an uncommonly used measure of organic matter thermal alteration (Wang et al.,
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2015). NU
Charsky and Herron (2013) examine Schmoker and ∆logR models into four
different wells drilled with both water and oil-based muds, and covering a variety of
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formations. They reported that these models have low accuracy with an average AAD
from core derived TOC of 1.6 wt% and 1.7 wt% for Schmoker and ∆logR methods,
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respectively. Also, when Sckmoker model was used in Bakken shale formation, which
was used originally by Schmoker to develop and test this model, the AAD from the
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Wang et al. (2015) modified the sonic-/density-based ∆logR models for TOC
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determination based on Gamma Ray (GR), resistivity, sonic, and density well logs. In
their models they redefined ∆logR with estimated slopes related to target shale to
remove the assumed linear approximation. They also suggested the use of more
common thermal indicators (Tmax or vitrinite reflectance (Ro )) instead of LOM, since
the use of LOM requires a conversion between (Tmax or Ro %) and LOM which can
Wang et al. (2015) also introduced the use of GR log to improve the prediction of
TOC. The revised ∆logR values based on sonic and density logs are expressed as
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shown in Eqs. 6 and 7, respectively. The TOC from the modified ∆logR including GR
can be calculated using Eq. 8. The modified models showed better results in
estimating the TOC when applied in Devonian shale (R2 was greater than 0.92)
compared to the original ∆logR technique (R2 of 0.82). The residue analysis indicates
the modified models are unbiased statistically compared to the original models.
1 m
log R log10 R Rbaseline t t baseline Eq. 6
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ln10 t t m
1 m Eq. 7
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log R log10 R Rbaseline baseline
ln10 m
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TOC log R GR GRbaseline 10( T max )
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Where Δtm is the matrix sonic transit time (µs/ft), m is the cementation exponent, ρm
is the matrix density (g/cm3 ), ρbaseline is the baseline density corresponding to the
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Rbaseline value (g/cm3 ), α, β, δ and η are matrix constants to be determined, Tmax is the
The estimation of TOC using Wang Models requires the determination of matrix
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constants which depend on the matrix composition. These parameters will be different
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for different formations This means these parameters have to be estimated for any
formation before using the model and this requires the knowledge of TOC from the
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laboratory.
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Based on literature survey, current TOC prediction models either cannot predict the
TOC accurately or needs tedious laboratory work to determine the fitting parameters.
The objective of this paper is to develop a new robust empirical correlation that can
be used to predict the TOC with high accuracy based on conventional well logs using
artificial neural network technique (ANN). The developed TOC correlation was
trained and built for Barnett shale formation and tested in both Barnett and Devonian
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Devonian shale was compared with the available correlations developed mainly for
Devonian shale.
2. Methodology
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The core samples analyzed for TOC determination were collected from the
Mississippian Barnett shale formation (Fort Worth Basin (FWB), North of Texas,
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United States). TOC was estimated using Rock-Eval 6, the samples were crushed (<
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63 µm), 5.2 mg of every sample was subjected to Rock-Eval pyrolysis analysis. The
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details about procedures and considerations for preparing the shale samples for TOC
intelligent (AI) to provide a brain-like tool which has the ability to estimate, identify,
simplest ANN structure, which consists of input layer, one or several hidden layers
(mid-layers) and output layer. The proposed MLP model in this work was trained
based on one hidden layer, so the whole structure has three layers.
ANN model was trained using 442 data sets from Barnett shale (90% of the data sets
was used for training and 10% was used for validation), the model was trained using
four inputs; (1) Deep induction resistivity log data (RILD), which is believed to be
altered because of the presence of kerogen in the rock (Passey et al., 1990; Heslop,
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2010), (2) Sonic transit time (Δt), which decreases as the TOC in the rock increases
(Liu et al., 2013), (3) Formation bulk density (ρb), generally decreases as the kerogen
content increases, and hence, organic matter in the formation increases (Schmoker,
1979), (4) Gamma ray (GR), although the relationship between gamma ray and TOC
is controversial (Luning and Kolonic, 2003; Jacobi et al., 2008; Gonzalez et al.,
2013), several authors confirmed that including GR data into TOC models can
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enhance the performance of these models (Heslop, 2010; Wang et al., 2016; Zhao et
al., 2015). GR is included in this study to train the ANN model. The TOC values
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derived from core analysis (explained earlier in Section 2.1) were targeted as outputs
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for training the model. NU
Table 1 lists the data range and the statistical analysis of the training parameters. GR
ranged from 23.01 to 179.85 API, RILD ranged from 3.65 to 171.90 ohm.m, Δt ranged
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from 52.29 to 97.09 µsec/ft, ρb ranged from 2.40 to 2.77 g/cm3 , and TOC ranged from
0.75 to 5.55 wt%. The structure of the proposed ANN model is shown in Fig. 1.
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The developed model was optimized by studying the effect of different parameters
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(the learning function, the transfer function, number of hidden layers, number of
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neurons, and number of iterations) on TOC prediction capability of the model. The
which will optimize the performance of the model was selected by constructing an
inserted for loops in Matlab. Each for loop was changed over all the possible values of
one of the model parameters (e.g: number of layers, number of neurons in each layer,
training function, etc…). The AAD and R2 for all of the combinations were compared
and the combination of the lowest AAD and highest R2 was selected.
The optimum number of iterations were selected based on the training and validation
errors. The optimum number of iterations is the one which will give the lowest
training error and prevent model memorization (model memorization starts when
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validation error begins to increase after a decreasing period while training error is
the well-known methods of optimization, was used because it showed the highest
prediction performance for the model compared to other methods (e.g: traingdm,
trainbr, traingda, traincgf). The use of tangent sigmoid transfer functions between
inputs and mid layer and pure-line function for output layer enhanced the performance
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of the developed model. To select the optimum number of hidden layers and neurons,
the model was tested in the ranges of (1-3) layers and (3-30) neurons for each layer.
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One hidden layer with five neurons showed the optimized performance for the
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suggested ANN model, and the optimum number of iterations is 42. Table 2
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summarizes the optimized parameters for the proposed ANN-based model for TOC
estimation.
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In this work, the training data set (465 sets) was collected from Barnett shale
formation. The training set was evaluated statistically to remove all outliers and
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unrealistic values. The outliers are removed based on the standard deviation (SD) all
the values outside the range of ± 3.0 SD are considered as outliers and removed from
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the training data set. After pre-processing, the training set (identifying the outliers and
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unrealistic values) 442 out of the 465 data sets were selected to train the ANN model
based on four variables (deep induction resistivity log, gamma ray log, bulk density
log, and compressional transit time). The input parameters were selected based on
their relative effect on the measured TOC. Fig. 3 shows that TOC is a strong function
GR, compressional time, and bulk density. The correlation coefficients were 0.81,
0.77, and -0.89 for GR, compressional time, and bulk density, respectively. TOC was
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was 0.51, Fig. 3. The selected training data after preprocessing has the statistical
To evaluate the developed ANN model, data from two different wells was used. The
first well in Barnett shale formation, and the second well in Devonian shale
formation. For the testing sets, the outliers and the data points which are outside the
applicable range for the suggested ANN model (based on the ranges showed earlier in
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Table 1) were removed.
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2.4 Evaluation Criteria
As mentioned earlier the proposed model was tested in two wells, the first well from
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Barnett Shale formation which is the formation used to train this model, and the
second well is from Devonian Shale. The second well is used to check the possibility
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approach was evaluated in terms of the average absolute deviation (AAD) and
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coefficient of determination (R2 ) between the actual laboratory measured TOC and
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the predicted TOC (from this model and the available correlations).
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of the proposed correlation. The first formation is the Mississippian Barnett Shale.
According to the United States Energy Information Administration this formation was
formerly considered as the main source rock of the conventional hydrocarbon plays in
al., 2013). In 2011, the cumulative gas production rate from this formation was 8.0
trillion cubic feet (TCF), with a proven reserve of more than 31 TCF. Several
publications contain general geologic background for Barnett Shale play (e.g: Munn
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and Riddle, 1957; Cook and Bally, 1975; Thomas, 2003; Ewing, 2006; Pollastro
et al., 2007).
The second formation considered in this work is the Devonian Duvernay shale in the
source rock in the Devonian conventional hydrocarbon system (Creaney et al., 1994).
Rokosh et al. (2012) suggest that this shale formation contains oil in place and gas in
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place of 61.7 Billion barrels and 443 Tcf, respectively. Recent industry production
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data confirmed that this shale play is liquid rich (Rokosh et al., 2012).
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The measured TOC range for the area of Barnett formation considered in this work is
between 0.75 to 5.50 wt % for a depth interval between 7750 to 8320 ft. The
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measured TOC of Devonian formation is between 0.75 to 5.12 wt% for the depth
The training set gave the best prediction of the measured TOC by using the
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parameters summarized earlier in Table 2, and 442 data points of (resistivity log,
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gamma ray log, bulk density log, and sonic porosity transient time) as inputs and the
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between actual and predicted TOC for the training set is 0.94 as shown in Fig. 4, and
the AAD is 0.99wt% of TOC. The weights and biases of the developed model were
It should be noted that the data provided into ANN model are automatically
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Y Y min X X min
Eq. 9
Y max Y min X max X min
X X min
Y max Y min Y min
Y Eq. 10
X max X min
Y is the normalized input parameter, Ymin = -1, Ymax = 1, X is the input parameter
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(deep induction resistivity log, gamma ray log, bulk density log, or compressional
transient time) which will be normalized by ANN, Xmin is the minimum value of
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input, Xmax is the maximum input value, the minimum and maximum values of
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different inputs used in this work to develop the ANN model are summarized in
Table 1. For example, the minimum value of GR (Xmin ) is 23.01 API and the
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maximum value (Xmax ) is 179.85 API, so GR of 50 API equals to -0.6558 API in
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normalized form.
Eq. 11 below can be used with the weights and biases listed in Table 3 for calculating
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N J
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i 1 j 1
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Where N is the total number of neurons, J is the number of inputs (gamma ray log,
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deep induction resistivity log, compressional transient time, and bulk density log) w1
and b1 are the weight and bias of hidden layer, w2 and b2 are the weight and bias of
output layer. Weights and biases of hidden and output layers are summarized in Table
3, Y is the input value in the normalized form. The use of equation form (like Eq. 11)
based on weights and biases for calculating the desired outputs in suggested before by
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For example prediction of TOC from (gamma ray log, deep induction resistivity log,
compressional transient time, and bulk density log), the values of w1 will be taken at j
= 1 for GR, at j = 2 for RILD, at j = 3 for Δt and j = 4 for ρb. Yj in Eq. 11 are as follow;
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1,1 , w1-1,2 , w1-1,3 and w1-1,4 are 0.9517, 0.5817, 0.9676, and -2.5309, respectively, (from
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first row of Table 3"for first neuron"), this could be repeated for all other 4 neurons.
it was tested in Devonian Duvernay shale. The performance of the ANN model in
initially for this shale) to check the possibility of generalizing the developed model.
Fig. 5 shows the well logs for well (1) (testing set-1) which is from Barnett formation.
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Track five shows the actual TOC (from conventional core analysis) and the estimated
TOC (using this model). It is clear that there is an excellent match between the TOC
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from the ANN-based empirical equation and core derived TOC, the estimated TOC
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has an AAD of 0.91 wt% of TOC and the coefficient of determination between
Eq. 11 was examined in Duvernay formation (which is not the formation used to
develop this model). The performance of Eq. 11 was compared with two of the
recently revised ΔlogR methods suggested for Duvernay formation by Wang et al.,
(2015). The performance of Eq. 11 was found to surpass the revised ΔlogR models.
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Fig. 7 compares the predicted TOC from the developed correlation based on ANN
model, Wang sonic based and density based models (Wang et al., 2015), with the
actual measured TOC. Fig. 7 shows that the developed correlation of TOC based on
the optimized ANN model (Eq. 11) is better than Wang models. For TOC values less
than 1.5 wt%, Wang sonic based model prediction was twice the actual TOC, while
Wang density based model values was more than three times the actual ones. The
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AAD of the developed ANN equation was 0.99 wt% TOC, while Wang models (those
developed for Devonian formation) have TOC of 1.16 wt% and 1.55 wt% for sonic
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based and density based models, respectively.
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The coefficient of determination for the TOC predicted from the developed equation
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based on the optimized ANN model and actual TOC is 0.89, which is higher than the
between Wang sonic based and density based methods with laboratory measured TOC
Fig. 9 compares the performance of Eq. 11, Wang sonic based, and Wang density
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based models in term of ADD and R2 , it shows clearly that Eq. 11 outperformed both
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Wang models (revised Δlog R models) with the minimum ADD (0.99 wt%) and
maximum R2 (0.89).
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5. Conclusions
ANN model was proposed to estimate TOC for unconventional shale resources in
Barnett and Duvernay shale formations using conventional log data (gamma ray log,
deep induction resistivity log, compressional transient time, and bulk density log).
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The AAD is 0.99 wt% of TOC and the R2 of 0.89 as compared to AAD's of 1.15
wt% and 1.55 wt% of TOC and R2 's of 0.65 and 0.22 from Wang sonic based
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For the first time, a new TOC empirical correlation was extracted based on the
weights and the biases of the optimized ANN model. The developed equation
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can be used to estimate the TOC based on conventional log data with a high
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accuracy without the need for ANN model.
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AUTHOR INFORMATION
Corresponding Author
*Email: elkatatny@kfupm.edu.sa
ACKNOWLEDGEMENTS
The authors thanks College of Petroleum and Geosciences, King Fahd University of
Petroleum & Minerals for Support of this work.
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http://doi.org/10.1306/2F919756-16CE-11D7-8645000102C1865D
[29] Schmoker, J. W., & Hester, T. C., 1983. Organic Carbon in Bakken Formation,
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United States Portion of Williston Basin. AAPG Bulletin, 67(12), 2165–
2174. http://doi.org/10.1306/AD460931-16F7-11D7-8645000102C1865D
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[30] Thomas, J. D., 2003. Integrating Synsedimentary Tectonics with Sequence
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Stratigraphy to Understand the Development of the Fort Worth Basin.
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Paper Presented at AAPG Southwest Section Meeting, Held in Ruidoso,
[31] Wang, P., Chen, Z., Pang, X., Hu, K., Sun, M., & Chen, X., 2016. Revised
http://doi.org/10.1016/j.marpetgeo.2015.11.023
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[32] Zhao, T., Verma, S., & Devegowda, D., 2015. TOC estimation in the Barnett
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Shale from Triple Combo logs Using Support Vector Machine. Paper
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http://doi.org/10.1190/segam2015-5922788.1
[33] Zou, C., Du, J., Xu, C., Wang, Z., Zhang, B., Wei, G., Wang, T., Yao, G., Deng,
S., Liu, J., Zhou, H., Xu, A., Yang, Z., Jiang, H., Gu, Z., 2014. Formation,
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This appendix summarizes the formulas used in this work for error calculations.
TOC TOC
N
1
AAD m i a Eq. A-1
N i 1
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Coefficient of Determination (R2 )
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TOC
N
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TOC a TOC m i TOC m
a i
R
2 i 1
Eq. A-2
N 2 N
TOC TOC
2
TOC a TOC m
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a i m i
i 1 i 1
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Where N is the total number of samples, TOC m is the estimated TOC, TOC a is the
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Tables
Table 1: Ranges of the parameters used for training the ANN model.
Parameters
GR RILD Δt ρb TOC
3
(API) (Ohm.m) (µsec/ft) (g/cm ) (wt%)
M inimum 23.01 3.65 52.29 2.40 0.75
M aximum 179.85 171.90 97.09 2.77 5.55
M ean 91.67 47.39 75.88 2.57 2.59
M ode 60.30 5.67 78.35 2.49 0.76
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Range 156.84 168.25 44.80 0.37 4.80
Coefficient of Variation 0.346 0.893 0.143 0.032 0.472
* GR is gamma ray, RILD is the deep induction resistivity log, Δt is the compressional transient time and ρ b is the bulk
formation density.
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Table 2: Optimize d parameters for the proposed ANN model.
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Parameter Value
Table 3: The proposed ANN-based weights and biases for TOC calculations with
Eq. 11.
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Figures
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Fig. 1. Designed structure for ANN model, with single hidden layer and 5
neurons.
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T ED
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Fig. 2. The training error and validation error with iterations, the optimum
number of iterations is 42 (less iterations will lead to higher error and more
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1.0
0.81
0.77
0.8
0.6 0.51
Correlation Coefficient, R
0.4
0.2
0.0
-0.2
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-0.4
-0.6
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-0.8
-0.89
-1.0
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R ay ivi
ty
tim
e
sit
y
t n
ma sis io n De
Ga
m Re ss lk
pre Bu
om
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C
6.0
5.0
T
R 2 = 0.94
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Predicted TOC (wt% )
4.0
C
3.0
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2.0
1.0
0.0
0.0 1.0 2.0 3.0 4.0 5.0 6.0
Fig. 4. A crossplot of predicted TOC from the proposed ANN model vs the actual
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Depth
GR (API) RILD (ohmm) dt ( ft/sec) (g/cm3) TOC (wt%)
(ft)
b
0 180 0 180 50 100 2.3 2.8 0 6
7800
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7900
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8000
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MA
8100
ED
8200
T
C EP
8300
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Predicted TOC
Actual TOC
from well (1) in Barnett shale formation (testing set-1), the AAD of TOC
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6.0
5.0
R2 = 0.93
3.0
2.0
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1.0
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0.0
0.0 1.0 2.0 3.0 4.0 5.0 6.0
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Fig. 6. A crossplot of predicted TOC Eq. 11 vs the actual TOC for well (1) in
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Barnett formation (testing set-1), R2 = 0.93.
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Depth
TOC(wt%) TOC(wt%) TOC(wt%)
(ft)
0 8 0 8 0 8
1100
1120
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1140
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1160
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1180
1500
T ED
1520
C EP
1540
AC
1560
Fig. 7. A comparison of the TOC predicted from (1) Eq. 11, (2) Wang sonic based
model, and (3) Wang density based model, with the actual TOC, for well (2) in
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6.0
(A)
5.0
Predicted TOC (wt%)
4.0
3.0
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2.0
1.0
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ANN Model, R2 = 0.89
Wang Sonic Based Model, R2 = 0.65
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0.0
0.0 1.0 2.0 3.0 4.0 5.0 6.0
(B)
5.0
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Predicted TOC (wt%)
4.0
ED
3.0
2.0
T
EP
1.0
ANN Model, R2 = 0.89
Wang Density Based Model, R2 = 0.22
0.0
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Fig. 8. A comparison of the TOC predicted from (A) Eq. 11 and Wang sonic
based model (B) Eq. 11 and Wang density based model, with the actual TOC for
determination.
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1.8
ADD
1.6
R2
1.4
2
1.2
ADD (%wt) and R
1.0
0.8
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0.6
0.4
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0.2
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0.0
rk) el el
wo m od mod
is ed ed
(Th as as
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Eq
.7 ic-b y-b
on sit
gs den
W an an
g
W
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Fig. 9. A comparison of Eq. 11, Wang sonic based model, and Wang density
based model for predicting TOC for Devonian shale formation in term of ADD
ED
and R 2 .
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Highlights
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available correlations.
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