Datos Antoine

x1 0.3 comp A B
x2 0.7 1 14.7074 2917.7
v1(cm3/mol) 79.84 2 16.4948 3593.39
v2(cm3/mol) 40.73
a12(cal/mol) -31.19
a21(cal/mol) 813.18
R(cal/mol*K) 1.987
P(kPa) 300
y1 0.3
y2 0.7
R(cm3*bar/mol*K) 83.14

T1sat(K) T2sat(K) Tin(K)

365.43 368.22 367.39

T1sat(K) T2sat(K) Tin(K)

365.43103441 368.22315448 367.3855185

T(K) z1 z2
361.23 0.4 0.6

C)Punto de burbuja
Psat1(kPa) Psat2(kPa) ɣ1(adim)
266.57 238.03 1.574
Iteracion de C
n Pb(kPa) y1
1 308.64 0.4077
2 312.26 0.4030
3 312.49 0.4027
4 312.51 0.4027

Psat1(kPa) Psat2(kPa) Pr(kPa) x1

266.57 238.03 245.93 0.2768
n ɣ1s(adim) ɣ2s(adim) ø1 ø2 Vsup(mol)
1 1.912 1.033 1 1 1
2 1.81294643 1.0459084 1 1 1.3593
3 2.08636676 1.01734798 1 1 1.3690
4 2.13407102 1.01425125 1 1 1.3721
 Wilson
C ʌ12(adim) ʌ21(adim) compuesto
-41.3724 0.53241 0.6435 a 1
-35.2249 0.5328 0.6307 a2 2
0.5329 0.6297 a3
0.5329 0.6296 a4
0.5324 0.6437 b combinacion
0.5327 0.6332 b2 1;1
0.5327 0.6332 b3 1;2
0.5328 0.6314 c 2;2

a)Punto de burbuja a 300kPa

ɣ1(adim) ɣ2(adim) Psat1(kPa) Psat2(kPa) Psat2c(kPa) Tcr(K) P1satcr(kPa)
1.56225 1.096193 316.64 291.95 235.17 360.88 263.86
260.05
259.74

Psat1(kPa) Psat2(kPa) Psat2c(kPa) Tcr(K) P1satc(kPa) x1 x2

316.638308 291.95 292.98 367.49 317.58 0.2834 0.7168

nto de burbuja
ɣ2(adim) Pb(kPa)
1.097 308.64
Iteracion de C) burbuja
y2 ø1 ø2 Pbc(kPa)
0.5923 0.9895 0.9876 312.260 3.622
0.5970 0.9887 0.9870 312.491 0.231
0.5973 0.9886 0.9870 312.505 0.015
0.5973 0.9886 0.9870 312.506 0.001

C)Punto de rocio
x2 ɣ1(adim) ɣ2(adim) Prc(kPa) x1c x2c x1n
0.7232 1.625 1.0827 293.39 0.2031 0.7969 0.2031
0.1802 0.8198 0.1802
0.1734 0.8266 0.1734
k1 k2 V(mol) x1 x2 y1 y2
1.699 0.8197 1.3593 0.2051 0.7949 0.3485 0.6515
1.611 0.8299 1.3690 0.1248 0.8752 0.2010 0.7990
1.854 0.8072 1.3721 0.1129 0.8871 0.2093 0.7907
1.896 0.8048 1.3721 0.1111 0.8889 0.2106 0.7894
 Propiedades
w Tc(K) Pc(bar) Zc Vc(cm3/mol)
0.331 506.6 47.5 0.257 228
0.564 512.6 80.97 0.224 118

Par
Tcij(K) Vcij(cm^3mol^-1) wij Zcij Pcij Trij
506.6 228 0.3310 0.2570 47.50 0.7131
509.59 167.01 0.4475 0.2405 61.01 0.7089
512.6 118 0.5640 0.2240 80.97 0.7047
ʆ12

a a 300kPa
y1 y2 ɣ1(adim) ɣ2(adim) Psat2cn(kPa) Tcr2(K)
0.4122 0.6015 1.574 1.097 231.15 360.37
0.4094 0.5906 1.575 1.097 230.83 360.33
0.4091 0.5909 1.575 1.097 230.80 360.32

a)Punto de rocio a 300K

ɣ1(adim) ɣ2(adim) Psat2crv(kPa) Tcrv(K) P1satcrv(kPa) x1crv
1.598 1.08573 245.38 362.13 273.49 0.2059
273.53 0.1823

x2n ɣ1c(adim) ɣ2c(adim) Prcr(kPa) δP

0.7969 1.819 1.045 291.31 2.08
0.8198 1.890 1.036 291.11 0.20
0.8266 1.912 1.033 291.087 0.018
ɣ1(adim) ɣ2(adim) δx δV δy
1.813 1.046 0.0318 0.3593 0.0485
2.086 1.017 0.0804 0.0098 0.1475
2.134 1.014 0.0119 0.0031 0.0082
2.142 1.014 0.0018 0.0000 0.0013
 Para c)
B'ij Bºij Bij(cm^3mol-1)
-0.5729 -0.6420 -737.4
-0.5907 -0.6488 -634.1
-0.6090 -0.6558 -525.9
-5.2700

0.51
0.04
0.00

x2crv x1n x2n ɣ1(adim) ɣ2(adim) Psat2crvn(kPa) T(K)

0.7882 0.2071 0.7929 1.805 1.046 245.43 362.14
0.8177 0.1823 0.8177 1.880 1.036 245.57 362.16

Newton c)
n 1
m Vm f(Vm) f'(Vm) Vm+1 Tol(%)
1 1 0.0325164452 -0.096729 1.33616024066 25.1586771
2 1.336160240657 0.0019838414 -0.08611014 1.35919865824 1.69500002
3 1.359198658243 5.6407302E-06 -0.08562505 1.35926453535 0.00484653
4 1.359264535345 4.4394793E-11 -0.0856237 1.35926453586 3.81447E-08

n 2
m Vm f(Vm) f'(Vm) Vm+1 Tol(%)
1 1.3593 0.0007214795 -0.07394214 1.3690218876 0.71272434
2 1.369021887604 7.9078837E-07 -0.07378065 1.3690326057 0.0007829
3 1.369032605704 9.398593E-13 -0.07378048 1.36903260572 9.30489E-10
4 1.369032605717 0 -0.07378048 1.36903260572 0

n 3
m Vm f(Vm) f'(Vm) Vm+1 Tol(%)
1 1.369032605717 0.0003182876 -0.10315027 1.37211827517 0.22488364
2 1.372118275172 1.2934684E-07 -0.10306655 1.37211953016 9.14631E-05
3 1.372119530156 2.1260771E-14 -0.10306652 1.37211953016 1.50336E-11
4 1.372119530156 0 -0.10306652 1.37211953016 0
n 4
m Vm f(Vm) f'(Vm) Vm+1 Tol(%)
1 1.372119530156 0.0007636089 -0.10729871 1.37923619486 0.51598593
2 1.379236194864 -0.00073281 -0.10287613 1.3721129665 0.519143
3 1.372112966504 6.7649331E-07 -0.1030667 1.37211953015 0.00047836
4 1.37211953015 5.8197891E-13 -0.10306652 1.37211953016 4.11523E-10
0.01
0.02
 Datos Antoine
x1 0.4 comp A B
x2 0.6 1 14.2456 2662.78
v1(cm^3*mol^-1) 58.68 2 16.5785 3638.27
v2(cm^3*mol^-1) 106.85
b12(cal*mol^-1) 381.46
b21(cal*mol^-1) 346.54
α 0.2965
R(cal*mol^-1*K^-1) 1.987
T(K) 80
y1 0.4
y2 0.6 a)Punto de bur
R(cm^3*bar*mol^-1*K^-1) 83.14 Psat1(kPa) Psat2(kPa) ɣ1(adim)
212.83 179.67 1.413

Psat1(kPa) Psat2(kPa) Pr(kPa)

212.8282242787 179.668495016 191.6

ɣ1(adim) ɣ2(adim) α12,x10

2.604 2.639 3.08

# x1 x2
0.8442 0.59 0.41
0.8442 0.45 0.55
0.8442 0.44 0.56
0.8442 0.445 0.555
0.8442 0.4456 0.5544

Paz(kPa)
250.20 250.20
 NRTL
C τ12(adim) τ21(adim) G12 G21
219.69 0.544 0.494 0.8511 0.8637
239.5

a)Punto de burbuja
ɣ2(adim) Pb(kPa) y1 y2
1.164 245.83 0.4894 0.5106

C)Punto de rocio
x1 x2 ɣ1(adim) ɣ2(adim) Prc(kPa) x1c
0.3601 0.6399 1.481 1.131 236.93 0.3007
0.2775
α21,x11 0.2687
0.4488 0.2655
0.2643
0.2638
ɣ1(adim) ɣ2(adim) #c E(%) 0.2637
1.177 1.393 0.845 0.094
1.176 1.393 0.844 0.004
1.176 1.393 0.844 0.004
1.176 1.393 0.844 0.000
1.176 1.393 0.844 0.000
rocio
x2c x1n x2n ɣ1c(adim) ɣ2c(adim) Prcr(kPa)
0.6993 0.3007 0.6993 1.597 1.090 235.83
0.7225 0.2775 0.7225 1.648 1.076 235.66
0.7313 0.2687 0.7313 1.668 1.071 235.64
0.7345 0.2655 0.7345 1.676 1.070 235.63
0.7357 0.2643 0.7357 1.679 1.069 235.63
0.7362 0.2638 0.7362 1.680 1.069 235.63
0.7363 0.2637 0.7363 1.680 1.069 235.63
δP
1.11
0.17
0.02
0.00
0.00
0.00
0.00