Calculations for P = 6.

0 kbar and T = 550degC

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g A4_5_grt1
2-site mixing + Regular solution gammas
Ferric from: Cation Sum = 8 for 12 oxygens
mixing terms from regular solution

oxide wt % cations sd activity sd %

SiO2 37.45 2.976 0.029 py 0.0062 0.00187 30

TiO2 0.01 0.001 0.003 gr 0.0138 0.00358 26
Al2O3 21.13 1.979 0.031 alm 0.20 0.016 8
Cr2O3 0.00 0.000 0.000 spss 0.00050 0.000189 38
Fe2O3 1.14 0.068 0.017 andr - - -
FeO 26.63 1.770 0.023 uvar - - -
MnO 3.48 0.234 0.007
MgO 3.25 0.385 0.012
CaO 6.90 0.587 0.014
Na2O 0.00 0.000 0.000
K2O 0.00 0.000 0.000

totals 99.99 8.000

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fsp A4_2_PL2
Holland & Powell 1992 model 1
Ferric from: all ferric
plag is C1 structure

oxide wt % cations sd activity sd %

SiO2 60.80 2.695 0.018 an 0.51 0.0185 4

TiO2 0.00 0.000 0.000 ab 0.68 0.0170 2
Al2O3 25.16 1.315 0.022
Cr2O3 0.00 0.000 0.000
Fe2O3 0.14 0.005 0.001
FeO 0.00 0.000 0.000
MnO 0.00 0.000 0.000
MgO 0.00 0.000 0.000
CaO 6.28 0.298 0.007
Na2O 7.52 0.646 0.015
K2O 0.33 0.019 0.003

totals 100.23 4.978

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bi A4_5_Bt5
Al-M1 ordered, site-mixing model + macroscopic RS gammas: (ann, phl, east, obi)
Ferric from: Tet + Oct cation sum = 6.9 for 11 oxygens. Max Ratio = 0.15
SF model parameters: Wpa=9, Wpe=10, Wpo=3, Wao=6, Wae=-1, Woe=10 (kJ)

oxide wt % cations sd activity sd %

SiO2 35.95 2.727 0.026 phl 0.024 0.00540 23

TiO2 4.68 0.267 0.007 ann 0.095 0.0127 13
Al2O3 14.46 1.293 0.023 east 0.0039 0.0022 56
Cr2O3 0.00 0.000 0.000
Fe2O3 1.13 0.064 0.016
FeO 22.95 1.456 0.021
MnO 0.18 0.012 0.003
MgO 9.55 1.080 0.022
CaO 0.00 0.000 0.000
Na2O 0.07 0.010 0.008
K2O 8.71 0.843 0.019

totals 97.68 7.754

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amph A4_5_Hbl6
Mixing model of Dale et al. (2005)
Ferric from: Av from max and min constraints. Holland & Blundy 1993

oxide wt % cations sd activity sd %

SiO2 41.92 6.299 0.101 tr 0.02424 0.00501 21

TiO2 2.02 0.228 0.010 fact 0.0024 0.00089 37
Al2O3 11.14 1.973 0.047 ts - - -
Cr2O3 0.00 0.000 0.000 parg 0.0006 0.00095 153
Fe2O3 6.03 0.681 0.163 gl - - -
FeO 16.15 2.029 0.175
MnO 0.47 0.060 0.007
MgO 8.51 1.906 0.048
CaO 10.10 1.626 0.041
Na2O 1.55 0.452 0.022
K2O 1.23 0.236 0.014

totals 99.11 15.490