Section- Straight Objective Type Questions 1. Which one of the following is natural polymer? (a) Starch (b) Nylon-6 (©) Kodel (d) Buna-S, SBR 2. Which of the following is biopolymer (a) Protein (b) Nucleic acid (©) Starch (d) All of these ‘3. Which of the following isnot biodegradable polymer ? (@) Protein (b) Nucleic acid (e) PVC (@) Cellulose 4, Monomer of Nylon-6 is (@) Adipic acid () Hexamethylenediamine (©) Caprolactam (€) All of these $. Innucleic acids monomers are held together by which linkage? (a) Glycosidic linkage (b) Phosphoester linkage (6) Amide linkage @ Both (a) and (6) 6. Natural silk is polymer of : (a) Amino acids (b) Nucleoside (©) Nucleotide (@) Adie acid 7. Which of the following is polymer of fructose? (a) Starch (©) Glycogen (©) Inulin @ Amylose 8. Which of the following is homopolymer? (@ Starch () Plexiglas (©) Orton (@) All of these 9. Monomerls of Saran is = (2) Vinyl chloride () Vinylidene chloride (©) Both (a) and (6) (@) Styrene 10, Nylon-66 is which type of polymer? (a) Polyamide () Polyester (© Addition (@) Homopolymer 1, Which of the following statements are correct for linear polymers ? (2) Linear polymers may be condensation as well as addition polymers. (b) Structure is well packed in mature. (€) Linear polymers have higher denisty, higher mp and higher tensile strength. (@) All are correct. 12. Which of the following is linear polymer ? () Polypeptide () Protein (©) Starch (2) Phenol-formaldehyde resin 13. Vuleanised rubbers are which type of polymers ? () Linear (©) Crossclinked (©) Branch-chain (@ Any one of these 14, Which one of the following is branch-chain polymer ? (@) Glycogen (0) Terylene «pve (@ Saran 1S. Polyamide linkage is present in = (@ Nylon () Sitk (©) Protein (@) All of these 16. Which of the following compounds cannot be a monomer ? (a) CHy>—CHOH—CH.0H (b) NHz—CH2—NH2 (©) CHs—CH>—NH2 @® ea NH 17, Which monomer will give cross linked polymer? (o coox-(Q)-coor (b) NH—CH,—COOH (©) HOH,CHN._N._-NH—CH,OH BCH NS zs NyN NH—CH,OH (@ CH,OH—CH,OH 18, Polymer obtained by the given compound ° HoH | CHO NON Home Nctizon is (2) Urea-formaldehyde resin (b) Phenol formaldehyde resin (©) Alkyd resin (@) Melamine-formaldelyde resin 19. Monomer/s of phenol-formaldehyde resin is/are (®) Phenol and formaldehyde OH CH,OH. CH,OH © OH HOH,C. CH,OH © CH,OH (@) Both (b)and(e) 20, Which one of the following compounds can be monomer of rubber (@) CH=CH (b) CH= CHC! cS e CH I (©) CH>=C—C—OCH; — (@) CH>=C—CH= CH 21, In. propogation step the reaction intermediate of radical polymerisation is: (a) Carbocation (b) Carbanion (© Free radial (@) Carbene 22. Which monomer will give radical polymerisation most readily? (@) C=C ©) Catts—CH—=CH (© CHy—CH=cHh a ct-pacth 23. Cationic polymerisation is initiated by be @ or: () NaNt — — Scanned with CamScannerom POLYMERS, 607 fo tub {4 Bos) ane) (0 Ving horde (a) Acton 24 Which of the following monomers will ive cationic 3%, Which of he flowing contain pre Um” robymematon (a) Natal rubber ‘t) Nyon 10 9 OlacH—ol ) CmcHt—eN {0 Peletylene (a) Dacron 9 40, Whi or te aot pyenes? ena econ (a) Payers bn ot cary any charge {ty Polymers have high sconty (0) Pyne seater ht 28. Which ofthe following monomers can undergo rail, cationic (8 Polymers have low molecular weeht vel! as amonie polymensaton with eal ene? 41. ntemoleclar force present nylon 8 (cn cmc: )Calte—CHm CH (a ander Wa by Mydiogen bond ! {@ Diple-Dipole teractions () Sulphide ine = 42. tet po inner is made by which polymer ? (o Cl CH—CN (Che cih (ora (Lean 24 I whch psymenston branching of chain cannot be pose? (© Nomex (a) Kevlar (a) Free abc (6) Catone 4x. Sornnts and taby fecting bots are generally made up of (© Anonie (a) Anionic and Zila Nata eee ‘oy Polyretane 27. Synitene ben ae prepared by whch plymensation? enema {a Payne (a Fre nde (by Ziegar Nata {Ak Whch ofthe following polymers are chloonated? (©) Cavome (a) Anon ere eee 38 ZeplarNana cays (0 Sin (Wy AL of hese (a Boal Tce Pacing eee (@ RAC (@ RBC: (a Styrene (by Acronnle 28. High densty polyethylene has which type of saute? {© Both and (a) Ving clone (@) Linear (b) Branch—CH=CH (©) CHy=CH—CH=CHa (@) CH=C—c=scHt 196. Preparation of nylon from hexamethylene diamine and adipic acid is an example of (@) addition polymerisation () graft polymerisation {€) condensation polymaisation (4) copolymerisation 97. Which one of the following is correctly matched? (2) Orlon, vinylebloride (b) Kodel, Terephhalic acid {) Neoprene, 2-bromo-1,3-butadine (© Dextrin, fructose 98, The monomer of PVC is (@) acronitile (©) etyllidine chloride (©) vinyl chloride @) ethylene glycol 99. The polymer obtained by beating adipic acid with hexamethylene diamine is () Bakelite (6) Nylon-66, (©) Terylene (@) Polystyrene 100. Bakelite is prepared from: (2) acetaldehyde and ethanol () ethane and ethanol (©) Salieylaldchyde and phenol (@) Formaldehyde and phenol 101. Which one of the following is « condensation polymer? (a) Poty vinyl chloride (& Patystyene (© Teon (8 Polyester 102. The polymerisation reaction shown below 2cH=ch 2, cH: ‘C—Cl eee = I=CHa: CuCh NAC Cem —cih—cr main, a -enp=cnen & would produce: @rve (neoprene (© chloroprene @ San 103, Neoprene, an important syieticrbbe,s produced by: {@) Polymetsation of chloroprene (8) Copolymerisation of styrene and butadiene (©) Polymerisation of isoprene () Copolymersation of butadiene and acrylonitile 404, Which reagent is used for converting propylene to polypropylene? (@) Th + (CH) Mg (0) TC + (C3Hs)sAl (0) TCA + (Catt )aPb (@ Tic + KTHE 105, From which of the following monomers is neoprene synthesised ? Scanned with CamScanner(2) @2-chloro-2-butene (©) )2-choro-2-botene (©) y-Lehloro-, 3-butadene (@) 2chloro-1, 3.butadiene (©) 2, 3dichloro-1,3-butadiene 106. What isthe structure of the monomer from which the lowing. polymer is made ? —CH—Cl—CH—cH—cH-cH— by day by bs bo be (©) CH=CH (@) CH>=CH-CH= City (a) CHy—Ciy 107. The choice of the mechanism in chain growth polymerisation depends on which ofthe following ? (2) The structure ofthe monomer and initiator used (©) The structure of te polymer and initiator used () The temperature and pressure of the reaction (@aandb (@abande 108. Chain growth polymerisation proceeds by which of the following mechanism ? (@) Radical mechanism (©) Anionic mechanism (a,b and c 108, Which of the following species can best serve asa radical iniiator for radical polymerisation ? (©) Cationic mechanism @aandd (® ROH (©) ROR (©) ROOR (@ RCOOR (©) RCOOH 110, Chain-growth polymerisation exhibits @ marked preference fr: (2) tilto4ail addition () head-to-head addition {) headtontail addition (4) head-to-mile addition () middle-to-head addition UL. Which of the followig are characteristic for Linear polyethylene ? (2) They are branched polymers (&) They are known as high density polyethylene (6) They are soft and flexible polymers @aandd @aade 112, Which of the following species can best serve as an initiator for cationic polymerisation ? (@) ROOR @® ROH @ROR (@) AlCl, (©) RCOOR 113. Which ofthe following is more likely to undergo both radical and ‘cationic polymerisation ? (@) C=Ci () CoHs—CH=CH (©) CH2=CH—CN (@) CH=CH—CoocHs (© CH»=CHCI MA. Which of the following monomers has the greatest ability wo undergo cationic polymerisation ? (@) CH; —CH=CH, eon-{O)-cttmcx, (cH es eon (6)-a—cn wou{O)-cHcr 11S, Which of the following monomers has the greatest ability to undergo anionic polymerisation ? (®) CH,—CH=CH, wox-{O)-crmcr, oct, i=CHy (HN. wai-(o}-aren, 116, Which ofthe following species can best serve as an initiator for anionic polymerisation ? (@) CH —CHy—CH>—CHy—Li (©) BF: (AIFS (@ HOOH (@) CHhy—Cliz—Cit>—O—CH>—CH>—CHy, Which of the following is more likely to form non-terminated polymeric chains called living polymers ? (2) Cationic polymerisation —(b) Free radial polymerisation i=CH, (6) Anionic polymerisation (da and b (ea and c 118. What is the difference between natural rubber and Gutta-percha rubber ? (a) Natural robber is hard and brite while gutta-percha is soft and rubbery (b) Natural rubber is natural while gutta-percha is synthetic rubber (e) Natural rubber has a cis configuration while gutta-percha has a trans configuration (@) Natural rubber and guta-percha rubbber are enantiomers (©) The monomer for natural rubber is isoprene while the ‘monomer for gutta-percha is 1, 3-butadiene 119. Which of the following are copolymers ? () an aterating copolymer _(b) A block copolymer (©) Arandom copolymer (4) A graft copolymer (6) All ofthe above 120, Which ofthe following is step-growth polymer ? (a) Polyethylene (©) Polyester (©) Polypropene (8) Polystyrene (©) Plexiglass 121, Which of the following are characteristics of ‘thermoplastic polymers ? (2) Strong and rigid (©) High degree of cross-linking (©) Can be remetted by heating (@aandb (Wabande Scanned with CamScanner2, What a eestomers ? 4 Elastic organis molecules that are added to polymers to 0 nem harder Se () Plastic that stretch and then revert to their orginal shape (@ Polymers that are shoft and sticky () Plastic that are hard and brite () Elastic molecules that are added to polymers to make them stretch more Section-II Linked Comprehension based questions (Q.No. 123 to 126) Directions In this section you have one short passage. After the passage you will find a few questions based on the pasage. Fist read the passage, and answer the questions based on it Passage Polymers are made up of small molecules, called monomers, Polymer which is formed by only one type of monomer is called homopolymer and which are formed by more than one type of ‘monomers are called copolymers. Natural polymers are biodegradable ‘whereas synthetic polymers may or may not be. Branch chain polysiers ‘may be condensation of addition but cross linked polymers are always ‘condensation polymers, 123, Which one of the following is biodegradable polymer? (a) Terelyne (6) Tefton (©) Cellulose (@ pve 124. Which of these are natural polymers? (@) Starch () Protein (©) Nucleic acid (All of these 125. Which one ofthe following monomers is most react polymerisation? (@) Cotls—CH Ha (©) CH Ha (©) Ca—6—cth (a) Ch Colts 126, Polymersaton using Ziegler-Natta catalysis is advantageous over free radial polymerisation because: (a) It can lead to living polymers via anionic polymerisation (6) It pemits step-eaction polymerisation resulting in a highly crosslinked polymer. (©) It gives highly branched polymer with a high degree of crystallinity (d) It gives linear polymer permitting stereochemical contro. Section-II1 Assertion and Reason (Q.No. 127 to 130) Directions: The following items consist of two statements, one labelled te ‘Assertion-A’ and the othe labeled the ‘Reason-R’. You ae \o examine these two statements carefully and decide the correct answer from the codes given below Codes (@) Both A and R are true and ris the correct explanation of A (by Bows A and R are true but R is NOT the correct explanation ofA (©) Abs true, Ris false say, A fie, Ris te 27 desetlon A": Naural rubber is cs polysoprene tog, Rasen": Naural rubber and gutta-percha are diastereomers * Rasen Celle is a natural polymer ™R': The monomer of cellulose 1s maltose SSE Rn lie embed w psec of CN sectont¥ Mathng Type Questo (Ne 13 0136 Fee a Oe ance cet er ig List List-It (A) Nylon. (1). Polyester (B) Terjlene ——-@)_-Polytetra Muorochtylene © Teflon @) Synthetic rubber (D) Neoprene (4). Polyamide Codes: A BoC D @2 3 1 4 (i eg 4s 1 3 2 @4 1 2 3 132, Match List (polymer) with List-II (constituents) and select the correct answer using the codes given below the lists: List List (A) Buna. (1) soprene (B) Bakelite Q) Propylene (©) Nylon-6 @)_ Butadiene and styrene (D) Natural rubber (4) Phenol and formaldehyde (5) Caprolactum Codes: A B Cc D @3 4 2 1 oer stern os 3 5 0 Ge ea 13%, Match List-l (monomer) with Lisc-ll (polymer) and select the corect answer using the codes given below the Lists List-1 List- It (A) Caprolactum, () Polyester (B) Chloroprene @)_ Nylon polyamide (©) Dimethyl terephthalate ——@)_ Perspex (D) Methyl methacrylate (4) Synthetic rubber ‘Codes: A BoC OD @2 4 1 3 cb) apes eet een @4 2 1 3 @4 2 3 4 134, Which one of the following pairs is NOT correctly matched? (2) Bis phenol + epichlohydrine; epoxy resin (b) Phuhalic anhydride + glycol; alkyd resin (©) Ist-diaminobenzene + Terephaloyl chloride; Decron (4) vinyl chloride; PVC 135, Match column- with column-II and select the corect answer from, the codes given below: Column Column-tt (@) Cellulose (p) Natural polymer (©) Suerose (q) Symbetic polymer (©) Nylon (8 Amide linkage (@) Protein (8) Glycoside linkage Scanned with CamScannerCodes a b c d 136. Maich column-I with column-] the codes given below: Column-1 (@) Nylon-6 Il and select the correct answer from Column-It (P) Biopolymer (b) Terylene (©) Protein (d) Starch Codes aog¢ges (q) Copolymer (1) Homopolymer (s) Synthetic polymer Scanned with CamScannerSection-I L@ 2@ 2© 40 5. @ 6.) 20 8. (d) 9.) (10. (@) BO Be BO We 6@ 6o 70 B@ %B@ 22O 16 BY BM WA 2230 26@ we %@BO Ba + i%®D@ 2O 2H BO HOG 3.06 30 37-0 8@ 3@ 400 10 2@ 8@ 46 46 40) 47.@ 8&0 4 500 SL (2) S2@) SR @ S455) 56) ST) SGC) G.© 62) BO — HL 65.) 66) 67. (@)—«B 0H) (C—O) LO 72@ TO TG) 7) 76.) )—7BL (a) 79. (b) 80. (2) 8 (2) 82) 83) B®) 85.4) 86) 87. (a) BB) (2) =) 91 (e) — 92.(0) 93.) 94.) 9c) 96). «97 ()—«9BL(C) 99. (b) 100. (d) 101. (d) 102. () 103. (@) 104. (&) 105. (d) 106. (©) ~—:107. (a) «108. (ec) ~—:109. (c)—«110. (c) Ul.) U2) 113.) 114. @) 5b) @) sd (e)—sd% (e)_~—«120. () 121. (4) 122.) Section-II 123. (c) 124. (d) 125. (c) 126. (d) Section-IIT 127. (b) 128. (c) 129. (c) 130. (a) Section-IV 131. (4) 132. (6) 133. (a) 134, (6) 135, a—p, s; bs; car; dp, r 136. a—t, s; b—g, s c—p, q; d—p, r Scanned with CamScanner