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A R T I C LE I N FO A B S T R A C T
Keywords: In this paper, a novel solar water heating system (SWHS), capable of reducing the impact of solar radiation
Solar water heating system intensity fluctuations, has been fabricated by using phase change materials (PCM) for thermal energy storage
Phase change material and inserted oscillating heat pipe (OHP) for performance improvement. Different working modes can be selected
Collecting efficiency according to the solar radiation intensity in different seasons and different climate conditions. A test rig has also
Coefficient of performance (COP)
been made for the performance measurement of the system. The full-year measurement in all kinds of en-
vironmental conditions has been carried out for a couple of consecutive years, in Nanjing city of China. The
system performances, such as collecting efficiency (CE), average collecting efficiency (ACE), coefficient of
performance (COP) and exit water temperature (EWT), have been measured and compared between the systems
with and without PCM. Under similar operation conditions, the system with PCM is illustrated to have much
better performances. In daytime, CE fluctuation with PCM is over 30% less than that without PCM. At summer
night, EWT with PCM can keep over 50 °C, while EWT without PCM has an obvious decrease. At winter night,
COP with PCM is over 3.0 that can make EWT reach to 50 °C in a much shorter time than that without PCM. The
system presented is proved to be effective and useful in the application of solar energy.
⁎
Corresponding author.
E-mail address: wuwei@njnu.edu.cn (W. Wu).
https://doi.org/10.1016/j.solener.2018.07.005
Received 19 April 2018; Received in revised form 11 June 2018; Accepted 2 July 2018
Available online 09 July 2018
0038-092X/ © 2018 Elsevier Ltd. All rights reserved.
W. Wu et al. Solar Energy 171 (2018) 604–612
is enhanced up to 16% by using PCM in SWHS. Papadimitratos et al. system during the simultaneous operation and the real water con-
(2016) presented a novel method of integrating PCM with solar col- sumption profile operation.
lectors. Using this method, the efficiency increased by 26% for normal Solar collector is the core component of SWHS to receive solar en-
operation and 66% for the stagnation mode. ergy and transform it into thermal energy. Kürklü et al. (2002) put
Among the PCMs, paraffin has some good properties for thermal paraffin in a flat plate solar collector. The results showed that the
energy storage and is thus widely used in solar heating system, heat paraffin enhanced the performance of the flat plate solar collector.
pump and other fields (Qi et al., 2016; Reyes et al., 2015; Feliński and Feliński and Sekret (2016, 2017) studied evacuated tube collector/
Sekret, 2016). Paraffin has suitable melting point, relatively high latent storage system containing paraffin. They concluded that the total
heat and are characterized by negligible supercooling (Zalba et al., amount of useful heat obtained from the system was increased by
2003). Moreover, paraffin is chemically stable, non-corrosive and melts 45–79%. They also found that the evacuated tube collector with par-
with no phase separation (Sharma et al., 2009). Sobhansarbandi et al. affin can delay the heat losing at night when the intensity of solar ra-
(2017) utilized PCM (octadecane paraffin) to increase the heat accu- diation was insufficient.
mulation for application in solar water heaters. Abokersh et al. (2017) Improving the performance of solar collector is of great significance
found that integrating the PCM in solar collector has a favorable per- for SWHS. Heat pipe has high heat transfer efficiency (Zhang et al.,
formance over the typical forced recirculation solar water heating 2017). The application of heat pipe in solar collector can obviously
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W. Wu et al. Solar Energy 171 (2018) 604–612
The schematic diagram of our SWHS is shown in Fig. 1. Main 2.2. Operation mode
components of the system are energy storage solar collector with in-
serted oscillating heat pipe, evaporator, compressor, water-cooling The measuring point layout of the system with different operation
condenser, external equalizer thermostatic expansion valve, water modes is shown in Fig. 5. Our SWHS is designed for home use, sup-
pump, shut-off valve, water tank, and so on. The specifications and sizes plying hot water mainly at night or the next morning. The water is
of the equipment are listed in Table 1. As may be seen from Fig. 1, the recirculated in a closed loop. In summer, as solar radiation during the
recycling path of heat pump is composed of serial connection of com- day is strong enough to highly raise the inner temperature of solar
pressor, water-cooling condenser, external equalizer thermostatic ex- collector, the heat pump stops working. The shut-off valve A and C are
pansion valve and evaporator. This recirculating pump is operating opened, B and D are closed, as shown in Fig. 5(a). PCM will transfer the
according to the water temperature. The pump should be manually instantaneous heat or the heat stored during the day to the evaporator
turned on when the temperature is below a set-up value, turned off after section of heat exchanger. Through the medium of oscillating heat pipe,
the temperature is over a set-up value. The water-circulating path is this part of heat is efficiently transferred to the condenser section of
Table 1
The specifications and sizes of the equipment.
Items Specifications and models Parameters
Energy storage solar collector with inserted Self-developed Total length: 1540 mm, Total length of evaporation section and adiabatic section: 1210 mm,
oscillating heat pipe External diameter: 4 mm, Internal diameter: 3 mm
Solar evacuated tube ϕ58 × 1.6 Length: 1.6 m, External diameter: 58 mm, Internal diameter: 47 mm
Water pump PB-H089EAH Maximum range: 8 m, Maximum flow: 25L/min (1.5 t/h), Rated range: 5.5 m, Rated flow: 13L/
min
Compressor CAJ4511Y Rated power: 0.75 kW, Working medium: R134a, Cylinder displacement: 32.7 cm3, 220–240 V,
50 Hz
Water-cooling condenser Self-developed Heat exchange: 3.5 kW, Inner tube: ϕ19 mm × 1.2 mm, Outer tube: ϕ28 mm × 1.5 mm, Effective
pipe length: 5.6 m
Plate heat exchanger ZL14-14D Heat exchange: 0.74 kW, Design pressure: 3.0 MPa, Design temperature: −196 to 225 °C,
Maximum flow: 8 m3/h.
Equalizer thermostatic valve FVE-1/2-C Refrigerating capacity: 0.49US.RT, Entrance size: 1/4″, Export size: 1/2″SAE
Water tank Self-developed 0.5 m × 0.6 m × 0.7 m, Stainless steel, Thermal insulation material: 50 mm
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W. Wu et al. Solar Energy 171 (2018) 604–612
heat exchanger, heating the circulating water directly. During night integrated measuring instrument. Pressure transmitters are used for the
period, the thermal energy stored in PCM is good enough to keep the measurement of the inlet and outlet pressure of condenser and eva-
required temperature. porator. K-thermocouple is used for the temperature measurement of
In winter or rainy days, the inner temperature of solar collector is tank water. A thermocouple is placed outside to measure the ambient
low due to the weak solar radiation. The instantaneous heat or the heat temperature. Turbine flow meter is for the measurement of refrigerant
stored during the day is insufficient to heat the circulating water to the flow in heat pump system. Glass rotor flow meter is to measure the
required temperature. Winter operation mode is then switched on. In circulating water flow. The data acquisition device, Agilent34972A, is
this mode, the heat pump will start to work, with the valve B and D to collect data for one time every 10 s. The main instruments and
opened, A and C closed, as shown in Fig. 5(b). The transferring path of equipment of the test rig are listed in Table 3.
the heat stored during the day is from the heat exchanger to the eva-
porator of heat pump, through the condenser side of heat pump, to the 3.2. Evaluation index
water tank. This part of thermal energy compensated by heat pump can
efficiently heat the circulating water to the required temperature. 3.2.1. Collecting efficiency (CE)
However, it is necessary to manually start the system ahead of time. We Collecting efficiency η is defined as follows (Azad, 2008):
are planning to realize the automatic control to switch operation modes
The energy out put from the solar collector
in our future study. η=
The solar energy projected onto the surface of the solar collector
3. Test rig and evaluation index where the energy output from the solar collector is used for heating
circulating water on the condensing side of heat exchanger. Therefore,
3.1. Test rig the collecting efficiency η can be expressed as:
c w ρqvw (to−ti )
A test rig for the performance measurement of the system, shown in η=
AI (1)
Fig. 6, has been fabricated and established in Nanjing Normal Uni-
versity, Nanjing, China (Latitude of 32.0719°N and longitude of Eq. (1) is for the evaluation of the SWHS’s ability to collect solar
118.8195°E). The PCM used in experiments is 48# paraffin wax, the energy and ability to heat water. We use (1) to compare these system
specifications of which are listed in Table 2. The amount of paraffin abilities, with and without PCM, under the similar conditions.
used in the system is about 44 kg, which can fully fill 18 solar evacuated
tubes. Solar radiation intensity is measured by solar radiometer (Global 3.2.2. Coefficient of performance (COP)
Water WE300) and solar radiation data logger (GL500-7-2). The power COP of the system is the ratio of heat gained by circulating water to
of compressor and pump are measured by electrical parameter the mechanical power supplied to the system, expressed as
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W. Wu et al. Solar Energy 171 (2018) 604–612
Table 2
The specifications of 48# paraffin.
Phase change specific heat (kJ/ Density (kg/m3) Latent heat
temperature (°C) (kg·K)) (kJ/kg)
2 2 2
ΔCOP
⩽ ⎛ 2Δt ⎞ + ⎜⎛ Δqvh ⎟⎞ + ⎛ ΔP ⎞
⎜ ⎟
Φw c w ρqvh (tho−thi )
COP = = The average collecting efficiencies (ACE) comparison between the
P P (2)
system with and without PCM is shown in Table 5, where ta stands for
ambient temperature, I for solar radiation intensity and all data is the
average value measured during daytime.
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Table 3
The main instruments and equipment of the test rig.
Items Technical Specification
Thermocouple OMG-TT-K-30-SLE, Measuring rang: −200 to 1300 °C, Allowable deviation: ± 0.1 °C
Glass rotor flow meter LZB-6WB, Measuring rang: 0.1–1 L/min, Measuring accuracy: 2.5%
Turbine flow meter TKLWY-10C, Measuring rang: 0.04–800 m3/h, Measuring accuracy: 1.0%Fs
Pressure transmitter MPM480, Measuring range of low pressure end: 1–1.5Mpa, Measuring range of high pressure end: 1–3 MPa, Measuring
accuracy: ± 0.25%
Electrical parameter integrated measuring AN7931X, Voltage rating range: 20.0–600.0 V, Current rating range: 0.03 A–5.00 A–40.00 A, Measuring accuracy: 0.5%
instrument
Solar radiometer Global Water WE300, Measuring rang: 0–1500 W/(m2), Spectral range: 0.3–3 μm, Measuring accuracy: ± 1%
Table 4
It can be seen from Table 5, under similar conditions (solar radia- CE comparison between the collector with and without PCM in summer.
tion and ambient temperature), ACE without PCM is about 5% higher
Items Strong solar radiation Weak solar radiation
on average than that with PCM for I > 300 W/m2 and at least 5% less
than that with PCM for I < 300 W/m2. This comparison result shows Without PCM With PCM Without PCM With PCM
that PCM is more effective to improve ACE in weak solar radiation.
The impact of PCM on heat output at various solar radiation in- Average solar radiation 464 463 270 265
tensities has also been illustrated as shown in Fig. 9 where: intensity (W/m2)
Average ambient 30.0 29.2 28.3 29.5
temperature (°C)
(1). The heat output without PCM approximately increases linearly Standard deviation of 32.72 34.03 39.24 39.17
with the increase of solar radiation intensity and it is 10.9% bigger solar radiation
than that with PCM for I > 300 W/m2. intensity
Average CE 0.58 0.51 0.53 0.63
(2). The heat output with PCM is 13.5% bigger than that without PCM
Standard deviation of 0.11 0.03 0.13 0.07
for I < 300 W/m2. It is obvious that PCM is more effective to CE
improve heat output in weak solar radiation, which is in consistent
with the comparison result from Table 5.
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W. Wu et al. Solar Energy 171 (2018) 604–612
Table 5 (2). in winter, the heat pump evaporator continuously absorbs heat
ACE comparison in summer. from the circulating water, which reduces the circulating water
Without PCM With PCM temperature and increases the heat transfer temperature differ-
ence. Therefore, the heat output from the solar collector increases.
2
I (W/m ) ta (°C) ACE I (W/m2) ta (°C) ACE
As shown in Table 7 and Fig. 11, the ACE with PCM is about 0.15 on
551 33 0.67 548 33 0.63
462 33 0.66 468 32 0.61 average higher than that without PCM, the average heat output with
423 33 0.63 426 31 0.56 PCM is 24.6% more than that without PCM. This is because the PCM
364 30 0.59 350 30 0.55 filled in the collector can reduce the heat loss of the system, which is
302 29 0.56 308 28 0.56 large in winter due to low ambient temperature. However, with the
286 29 0.53 283 28 0.58
increase of solar radiation intensity, the heat stored by PCM increases,
279 28 0.54 277 27 0.59
258 26 0.53 252 26 0.64 and less heat will be transferred to the heat exchanger, thus the heat
output from the system with PCM is getting closer with that from the
system without PCM.
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W. Wu et al. Solar Energy 171 (2018) 604–612
Table 6
CE comparison between the collector with and without PCM in winter.
Items Without PCM With PCM
2
Average solar radiation intensity (W/m ) 365 319
Average ambient temperature (°C) 10.2 6.6
Standard deviation of solar radiation intensity 38.32 38.85
Average CE 0.78 0.87
Standard deviation of CE 0.10 0.07
Table 7
ACE comparison in winter.
Without PCM With PCM
2
I (W/m ) ta (°C) ACE I (W/m2) ta (°C) ACE
Table 8
Performance comparison at winter night.
Items Without PCM With PCM
Fig. 11. Heat output – solar radiation intensity curves of the system in winter.
Average ambient temperature (°C) 10.1 5.6
Average COP 1.55 3.18
26 °C corresponding time 16:30 16:30
35 °C corresponding time 17:40 17:30
45 °C corresponding time 19:40 18:30
55 °C corresponding time 23:20 21:10
The time from 26 °C to 55 °C (min) 410 280
Fig. 12. EWT comparison between the system with and without PCM at
summer night. 5. Conclusions
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W. Wu et al. Solar Energy 171 (2018) 604–612
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