y obi hee : ‘ rion applying form JS a auaitatve the sat (45) rurangens oven at ion applying formal groy, Carbonate Extract : Mix the given salt with solid NajCO3 in 1; 3 tilled water into it, ina beaker. Boil for some time and filter. The filtrate jg Observation Inference A colourless gas having @ CI suspected pungent smell evolves. Dense white fumes are formed. | Page 1spn ou renner om : 63) entification of anion preparation of Sodium Cay ix the salt with solid Na,CO3 in 1 : 3 ratio ina ae er t0 it. Boil, cool and filter the contents. The filtrate is sodium a a tyS0) teat eae ‘ml of cone, Sc ‘which | C202 is suspected of CaCl; solution, 3,_| Now add dil. H2S0, or acetic acid, The white ppt. remains insoluble. | C03 confirmed tification of cation No. Experiment. Observation ipteseneat 1. |Toa pinch of salt, add NaOH solution and|A colores gas with a pungent | Zero group present heat. ‘smell evolves. "ae eee 2. |Bring a moist red litmus paper near the| Ittuns blue. NHS eas. ‘oe Seeal iat 2. e . [A Blass rod moistened with co s brought near the r Pass the d reagent,_ Page 2W Procedure — Identification of anion Preparation of Sodium Cai 11:3 ratio and add about 20 ml of distilled water 0 " rbonate Extract : Mi Nootan'SC Chem) 2b, } ~~ ix the given salt (C-16) with solig " Boil for some time and fil a it. Boil ter. The i, sodium carbonate extract. S.No. Experiment ‘Observation. 1 Heat a pinch of salt with conc. HzSOq- ‘Add copper turnings to the above test tube. Neutralize 5 mi of sodium carbonate extract with dil, HCI and add to it freshly prepared equal volume of FeSO solution. Now add conc, HS0, from the side of test tube. Light brown fumes are evolved ‘with pungent odour. The brown fumes become more dense. ‘A brown ring appears at the junction of two liquids. Identification of cation Preparation of Original Solution (0.S.) : The O.S. is prepared in distilled water, Experiment (Observation (OS. + dil, HCl, Filter the contents. Dissolve the ‘precipitate in hot water and divide the | solution intotwo parts: ‘White ppt. is formed. Page 3pon 15 cre (3b Maru {651 Experi Teale abou mi tans Observation ___lnference extract with dil. HCI and agg onal | White ppt SOF" suspected solution. Bac Tee etiam a0 Gt. HOL | rept dust soe nt. | 50 ented ntifcation of cation Preparation of Original Solution (0.5, The original solution is prepared in distilled water. Experiment. I Observation inference 5+ ail HO. a canoe Pass H2S gas to the above ‘solution. Black ppt. Group Il present Fiter the solution. Retain the fitrate for the next group. Dissolve the ppt. in 60s, HNO, and divide in two parts (a) To the frst part, add NHOH soluton mw ores 10H solution | Dep bue solution cu"? cont (0) To the second part, add KalFe(CN)q]| chocolate brown ppt is formed. |__ Cu"? confirmed solution. Result ‘The given salt (C-18) contains: Anion : Sulphate (S03) Cation : Copper (Cu’) Page 4| al Nootan (SC Chem ity 3 ay 166) Identification of cation Preparation of Original Solut Experiment alt mixture is soluble in distilled way, cr, ion (0.S.) : The § ‘Observation Group | absent ‘No ppt No ppt: sh brown pot. formed: Group I absent 1. fos. + it Hel 2. | Pass Ho gas to the above content «5, add few drops of | Rec pinch of Group Ill present 3. | To fresh portion of O. ‘cone.HNO3. Boil and cool. Add a NNHgCl and excess NH4OH solution: Filter the contents, Retain the filtrate for further group analysis. Dissolve the ppt in dil, HCI and divide into two parts: (a) To the first part, add KalFe(CNe} ‘A deep blue colou solution. (b) To the second part, add KCNS solu WD Result The given salt (C-17) contains = Anion : Nitrate (NO3) red solution. | Fe”? confirmed Fe"? confirmed fon, | Blood red colour. Page 5sc roms Lab Manat xy (71 Experiment Taference (95. + dil HC ‘Observation es 8 1 ts ation pa ome eis Bol of HS eas fom the above No ppt formed. Group absen ‘add a pinch of NH.CI and excess oR. Now| A gelatinous white ppt. is formed. | Group Ill present solution. excess of NH,OH is ter the conti. Ren Euseavent sours, te fate to minimum amount of dil. HOI and ce gi sohiion int two) paris e the (a) To the first part, add solid NH4OH solution. NH4Cl and excess a white gelatinous ppt. Is formed. 1) 0 the second part, afew dy 4 of blue | A fi red. litmus solution and NHGt ioe, of Blue | floating blue lke is formed. is OH Sotton gag ar confirmed ‘Av? confirmed Result ‘The given salt (C-18) contains : anion : Acetate (CH3COO™) Cation : Aluminium (AI) JEXPrRIMENT 7 Object cation and one anion applying formal ontaining ont Page 6Nootan 'SC Chem yay a Sh 2) Identification of cation Preparation of Original Solution (0S.) «the original solution is Prepared in diy, : a OS. + dil. HC! Pass HpS gas tothe above solution Boil off Ho from the above solution Add | NO PP 2 pinch of NH,Cl and NH,OH solution in Now pass HS gas othe above solution. Dirty white PP Filter the contents. Dissolve the pp. into hot dit. HCI and divide the solution into ‘two parts : (@) To the frst part, add NaOH solution] White ppt. appears which top by drop til in excess and pass| dissolves in excess NaOH solution, HS gas into it, (0) To the second part, add potassium | Bluish white ppt. formed. ferrocyanide solution. formed. Page 7sc onemisty Lab Manual xa) rifeation of cation (91 of Original Solution (0.8. The Oi prepared in dil. HCL Experiment Observation Inference 05. + ait ACI aS Group 1 absent ass HoS Ea ito the above solution. | No put Group tl absent Boil off HS gas from the above solution, Group Il absent Add few drops of conc. HINO, Boil and| NP cool. Add. solid NH,CI and. NH,OM. Solution in excess Pass HeS gas into the above solution. | piety white ppt. formed. Group IV present Filter the contents. Dissolve the ppt. in hot dil. HCI and divide the solution into two parts (@) To the first part, add NaOH solution White ppt. appears which cisoles| Zn" confirmed drop by drop til in excess and pass in excess NaOH solution. HS gas into it Zn"? confirmed. (b) To the second part, add potassium| Bluish white pp. formed. ferrocyanide solution ‘Anion Carbonate (C03) Cation : Zine (Zn?) Page 8= Nootan /SC Chem, 7 (70) emt Identificatic on it reat residue of sodium carbonate extra . .d by dissolving the ses im dig yy Ue Preparation of Original Sol in dil. HNO, This is used as 0.S. for cation .) : The lation (0. ree epare or the O- OS. + dil. HCL Pass HS gas into the above contents. Boll of Hs from the above solution. Add] No PPE ‘a pinch of NH4Cl and NH,OH solution in excess. Pass HpS gas into the above solution Fite the contents, Dissolve the residue Scarlet re PPt in aqua regia. Evaporate the solution t0 ‘dryness. Add water and NH4QH in excess followed by few drops of DMG solution. Page 9Wun 50 Chemisty Lab Manual Xi 7 3.) : The salt is soluble in distilled water. Experiment Observation paeeree OS. + dil. HCI aE ‘Group | absent Pass the H2S gas into the above solution, | No ppt poe at Sy Boll off HS gas from the above sot Group il absent ae Pass HS g2s to the above contents. | No ppt eae Boil off H2S gas and add a pinch of White formed. Group V present HCI, excess NH4OH solution and eed paces (NH_605 soto, Filter the contents. Dissolve the | A yellow ppt. is formed. Bat? confirmed precipitate in hot dilute acetic acid, Now. oF add potassium chromate solution. Result ; ‘The given salt (C-18) contains : Chloride (CI, Barium (Ba’*) a 2-D) surscun tne ae ) sbinokdlas cei Page 10(72) Nootan 'SC Chemisty ay ‘The salt is soluble in dil. HCl. Identification of cation Preparation of Original Solution (0-S-) + S.No. Experiment ‘Observation Inference roup Il absent 2. | Filtrate of group | + Pass HS gas int it. No precipitate. ere a OU Il abe 3. [filtrate of group I + A pinch of solid | No precipitate. a NH,Cl and excess of NH,OH solution. ee 4. | Pass Hos gas tothe fitrate of group il| No precptate formed a r to the content of the test tube. v 5. | Bo off HoS gas. Then add litle NHyCl, | White precipitate obtained. | Group V resent excess of NH,OH and excess. of (NH4)2C03 solution. Filter the contents. n Dissolve the residue in minimum amount of hot and dilute acetic acid. ivide the solution into two parts : Page 11remistry Lab Manual Xi! cation of cation paration of Original Solution (0,$,) : Original solution is prepared in dilute HCL. Ene OeaTvatial [__Inference 5. + dil HO! mea oe pass HaS 5 tothe above solution, vl Group 1! absent off HS 85 ffom the above solu Group Il absent Gygol and NHgOH solution in excesg, 0 At Solid | No po. pass HS 885 to the above solution, - No ppt. pail off HoS 2s. Now add litte NH,CI, excess : FigOH and excess of (NH,),C05 solution, n> | Mite Pot. obtained Fitter the contents. Dissolve the resi rrinimum amount of hot and dilute the solution into three parts: {@) Tothe first part, add potassium chromate (KsC10,) solution. (b) To the second part, add ammonium sulphate (NHg)2S0g solution. “ (To the third part, add ammonium oxalate (NH4)2C20« solution. Group V absent Group V present idue or ppt. in acetic acid. Divide Result — "he given salt (C-15) contains : ‘Anion Carbonate (CO% ) Calcium (Ca’?) Page 12(74) Identification of cation Nootan ISC Chemisty a salt is soluble in dilute HCL. Preparation of Original Solution (0.S.) : The (Observation S.No. Experiment 1. los. +i Ho. 2._| Pass HaS gas into the above solution. 3. _| Boil off H2S gas from the above content. ‘Add a pinch of NH_CI and NH,OH solution in excess, 4. | Pass HS gas into the above solution. 5. | Boil off HS gas and add to the cool solution, @ pinch of NH,CI, NHgOH and excess (NH,)2C0s solution. 6. | Boil the contents to reduce the volume. ‘Add a pinch of NH4CI, excess NH4OH ‘solution and saturated solution of disodium hydrogen phosphate solution. Scratch the ___|inner walls of test tube with glass rod. ‘No ppt. No ppt. No ppt. No prt. No ppt. A white crystalline ppt. is formed. Group | absent Group I absent Group Il absent Group 1V absent Group V absent Page 13SC Chemistry Lab Manval Xi! cation of cation n of Original Solution (0.s Experiment 7s] ) : The salt is soluble in distilled water. Observation. Inference excess, HS gas into the above solution. off HS gas and add to the cool olution, a pinch of NHaCI, NH4OH and (NH4).C05 solution. il the contents to reduce the volume. No ppt No ppt No ppt. No ppt No ppt. ‘Awhite crystalline ppt. is formed. Group | absent Group Il absent Group Ill absent Group IV absent Group V absent. Group VI present and Me’? is confirmed. Page 14