(9 Ye / QUESTION BOOKLET acf Chemistry ae! Code: OP25 gfe i yet Bh der / 2501484 Number of Pages in Bookles : 64 CHEMISTRY gfrar 4 west ai ten / OP . Number of. Questions in Booktet : 200 2 [Al ete ‘ea / Time : 342 Hours gaia / Mavinum Marks : 100 INSTRUCTIONS 4. Anawar all gue 2. All questions carry equal marks 5, Orlane answar fs to be ghen for each quoston 2. iftaate thant one anowets avo murkou, H Would be ested as wrong answer. 3! ach question has four akerttva rspoeses metked sotaiy a8 12% 4 fu have to darken only ons ‘tale or bute Indcatng tha corcect ancwer on the Anau! Shosi usiny SLUE BALL POINT PEN. ‘Ve part of the matk(e) of each question will Be docucted for eneh wrong antuer. 'A wrong snsier magne an Ingorrect answer OF more than ore answers fo: ary quoston. Loading ai she rloiant cles or [bubbas of any gieston blank wil not be. consiceted as wor anewsr.) 7. The condiiste should ensure thal Serna Coda o! tha Cuestien Pacer Bvotit and Answer Sheet must be etre allt: spening the envelopes. In case ney ore alent a eanciaato must obion another Cuesion Paper of me sama dares. Cardidale himself sic be responsible for ensulitg ths. 8, Molile Poone or any ofr elton gadget hr tha aigminaton hal isfy pronates A cansidate found ‘wily ary of such objectionable mates! wit hawner wal be aticty salt a5\per ies, 9, Fleage carecty fl your Rol Number in OMA, Sheol. § marks vill be decucted for fing wrong or ingomplate Re Sumbot Warning? Ifa candle is ound copying ct If ay unaulbor'sed mata’ is found In nismhot possession, FER would be lodgad aganctrimyhet in bo Pcboo Staion aa heise woulda ibe prosecuted Under Section 9 of he ALPE. (Prevention of Untarmeans) Act, 1e¥2. Commisscn ray at8o dove enter pormaneny from sli ature cxaminatons of he Commission, 1. weit ar re 2 al sedi & sie an EA 3. order a er oe A sae Sms As 8 alten ore BF ah gen A ge Be re ee AT | Swe ee Bere aftr wee FOG FR a: 1, 23, an fre Bs ate ot hee ceed gq and 8 reer Yo ME area wea A Got eae oe a Sree BH BG OTH 6. ora naa Tae eee cis a 1/3 om ita ae Ta aa aed age oer ave Pah wee vey hfs etre WB 2 Pee a ge 3 eg An Ea che se Fee fl eo aT 7. oi na a gk TC Woe Fv at Ae we wAl an Berar As wea a i) Se a oleate oe Oe olen GL aE Posen et aes E wet at athe SRN ET ogra on eee ara ome erat aerdy one eh: shana as vce eee Ua ht ot gab lio at #1 a Pe opel oe Rh it aia seh Bott Ba Sin ere ae) Progreso 9. uch oon Gan ere i oe. rE Te THT es aT RL Ta ote rg He HA gE Sk strata 2 8 ofan ga 2 at ane ene = spre wid asa seg a Oe we & wo we aE cars wed ork 8. eh ote feces 3 scat ot oe A re one. A 4, ORT BrP A eA, sia, 1992 3 Fro 3 eae atdeh a aint aa wah A arse at Maar 8 rc tata ah rr wa eas ar ween BL OF25_AL . vo RMGIRINEEA IE fConed.How many orbitals will be present in the 3° shell a3 @ 5 @) 6 @ 9 drat sia FT feat wae oahat eB? ay 3 Q 5 GB) 6 @ 9 1 Element having quantum number n= 4 and S=~ will possess following, number of electrons ay 16 @ 8 8) 2 @ 12 Faweq TEM n= 4 cer set Teta aa F frat den A stags og ant: a) 16 @ 8 @) 2 (4) 12 Element with atomic number 57 belongs to () 5 = block Q) p - block @) d - block (4) nobel group WH Wer $7 ae ae Tad Fs (Dos - ae Q) p- aie G) d- wie @) afr ae Which element will form cation most easily 7 () Ne @) Mg @B) Sr 4) Li aire ae waite onart @ srr tm 7 (Ne Q) Mg G) Sr @ i ‘Number of unpaired electrons present in chromium (At, No. 24) atom is a) $s @) 4 6) 6 @ 3 wii (6. &. 24) were H orate each aS Prcell wear wafer ait? as @ 4 GB) 6 . @) 3 OP25_A} 2 LINHA Conca.10 The interpretation of 3 unpaired electrons in electronic configuration of Nitrogen atom is based on (Auf bau principle (2) Paul's’ rule (3) Hund’s rute (4) (mt) rule ardor vey #3 eatin steht & ag ar ar gaagite oiftiferre annie & : () aie-ai rare 9 Q) wet % Pee G) ps & Pan we (4) (at rane Highest lattice energy will be of a) Lil @) Licl G) LIF (4) NaF eee wating oie Gat eri (1) ° Lil @Q) Lic @) LiF (4) Nak Lowest radius will be of : (1) Mg?+ @) ABY @G) Na @) Nat ep Arar eri: () Me? (2) ABY @) Na (4) Nat The general outer configuration of most electronegative element is : +) ns? ap? Qo npt (3) ns? mp5 (4) ns? npS walftrs fered cea a aT aeq Brae ee — (1) ns? np? (2) 1? npt @) ns? np> 4) ns? ops The constituents of stainless steel are (1) Cu + Sn + Fe (2) Fe + Cu + Zn G) Fe+ Cr+ Ni @) e+ Co+Ni were Rit S ory e : () Cut Sn + Fe Q) Fe + Cut Zn @) Fe+Cr+Ni (4) Fe + Co+ Ni oP25_Al 3 IMMRNININEH] | CConeet.u 12 13, “4 15 P25 Al ‘ IRUTMITIEBY Cone Which of the following properties is related with sequence - F > CI> Br>1 Q) Electron affinity (2) Blectronegativity @) Atomic radius (4) Boiling point Pea Yd era a ge wa @ daft 87 F> Cl> Br>1 (1) sagt agar 2) Pregame G) Tey fear @) Faerie The compounds of alkaline earth metals have the following magnetic nature (1) Diamagnetic (2) Paramagnetic (3) Ferromagnetic (4) Antiferromagne arta yar angel & aia fee van ot gave wpit waa & 7 (1) 7 wget Q) sepgrrerr GQ) dhegaata - 4) sfarctegreairy In radioactive decay which one of the following moves the fastest ? (1) a ~ patticle ©) B - particle @) y= rays (4) Positron Yfeteea aa A aeifire deer a after & Q ao : Q) B-= G) y- am @) ater Which of the following elements is the end product of natural radioactive series ? Q) Pb- @) Sn gc 4) Bi fer 2a aia ae wpte YWeiefeer aot ar aan aoe der? (Pb (2) Sn @ c @) Bi Half life for first order reaction is 1000 seconds. Its velocity constant will be QQ) 6,93 *10- sec (2) 6.93 10 sect G3) 0.693 seem! (4) 69.3 sec! aie vai gaa af afifear an ariorg wr 1000 dems & ct yaar or Renias a Q) 6.93 «104 dave! (2) 6.93 ~10-4 depose! (3) 0.693 gas? (4) 69.3 dae!16 Asbestos constains () K and Mg /@) Ca and Mg (3) Zn and Mg (4)' Na and Ca udeta 2%: a KaMg @) Caa Mg @) Zn = Mg (@) Naga 17 For artificial transmutation of nuclei the most effective one is : (1) Proton 2) Deutron 3) Helium nuclei. (4) Neutron aie & gfer gla oft & fay wad wah & a) ae @ er G) Seten arbre @) sR 18 Which of the following does not take place by a decay ? a) 380s 3th @) 3th B8Ra @) Beka RP Ro (4) 2Bi > 23P0 fra Ha Sire o- ea orem ae Bt wT EF a F8usth @) 5arTh— geRa @) BSRa— 2Rn 4) BB Bis 2 Po 19 Hybridisation present in CIF; molecule is (1) Psp? @) spd 3) dsp? @) spa? CIE; omy H Gaet & : (I) sp) (@) sid @) dsp* (4) spia? 20 Bond angle present in HS is : (1) 104931" (2) 107°48' (3) 91930" (4) 109° 28) HS 4 de ator b (1) 104°31" (2) 107° 48! @) 91°30 (4) 109928" op2s_Al s FINNIE IRE, tones21 Shape of SF, molecule is (1) Trigonal_ bipyramid 2) Distorted tetrahedral G) Square planar (4) Square pyramid SE, oy at ongft & (1: Breteire eee @) Pape agora G) we ae 4) witere frafis 22 The crystal structure of NaCt is (1) Rhombohedral 2) Cubic @) Monoclinic (4) Triclinic NaCl B Pret eee t 1) Presto Q) wie G) Gera (4) Brae 23 The molecule having bond order 3 is a) 7H, @) N; G) 0; (4) He* ory freer dy wr 3b: @ Hy @) N @) 0, @) Hest 24 Which, of the following ionic radius would be maximum ? ad) ch (2) NB @) OF (4) Mg?* Pet @ faaet ome Pea aftepay & ? ay ce Q) Ne 6) o> Mg OP25_Al ' ‘6 COMTI &Coed..25 The atomic number of an element is 22, The highest oxidation state shown by it will be qi @ 2 B) 3 @) 4 wm 7a A Teny dem 22 31 qed are zat af wen onatect wet & ao @ 2 @) 3 @ 4 26 Oxidation number of Mn in MnO, is : m2 @ 1 GB) 2 @ 4 MnO, 4 Mn at ameter den & QQ). 2 @ 3 GB) 2 a) 4 27 Which element is reducing in the following reaction ? TiC1, (1)+2Mu(s)—* > Ti(s)+ 2MgC1, (s) a) Ti @) Mg @ cl (4) Mg and Cl fra afiteat ¥ for ae am ome A Te? TiC1, (1)+2Mg(s)—* > Ti(s)+2MgCl, (5) a) Ti @) Mg @) ¢cl @) Mgacl 28 The oxidation number of sulphur in Na)S,Og is + @) 40 @ -40 @) 25 @) 20 Na$,0, % tae of omntern det} : a) 40 @Q) -40 (G) 28 @) 20 ons.Al 7 HIN. 1Cone.29 Which of the Following is Lewis base ? Gy Co 2). BFS 3} Alc) 4 BO fer 4 ao qa att (i) Co" (2) BE; @) Alc, @) 1,0 30 Which of the feltowing solutions will be basic > 4) HOC 2) Nac! (3) Na,SO, (4) NH\NOs Roy Ba eran fewer erie cm 2 fy “Hoel (2) NaOCl 2) NaySO, (@) NHNO; Atomic nambers 33, 31, 49 represent the following family Carbon (2) Boron @) Oxygen (4) Halogen WN Fer 13, 31, 49 fea sere wi esti #7 ct ert Q) aa seiner a) thr 32 Which ol the following pairs will show diamagnetises (1) Na, Nat ©) cut cut? @) Ce ay Cn er Per ® 3 ahem on witgerra afar? #1) Na, Nat 2) Cut, Cat? By Ca, Ca 4) Cr Ce 33. Highs) ionisation potentiat will be shawn by species CD Mri? (2) Mn Gh Matt @) Mré feet wa wcities emer Bere entai oem 7 @) Mnt® @) Ma! (3) Math (@y Mn OPI AY 8 CAERIEA [Conc34 36 37 Jn which of the following compounds chromium shows meximum r a) ) Cr0,Cly a) @) CrCl, fre at chit # wan wee sree Be alt 7 (1) KxCr,0; @) CrO,Cl, GB) G80); (a) CrCl, Neutral oxide is, Q) Sn0, @ co 3) ZnO SiO, veri cigars & 2 (1) Sad, : 2) eG @) ZnO 4) SiO, Chemical formula of 'Borax' is (1) Na, [B,0, (01%), |-8H,0 Q) Na,[B,0,{08), |-21,0 B,0,(OH}, |-8H,0 (4) Ne,[B,0,(0H), |-28,0 areaa on carats gx: () Nay [B,0, (0%), (2) Na 1B,05(0H), | (3) Na,[B,0,(0t1, SH, . ; : a) Na,[B, 0, (08), | When an alletrope of carbon is heated in an electric arc in the presence of Argon, % produces () Crown ether (2) Graphite (3) Fullerene (4) Diamond anh a wikait 2 gs orb ari aa & oe wT ee ay SA eat () wrt gaz Q) tage Q) gare a) Ae ors. Al ’ IESE. fone38 aL a2 Froth floatation process is related with following form of ore (1) Oxide Q) Sulphide @) Chloride (4) Carbonate at war fet fea 9 @ fee var & ome a waftar % 7 (1) Sarees Q arms G) Fine @ BRR Heaviest metal is : (1) Tungsten (2) Osmium @) Gold (4 Lowrencium watiies art ong % = QQ) area Q) steer @) wt @) dtfem The heating in hot air to oxidise sulphur from pyrites, is called (1) Calcination Q). Oxidation G) Roasting (4) “Smelting aga 4 8 ine a oreterr Th ea art wet wT wet e : QC) aeiect 2) wet @) ow @) wert Strongest metallic bond is present in QQ) Fe Q) Cr @) Mn ) Se watfis oftagmt often dy softer () Fe @) Cr @G) Mn (a) Se Cyanide process is used for the extraction of : qd) Ag (2) Au @) Cu @) Zn werngs Pfr ar oat frat vite | faq dare 7 @) As @) Au GB) Cu (4) Zn Ors Al " IMIR TAN] toned.43 Common co-ordination number of Cu* ion may be 2 Q 42 Q) 46 GB) 24 @) 6,2 cut Oo are arcaaten ei : ay 142 Q) 46 GB) 24 (4) 62 44 tn [Co(NH,},Cl, JCI, the charge on cobalt is G42 Q) 43 G) 41 @) +4 [cofne,), ct, Jor A steree we sitar & q)y +2 Q) + 6) 4 @ +4 45 Diethylenetriamine ligand is (1) Monodentate (2) Pentadentate (3) Bidentate (4) Tridentate aruiraects dies & » (1) uae 2) teed 3) fester 4) Breda 46 Which of the following acts as ambidentate figand ay) eN- (2) pyridine (3) acetylacetonate (4) CNS fer A a aba wernt dies ee ay en" @) Frege G) Waeiete @oCNS™ OP25_A] u TANI NTE (Comet.2. 47 Effective Atomic Number of metal in complex [Ma(H,O], } is qd) 33 (2) 35 GB) 36 (4) 38 ign [vn(tt,0),[° 8 ag nd wemg gon & : Q) 3 Q) 35 GB) 36 (4) 38 48 The compound [coc (NH), | has the following name (1) Potassium diamminotetrachlorocobaltate (11) (2) Potassium diamminetetrachlorocoboltate (IIT) (3) Potassium diamminetetrachlorocobalt. (ITI) {4) Potassium diamminetetrachlorocobalt (11) chr x[coct, (8H), ] mame: (1) defer severed wart (11) Q) Sefrar serie state (111) G) Meher seeetiaegracirtt saree (IM) @) deren seeitgadt sae a) 49° The ligand EDTA in [Mg(EDTA}]~ chelate is (1) Pentadentate (2) Tetradentate 3) Hexadentate @) Bidemtate [Ma(epra) az 4 chive Epa & (1) - fede @) water G) seed (4) feet oP2s_A] 2 CNMI ANTE toned.50 Which of the following statements is correct for XeF, molecule ? (1) sp3d2, square planar, two lone pairs, four unpaired electrons (2) sp'd, trigonal bipyramid, two tone pairs, four unpaired electrons (3) dsp*, octahedral, six unpaired electrons, no lone pair (4) sp'¢?, square pyramidal, three lone pairs, two unpaired electrones XeF, ay faq fer 7 a vam wer at 7 CQ) spe? aatore wae, a @azin ge, ar agar seagtt (2) spd, Brenita fefenitta, @ gtagit gm, ae age getagit @) &sp' aepama, w: eataa wats, ae ga et @) spe, ante freita, dh gaia ge, a oraitng stat For diborane which of the following is correct ? (1) sp hybridisation, linear structure (2) sp? hybridisation, banana bonds. (3) sp* hybridisation, banana bonds (4) sp hybridisation, banana bonds smaita & fry Pet 7 a wa es () sp eae, tar Seri (2) sp? farm, sar Fey G) sp? daa, wr Ta (4) sp eae, FART aT 52 The second most abundant element on the earth's crust is (1) Aluminium (2) Copper GB) Silica (4) Carbon aa ara a an a ae gue waits xen ae ate 7 (weir @) ata G3) after @) ad 53 Which of the following shows sandwich structure ? (1) Fullerene (2) Crown ether (G3) Fetrocene (4) Porphyrin astra deen fer 4 a tre cai & 7 (gate 2) wer fae @) ar @) wer op2s_Al 8 UANMLAMITIRBAMY | tomes84 For Al(OH), = Alt? 30H, the solubility(s) will be a Ky oy ihe 7 K a Ks elt Ky] fal o [a AI(OH), = AIY3-+30H7 % fry Petar (5) eh = oy Se 4 $8 What is the solubility of AyCl in a solution of 0.1M NaCl ? [K,,=tixto"?] q) 01M Q) 11* 108M @G) Ll x 109M @ tix 10M 0.1M NaCl facet 4 AgCl # fraser gar ert 2 q) 01M Q) 11 « 106M @G) Li» 10° M (4). 11 * 10°! M 56 If AgNO, is added to an aqueous solution containing 0,01M each of CI", Br and T- ions, the correct sequence of precipitation is Q) Br, cr, Q) ber, Br 2G) Br cr” @) Bry cr .——uit_o_f Bi-0.01M Cr, Bra br aed (were %) ¥, ¥ AgNO; Prom wet & at stad, et wat wT ee — Q) Br, chr @) 1, Ch Be @). 1, Br, cr @) Br cr on2s_A] 4 CIMA (ome.s7 58 59 Maximum conductivity would be of (1) K,Fe(CN), [0.2M solution] 2) K,Ni{CN),[0.1M solution] @) FeSO, -Al, (S0,), -2471,0[0.1M solution] @ Nal Ag(S,0, ), Je 1M solution} efter area eft 1) KyFe(CN), [0.1M Resa] 2) K,Ni(CN), [0.1M feere] (@) FeSO, Al, (S0,), -2411,0[0.1M rer] @) Nal Ag(6,0,), [o.1M tem] Which of the following is suitable indicator for pH titration of weak acid and weak base ? (1) Methyl Orange (2) Phenophthatein G) Phenol Red -(4) Methyl Red ade ova a gd are & wor pH apart Bg sryeA ges era a dae (1) Afaet sift @) Retevacia G) fee t (@) frame te 19889 poi4 9Ce"? is a group of : (1) Isotopes (2) Isobars (3) _Isotones (4) Isodiapheres 4 1348 yok" goce!? um wag Bs (1) angaterea (2) angered G) angetarr 4) onder OF25_Al 8 TINUE Conc60 61 62 In galvanisation, iron surface is coated with () Tin (2) Chromium G) Zine (4) Nickel feta 3 ate gas we afte Par ann & = Q) @) xfer GB) Rie @) Pro Which of the following bonds is largest ? a) CF @) CCl GB) CH fer TG wea ae ee: ay CF @ CC @) Cer @ cH Which of the following is least reactive ? ti N w 0 Q) - Hu” CHy a) =O (4) =O 7 CH fra a O ant om feaata 1 H ay 4 =O @) So =O a HO” CHa. CHa 3) C=O @ =O ne CHy ors 44 6 iE 1Com.63 64 65 66 Which of the followitig is most acidic @) CH,COOH (2) CH,CICOOH G) CHCI,COOH (4) CCI;COOH fm te awd afte amie % : . G) CH,COOH Q) CH,CICOOH @) CHCI,COOH . (4) CCL,COOH Which of the following bonds will have lowest bond energy ? a) CaN @) CaN Gy) C-N @) =C-H fer 3 8 wat am ar oat Roast & 7 ay @) G) C-N @ Repulsion will be highest for (i) bp. ~ bp. @ Ip. - dp 3) Lp. - Ep. (4) Lp. — fiee radical See Yo aed afte witrertr er: (dp ~ bp. 2) fp. ~ dp. GB) Lp. = bp. (4) Lp. = Fat A Number of resonating structure will be lowest in : @ Q) CH, G- ons CRy 6) (4) CH,-CH=CH, Peet % qed wn orga erent et ter rt: (1) CH, ~CH=CH—-CH, @ Oy ~ CH= C~OHy CHy @) ON, -C=0-CHy (4) CH,-CH=CH, Cy CHy OP25_Al " TONITE INN, Com.67 68 69 P25_A] 18 ‘The reason for relative stability of the following sequence of alkyl free radical is: tert. alkyl > sec. alkyl > pri. alkyl > methyl (1) Resonance (2) Mesomerie effect (3) Hyperconjugation (4) Inductive effect afer qed gee & da wnt tg fet a & fee art t afters uae > fers ufeer > wets uaa > Afr Q) syne 2) trattfes we GB) oft ager @) Tee waa Which of the following is a nucleophile ? Q) ZaCl, @ Alc @) R-Nt=N (4) R-MgxX Per a afiwert & : () ZnCl, @) AICI, GY R-Nt=N (4) R-MexX C)HBr+OH?— C,H,OH+Br. The above reaction is (1) Electrophilic substitution (2) Blectroy addition (3) Nucleophilie substitution (4) Free radical substitution CyH{Br+OH?— C,H,OH+Bro | set aiff & - Q) seed uftenct Q) wee ares Q) afterchet sftreme G@) yar ype wire IFN tomes...70 n 2D NH-OH N Hy, 1H oO (1) Substitution reaction @) Addition reaction (3) Rearrangement reaction (4) Displacement reaction NH-OH NH = ©) ote: on (were (2) ara G) gifiene 4) Reena TUPAC name of CHa — OM; CH; —CH—-CH 3 (1) 2-methyl-3-ethyl pentane (2) 3-methyl-2-ethy! pentane CH —CH2— CHa 3) 3-ethyl-2-methyl_ pentane (4) 2-ethyl-3-methyl pentane CHs — CHg— CH —CH2~ CH3 @1 TUPAC 4m & : CH3 = du ~— CHs (1) 2a 3.x FS 2) 6G) @) 2-ofrr-3Afirer ter Heptane exhibits the following no, of isomers, : @ 7 @ 5 G) 6 a) 9 Bea & Pe ered Bae: a) 7 Q@ 5 G) 6 @ 9 ons AI (ANTHEA 1Con..B 14 15 76 2R-X+2Na—+R—R+2NaX reaction is known as (1) Clemmenson: (2) Wolf - Kishner G) Wurtz (4) Kolbe 2R-X+2Na—-R—R+2NaX abe aT wat & — () attr 2) see Pree 6) a 4) ore Which halogen reacts with alkane rapidly with explosion ? Qa i @) Bry @ 4) Ch wot & eer diner tess Gene B ae afifieer wor #7 Ob Br G6) Fy a Ch If n-butane is heated in the presence of AIBr, / HBr, the product will be (1) Benzene 2) n= octane G) Dibromobutane (4) Isobutane aft nea a AlBr, / HBr & wa wh wt a zene we : 0) air 2) n+ ae G) sigaitteea 4) omega Hs - CH2~ CH = CHa +HOC] —> A Ais () CHy~ CH CH-CHe — @) CHy ~ CH~ GH Cl cl OH oH a @) CH -CH—OU-CHs (4) CH ~ CH - CH —CHs OH Ol cl OH CHs - CHg~ CH = C2 +HOC] —> A At: a) CH ~ CHa 6H ~ GH Q) CHy ~ CHy- CH ~ (Hy Cl OH on cl @) CH3—CH-CH-CH3 (4) CHy-CH-CH-CHy oH Ol cl On on7s Al 20 TROT tone...7 78 9 Ni(CN). 2 Cyclooctatetraene ; Ais 65°/200AtmP ) Ethene (2) Butadiene (3) Acetylene (4) Butyne Ni(CN), . @5°/200ammp SERA RERET 5 AE Q) air @) apt @) witeier @) aE CHC, +HNO,~>A, A is (1) Chloral (2) Trichloroketone 3) Phosgene (4) Chloropicrine CHCl, +HNO, A, A ® = (1) aie 2) aaah ates 3) wrest @) mira OH +CCL, +4KOH > A+4KC1+2H,0, A is: (1) Benzoic acid 2) Cinnamic acid (3) Salicyldehyde (4) Salicylic acid OH +CCl,+4KOH— A+4KCI4+2H,0, A 8: () Figs ort Q) Refre ort G) achaeere (4) Siffre ere oF2s_A] 2 CNMI IAT; toned.80 Pyrane is used as (1) Antiseptic (2) Fire extinguisher G) Explosive (4). Cooling agent cage sain & ya yar Ss (tpt Q) after G) fretem 4) tare 81 CH, CH=CH, 26, , WOH, ; Final product will be 202 Q) Acid Q) Aleoho! G) Aldehyde (4) Ketone -CH= BBG NaOH. ; : CH, -CH=CH, "8A, 1,05 B; ofan sare em: C) or (2) Ueateter G) wees °@) Steer 82 Cause of solubility and high b.p. of an alcohol in water is (1) van der Waals’ force 2) Inter molecular hydrogen bonding (3) Intramolecular hydrogen bonding (4) Dissociation of molecules wera & sey aie wi we A wa fier a oro é : Q) ast - ane ar 2) Ren tage de GQ) serasrys eee dy 4) api a Reine 83 In Victor Meyer's test, tertiary alcohol will produce the following colour : (1) Red (@) Blue 3) Yellow (4) Colourless Faeex Far vila 8, giiae uebieier Pr tr oe wt — (>) am Q) Aer G) te @ ota A 2 MEET M) #omea.84 86 Oxiranes are (1) Cyclic ‘acids (2) Cyclic aldehydes (3) Cyclic ketones (4) Cyclic ethers tier &: Q) eet oT @ war wdlegs G6) wir ae 4) wart ee f . Rag cre ESO @ wa HL reaction is known as oO 0 (D Perkin's (2) Knoevenagel's @) Rosenmund's (4) Cope - knovenagel’s Repo HBS 6 ancl afiina rit anit & + 0 0 Q) wie Q) Wate @) teres @) Bo ~ aaa Urotropene can be obtained by the reaction between the following reactants : (1) Acetone + hydroxylamine (2) Formaldehyde + ammonia (3) Acetaldehyde + hydroxylamine © @)_ Benzaldehyde + ammonia Fier FO fet fare meq often or qed wim 7 () ats + epi ei @) witemgs + omit G) Weems + agit wir 4). Sardies + aritfrar P25 _Aj 8 LOMITA (Come.87 89 cHO MOH A, A is CcHs~~CHO+CH, () B- diketone 2) Trioxane G) Cinnamaldehyde (4) Crotonaldehyde CoH —CHO+CH, -CHOWOK a ae: Q) B- seater 2) gifeiiett G) Rrvndters (4) were A+[R} 28 -R-CH,-R+H,O, A will be (D Acid ) Psi. sleohol (3) Aldehyde (4) Ketone A+(h} 222 RCH, -R+H,0, A8 : qd) ar 2) mafia oeateier G) wees (ater Acrolein can not be obtained by the following reaction () Glycerol + KHSO, @) Allyl alcohol + MnO, (3) Propene + 0, + CuO . Al,O3 / 35°C (4) Ketone + Mg + Hy'O Per 8 & fea afitiar are gate ma ag Beer a aaa 7 (i) mirriey + KHSO, @) efaa ceateia + Mn0, G) FTF + 0, + Cu,0 . AIO, / 35°C (4) it + Mg + H,tO Crotonie acid can be produced by (1) Oxidation of aldehyde 2) Oxidation of ketone (3) Condensation of aldehyde (4) Reduction of ketone pram sma wert a wea Bs () Where & crete a |G) aie & onto a GQ) wees & Gar & (4) de & one 3 OP25_A] . 2 HIRSUAUEMIEAE (Cone...a 92 93 84 OP25_A] 28. WHORE (Conte... Acid which is present in Red ant is = (1) Crotonic @) Acetic @) Formic (4) Valerie ara WAH waiter oma e : Cl) miter (2) Utara G) whe @) aie If a cyanide is hydrolyses. the product will be : () Ketone (2) Schiff’s base @) Acid () > Ester cafe errs a ata aques fen oe a sere er Q) Bree @) Are ae GB) FT GQ WRT CH, —OH is known as : . cooH (1) Glycol (2) Glyoxalic acid 8) Giycotie acid “ @). Glycine CH,-OH arn set & : i COOH C1) eEReTRT (2) areata erat 3) Tenge arr 4) rng Reformatsky reaction is useful to produce (1) q@-halogen ester 2) B-hydroxy acid (3) a-halogen acid (4) B-hydroxy ester Remifexty ora Pr a seer # wwe : acti we | (2) p-megeedt or GB) Reiter ret @) B-wagrRa WRT95 97 OP25_A} 26 Mallic acid +HI— Product which is (1) Formyl acetic acid 2) Tartaric acid 8) Succinic acid (4) Fumarie acid Afre ort +HI— 3 care em: Q) BR ofa ora Q) aes ema G) ara re srt 4) RARE oT CH,CONH, +Br, +KOH —P+2KBr+K,CO, +2H,0, P ig Q) Acid 2) Ester @) Amine (4) Cyanide CH,CONH, +Br, +KOH > P+2KBr+K,CO,+2H,0, p =: oT @) BRT @) ir 4) TERS ‘The reaction between ester and. water catalysed by base is known as (1) Reduction Q) Hydrolysis 8) Saponification (4) Inversion Wet a re A afin ame sake Ft woke H ah t ct aeant F: dd) rere Q) Wa-smaet @B) agtect @) xi The intermediate which produces by nitrating mixture during nitration is called : (1) Nitrate ion 2) Nitrite ion (3) Nitronium ion (4) Nitrosonium jon TRS wa ager fer ae ce aad! wea F : Q) ARE ret Q) TR aE G) Rte sit @) agree omer99 Azobenzene may be produced during ‘following type of reduction of nitrobenzene in the presence of (1) Acidic. medium @) Basic medium ) Neutral medium ) Hy gas sagas & ome a wstste we waa Per 2 @ sh wert outed am ae &: 1) aeetier @ arte G) sari (@) Hy ta ot soar 100 Pictic acid is : coon NH: a) “or” 2 oy NOs OH OCH; 6 Yor ® “oy NOs NOz fie omer t+ COOH NH2 a) “oe 2) “Yor NOz OCH; 6 mney @ ey" NOg NOZ = OF2S_A} u MONTE Cone101 Which of the following amino compound will show maximum basicity ? NER NE NH Oo) @ NE NEB 8) Olan @ Oo NH free 2 8 ara wht dite waite ence ante 3 7 NE Nik NH, a) Q) NHe NER 6) Olen 4) NFR 102 CH, -NH, +A +3KOH —CH,N2C+3KCI43H,0. A is : () CCl 2) CHy G) CHCl (@) CHCl, CH, —NH, +A+3KOH — CH,N=C+3KC1+3H,0, 4 ® : (). CCl, @) CHy @) CHC, CHCl, onis_AI * INILIAYRIE (Come.103 104 105 cu,cl ter CoHsN3 cl HCL CoHsCt +N, above reaction is known as : (1) Baz Schiemann’s (2) Gattermann's G) Sandmeyer's (4) Mannich cee fue NFCA CoH Cl+ Ny sifiirar weereih & — Q) wea — sar Q) Tew G) Westar (@) Aire () CsHSN 7 CHCHO +H1,C-(COOC,Hs), —",0 crotonic acid above reaction is known as (1) Perkin's (2) Knoevenagel’s ) Schmidt (4) Wittig () CSH3N CH,CHO +H,C-(COOC,H,), igo 7 Brie are Pitre aah & a) afr Q) Werte () fre @) Ber If malonic ester reacts with urea, the product will be (1) Urotropene (2) Mecetylene (3) Barbituric acid (4) Cyclopentanoic acid cafe AfvPee met var afta & mez aia A at gene den: 0) qari (2) iRRet G) Tye ore () argeiiveriga arr or2s_A] ° CANMTATAM #Conee106 If sodium salt of A.A.E. is heated with Ip and hydrolysed with acid, product will be : (Valerie acid Q) Adipic acid (3) Succinie acid (4) Glutaric acid afe qaeigtRe wer & aise wa a1, & wer eh ae ory aro amt amet met t at vere erm: (1) Aas era 2) Usa ora G) wteafrs are 4) 7yehes set 107. Diketene can be synthesised from (1) Acetaldehyde Q) Acetic acid (3) Acetoacetic ester (4) Acetone secre or teeter feat a wa F - GQ) wiRetargs (2) uaa ore @) wate ger 4) uate 108 If RMgX reacts with CO,, it produces : (1) Acetone 2) Ester (3) Aldehyde (4) Acid af RMgX @ oft®en CO, @ Het F at Te: (1) water i 2) TET G) wetter Gor 109 CHjMet +? ey CH,~ CHO MET Reactant will be (1) Ethyl acetate (2) Ethylene oxide G) HCN (4) CI-NH, CHjMgl+? > cHy- CHO + Mg! eens = Rafer. “Nie arora: em: Q) iar wee @) wengis sifeenss G) HCN . (4) CNH, or2s_Al so IMNOVALNIEK AY Fonte.110 Chlorophyll pigment has the following metal : a) Cu @) Fe G) Mg. @ Li weiriitea Gr 7 fet ng edt b a). Cu @) Fe @) Mg @ Li U1 Acetyl acetone will show : (1) Stereo isomerism 2) Optical isomerism @)Tautomerism (4) Metamerism ufttts cates eater — Q) fier areca Q) weirs wrest G) Sarat @) Fear 112 Which of the following does not have chiral centre 2 (1) 3 - Methyl hexane (2) 2 - Chlorobutane ) 1 - Chloro butane (4) 2 - Butanol fra 8 & Reet feta tex ef a? GQ) 3 - Bra tat 2) 2 - ater @) L- wea @) 2 - Serie 113° Which of the following fact is correct for meso-tartaric acid (1) . Two chiral centres, optically active (2) One chiral centre, optically active (3) Two chiral centres, optically inactive (4) One chiral centre, optically inactive fra FS are cea chet-erite ara & fae wet t ? Q) & fit Se, wenfire afer 2) we fier are, waits afr @G) ot fea &, varie ofa @) we Peet ee, gene sifiea OP25_A] 3tU5 6 OP25_A} 2 TIMEIINIEIM | bo COOH molecule fas following nomenclature of R and $ system (1) 2h, 3R Q) ) 2K, 38 @ COOH HO. jp ay a Ra Ss vafa 4 naw em : H OH cooH ()) 2B BR (2) 28, 38 8) @) 28, 3R Bre vy G=C molecule has following momenclature / \ a 4 (2) & form 2) Z form @} R form (4) S form mm : ys Cay an amare din a’ Nu Q) E mer @) Z yer @) R war (4) § were Which of the following is not correct for fumaric acid ? Q) Cis - form 2) Geometric isomer of maleic acid (3) Dibasie acid (4), Trans form ware oe & fg an wet wae EP ) fae ~ were Q) ates ore a citi aware G) facia ara 4) ERE ware(3) Fischer formula (4) Flying wedge formula 4 H H H H A write a at vat deen ott antl & : (1) Ber waver aa @ vied a G3) Rear aa 4) Fn aa a 18) Starch is (1) Teisaccharide 2) Disaccharide 8) Poiyseecharide (4) Oligosaccharide en () alta Q) stars G) Wee (4) alifinirterrgs 119 Which of the following is a ketohexose ? () Glucose Q) Fructose (3) Osazone A) Starch fer @ viva added & 7? Q) qr (2) ware G3) stars (4) ered 120 If cane sugar is heated above its melting point it gives (1) Molasses 2) Lactose G) Ribose (4 Calamel ae ager a saa aie & Ga wi Pen oe a ora em: (i) arene Q) ae 6) use 4) Saree onss) s IMATE FComea. The above structure of staggered ethane is known as (1) Newman projection formula (2) Sawhorse formula124 122 123 ‘The bond present between the glucose units of cellulose’ is : (Q) a - Glycocidic (2) B - Glycocidic G) © ~ Giycocidie (4) .¥ ~ Glycocidie ample B aate wort & mer whet wa sem t () o - Taga 2) B - Tapas @ o- (4) y= rate ce - Amylose and B - Amylose / Amylopectine are part of the following carbohydrate (1) Sucrose (2) Cellulose (3) Starch (4) Maltose = Wages wear B= cmrectarengcititier fret wrtteege Bi wm F: Q) ate Q) tere , @) ed (4) Breda {D] Glucose =8"*—[D] - Mannose ; above reaction is known as Q) Conversion (3) Epimerisation [D)seas * (1) aR GB) Bar CHs 124 O fo Sete, Q) Wurtz!'s 6G) Clemmensen's CHs 6) 10 £00282 ) ve G) wt OP25_A[ 2) Inversion (4) Mutarotation [P| rie 5 wae afar aeeredt & ~ 2) wea (4) witatigeer ect CHO reaction is known as (2) Btard's (@) Friedel Crafts! CHO. attire art oni & : Q) we @) Wiea-amee 4 IMEBNI TENA fom.1s 2(O1+eu_A$ A*Cula, A will be (1) Benzene @) Cyclohexane @) Biphenyl (Naphthalene 2{O)-1+eu4A A+Culg, A@T: () asi 2) Tree G) aes G@) Aer coOag Br ccl 126 + oo +AQBIY+ CO; 4» above reaction is known as: (1) Rasching (2) Friedel Crafts! (3) Hunsdiecker's method (4) Sandmeyer's COOAg +67, Se, portent (yar Q) Wise — mace G) gesiar Pfr (4) aestay 127 Which of the following is not correct for BHC ? Q) tt acts as insecticide (2) It has 10 stereoisomers (3) ts y isomer has aaaeee configuration (4) It is known as lindane BHC % fay fra & aa wll we et 7 Q) Fe temere % Q) sa lo Biman dae G) gh y waa a aaseee Ree tar & 4) 8 fret & ae SH ord F OP25_Al 8 MILE TIAL tone.128 Which of the following is an enzyme protein ? Q) Albumine (2) Insuline G) Trypsin 4) Myosin fer @ aoa cone eH 7 (wear Q) Far @) Rr @) mie, 129 Proteins give following colour with Nivhydrin test. (1) Yellow (2) Orange (3) Bhe (4) Purple Preis & wer ite ota F Pret tr aa F Q) tet @) aret 3) she 4) art 130. In saponification of oils which of the following can not be produced ? (1) Glycerols Q) Alcohols (G) Esters (4) Aldehydes aati & aptacn Yo an al wt waar & ? a) Peverefer (2) wearer GB) Wet @) aes 131 Solidification of oils can be done by , (1) Oxidation (2) Saponification (3) Hydrogenation (4) Hydrolysis ant ar ae air wre den 8 fea arr e Q) aretecr (2) meter G) aagsrharer G@) Fr set OF25_A 36 COMET ICM, KC omed132 The cause of the denaturing of oils due to air and moisture which produces bad smell is (1) Hardening of oil (2) Rancidity by oxidation (3) Saturation by hydrogen (4) Solidification by reduction et er ag wd ah ara aga Fa a uw gf ia ont arch, gam wet ts Q) tat ar aa on Q) oreftert are tas eT G) weer ara aga aT @) omer aa da er 133 Sodium salt of dodecyl benzene sulphonic acid is known as () Soap Q Paste G) Shampoo (4) Detergent Stenger asta aeetfie oer or aisar cam AT aI F 0) wer @ te @ 4) sree 134 U. V. Spectroscopy is based upon (1) Transition of electron (2) Vibration of electron @) Spin of electron (4) Rotation of electron ULV. Saket orate & Q) wieght & Ga a Q@) wag} a G) wat & wl we @) wit & yA 0725_A] 7 IMLELTOAIM !Coned..135 136 137 Which of the following sequence is correct energetically ? (1) 646% >Ron* on nt>n>o* Q) vo0t >nont anomtooso* GB) 60* >n0* >ramonsrt 4) nont >xon onsotso7ot fer Ya aro wa oot ty wee? () got srt ono Rt>nsot Q) n+0* >not snot oos* QB) 040% sn30* snort one @) nant >noR* >not 350" In bathochromic shift (1) yay Value decreases 2) Aya Value increases max G) Energy increases (4) Frequency increases avi Brame ¥ : (2) Binge HRC TB 2) Age AE eat & ‘max G) wat aad % 4) angha watt & In dilute solution of alcohols, O-H stretching vibrations will be present in the region : (1) 3680-3550 em? (2) 1420 - 1330 om! (3) 2800 - 3000 cm (4) 1260 - 1000 cmt wreieien & aq famat 4, 0-H a ser Pret aa 9 okem ehh: (1) 3680-3550 em! . (2) 1420 = 1330 em! (3) 2800 - 3000 cnr! (4) 1260 - 1000 em! oss Al 38 IMME ome.138 139 140 141 ‘The characteristic peak for C = O stretching vibrations will be present in the region : (1) 1315 - 1280 em! (2) 1440 - 1395 cm! (3) 1720 - 1706 cm! (4) 1620 - 1590 om"! C= Om am Ff mam ait Pre as Food ait: () 1315 - 1280 cnr? (2) 1440 - 1395 cm 3) 1720 - 1706 cm! (4) 1620 - 1590 cnr! N. M. R. spectroscopy is related with (1) Spin of electron (2) Rotation of electron ) Spin of proton (4) Spin of nucleon NM, R, eaheatdy wafers &: () wag & won a @ wat & ga a G) da & wa a @ ape & sor a In 'H NMR spectroscopy the following compound is used as reference ()) DMF (2) CCl, @) TMS (4) Benzene ‘HNMR tagkart 4 fret dite def tq coat & ()) DMF Q) cc G) TMS. 4) air How many peaks will be observed in NMR spectra of CH, -CHBr, and GHy GA, Br Br am 31 @) 21 G) 3,4 4 22 CHS CH. CH,-CHBr, ef? i NMR Beg A we: Rima sink ars a? 31 @ 21 GB) 34 4 242 on25_Al » IRMA, (Come.442 Which of the following is not used as an explosive ? (1) Trinitrotoluene (2) Trinitrobenzene (3) Picric acid (4) Nitrobenzene fer 9 @ fear ore um fetew & wo AF ad fear ona 7 Q) agradecer 2) weds G) Rites oT 4) Teg asi 143 Which of the following is Boyle's law ? 1 re i (2: Tr a a @) Ve i @B) Par (4) PVeRT Prt 9 8 ata a fret = aq ores Q Ver 5) Pat 4) PV«RI @) vy G) PV«RT 144 Which of the following is correct sequence ? GSC > Ooms 2) Cans > Emp >E Gy Cans? > Epp 4) Sug E> Cons Pret 3 atrer we web ? Q) SC? Cig > Cong @ Cong > Srp >E 8) Sins? > Cp (4) Cp > > Cras OP25_Al 0 CARRIAGE Foes...145. Correct van der Waals’ equation for real gas is () pV=nRT e) (p+ge}u-tiear @) pVeaRT 5 (r+ge]e-weer 2 2 6) (+ v—syaane « enw [vet 146 Critical temperature of a gas is (2) TL =3b @) T,=ab/P, @) T,=3b (Ty =ab/P, 147 In law of corresponding, states [rs A ]bo-i-%, Ais (ay na?/v? @ m @) 3797 @® en ara sexe % Pram [eeA,|O-H]=80.9 ae: Oy nef? @) nb GB) 3/67 @ 973 0P25_Al “ MIE); tome.148 149 150 For an ideal gas which of the following is not corect ? ay C,=eHet Q) C,-4E/ at G) Cp=O +R (a) C= aT ¢ oP um orest te tg Per a & aa wat wet 7 a) ¢,=4eeT @Q) C= dE sat GB) Cy= Cyt @) C,.= dT / dP The science which deals with energy associated with chemical and physical changes is called (1) Chemical dynamics (2) Spectroscopy (3) Thermodynamics (4) Electrochemistry ag Ret ot fedt carate sit wifes oftads Sr oat t water e, ame & CU) Tarte wernt 2) Bagterrd GB) ws @® Pegereniat Process in which no heat exchanges between the system and surrounding, is called : (1) Tsobarie (2) fsochorie (3) Adiabatic (4) Isothermal ae vant firey oer cer vftnfides & ser Gon fate ae etm, wean & : C) arene @) ware G) tere @) wren 0725 A] ° MEET NIGAT| &Coned.151 Which of the following is not correct for Joule-Thomson’s experiment ? dE . dH offle Elem o [el@jm © Ble Us amen wir tg Per Fa Sm att wet 7? o [Blo EL -tom 6) [-2:] om @ ( ap \, 182 For exothermic reaction, AH is : (). -Ve @ +e @G) 0 @ + esr afte % fry aH & + () -Ve Q +e GB) 0 @) +1 153. Calorific value of food materials can be known as (1) Heat of formation (2) Heat of neutralisation (3) Heat of combustion (4) Heat absorbed by food sey oad & Sethe ar at oer ore & + (1) axe Gat Q) sere oat G) ww Gat @) Sir ae east oat OP25_A] 43 UNH IT toned.154 Entropy of Universe is = (1) Decreasing always (2) Increasing always (3) First decreases then increases (4) First increases then decreases mene H wah ehh & : . Q) Fen a @) wim sae G) wee om fee mre @ et oar fier aA 158 The working of reffigerator is based upon which of the following laws of thermodynamics 7 (1) Zeroth (2) First G) Second (4) Third Spier an eet Gort & aise Prem ve orenftr B 7 CQ) @) we (3) Reta (4) wre 156 The entropy of all pure crystalline solids may be: taken at absolute zero | temperature (1) Unity (2) Infinite G) Zero : @) =AH We aT TTT ge Preheat A AH Pot & aaa at ae: () gag @) oT G) TF (@) =4H 187 To get | litre of 10% solution of glucose by weight, how much glucose is required ? (1) 10 gm 2) 40 gm 3) 100 gm G80 gm RTE BIT TATA wT 10% wat 1 fete Rar wet wet ty Peat veya vt sreagaaat enh 7 a) to at @ 40 7H @) 100 7H @ 80 mF OP25_A] 44 (ANIL &Coned..158 Osmotic pressure (r} is influenced by the concentration (C) of sugar solution at. constant temperature as follows q@ ret Q aKC @) m=C (4) R=KIC fere ary Fe Tee ae (x) aber Perera area (C) era eT WHE a wnat em? Mee 2) meC GB) m=C @) z=KiC 159 Lowering of vapour pressure of a solution is related with (1) Boyle-van'tt Hoff law (2) Gay Lussac law (3) Henry's law (@ Raoult's law faery a are aa ar wer Pee @ wafer & (aaa Prat Q) Agee ar Fer @) Fat a fen @) we aw Per 160. Freezing point of a solvent will be chaiiged on addition of solute as follows (1) Increases (2) Remains constant G) Decreases (4) Randomly wm Rares a Rais feta & fet we Pret ware aera & Q) are (2) fx teat % G) wr ta = 4) strat ware a opes_A] 4s CNMI ITAM| KComt.161 The relation between degree of dissociation o and i and n is fete GAR oo TH i aon H Rae @ fie inl nal a-l 8) Oo ZW 162 If aA+bB= cC+dD is a general reaction, equilibrium constant is expressed as _ [alle] _ [AF BP a) Ke elf} Q) © [cD > x _Lellel [chr © SFa) [pl OSAP BP af aA+bBe cC+eD we ara afte &, at ure Renia der . _{AlpBl _larer 0 fel @ eer (4) Ko= (cir [oP (al BP OP25_Al ne TIMMUEUNNEN | tome.163 16: z 165 The relation between Kp and K, for a general chemical reaction at equilibrium is: @) Kp=Ke (RT) Q) Kp=K,(RT) @) Ky=K,(R1y" @) K.=K,(R1" Kp a Ky Wee we aera caehe aie a fey erase Ie fot on Q) Kp=Ke(RT)"™ @ «, K,(RT)" @) Ky=k, (RT) (@) Ke=K,(RT}" For reaction C{s)+COo(g) = 2CO (8) if pressure is increased, the reaction (1) remains at equilibrivm (2) moves in the forward direction (B) moves in the reverse direction {4) is not affected ©(5}+COp(g) = 2CO(s) eaftfiven 3 fre aR are wera ong a cifeftraT QQ) we eh @) om fen % ast G) sate fen ¥ ae 4) sora wet The order of Hy +Cly ==? 2HC! reaction is (1) Three Q) Two G) One 4) Zero Hy +Clp 2 2KCl afifear a aie % a) aa Qa 8) OT OP25_Al a CINTA) tone166 167 168 If half fife of a first order chemical reaction is 10 sec, its velocity constant may be : (1) 2.303 sec! 2) 0.693 sec"! G) 0.0693 sec"! 4) 0.2303 sec"! au um wm ate werie aftien a of ong 10 are $ at sua am tacts st (1) 2.303 8-1 Q) 0.693 a! . G) 0.0693 a"! @) 0.2303 a The velocity constant for saponification of methyl acetate may be calculated using following formula : 2.303 a QQ) Kex/t @ Ka log 1, x alin fo =—*_. @ Kayne @ K=alars) Aer wee 3 argon fing Ber Rarer omer ey Pt ga en 2.303 @ Kexit @ K== Slog 1 ¢, x =-In—2 — @) Kane @) Kars) According to collision theory of kinetics 'Z' is (1) Collision number (2) Collision diameter 3) Probability factor (4) Frequency factor aarti & cane fara & ogee Zt 0) war ter Q) eae oe @) wien wee ) srgfr wee OP25_Al 8 IMMUNE AE (oneal. cena ot i en169 im For nA P, if concentration of A increased by twice, the rate of reaction increased by 4 times, order of reaction is Qa @) 2 GB) 3 (4) 0 oAP attra 8 ak A dt treet gph at ont & at ar 4 gH ag caret 3, oftfen ar aife att mod @ 2 gy) 3 ao If one mole of NaC! dissolved in one cubic meter of the solution, its molar conductance is (1) Greater than equivalent conductance (2) Smaller than equivalent: conductance (3) Equal to equivalent conductance ©) infivite ‘aft uae Ble NaCl wt wm ot tex Peer AH frend & at geht ater aera ert: CQ) grains aera @ citer Q) Gee amen & a GQ) qate uae & awa On dilution, the specific conductance and equivalent conductance of KCI changes as fellows respectively = (1) Decreases, decreases (2) Increases, decreases G3) Decreases, increases (4) Increases, increases KC at Sree arreer aer gee aaa ager wart ae Pret were @ was. aRafta eet: () a, ay Q) afte, a 4) afte, arftrer ” THNRRIAITE TIE Come.172 The conductometric titration between strong acid and strong base can be shown by following figure @ |< ® NZ — So g 3 ® § \Z © 3 — va Vv @) Le & iW 173. For a binary electrolyte, degree of ionisation o, is a Ke @) VKIC @) Kc? @) Crk? em fone fags one & fy erat At Hono & M KC @ JRC 8) RIC @ OP25_A] 50. | Conta...174 In Daniell cell if the Ey=Ep+dE the reaction will be O) zn+cu*? + Cut zn? 2) CutZn"? > Za+Cu? @) Zn+Cu? Zn? + Cu (4) Reaction will stop afaw aa FEL =Ep+de a dt afeiisar ait () zn+¢u"? > Cut zn? 2) CutZn*? > Zn4Cu"? G) Zn+Cu = zn? Cu @) atten em amet 175. The potential of standard hydrogen electrode is (when ayy =1) (lt) 0,059] (2) Unity GB) Zero (4) Infinite ree eredoet gdahs om fire hm wah (ayy =) (1) -0.0591. 2) ea @) a @) or 176 Which of the following is calomel electrode (Pel Fe Bet? @) Agis)| AgCi{s)1 CU GB) Hg(s)|He2 Clo{s)| Cr @) Pb (Hg)| Pb’? fea 4 a tesa eagle (CU) Pt| Bet, Bet? 2) Ag(s)| AgCi(s)| Cr GB) Hg(s)| Hep Cly(s)| Cr (4) Pb (Hx)) Po? OP2s_A 5 COMMON Cometa7 178 179 Concentration cell with transference is an example of : (1) Electrode concentration cell (2) Amalgam concentration cell (3) Gas concentration cell (4) Electrolytic concentration cell attrrie aftr ara Ye Fe wer om saeet & () wats wrt oe QQ) sre area Bet G) ta aaa aa 4) wagine wat ta If the concentration of H* has been found out experimentally as 1,0 x 10-7 M at 298K, the value of K, will be : Q@) 1x 107M @ 1* 107M G@) 1 « 10-4 M? (4) 1 1014 M2 298K ye watt art At ot arse ae 1.0% 107 Mowe we aK, oT am em: @ 1« 107M @) 1* 107M @) 1 * 10-4 Me (4) 1 « 1044 MP How many phases are present in the following two mixtures respectively @ [KCM(s)+Naci(s)+Ca(NOs), (3)] Gi) Alloy [Cu+ Sn] Qo out @) 342 @) 34 @) 242 Pre ot feat Hamm: feat seed coker @ @ — [KEI(s)+NaCi(s)+Ca(NOs), (8)] Gi) a ag [Cu+Sr] q@ioit Q) 32 @) aH 4) 242 ons_Al 2 MOUTH, tone.180 Degree of freedom for ice —— water = vapour system at 0.0098°C and 4.58 mm (Hg) pressure will be : a 2 @ 1 GB) oO a) 3 ah = ae = ay dat & fre 0.0008°C ame aan 458mm we eww ea A ate et om aT mM 2 @) 1 GB) 0 @) 3 181 At .03 mm Hg pressure and 95.6°C temperature the following equilibrium will exist for sulphur system : () Sp Sy @) Sp Sy Sy Sy ® SRS, 0.03 mm Ure ze Fa 95.6°C aT Te ReHe aa & fare et eT eT: Q) Sp——=Sy 2) Sp Sp Sy GB) Sp— Sy —=5; A Sp—=S;, 182 Which of the following will be non-variant for CO, system ? (1) Vapour pressure curve (2) Sublimation curve 8) Fusion’ curve Triple point CO, Ha & fre Prt FS aia ore F 7 CG) wer ar ae QQ setae a G) THT am @ Bo fag P25 _A] 8 {O08 | (Conta...183 The composition at Eutectic point of (1) 94.4% Pb and 5.6% Ag Q) 5.6% Pb and 94.4% Ag © 3) 2.4% Ag and 97.6% Pb (4) 97.6% Ag and 2.4% Pb ae-ften da tg wer. wife fg we dae a (1) 94.4% Pb ait 5.6% Ag (2) $.6% Pb sit 94.4% Ag Q) 24% Ag ait 97.6% Pb 4) 97.6% Ag ait 2.4% Pb silver system = 184 Which of the following figures will be obtained for Aniline-Hexane system ? @ —- a @ EX «) Le Which of the following properties is not for colloidal solution ? (1) Electrophoresis Tyndall effect G) 1 +280,° aia, Fee A A a Pert Sreret fier tah ot wart F 7 Q) Fe? amet % Q) Cu? amr @) re? a Cy? Si ot) at orem at 7 Prat we Who developed the. tong form of modem periodic table ? (1) Lothar Meyer Q) Niels Bohr ) Mandeleev @) Moseley anytes oret ante ar ath aa fret Fa feet feesfear fe 2 Q) tere Fez 2) see see G) Ferta @). thet oFzs.Al 86 LRTIUEALERRHIT (Cones...192 193 194 ‘OP2s_A] 87 The carbonate ore of iron and sulphide ore -of copper’ are respectively: * (1) Limonite and Malachite 2) Siderite and Chalcocite (3) Hacmatite and Chaleocite (4) Magnetite and Azurite fer a a che or oie ore ul aie ar aeHeS aE mam: F ()) ferirge a Aare fede 7 areahae @) eee @ ratage 4) Aeene a WE Acetaldehyde and acetone can be distinguished by following test : QQ) Molisch (2) - Bromoform (3) Solubility in water (4) Tollen's wiiedere a uetata wt fer cham are Rie we amd Fe () Tift 2) ahaa G) st F fara @ adr Condition, for the precipitation is (I) Tonic product = Ky, @) tonic product > Ky (3) Tonic product < Kyy (4) Konic product < Ky aad ¥q uittattal & Q) SRR WHET = Ky, Q) orem WET > Ky G) omer [EM < kK, 4) ae WHET < Key195 Solution of pi = 0 is ) Neutral Q) Acidic (3) Basie ‘ (4) Amphoterie pH = 0 a Pret & Q) seer ) air G) ata @) sari 196 Natural gas contains () Methane 2). n-Octane G) Heptane (4) Butane wpe fa ae cd) far Q) naiiaet @ te 4). ae 197 The composition formula of Gypsum is (CaSO, 2) CaSO,-27,0 @) + [CaSO], 220 (4) 2CaSO4-H,0 fram ae duet aa & Q) CaSO, Q) CaS04-24,0 G) [CaSO,],-H20 (A) 2CaSOy-H20 OP25_A] 58 HILUAUULITUL A (Conea...198 Which of the following is not a constituent of RNA ? (i) d-Ribose (2) Phosphate G3) Adenine (4) Pyridine RNA wt oad Prep a Te: Q) d-amata @) Bike @) wife (4) reer 199 Which is most abundant gas in the atmosphere ? (1) Oxygen. @) Helium G) Nitrogen (4) Hydrogen agra # gaits aERad & vg ont arch ta Be (1) sree @ afte G) TRE @) ego 200 Radioactive iodine is being- used to diagnose the following disease of : (1) Bones Q@) Kidneys (3) Blood cancer (4) Thyroid ehates ahd Par FS aes Mr Bt wer FA owt F 7 a) asth & Q) yee G) aS Far 4) ars ors al » iHome.SPACE FOR ROUGH WORK 353 ar & fea we OP25_A] © IIIT ¢Conea.SPACE FOR ROUGH WORK / = are & faa are oP25_Al 6 TANKER ContSPACE FOR ROUGH WORK / aed arm % fe 7 OP25_A} a INIA) tComte-SPACE FOR ROUGH WORK / 33 34 % fea ore OF25_A] 63 TIRENINTTIEINL - KConea.SPACE FOR ROUGH WORK / a4 aH % ford STE OP25_A] “ HINER