ALC GEQO. — 2019 yfcar t gei at der: 24 ‘Number of Pages in Booklet : 24 2120 120 Paper Code : 16 Sub: CHEMISTRY 3.00 THE ‘Time : 3.00 Hours Paper - II seer yer ion! Question Paper Booklet No. Gomade- 24.00.01 7198893 aaftrenerst sia : 200 Maximum Marks : 200 pees Yr sees | doe vets ar wt ata we wheal ae Bis we Sf ae seme ARIE ae Tene QR a sites tat aww ais BL ye GH feet A at tere vies gam wana wet SCS | ten BARRA we A Aree sree A ahh | On opening the paper seal/polythene bag of the Question Paper Booklet the candidate should ensure that Question Paper Booklet No. of the Question Paper Booklet and Answer Sheet must be same. If | there is any difference, candidate must obtain another Question Paper Booklet from Invigilator. | Candidate himself shall be responsible for ensuring this. Cc wiataal & fae FT awit ae aoe die wh wet & oie war E pees mer an dearer wes at sat Sta | ee 3 afew sae 88 a en er sae eT eT (after oar wa & | and a eel are Roe we aor we eer ae aT Bae Go it et vag ta & oa eT | 6. ON seer ie er see a | aT sedan ference Sh AT AG ah soe ree we seca 3 Sear oe ale wife Fer = | as er ee et 1/3 TET ATT TET Spar Saver Srp et aver fd ot aes oes he See AE fd er & elon a ae wa oT sree 5 AT AT ST | 8. shee keer wens on re nan ert afm & | ae feat mer ore teh até fie aT fect & ot seis free a ar Praargare eh ori a. ager sro hr ae he ae ee IT Se rere moe anh ae sere eT eS Se op oT Qatar amt t so. af Fe er fare ig sg eam ae ot eA oe a feet wen ash eel Sth eo #1 eral are one soo aa a at at Ta TE atte agin ave ok mr, oh se ote & fae es A se oh eet Ee fe Fst aw sea re at wh far et eel os Bw Tt Pe sh ves ia & Far eT TNSTRUCTIONSFORCANDIDATES ‘Ansar all questions. ‘All questions carry equal marks. Only one answer i 10 be given for each question more than one answers are marked, it vould be treated as swronganser. 5. Each question has four altemative responses marked serially as 1,2, 3, 4 You have to darken only one circle or bubble indicating the cometanswer onthe Answer Sheetusing BLUE, BALLPOINT PEN. 6. The OMR Answer Sheet is inside this Test Booklet. When you are directed to open the Test Booklet, take out the “Answer Sheet and fil inthe particulars carefully with blue ball point pen only 113 part of the mark(s) of each question will be deducted for each wrong answer. A wrong answer means an incorrest answer of more than one answers for any ‘question. Leaving all the relevant circles or bubbles of any {Question blanc wil not he considered as wrong answer. 8. Mobile Phone or any other electronic gadget in the ‘examination falls strictly prohibited. A candidate found ‘with any of such objectionable material with hier will be sively dealt as per rules. 9. Please corteetly fll your Roll Number in O.M.R. Sheet, § Marks can be deducted for filling weong or incomplete Roll, Number, 10, 1fthere is any sort of ambiguityfmistake ether of printing oF Factual nature then out of Hindi and English Version ofthe ‘question the English Version will be teated as standard ‘Warning : Ifa candidate is found copying or ifany unauthorized materia is found in hisiher possession, F.LR. would be lodes gains invierin the Police Station and heshe woul Table tobe rosesuted. Department may also debar himiher permanently nv all ture examinations, —— ~~ Faalaguaralaaws tatiaa ee heen Do not open this Test Booklet 16-c0 IHNWS Flat [Co(NH,), Cl] Cart anftree H AgNO, & saafta Agci % Ate =A rene ao Qt (3) 2 (4) 3 Frafetan 8 sm ar gm cece 8? (1) XeF,, IC, (2) NHy BF, @) PClyICls (4) SOF,COR | ‘orgattaetiors & ce a srace ee | () Fe wR area a | (2) Beem strata wae | @) we yas a es dive ora fergret ara ere fea ra 2 | G@) 3 ory sae F of ah eeagis 3 Sa GAIRR Bia B | freafafer ae a dea sofia race wei se cat 7 \ (1) [PU(NHS),C/,] | (2) [Ni(CO),] (3) [Co(NH,),(NO,),) | (4) [CoCI,(en),] | [PUNH,),J [PtC/,] 1 et TUPAC ATA i (1) Matera (1) taster ay (2) Sgneierstfenm (1p tgrachtteraeie i a ' (3) Sartehreeas (1 Rgractirafear cay | (4) artehreatee (1p egracireaPee (11) ffearar site fratited Ree ug | sommes attire 8 2 (1) Ru (2) Rh @) Pa (4) Pt The number of moles of AgCl precipitated by 1 mole of {Co(NH,), C1,]C/ with excess AgNO, is a) 0 Q) 1 GB) 2 @) 3 Which of the following pair is isostructural ? (1) XeF,, IC (3) PCI,, ICI, (2) NH,, BF, (4) SO}, co} The — incorrect dioxygen is (1) itisa biradical. (2) its bond order is two. (3) its magnetic character has been explained by valency bond theory. (4) its molecular orbital has two last electrons with parallel spins. statement about Which of the following complex does not show geometric isomerism ? (1) [PUNH,),Ci,] (2) [Ni(CO),] (3) [Co(NH,),(NO,)3] (4) [CoCt,(en),] The correct TUPAC name of, [PUNH,),] [PtC/,] is (1) Tetramine platinate (II) Tetrachloro platinum (ID). Tetramine platinum (II) Tetrachlorido platinate (II). Tetramine platinum (II) Tetrachloro platinum (ID. Tetramine platinate (II) Tetrachloro platinate (II). Wilkinson catalyst is a co-ordination compound of which of the following Q) G 4) metal ? () Ru (2) Rh (@) Pa (4) Pt16 Frafefiaa 48 ats ar erat sae Haile 3 far aeias ot eel ea 8? (1) Mn (2) Mo (3) Mg @ w arene HFA [Co(NH,),Bry]C/ FF ‘ft panera cater & 2 (1) eh Gy IPL (2) ae Satta 3) sanftta Gam Sar (4) tare serrata ae a, St teenie el 8 Q) wafer Q) afer @) ahaa ) ehar frafeifiad # & aia ar eget sega ‘BraER watfad & 7 (1) [CoFg 2) [Co(NH,)}** (3) INICN),P A) [Co(C,0,)5]*° wa Hiefirae BetAMEATSS K,,[Fe(CN),] firm FeCl, % Bra aad ar @ at re an firm agp aH HAM STATz 7 (1) Fey [Fe(CN) ]5 (2) Fel! [Fe!" (CN),J- (3) Fel! [Fell (CN)] (4) Fell [Fell (CN)¢]*° ariferted arg 8 a ar settee Wi +4 sriaefianer araen weft seat & St Re we aren ayellites satires 2 2 () Eu (2) Ce @) Yb (4) Na RNA tay DNA Peta omy €, HH free Raa a: (1) Larat saat (2) fate ant (@) Pte wide weCeHTEAT (4) Dearest “AWhich of the following act as promoter for iron in Haber’s process ? () Ma @) Mo @) Me aw Octahedral complex (Co(NH,),Brj]Cl exhibit which kind of isomerism ? (1). Linkage and ionisation (2) Geometrical only (3) Geometrical and ionisation (4) Optical only An element, which is not an actinide, is (1) Actinium (2) Thorium (3) Uranium (4) Neptunium ‘The complex showing paramagnetic behaviour is Q) [Cor (3) [Ni(CN),F (2) [Co(NH,).F* (4) [Co(C,0,)57° When potassium —_ferrocyanide K,[Fe(CN)q] is treated with FeCl, blue colour is obtained due to the formation of (1) Fey [Fe(CN)g]; (2) Fell [Fell (CN), (3). Fell! [Fel (CN)¢) (4) Fell [Fell (CN),I* Which of the following lanthanides exhibits a well known ‘4 oxidation state, which is a good analytical reagent ? (1) Ew Q) Ce 3) Yb (a) Nd RNA and DNA are chiral molecules, the Chirality in.them is due to (1) L-sugar component (2) Chiral bases (3) Chiral phosphate ester units (4) D-sugar componentFrafefiad 4 a ata ar fee area wae aaa 7 (1) CgHsCH,CH-COOH N=CH, (2) (CH,),.-CH- CH, -CooH | CH; (3) CH,CH,CH —COOH NH, (4) CHa -c- CHO 9 Tapeta t rafeifiga 3 area mf a Sitesi ara & () Wifes sme 4 Re aegistia ar onftrer 2) antes tania a G) Tg aevie ae (4) aes aftrenhs o-D —7ERB Way B-D — TESS A a ‘Bear ar Faire yea (1) +19° @) +12 3) +112° 4) 452.78 rehire tel amet 3 orf ae (1) fee 2) atietia @) TR (4) Feta stch@ Gt 9a arg HNO, & arr mf woe 8, ah ten 1 ore den, ga adie wae et (1) Farerefipa ater (2) Seisifees wearer (3) argate wdieror (4) Frere veer Which of the following can exist as a Zwitter ion ? (1) CgHsCH,CH-COOH N=CH, (2) (CH), CH— CH,~COOH /CH, SCH; @ CHCH,CH coon NH, a) fe ~¢-CH)-C- On 3 N I cHo ? Osazone is formed when glucose is heated with (1) Excess phenyl hydrazine in acetic acid. (2) Excess Bromine water. ) Concentrated sulphuric acid, (4) Tollen’s reagent, The specific rotation of equilibrium mixture of a-D — glucose and f-D- glucose is (1) 19° (3) +112° Which of the following amino acids is not essential ? (1). Tryptophan (3) Lysine Proteins when heated with conc. HNO; give yellow colour, the test is called (1) Ninhyarin test (2) Xanthoproteie test 3) Biuret test (4) Millon’s test (2) +111° (4). +52.79 2) Tyrosine (4) Valine20. a, 2. 23. rete way Petia S ' wie Q2) SretaESH (3) Feed (4) Be Prafatea fra aftreds & afiier, eget i afer ays A GPE UR? (1) HI (2) NH,OH (3) whfes tregre (4) H,0 ae pH fre wad ary we eT ROT rrae TEi TES Q) Bafana fg (2) sareistenet pH (3) atefa pH (4) afta pH antifertigg sta (i) Fetter Gi) Heifer Gi) ARR Gv) attra ‘rife star 8 - a) @aKGi) Gi) BR Aiv) B) Maki) Gated) sagetion arti & tee sree Hertz (1) geies ort we Fa-ageia — aera archer at fee BATS | (2) a ae wa we wiehe TAR GMT afta a8 8 1 (3) RNA @ va-aqedia — ae FT Dargata aft @ | (4) DNA sta are ea & 1 2. Glucose and mannose are (2) Diasaccharides (4). Anomers (1) Epimers (3) Ketohexoses Reaction with which of the following reagents indicate the presence of carbonyl group in glucose ? a) HI (2) NH,OH (3) Acetic anhydride (4) H,0 The pH at which there is no net charge on the protein molecules is, (1) Isoelectric point (2) Neutrilization pH (3) Acidic pH (4) Basic pH ‘Among the proteins, @. Keratin Gi) Myosin (iv) Albumins the globular proteins are () @andGi) —@) Gi) and (iv) (3) @and(iv) (4) Gi) and (iv) (ii) Insulin Regarding nucleic acids false statement is (1) Nucleic acids are chains of five- membered-ring sugars. (2) These ring-sugars are linked by a phosphate group. In RNA, the five-membered-ring sugar is D-ribose. @) @ ‘There are five bases in DNA.24. 25, 26. 21. 28. Fraferaa 4 & ata ar tities attra S | 240 wee? a a) Q) @) aA 4 C3 Ten- dam afiien | Pitta 2 () earditen arm qereadt Q) ards Herat Q) art ead G) BH tera eee % fremngan tenia § ngtaehit i ter er () 10 Q) 12 @) 14 (4) 20 eh scaler Prafatac ta fea aren simmer aT 7 ‘OH ci oO" o& CH; @) (oY @ oO Prafetar Ft ama weft ar adh mr aha: NH (1) OH® > CH, = CH®> CH =C?> CHP (2) OH®> CH= C®> C)Hs°> CH, = cue (3) CH= C*> C,H,°> CH, = CHE> one (4). CyHs®> CH = CH®> CH = C°> on? i i | | | | | i | | | | | | | | { | | i | | i ! | | | | | i | | j | | | | | | 28, 26. 27. 28, Which “of ‘the following is not an Reimer ~ Tiemann reaction involves a (1) Carbonium ion intermediate, (2) Carbanion intermediate. (3) Carbene intermediate. (4) Free radical intermediate. According to Huckel’s rule, number of m-electrons in Anthracene () 10 @) 12 @) 14 (4) 20 Which one of the following will be easily attacked by an electrophile ? ear oO CH; @) (4) Select the correct order of basic nature of the following : (ql) OH® > CH, = CH® > CH =Co> CHS OH® > CH = C®> C,H,°> CH, cH CH = C°> C)H,°> CH, = CH®> ou? C)H,°> CH, = ous Q) 3) @ CH®> CH= C°> 1629. 30. 31. 32. 33. 16 fated fra sera ar1.ter = : daitatfienn Bian 2 ? (1) BR A @) =a Q) srr (4) are we weirs airs fare Uns fierce fees grr wera: Bae (1) farmer hehe (fee) (2) Rates sere (3) Ferra er aR (4) AE seg ae TT frafataa gaa qeei #8 Sh aT waits eg 2? ge (1) CH,-CH-CH-CH, (2) CH,-CH,-CH-CH; ga oe (3) CH, -CH- CH-CH-CH, CH, Oy CH,-CH-CH-CH,CHy frafatta 3 8 ata a cage Ae a? (1) BF; (3) (CH);N @) No, @ & Preferfiaa stftafiran aor yet STE 2 : CH,—CH,—CH,-CH-CH, o>? Br (1) CH, ~CH~CH,~ CH ~ CH, OH (2) CH,-CH,- CH, - CH=CH, (3) CH ~ CH, ~ CH, -CH,~ CH,OH (4) CH,-CH,- CH=CH -CH, 29. 30. 32. 33. of alkane of the Halogenation through which intermediate ? (1) Free radical (3) Carbanion proceeds following (2) Carbocation (4) Carbene Unimolecular nucleophilic substitution of optically active substrate mainly gives (1) Retention of configuration (2) Racemic product (3) Inversion of configuration (4) No product is formed Which free radical from the following is most stable ? os (1) CH,-CH-CH~CH, (2) CH,-CH,~ CH=CH, Gis gs (3) CH,-CH-CH-CH-CH, cH, Lae (4) CH, - CH- CH-CH,CH3, Which of the following is not an electrophile ? () BF; (3) (CH; 2) No, @ & ‘The major product of the following reaction is Alcoholic CH, -CH,~CH,—CH-CH, 5g? = i KOH Br (1) CH, ~CH,~CH,-CH~CH, OH (2) CH,-CH,-CH, ~ CH=CH, (3) CH,-CH,~CH, ~CH,~ CH,OH (4) CH, -CH,-CH=CH-CH, a34, 35, 36. 37. 38, Froferara a a1 ser $1 safe fara area 8? () FHI (ee Fe) aaa efi ae semana en | (2) afer a ar Ueret tongs rer safe eri A sizer a fase me | @) 3° Yera tes dat & sy afta 2a 8 1 @) Syl afer ere: Sifees Facrrereri Hee at 1 Syl sfiBear % fore Patter # a ah a waite Brest 2 (1) CgHsCH(CH,) Br (2) CgHsC (CH) (CH) Br (3) CgHjCH (C,H) Br @) C,H,CH, Br “Towett” A aR & fara a fea srere re fen 7 (1) Strate; state (2) orrtfires ferro (3) Traine Rarer (4) Taira: saftrsiteo srgetia oer ae She (1) Uistarghre ager (2) Tieitergs agers (3) dietierer age (4) Sisteengeta agers frefefirr # @ ata at cafteran resin waif: chage & qa aa were ? (1) Apay = 260-nm (2) Rigg = 680 nm (3) Amex = 486 nm (4) 2... = 540 nm. f 34, 35, 36. 37. 38. Which’ of the following statement is incorreet for Sy.1 reaction ? (1) Step = I is the slowest and reversible, (2) The rate of reaction depends on concentration of both alkyl halide and nucleophile. 3° alkyl halide undergoes Sy reaction very fast, @) (4) Syl reactions are generally carried out in polar protic solvents. Which one of the following is most reactive for Syl reaction ? (1) CgHsCH(CH,) Br (2) CoHsC (CH) (C,H) Br (3) CH CH (CH) Br (4) CoHsCH, Br Chromatography principle was proposed by ‘Tswett” on the basis of (1) Relative absorption (2) Relative distribution (3) Relative diffusion (4) Relative adsorption Nylon threads are made up of (1) Polyvinyl polymer (2) Polyamide polymer (3) Polyester polymer (4) Polyethylene polymer Which of the following absorption maxima is not in the visible region of the electronic spectrum ? CD Agpax = 260M (2) Aggy = 680 nm 8) Ayan = 486 nm (4) Aggy = $40 nm 1639. AL. 42. 4B. 45. no at ath x* Samm wefifa we | aren aT e (1) Agee ! Os 1 (3) fecha | (4) eat | wie & NMR eaga 4 ferret Fr eon a | ag 1 (2) 3 | @) 4 (4) 2 ! ‘eater are ar, Te AT: | | (1) 313 nm 2) 303 nm ! @) 293nm (4) 273 nm 12 seachdbita grea a2 ae | NMR ferret t seen 2 | a 3 @4 | GB) 5 a 6 | api ea a resitthiga agers 2 (1) atateiet (2) eae | (3) siete (4) Ranta i IR Baga Hi fioreite a =A Te ehh - (1) 3000-2000 em? (2) 1500-500 em-! (3), 4000 - 3000 em! | (4) 3000-1000 cm"! Hreropreft wtestiary 2 (1) weit Prier (2) ebeiareter (3) sieciteenfer (4) egrergacia 41. 42, 45. Chromophore showing both x — and n> n* transition is (1) Nitrite (2) Conjugated diene (3) Acetylenes (4) Ethylenes Number of signals in NMR spectra of Ethanol will be qt @) 4 @ 3 @) 2 Calculate 2,44 for following compound (1) 313 nm 3) 293 nm 2) 303 nm (4) 273 nm The number of NMR signals produced by 1, 2-Dichloropropane are a) 3 Q) 4 @) 5 (4) 6 Which one of the following is fully fluorinated polymer ? (1) Thiokol 2) Teflon (3) Pvc (4) Neoprene The range of the fingerprint region in the IR spectrum is (1) 3000-2000 em” (2) 1500-500 em (3) 4000-3000 em (4) 3000-1000 em Bactericidal antibiotic is (1) Chloramphenicol (2) Erythromycin 3) Ofloxacin (4) Tetracycline46. 47. 48. 49. 50, frafeied 4 8 ala aft ongftr Wifes, ae HC —He dea ate aa araritoor at safifa sae 8 2 (1) 650-900 cm"! (2) 3000 ~ 3100 em (3) 1500 ~ 1600 em (4) 1000-1100 em frafafad 4 8 fra aged & ‘Frain waren Sara 2? (Q) 1, 3-0qgreré (2) 2-9 -1,3-=ygTErs 3) Gaigeirsieet (4) 2-1, 3-2grEr amare ta 4 rat en HCI eR sre wait amr Fo aegis sre APE O.01 mol/L & | STARE Te =A pH eft — qi 2) 0.01 (3) 2 @ 14 farafafisn orl ft affiBreratt @ Be, en at 2 St te a Fogg te at Fey ES FO771V Za ayy t 26° Zig, B= 0.76 V (1) 00LV Q) 1.53V G) -1.53V (4) 230V ad del Bea a ari} are we (A) ASAT +6 ERs =- 0.56 V (B) BBY +e Egjge= + 0.562 V adi sat 1 AR Q) (A) 3h &) Set A eae: Bier (2) (A)shk (B) errr era: Seas G) (A) Fe: Beer arg (B) AE | (4) (A) Bet Sita a & Bier (By ea: ARTE 47. 48. 49, 50, Which of the following frequency shows C ~ H out of plane bending absorption for aromatic ring ? (1) 650-900 em=! (2) 3000-3100 er (3) 1500-1600 em (4) 1000-1100 em Neoprene is prepared by polymerisation of which of the following ? (1) 1, 3-butadiene (2) 2-chloro-1,3-butadiene (3) Acrylonitrile (4) 2-methyl-1,3-butadiene ‘The hydrogen ion concentration in our stomach due to abundant HCY present in gastric juice is 0.01 moV/L. The pH of gastric juice is ai @) 2 2) 0.01 (4) 14 What will be £2 1 from following half cell reactions ? FeH gy tO Fe gg B= 40.77 V Zi?" gq) + 20“ > Zr) E°=-0.76 V Q) 00LV Q) 133V @) -153V (4) 230V Based on following two values : (A) AAT +e B+ =-0.56V (B) Bo BY +e", Eggs = +0.562.V Based on E° for two half cells, select the correct answer, (1) (A) and (B) are spontaneous, (2) None of (A) and (B) is spontaneous. (3) (A) is spontaneous, (B) is not. (4) (A) is non-spontaneous but (B) is spontaneous. 1651. 52. 54, 16 wa 1 oad faga oars vat facet @ I ae a Aaa AA aT HH ar Reet SPT (RAT A 63.5) ? () 65g @) 127g (2) 31.758 @ le a - Aiea NSjexcoone ~ 224 ohm! emg ex acy = 38:2 ohn 2 y= 203.0 ohm! em?g eq? (1) 39.5 oho! em?g eq”! (2) 288.5 ohm! em?g eq (3) 289.5 ohm”! cm?g eq”! (4) 388.8 ohm! cm?g eq! 4 omg eq?! ag da ofthat AB aq) + © > ABS & fae acragte fava RT (1) B=Eggtig tp TAB) RT Q) E=Eggtigg — FAST RT B) E=Enggting pio [Ag'? 1 TAg"] (4) E=Eqgiy, aifefza deine ecegiel # Peer Q) 40M KCI acta (3) 2.0M KCI eet 4) 0.1 M KCI Seite a 52. 53. 54, What weight of copper (At. mass deposits when | Faraday of electricity is passed through cupric salt solution ? () 65g @ 375g @) 127g @) Ve Calculate the value of icuz,coon if 2, xcn,coone = 224 ohn Yemgedr! 2S oj = 38.2 ohmlem*g eq! 92 HCI 203.0 ohm-'em?g eq! (1) 59.5 ohmem?g equ! (2). 288.5 ohm-!em?g eq! (3) 289.5 ohm!em?g eq! (4) 388.8 ohm-'cm?g eq? ‘The electrode potential for the half cell reaction AB ag t © Ages RT - () E=Eggtiag tp mae] RT 2) EWE ggg ~ pn Agt) RT 2 @) E=Eqstag— FAS? RT 1 @) E=Engtag + F Tag Among the following Calomal electrodes, the standard electrode potential of which electrode would be highest ? (1) Sat. Calomel (2) 4.0M KCI calomal (3) 2.0M KCI calomal (4) 0.1 MKCIcalomal55. 56. 57. 58. Frofefera 8 8 ata an sacri ora am atg 217, a 3 Za |Z =—0.7625 C43, | Cri =-0.740 2H aq] Hyp) = 0.00; Fe3* | Fey = 0.770 () 2% Q) Cre (3) Hyg) (4) Feo) Wa oma Al og a wit ache ‘Facer i gain sar 8, at ait Reenter a ae FH vs RK Aafia a aa e wie (2) Fy was Fe < Cu 2) Oi aT Hae srs Pers get asm | 3) IR BAe srr ra sre aare! 4) sae aan FH facta sat aa A afm 21 25 °C Howe gat fagn—smeed 4% feiss Bt APT (a) 2 x 10% | af SHAT AS 500 x 10+ Sm? mol"! 3 wa ‘seebt aier area ara At | (1) 10°” Sm? mol (2) 10° Sm? mol! (3) 10° Sm? mot! (4) 104 Sm? mor are gage faye way arene ferte arated 2 Ely Tasp le K, ° _ 0.059 Q) Eat =n log K, (3) Ey = 0.059 n log K, o _logk, @) Fenn 2 55, 56, 58. Which out of the following is strongest reducing agent if 17, = CFT Cem Bn | 2g = 0.762; Cx, | Cry =—0.740 PH oa] Hayy = 0.00; Fe, | Fez! = 0.70 ‘oa | Fea) (Zn 2) Cry, GB) Hyg (4) Fe (aa) When Iron rod is dipped in copper sulphate solution, copper is displaced and it gets deposited on Iron rod because (1) Atomic number of Fe < Cu (2) The standard reduction potential of copper is more than iron. The standard reduction potential of copper is less than iron. The iron salt has more solubility than copper salt. AL25 °C, the degree of dissociation («) of a weak electrolyte is 2 x 10% Calculate the molar conductance if its A; is $00 x 10 Sm? mol! (1) 107 Sm? mor! (2) 10° Sm? mol! (3) 10-8 sm? mor! (4) 104 Sm? mor Standard electrode potential and equilibrium constant are related as. ° mn (Ese = 0.055 198 Ke 2 _ 0.059 @) Fein oe K, (3) Bf.y = 0.059 n log K, (4) Bg 1639, 60. 61. 62. 63, 16 ofS dg Fer =r EMF eT Pr/Ha(P IH" gayll Ha(P,)IPE R; Fi a) Sr ing Q Spine P, @) ring? @) SHAR aE rater He Parl deh weet 8 2 G ga a de seen A aha aa’ | um Greets dla or aT OK a 11S K TH aS STAT | 2NaHCOy, > NajCOy) + COs) + Hg) Hyg) > 2g) a) @) (3) @ Fe are St otiar wae a ened rel aT () Fevers a send A siften see Q) 7H Q) wea sae (4) fat fiat gro ste gene wer eet after : 2A + B > 0, & fea AH = 100 kJ mot! 3% AS = 0.05 kJ k mol !@ | 4g Aa ga f% AH UE AS & aR aR Pale gi wa @ a fee am 7 7e after arearaeen B aft 2 (1) 2000K (2) 500K @) 5K (4) 100K srebfefan ari a farrest ahara ater arereran Bates Si 2 (1) Na* (2) Lit (3) OH @) cr 59, The EMF of the cell given below PUHG(P, IH gl Ha(P)IPt ar Pt Rr Py © Pap) oping P. (3) Bing (4) None of these In which of the following the entropy decreases : (1) A liquid crystallizes into a solid. (2) Temperature of a crystalline solid is raised from 0K to 15 K. 2NaHCO,,, > NaCOyy + CO) * 130%) Hag) > Hi @) 4 The factor that does not influence the enthalpy of reaction is (1). The physical state of reactants and products. ‘The temperature. The pressure or volume, The method by which the final products are obtained. Q) G) @ For the reaction : 2A + B > C, AH = 100 kJ mot! and AS = 0.05 kJ k-tmol-!, Assuming AH and AS to be constant over the temperature range, the temperature at which the reaction would be at equilibrium is (1) 2000K 2) 500K @) 5K (4) 100K Among the following i s, the highest limiting molar conductivity is of (1) Nat @ Lit @) ON @ cr65. 66. 61. 68. Peal gered aor ater Preis Tere A ric wer 2 () waraead (2) sania: (3) Bae Brae G) Werte AG? (KJ mol} & fa 7 ara & sree wUugetiea fs aad se arr feria aT ar five Fra ar 7 . (1) AG?=-100 @) AG?=-50 G) Ace (4) AG°=+100 HPMB EA 2 Chyy > Claygy FAG AH AS % fare @ (1) Oat arorerr Q) dat ere (3) AH Rares Sik AS eTETH (4) AH Sates oi AS aa fefeter saree afeot a aafia A faa Ged th: AH =~3267.7 kJ Gi) Cig) + Ogg) F COs AH= -393.5k Git) Hayy) + 4 Orig) > H20 ps AH =~ 286.2 (1) 481k (2) -48.1 kT (3) 2588 kJ (4) -2588 kt we oftfren ar fee aa, AH FT ama & ara viata frafefied Fa fara ara 2 7 () ac, @) AG 2) AU (4) Ac, As + J Ong) > 6 COrg) + 4 The molar extinction coefficient of a substance depends upon (1) path length (2) absorbance (3) its concentration (4) wavelength Based on the values of AG® (in KJ mol"), identify the system with highest value of equilibrium constant. (1) 4G?=-100 @) AG @) 4G For the reaction 2 Clg) > Clay the signs of AH and AS are (1) Both negative (2) Both positive (3) AH negative and AS posi (4) AH positive and AS negative From the following thermochemical equations, the enthalpy of formation of benzene will be : 15 Cog + J Once) F © COr@ * 31,0, MH = - 3267.7 1d GI) Cy + Ong) + COrg AH= -393.5k) Gil) Hyg) + 4 Ong) > H20 95 AH =~ 286.2 ks (1) 48.1kI (2) -48.1K0 3) 2588 KI (4) -2588 Kd ‘The variation of AH of a reaction with temperature at constant pressure is equal to which of the following ? Q) ac, (2) AU @) AG (4) acy 1669, 10. n, 2. 7B. 16 aHftfarar Ag,O > 2Ag + % O, & few | 69,. AG for the reaction feet Pfft ay 4% AG & aR 10.0 kJ mol, 38 aa oe Prafeticn Hae oe were? () fara otfeargs Rrafea dene fireae way atatisa tar 2 2) fie a aiedise fhe free wiaargs @4 € 1 3) often areraear 8 8 | @) afifeen act or fear # on gach 2,3 Goes fem a amt? Prefered 4 @ fareeht mrt ter tet (AgH®) 298 K 4 Bet HEEB 2 (1) Bragg 2) Bray 3) Cage) @) Clay Th yam & vaty uRfeaea F a a fora adh Fearfer 8 () AT=0 (2) ap=0 GB) 4 Gy w=0 frafefad i @ fea acta fee a fei farg frac em 2 (1) O.1mBaCh, (2) 0.1 mare (3) O.lmNaCr (4) 0.1 mB FeCl; F4 K,[Fe(CN),] & Beat aa & a fen a1 ser em @ | aA 0.01 M FeCl, WH 0.1 M K,[Fe(CN),] #1 aaron fareehl gra ae few Rega yer fen sre A | B 01M !' 001M Fels Ka[Fe(CN)e] | SPM ister 1 sera eo a) Aw Q) BH G) ei Aaa (4) TAGaaBA 15 70. n n. 73. AgO + 2Ag + % O, at a certain temperature is found to be -10.0 kJ mol"! Which one of the following statement is correct at this temperature? (1) Silver oxide decomposes to give silver and oxygen. (2) Silver and oxygen combine to form silver oxid (3) The reaction is in equilibrium, (4) The reaction can neither occur in the forward direction nor in the backward direction, Standard molar enthalpies of formation (A,H®) at 298 K for which of the following is not zero? (1) Bray 2) Bryy, @) Cgrapriey (4) Clay) For the process to occur under adiabatic conditions, the correct, condition is () aT (2) Ap=0 @) 4 (4) w=0 Which of the following aqueous solution have the lowest freezing point ? (1) O.1mBaCr, (2) 0.1 m Sucrose G) 0.1mNaC/ (4) 0.1 m Glucose FeCl, when reacts with K,[Fe(CN),] produce blue colouration. If 0.01 M FeCl, and 0.1 M K,{Fe(CN),] are separated by a semipermeable membrane as shown in figure A | B oiM | 001M KaFe(CN)g| | FeCl SPM the blue colour will be developed (1) Ina Q) InB (G3) Botha &B (4) Neither in A nor in B14. B. 16. 71. 8. frafefisa 4 & fara free on fear aH 8? () 0.1MK,Cr,0, 2) 0.1 MNH,CI 3) 0.1M AL{SO,); (4) 0.1M BaSO, wa tafe wt action # Preven rat 8 at aS nea aegh we aaa 2, dt uRurefi fae feerer (1) Use ® fae 8 sores fart (2) Tae Fam @ ares fra (3) sees fan 3 ae freer aa (4) arama Fatt at af NOB rig, % Fraion = farenate ® NO + Brag) + NOBryg) RDS. NOBry9,+ NO) PSs 2NOB rig) NO gy 3 Bee SARE AY aI eh @ 0 a 3 @) 1 (4) 2 w ye wie an feria a fafefad ‘Ses GAT TAT STAT (1) Lmor QQ) Lot's! @) Lt @ L' mols! mol" em aie Al often, & fare 99.9% after yl a8 =r ar 50% yi aA or era aT e 7 () 50% @) Sa 2) log (4) 2.5 aT | 74. Which one of the following solutions have lowest freezing point ? (1) 0.1MK,Cr,0, (2) 0.1MNH,CI (3) 0.1M AL(SO.), (4) 0.1M BasO, When acetone is added to chloroform, hydrogen bond is formed between them, resultant solution show (1) Negative deviation from Raoult’s Law. Positive deviation from Raoult’s Law. Q (3) No deviation from Raoult’s Law. @ ‘Volume shows slight increase. The mechanism for the formation of NOBrig) is NO + Bryg) > NOBr a9) RDS NOBry9)+ NOgy— > 2NOBrig) Find the order of reaction with respect to NOw) a 3 Qo Qi (4) 2 The zero order fate constant is expressed by the unit (1) Lmort (2) Lmor!s! (3). L7 mor" (4) L mols For the first order reaction, the time required for 99.9% completion of reaction is how many times that required for 50% completion ? (1) 50 times (2) 10times (3) Stimes (4) 2.5 times 1679. 80. 81. 82. 83. 16 feet often 3 trom A ones ‘Riga TT aH SAAT at, BTA Brome’ | safer ahi AR ae ar? (1) 3 (2) 2 @) 1 4) 0 we free 4 dit am A, Baik C, wea 0.2 He @ aa ses ther isthe ae (1) 0.2 (2) 0.6 @) 1 @3 al — 1 aah — 11 ht aera wa ai A fea ats & agen adi am wid @f-i as A BC a1 2 3 Q@2 3 4 1 @3 4 1 2 @4 1 3 2 often: A+B sera A semi 3% sta 8 aaiftra an artes art a a: [A].M_[B],M__ Rate [Ms] 01 0.2 4x10 0.2 0. af sitiiea aa Fem: a1 = k (Api, (By? I TER ae a, at wa aR (ny +n) UT ST (2 @) 3 @)1 a4 mrciset fara ¥ alee ait ar TERE () Inmaaa Q) 13 1000nm (3) 10¢nm@ 10° nm (4) 10°nm | | i ” 79, The ty, of a reaction is doubled as the ai concentration of the reactant is doubled. What is the order of the reaction ? () 3 (@) 2 GB) 1 (4) 0 A solution contains three components A, B and C, 0.2 mole each, then the sum of their mole fraction is (1) 02 Q) 0.6 @B1 (4) 3 Match List — I and List — II and select the correct answer using the codes given below List -1 List - 1 A. Aerosol 1. Butter B. Gel 2. Froth C. Emulsion 3. Milk D. Foam 4. Fog Codes : A BC D Mto2 3 4 @2 3 4 1 B34 1 2 @4 1 3 2 The rate data for the Kinetics of the reaction A + B -> products are assembled in table : [A].M_[B],M__ Rate [Ms] 0.1 0.2 4x10 0.2 04 3.2 x 107 If the reaction be obeying rate law Rate =k [A}", (B]"2, find the value of total order (n, +3), (2 GB) 1 ) 4 The size of colloidal colloidal solution is (1) Jess than 1 am Q) 1 1000.nm (3) 10 nm to 10% nm (4) 10° nm Q) 3 particle in84. Ua sem aiite A often : A see 85. 87. 88. & wm ae & ar facie sr a Las x lost A SAAT 8.0g4 2.0 g Gi fi feet aaa eT? (1) 802s (2) 1205s @) 601s (4) 200s ‘Frforion 8 8 rer aft ai ai, TEST () ef era Q) APRA a aT @) Wah ays 4) are wea artes faach A weasree 8 ag fa a am sit aa, aregiord at Peaferfiad 43 feel unafiia ac 8 ? (1) area erage # (2) age & wears F (3) aIRgisr & staat # (4) tehai omer tt sta wet aa Hi agate Pareror ToT a 2 (1) oRh a sae arr A wiekes aL AIgeeal SI SAAT | (2) Wea otiaeisrs Ft ren eer eT | @) wha siekes war aH I A Ara I (4) siesta ar aH tae ae aadifen At gfe A ah a DDT@ a (1) terarfes (2) srtafartrencotta were 3) Safretereta ress @) wh 84, 86. 87. 88. ‘A first order reaction A > product has @ first order rate constant 1.15 x 10° st How long it will take 8.0 g of A to reduce to 2.0? (1) 802s @) 601s (2) 1205s (4) 200s Identify intensive quantity from the following = (1) Enthalpy and temperature (2) Volume and temperature (3) Enthalpy and volume (4) Temperature and refractive index During lightning, the——high temperatures and pressures created in the air convert nitrogen into which of the following ? (1) Hydrides of Nitrogen (2) Sulphides of Nitrogen (3) Oxides of Nitrogen (4) Amino acids and Protein Eutrophication in waterbodies results due to (1) Run off of large quantities of phosphates and nitrates into water. (2) Increased oxygen content in ‘water. (3) Presence of small amount of phosphates and nitrates in water. Suppressed growth of algae and bacteria due to high oxygen in water. @) DDT is a/an (1) Antibiotic (2) Non-biodegradable pollutant (3) Biodegradable pollutant (4) All of these 1689, 90. om. 92. 93. 94, 95, aig a3 ar Gan a teaeiiee a are (1) Fatereer (2) ae G) Wea ry (4) wha sere fra 8a at at saftrenan atta feet & 2 (1) wfrserss (2) Are acts 3) asia 4) a werrercraratis sain feree re atar 2 ? (1) NO, WSO, (2) NO, wa CFC (3) 05, NO, wf CFC (4) NO,, 0,, wrifesergs, Tatiaei- ferrgzz (PAN) frafatad 4 3 gem yoda a favre forte (2) N,O (2) CH, (3) CFC (4) CO, vei i sre wetn Prafafod 3 a farecht safeata 8 2 2 (1) Caso, 2) Ca(HCO;), @) CaCl, (4) MgCl, frafefad 4 8 ata a1 siivtretesre Fier 8? (1) acne Q) te (3) feist (4) tere audi A fiat gen Pafefaa a Fraar sain we ata cara Hse E 7 () CCl, QQ) af (3) afar co, (4) C1,C=CCr, | | i i | 89: White lung cancer or asbestosis is caused by (1) Silica (2) Paper (3) Asbestos fibers (4) Sugar products Which of the following is greenest solvent ? (1) Formaldehyde (2) Benzyl chloride (3) Benzene (4) Water Photochemical smog is due to (1) NO, and SO, @) NO, and CECs (3) 05, NO, and CFCs (4) NO,, 05, Formaldehyde, peroxy acylnitrates (PAN) The maximum global warming potential among the following is of (1) N,O @) cH, (3) CFC (4) CO, Temporary hardness of water is due to presence of which of the following ? (1) Caso, (2) Ca(HCO,), (3) CaCl, (4) MgCl, Which of the following is organo- phosphorus pesticide ? (1) Malathion (2) Aldrin (3) Lindane (4) Heptachlor Use of which of the following for dry cleaning of clothes is a use of green chemistry ? (1) CCl, (2) Benzene (3) Liquified CO, (4) Cl,C=CCl,96. 98. 99, 100. 101. We as den n= 3 daft gar | wears ot Bem Parcel rh 2 a) 3 Q) 6 | @) 9 4) 18 frafefed 4 & fad saan afer deh afters oT 2 () P Qs @) cr (4) F frafetics #8 ae ary ifeen aor | ere 8 ger & fore wel eB 7 i (1) yaaa tr safe | | (2) y sitttra eh arte | G) ye daar er ate | +2 | (4) ff yParay dz | aifiam ar etegifis fer 3alasth | HAT 34s! 8 RPG | (1) 3d ae 4s Ft geet t sea Sat ae \ a (2) 3454s! ua earg ard ot ferarra z | 3) Sri sda 4s meret N>O>F (2) O>N>FRC | (3) O>F>N>C (4) F>N>OFC | 1=5% far waa Ht pe Gens () 13 (2) 17 i @) 9 @ . 20 96. ! 100. | 101. What is the total number of orbitals associated with the principal quantum number n=3 ? a 3 B) 9 Which of the following have the most negative electron gain enthalpy ? a) P Q) s (3) Cl (4) F Q) 6 (4) 18 Which of the following properties is incorrect for the solutions to the Schrodinger wave equation ? (1) w must be continuous. 2) y must be finite. (3). w must have three values, (@ f vardyde=1 The electronic configuration of Chromium is 3454s! rather than 344s? because (1) 3d orbital is at higher energy than 4s. (2) 3d54s! is stable half filled configuration. Both 3d and 4s orbitals have same energy. 4s orbital configuration has low stability. GB) @ The correct order for first ionisation energy among the following is (1) C>N>O>F Q) O>N>F>C (3) O>F>N>C (4) F>N>O05C Total number of orbitals for /= 5 are (1) 13 Q) 17 @) 9 @ 1 16102. 103, 105. 106. 107. “feo veg a softer dt gach art aaien emt wre adi A watt Sag mem Prefered a a fer 8 2 (1) Week agasia ferret Q) Ba atten agen a fay G3) stipes Fray @) +) Pam BO Sal sri, fr a (n+, wlan ota an 8, Ber merei Al den 2 M 3 @) 15 2) 18 @) 10 FSH eT |= 4 Paha ae & C1) dame G) gare Prafetiaa 88 veniam seri A ag Gaia aim share? () 3s<3d<4s<4p <4d Q) 1s<2p<3s<2s<3d G3) Is<2s<2p<3s<3p (4) Is<2s<3s<2p<3d (2) Bamere 4) hare w& way & sified saat a a ‘watftes tat a ard 2 (1) ns (2) np @) nd (4) of Prafefaa saita ante, frei gs & ‘agen Pram ft rere sai ate 8: 4) (47% @ (4) 4 14Tt B) Lt tTitlt @® [t/(4141F 24 107. . “No two electrons in an atom ean have the same set of four quantum numbers” is the statement of which of the following ? (1) Pauli Exclusion Principle (2) Hund’s rule of maximum multiplicity (3) Aufbau Principle (4) (n+) rule In all energy sublevels for which sum of (n + 9 is less than 5, the total number of orbitals is Q) 13 (2) 18 @) 15 (4) 10 1. The quantum number /= 4 refers to () orbital (2) orbital 3) g-orbital (4) h-orbital - Which of the following is correct order of increasing energy of atomic orbitals ? (I) 38<3d<4s<4p<4d Q) Is<2p<3s<2s<3d @) 1s<2s<2p<3s<3p (4) Is<28<3s<2p<3d Which of the following orbitals in an atom is most penetrating ? (1) ns (2) np (3) nd (4) nf The orbital diagram in which the Hund’s rule of Maximum Multiplicity is violated, is w (4) (4 Tt @ (4) 41tTF @ 4) TT » (4) Ala tt108. 109. 110. 1. 112, 113. 114, aifean & detsenat ste 3 ectagit Fr qin GET (n, |, m, 8) % (1) 2,1,-1,-1/2 @) 3,0,0,+1/2 V2 @) 3,2,2,412 Biefis (PH,) & fare BH eI Fe FA a? (1) we ore ae rach a3 I (2) wearin A gern Hare anda 8 | (3) eat aera Prafesia 2 | (4) Bae sere saftrerert EB BH, i Presferfiaa aear H Ge 26) a a: @ 2 @) 3 @) 4 a 6 Prafefiaa 3 a ata aftrnan sect 2 (1) CH, (2) NH, (3) H,O (4) HE gedit, a spite A often & frafafaa Ha ae a sere wet Fei eae? a) BN), (3) BANHy (2) ByH, 2NH; (4) ByH,-NHy frafafar fea ope fa a seit freer are 369 4 Pear Tae? () 34 He (2) ANe (3) HAAr (4) WAXe dcisni & fee vite oF a Frafira gfe arrange wel eta 8? (1) aera eae 2) weagR fee Ga (3) Ferg aserrereeeT (4) sree Prere, 109. i. 112. 113. 114, |. BAH, has . The valence shell electron of sodium has the quantum numbers (n, /, m, 8) () 2,1,-1,-12 (2) 3,.0,0, +1/2 (3) 3,2,-2,-12 (4) 3,2,2, 41/2 Which is incorrect phosphene (PH,) ? a Q) (3) Ithas pyramidal structure. (4) It does not possess property. statement for It has an odour of Rotten fish. Its less basic than NH reducing following of (Be ~2e) bond : (ay 2 @) 4 number @) 3 ) 6 Which of the following is most acidic ? () CH, (2) NH; 3) 1,0 (4) HF Diborane and Ammonia on reaction does not give which of the following products ? () (BN), (3) ByN3Hy (2) ByH,: 2NH (4) B)H,-NH; Which of the following noble gas is used as cryogenic agent ? (1) LiquidHe (2) Liquid Ne @) Liquid Ar (4) Liquid Xe Halogens do not follow a continuous and regular increase or decrease in the physical property : (1) Ionization enthalpy (2) Electron gain enthalpy (3) Electronegativity (4) lonic Radii 16115. 116. 117, 118. 119, 120, 16 ae toate, fra valine ser 8 a) o Q)s ! (3) Se (4) Te aati A gern a ditsia A frenefierar 116. (1) Fra Q) afr e1 G) waRaI ) Sa a ral weike set [XeO,]> at steerer ta. SaeM, ew sree wa Seah att i (1) +6, spid?, aferracta (2) +8, sp¥d?, sremeERT | (3) +7, spa arf Freee i (4) +8, Psp, sremerhta Xe oh dae sien & del Fgh | us. aah — 1a Penge | at wt | 1 XeO; a, sp3d? ane Il XeF, b. spd Feput TI. XeOF, c, spd aa IV. XeF, d. sp) aaa as | Ion om ww i aioe db i Qd baie @d ec ab @b ac d | argh a1 rafetaa a a sieaes | 119, sein a8 2 i () N,0 2) N,O, | (3) NO, (4) N,0, | HX fea pKa aay, 2 120. (1) HF 2) HCI @) HBr (@) HI 23 | 118. The chalcogen having highest number of allotropes is a) o Qs @) Se (4) Te The reactivity of Borazine as compared to Benzene is (1) less (2) more (3) equal (4) None of these Oxidiation state, hybridization state and geometry of perxenate ion [XeO,]ris (1) +6, sp¥¢2, square planar (2) +8, sp¥d?, octahedral (3) +7, sp3d3, square pyramidal (4) +8, dsp, octahedral . Match the List ~ 1 with List ~ II with respect to hybridisation of Xe. List -1 List — 11 I XeO; a. spd? hybridisation I, XeF, b. spd hybridisation Il. XeOF, —c. spd hybridisation IV. XeF, d. sp* hybridisation Codes : Ion om wv ()a © d b Q@d bac Bd oc ab @b aie d Which of the following oxide of nitrogen is not acidic ? (1) N,O (2) NO; @) No, (4) NO, HX, which has lowest pKa, is (1) HE @Q) HCL 3) HBr @) HI16 we aert a fre AA / SPACE FOR ROUGH WORK 24