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Atomic Structure J Date Planned: // CBSE Pattern Expected Duration : 90 Min Actual Date of Attempt: / / Level - 0 Exact Duration _ Very Short Answer Type (1 Mark} 1. s ae 6. trons to form Ni’ ion. The atomic number of nickel is 28. From which Nickel atom can lose two el orbital will nickel lose two electrons? Caleutate the number of angular nodes and radial nodes present in Sp orbital An atom having atomic mass number 13 has 7 neutrons, What is the atomic number of the atom? An atomic orbital has 1= 3, what the possible values of m. Using s, pand d notations, deseribe the orbitals with following quantum numbers: oo n-Lf-00 GB} ne2r-0 @oneae=l |=) n= 4r a2 Js angular momentum of an electron in an atom quantized? Explain. Short Answer Type-I (2 Marks} 10. M1 12. almer series in the hydrogen spectrum corresponds to the transition to n= 2 fron 4 ‘This series lies in the visible region. Calculate the wave number of line associated with the transition in Balmer series when the electron moves from n= 4 orbit Ry = 109677 cm) According to de Broglie, matter should exhibit dual behaviour, which is both particle and wave nature However, a cricket ball of mass 100 g does not move like a wave when it is thrown by a bowler at asp “100 km/h, Calculate the wavelength of the ball and explain why it does not show wave nature. Chlorophyll present in green leaves of plants absorbs light at 4.620 x 10!'Hz, Calculate the wave l »! radiation in nanometer, Which part of the electromagnetic spectrum does it belong to? is ball has a mass 10 g and a speed of 90 m/s. If speed can be measured within an a ! 4% what will be the uncertainty in speed and position? electron, so mutual repulsion between electrons is absent. However Hydrogen atom has only one Fons is significant, How does this affect the multi electron species mutual repulsion betweer. the ele rnergy of an electron in the orbitals of the same principal quantum number in multi electron species © distance between 4® and 3" Bohr orbits of He™ is hydrogen atom in the ground state is excited by monochromatic radiation of wavelength > A. The ‘oulling spectrum consists of maximum 15 different lines. What is the value of wavelength Key Loy7370N 8) Short Answer Type-tI (3 Marks) 14, 15, 16. State limitations of Rutherford’s model ot the atom Define atomic en ssion spectrum What are the laws of photoelectric emission? 17. Whyare Bohr's orbits also known as energy levels. 18. Electrons jump trom fourth energy level to finally first energy level in one mole hydrogen atom. How many maximum possible numbers of photons can be emitted? 19. Arrange the cleetrons represented by the following sets of quantum numbers in decreasing order of eee a 6) 3. f-Lme= Le s=-1/2 © 0) 3, /=0,m=0, s=-1/2 Long Answer Type (5 Marks) 20. (A)_—_Caleulate the number of electrons which will together weigh one gram. (5) Calculate the mass and charge of one mole of electrons. 21. (A) Calculate the total number of electrons present in one mole of methane. (5) Find (a) the total number and (b) the (otal mass of neutrons in 7 mg of "C (Assume that the mass of neutron = 1.675 « 102 ki) (C) Find (a) the total number and (b) the total mass of protons in 34 mg of NHs at S.T.P. (Assume the mass of proton = 1.6726 x 1027 kg) 22, A photon of wavelength 4 « 107 m strikes on metal surface, the work function of the metal being 2,13 eV. Calculate (a) the energy of the photon (eV) @) the kinetic energy of the emission and (C) the velocity of the photoelectron (1 eV = 1.602 x 101%), 29. 4 25 wart bulb emits monochromatic yellow light of wavelength of 0.57 um. Calculate the sate of emission of quanta per second. 24. How much energy Is required to lonise a hydrogen atom ifthe electron occupies n = 5 orbit? Compare Your answer with the lonisation energy of hydrogen atom (energy required to remove the electron erg 2 orbit 25. owing results were observed when sodium metal is irradiated with different radiations Calculate (a) threshold wavelength and (b) Planck's constant. 500 450 400 2.55 4.35 95.20 Date Planned: __/__/__ Daily Tutorial Sheet Expected Duration 590 Min | Actual Date of Attempt: —/ / ne Level -1 Exact Duration 1. Compared to the mass of lightest nuclei, the mass of an electron is only fappros.) 1/80 (1/800 © 1/1886 © 12800 2. Which of the following is isoelectronic with carbon atom? w oN ® 0 (Xa o x 3. Which of the following pair is isodiaphers (Cand [Na @ 3iMy 'Na (©) He and 0 Cand SN 4. The ratio of e/m, Le. specific change for a cathode ray (A) has the smallest value when the discharge tube is filled with t ®) —isconstant (©) varies with the atomic number of gas in the discharge tube @) varies with the atomic number of an element forming the cathode 5. In photoelectric effect, the number of photoclctrons emitted is proportional £6 (A) intensity of incident beam (B) —_requency of incident beam (©) wavelength of incident beam D) Alot the above 6 _ Einstein's photoelectric equation states that: ° Here, Ex refers to (A) Kinetic energy of all ejected electrons (B) Mean kinetic energy of emitted electrons (©) Minimum kinetic energy of emitted electrons, ©) Maximum kinetic energy of emitted electrons, 2 The maximum kinetic energy of the photoelectrons is found to be 6.68.10 J, when the metal 1s irradiated with a radiation of frequency 2 » 16" Hz, The threshold frequentey af the metal i abou ny 10s @ oixios! © 25.10%." op 4s1o!s 8. Hobes theory ts applicable to ite ou © te D) None of these ° fhe radius of frst orbit, the radius oF orbit af the Baton ill be (ayn mov © ¢ Ore 10. he principal quantum manber of H-atom ortstal # tthe eneng’ at eis Sa wall be it m2 © o4 © ow 11. Which of the following electrante te tu hyatrogen atom wall emit kangest amount of eweny (Q Fromnedionet OH) Pumne ston ©) Romnesined fe) om eton 12. 14. 15. ated from rest through a potential difference ‘The mass of an clectron is m, its charge is € and it is accele ted by formula: V. The velocity of electron ean be ealeul V fev [2ev) Vm a baa (D) None of these ‘length in Balmer series of He n Lyman series is x, the longest w: If the shortest wavelength of H-atom 36x 5x x (C) = ) «a . B) 7 Ce According (© Bohr's theory, the angular momentum of an electron in 5® orbit is: h hb 25 ) © 10 o the If the energy difference between the ground state of an atom and in excited state is 4.4 « 10 wavelength of photon required to produce the transition is: 2.26 10°? m 1.13 «10°? (©) 4.52 «10-8 @ = 452%10'?m | Date Planned: _/_/ Daily Tutorial Sheet - 2 Expected Duration : 90 Min Actual Date of Attempt: / _/ Level - 1 Exact Duration 16, Consider the following statements for an electron moving in_nth orbit of hydrogen Uke species of atomic 17. 1s. 19. 21. 25. z a L Kinetic energy « TL —_ Frequency of revobution Zz TH, Coutomsbie foree of attraction + TV. Momentum The corrvet choice is woo (a © um (LY The correct statement about proton is: (A) Tis nucleus of deuterium, (8) isan ionised hydrogen atom (©) tis.an ionized hydrogen molecule {D)—Itisan a particte When a gold sh is bombarded by a beam of «a particles, only a few of them get deflected. whereas most go straight, undeflected. This is because (A) The force of attraction exerted on a ~ particles by electrons is insufficient ©) The volume of nucteus is much smaller than atom (©) The force of repulsion acting on fast moving a ~ particles due to nucleus is very small @) The neutrons have no effect on a ~ particles ‘The charge to mass ratio of «- particlesis approximately... the charge to mass ratio of protons @)— sixtimes, = B)—fourtimes (©) hal ©) wo times Which of the following atom does not contain the same number of protons and neutrons in its nucleus? Carbon B) Deuterium = (©) Tritium ) Nitrogen ‘The radius of which of the following orbit is same as that of the first Bohe's orbit of hydrogen atom? Wo Lein=2) OL m=3) (Ben De According to Bohr's theory, the angular momentum for an electron of 3" orbit is: w B) oO om 2 The ratio of kineuc energy and total energy of an electron in a Bohr orbit of a hydrogen like species is a | () 1 @ 2 o ‘The number of photons emitted per second by a 6O W source of monochromatic light of wa nm is: (h = 6.63 «10% Js) wo 4-10 ® 15x10" (c wo Mm = 2.10" The ionisation enthalpy of hydrogen atom is 1.812 < 10°F mot | The energy requited to excite the election in the atom from n= 1ton = 2s (A) 651-10" J mol! (B) 656.610" Jmol | «© 7.56 10" J mol | (D) 9.84 10° J mol 10 8s. what 6 the frequency? 26. Time period ofa wave ts ~ A Sx1o%s! (B) 21075" © 23 104s! (D) 5x 107s! 27. Anelectron from one Hobe stationary orbit can go to ext higher orbit (A) by emission of electromagnetic radiation (B) by absorption of any electromagnetic radiation (©) by absorption of electromagnetic radiation of particular frequency ©) without emission or absorption of electromagnetic radiation 28. Anisobar of "Ca is “w “Ar ®) kcal © iW i) Sar 29, The energy of second Bohr orbit of the hydrogen atom is -328 k:J mol”! ; hence the energy of fourth Bohr orbit would be: (A 41 kJ mot loneese a raienenel © 164 kJ mol! () -82 kJ mol! 80 ie sas ofthe first Bohr orbit of hydrogen atom is 0.529. The radius ofthe third orbit of H will be: W s464 ® 0.7054, © 1594 OM 4.764 Date Planned: —/_/_ Daily Tutorial Sheet - 3 Expected Duration : 90 Min Exact Duration: j Actual Date of Attempt : _ / level - 1 31. 34, 37. 39. al. Which one of the following sets of ions represents a collection of isoelectronic species? oa )—Ba?*, Sr", K*, 8? Ww Kore (NP .0% Which of the following statements does not form a part of Bohr's mode (DB) 1, Na’ Mg?" Ca? 1 of hydrogen atom? rons in the orbit is quantized rest to the nucleus has the lowest energy Energy of the ¢ (B) The electron in th orbit ne cleus bits around th (C) Electrons revolve in different (D) The position and velocity of the electrons in the orbit cannot be determined simultaneously particles are represented by (@) lithium atoms ©) helium nuctel (C) hydrogen nuclei (D) None of these The transition of electrons in H atom that will emit maximum energy is “a Ng>n2 B) ny ony © — nyon, © = neon, 1312 /n? kJ mol! then the energy required If the energy of electron in H atom is given by expressior to excite the electron from ground state to seconé orbit is: (@—328kJ/mol (B)_— G56 kJ/mol [C)_——-984 kJ/mol ‘The work function of a metal is 4.2 eV. Ifradiations of 2000 A fall on the metal, then the kinetic energy of, © 1312 kJ/mol the fastest photoelectron i 1.61079) @) 16x10y 832x105) BA «10D cy ‘The ratio of the radii of the three Bohr orbits for a given atom is: 72s Be 12a ro) 4:9 @)1:8:27 If the threshold wavelength (ig) for ejection of electron from metal is 330 nm, then work function for the photoelectric emission is: 2610s Bw) 12x10) BIO) x10"? In excited H atom, when electron drop from n = 4. 5, 6 ton = 1, there is emission of ® (A) UV ight (8) Visible light ()— IR Light ©) Radio waves In Bohr’s stationary orbits: (A) electrons do not move (B)—clectrons emit radiations while moving (C) energy of the electron remains constant (©) angular momentum of the electrons ish / 2x The de Broglie wavelength in this ease is ® pproximately. (a) otA (B) 1000 © A oo) 10K Dally Tutorial Sheet - 4 Expected Duration : 90 Min Date Planned: /__/ Actual Date of Attempt: /_/ level -1 Exact Duration : 46. 47. 51. 53. 57. The wave nature of electron is verified by 1A) de-Broxic (B)—__Davisson and Germer (©) Rutherford ©) Alor these The uncertainty in momentum of an electron is 1+ 10 © fgg am fs. The uncertainty in its position will be (t= 6.62 «10 kg m?/s) 2.36.10 7%m 6) “107% m © 227.10 m © 527-10%m o The two electrons in sub-shell of K-shell will differ in: Azimuthal quantum number (A) Principal quantum number © (©) Magnetic quantum number (D) Spin quantum number The number of orbitals and subshells present in the shell with n= 4 is: 8.2 ® 164 © 18.3 Om 325 The number of electrons in the valence shell of calcium is: wi 2 @® 4 Co o 8 The ground state electronic configuration of nitrogen atom can be represented as: » WW) Co » Wo oy © ff CLM ©) Allof the above How many unpaired electrons are present in Ni cation? (At. No. = 28) @ oo 2 © 4 ™ 6 An electron, a proton and an alpha partide have KE of 16E, 4E and E respectively, What is the qualitative order of their de-Broglie wavelengts? A> ay>hy ® © Oo) Which of the following sets of quantum numbers represents the highest energy of an atom? © Wo ne3lelm=Lsari2 ®) 3 2 © n= 4,120,.m=0,8=41/2 ) ‘The number of radial nodes of 38 and 2s orbital are respectively (a) a1 (B) 0,2 (c) 12 (D) 2. In hydrogen atom an orbit has a diameter of about 16.92 A, what is the maximum number of electrons, that can be accommodated in that orbit 2 a 6 ® 2 © 50 ) The number of waves in a" orbit are aon on OO. cD canehataesidenconemiaieenionel uum of an electron is given BY 58. The magnitude of the spun anlar momenta of 7 " ss sys ®) x oa None of these @ s-2.2 59. Which of the following sets of quantum number ts INCORRECT? , po3m--38 @ = n-5/-4m-a8-64 am on-sl-3 5 2 am on -6/-0.m-ehs ; (Mo on-4s-2m= 28-0 fet ni © mm o 1m 60, The correet set of four quantum numbers for outermost electron of potassium ( 1 1 © 4.0.0.5 m 3.0.0. @ 4104 ta Cea, 2 2 Date Planned | Daily Tutorial Sheet - 5 Expected Duration : 90 Min | Actual Date of Attempt: / / | Exact Duration Level -1 61. 62, 67. 70. 7. A body of mass x ky is moving with a velocity of 100m |. [hs de Broglie wavelength is 6.62 «105m, Hence, xis: (hh 6.62 < 10" sy Wonks mH 025 ke (O15 ke M 02ke The values of four quantum mumber of valence electron of an element aren = 4, L= 0, m= 0 and 1 S15 The element is: oo © Na Ds wok {um of anv electron ina dorbital is ‘The orbital angular mome a Pa = >» ao o 2 ww Be wan 2r ae de-Broglie wavelength of electron in 2" exeited state of hydrogen atom is: [where 1 1S the radius of 1 orbit in H-atom] a] 9 ©) 31 © 6x ‘The H-spectrum show: (A) Heisenberg’s uncertainty principle (B)_—_—Diiffraction (C) Polarisation ©) Presence of quantized energy level Electrons will first enter into which set of quantum numbers-n =0orn=3.1 ©) data insufficient 0 ~— (B)_ both possible (C) 1 =3. wo on=5, Which of the following configurations is incorrect? a) 1s*2s* 2p? 2p? 2p? (B) 1s? 2s? 2p) 2p), © 1s*2s* 2p! ap) ap! (D) —_1s22s? 2p°3s? 3p® 3a5 4s? Which of the following set of quantum numbers is an impossible arrangement? @ n=3,m=-28=41/2 ® = n=4,m=3.8=+1/2 () n-5,m=2,8=-1/2 @ = n=3,m=-3,8=-1/2 Which of the following sets of quantum numbers is not possible? a n-4.l-Lm-=0,s=+1/2 ®) n=4,[=3,m =-3,s=-1/2 ‘ +2,9=-1/2 @) nn =4. f= m=0.s=-1/2 (c) no4,f--1m 1 The wavelength associated with its motior iy with a velocity of LOO ms icket ball of 0.5 kg is mov (a) 1/100 em (B) 6610 “im © 182-10 %m © 66.10% m ‘The set of quantum numbers not applicable to an electron: (1, Lm, S) (a) Liisi @ 100 172 (c) 1,.0.0-1/2 @M) 2.0,0,+1/2 Paragraph for Question No. 72-75 A neutral atom of an element has 2K, 8L, 9M and 2N electron 72. The atomic number of element is 2 o 28 “2% @ 21 bi 73. ‘The total number of s electrons are o © wos ® 6 cer 74, The total number of p-electrons are: 24 w 6 ® 12 oOo e 75. The total number of d-electrons are: tele oe @ 1 @ 2 Daily Tutorial Sheet - 6 Expected Duration : 90 Min Date Planned: __/_/_ Exact Duration : i level - 2 76. 77. 78. si 82. Actual Date of Attempt: _/ \es obtained in Hohe spectrum of hydrogen atom when an electron is excited ‘The number of spectral 1 from 5" orbit to ground level 1s @ 10 mM 5 oO & ™ 15 the wavelength associated with a gol ball weighing, 200 {and moving ala speed of 5 mb tis of the order 10 ay @ 10m 10m ww 10m On the basis of Boht’s model, the radians of the 3 orbit is (A) equal to the radius of first orbit (B) three times the radius of first orbi (©) five times the radins of first orbit (D)__nine times the radius of first orbit The filling of degenerate orbitals by electrons ts governed by rule (A) Hund’s (B) Aufbau (©) Pauls (D) None of these ¢ radius of an atomic nucleus is of the order of a 0m @) 10m © 10'Sm @ 10m the third energy level. there are ......... Orbitals: @ 9 @ 8 oO 7 mo 6 When there are two electrons in the same orbital, they have......spins. (a) Parallel (B) Symmetric = (©)_—Antiparallel_— (D)_—_None of these ‘The number of spherical nodes in 4s orbital is: a4 ® 0 oO 2 mo 8 How many electrons in an atom with atomic number 105 can have (n+ 0) a 30 ) 17 oO 15 @) Unpredictable ‘The wave mechanical model of an atom is based upon which of the following equations? (B) de Broglie’s equation (A) Schrodinger’ equation ©) All of the above (C) Heisenberg uncertainty principle OO a Date Planned: _/ _/ Daily Tutorial Sheet - 7 Exact Duration Actual Date of Attempt: _/ Level - 2 i 87. 89. 21. 92. 93. 95. ts subshells is of the order dcfep Ta 4 4 s 1| PE dl \ © a » 32 + "99. Which is/are correct graph with respect to paotoelectric effect? oO ’ 4} “a () “ (c (D) ry t| ) v—> 4 > “100. “101 “102 “103. “104, “105. ® number n only Select the correct statement {s) eit areal wave function which depends upon qual (Radial function [R¢] Is a part of wave funet nee re eee (8) Anautar function depends only on the direction, and is independent to thy ncleus jeular point in space (C) v2 (r.0.6tis the probability density of finding the electron at a particular po Pi 2 ‘ctron being present at a (©) Racial distribution function 4st2R?) gives: the probability of the electron being distance ¥ from the nucleus List fi He Select the correct statementts) 0 is symmetrical about the nucleus (A) An orbital with 1 sally symmetrical about the nucleus An orbital witht (©) Sd. is spherically symmetrical about the z-axis, ©) Allare correct In @ sample of H-atoms electrons are de-exeited from 4" excited state to ground state. Which it oe correct statement? (A) Nolline observed in P-fund series (B) Total ten lines observed in spectrum (©) 4 line in UV-region and 3 line in visible region are observed (D) One Line observed in Brackett series Select incorrect statement(s). (A) Ifthe value of l= 0, the electron distribution is spherical (B) The shape of the orbital is given by magnetic quantum number (©) Angular momentum of 18, 2s, 3s orbit electrons are equal (D) In an atom, all the electrons travel with the same velocity Hydrogen has: (4) half filled subshell (®) half filled she, (©) one electron in valence shell (D) half filled orbital Select the correct statements) o (A) tn wave mechanical model the energy of electron in the orbital remains constant an (8) d,, orbital lies in yz plane (2 Nodal planes are yzand xyin dy, orbital (D) All of the above [Date Planned: _/ _ | Daily Tutorial Sheet - 9 Expected Duration : 90 Min [ Actual Date of attempt: /_/__| level - 2 Exact Duration : +106. Select the correct statement{s) regarding ‘py orbital eo (A) Total number of nodes are 2 (B) number of maxima in the curve Amey? vs ¢ are two (©) Quantum number n. Land m for an orbital may be 8. 1-1 respectively () the magnetic quantum number may have a positive value £107. Choose the correct statements among the following © (AM Anode is a point in space where the wave function ¥ has zero amplitude {B) The number of maxima (peaks) in radial probability distribution function is (n~ 0 (©) Radial probability is 4nr2R2 0) ©) w? represents probability density of finding electron #108, Select the correct statement(s ®Q (A) Heisenberg’s principle is applicable to stationary electron {B)__ Pauls exclusion principle is not applicable to photons (©) For an electron the product of velocity and principal quantum number will be independent to principal quantum number ) quantum numbers land m determine the value of angular wave function +109. Select the correct statement (s): © (A) Lower value of quantum number | indicates that there is a higher probability of finding the 3s electron close to the nucleus than those of 3p and 3d electrons (B) _ energy of 3s orbital is less than for the 3p and 3d orbitals (C) At the node, the value of the radial function changes from positive to negative (D) The radial function depends upon the quantum numbers n and | *110. For radial probability curves, which of the following is/are correct? ® (A) The number of maxima in 2s orbital are two (B) The number of spherical or radial nodes is equal to n (C) The number of angular nodes are (0) 3d? has 3 angular nodes ‘LLL. Choose the correet statement (6): © 1 atomic orbital depends upon azimuthal quantum number (A) The shape of (8) The orientation of an atomic orbital depends upon the magnetic quantum number (C) The energy of an electron in an atomic orbital of multielectron atom depends upon principal quantum number only The number of degenerate atomic orbitals of one type depends upon the value of azimuthal (@) —— ent raeted by the nucleus and has a low potential energy SIZ, Select the correct state the nneteus is more te energy iit stays in one orbit (A) Ancleetron ne: (8) According to Bohr's theory, an electron continuously radi (©) Bohr’ model could not explain the spectra of multielectron atoms ()—_Bohr's motel was the first atomic model based on quantisation of energy “113, Scloct incorrect statementish Only three quantum numbers eeded to define an orbital Tand mare w {B) Four quantum numbers are needet! for complete deseription of an electron (€) —DWwo quantum numbers n and Lare needed to identify subshell and shape of orbital (D)__Sphiting of spectrum lines in presence of electric field is known as Zeeman effect *114, Mie angular momentum of electron ean have the value(s} a (B) 2 co) ©) 2. a roglie Wavelength of neutron at 27°C is 2. The wavelength at 927°C will be ) el o = 2 «a Date Planned: /_/_ [__ Daily tutorial sheet - 10 Expected Duration : 90 Min Actual Date of Attempt (onjanaa| level -2 Exact Duration : 2 116. 17. "120. a2a. 122. 123. 124 ‘A photon was absorbed hy a hydrogen atom in its ground state and the electron was promoted to the ith orbil, When the excited atom retumed (o its ground state, visible and other quanta were emitted. Other quanta are: @ o251 ® 532 91 ™ 451 Of the following, radiation with maximum wavelength is wou (B)— Radiowave — [C) Xray o oR Zeeman effect explain splitting of Hines in: (A) Magnetic field (8) Electric field (© Bon (©) None Which of the following statement is not true about electromagnetic waves? (A) Are transverse in nature () Are produced by accelerating charges (C)__ Travel with the same speed in all media (BD) Travel in free space with speed of light Which of the following orbitals has /have zero probability of finding the electron in ay-plane? wp B dy, © dx Mx If Hund’s rule is not followed, magnetic moment of Fe"?,Mn’ and Cr all having 24 electrons will be in the order (Fe? < Mn" «cr (Fe =cr Visible photon > Thermal electron (5) Thermal proton > Thermal electron > Visible photon (©) Visible photon > Thermal electron > Thermal neutron ©) Visible photon > Thermal neutron > Thermal electron 20. The total number of orbitals associated with the principal quantum number 5 is © 2016) wis ® 10 © 2 o 235 21. A stream of electrons from a heated filament was passed between two charged plates kept at a potential h difference V esu, Ife and m are charge and mass of an electron. respectively, then the value of (where ‘is wavelength associated with electron wave) is given by ®aore) w meV ) —Amev (© y2mev ©) mev 22. ‘The radius of the second Bohr orbit for hydrogen atom is: (Planck's Constant h = 6.626210 Js; mass of electron = 9.109110 kg; charge of electron = 1.60210«10%C; permittivity of vacuum 6.554185 -10 kg 'm SA?) (2017) wy 212A @ 165A © 4.764 ©) 0.5294 23. the shortest wavelength in Lyman series of hydrogen atom is A, then the longest wavelength in Paschen series of He" is @ 2017 5A 9A 36A 364 w e » & © . o 24, The electron in the by 1 atom undergoes transition from higher orbitals (0 orbital of radius 211.6 pin. This transition is associated with Oar (A) Lymanseries (8) Balmer series (©) Paschen series (D)_——_ Brackett sertes 25. Fjrction of the photoelectron from metal in the photoelectric elfect experiment can be stopped by applying metal is (2018) fs used. ‘The work function of th 0.5 V when the radiation of 250 fa Sev ae 550 MO = 45ev 27. 29. 31 atom is 2018) ‘The de-Broglie’s wavelength of electron present in first Bohr orbit of 1 220.5294 i ee @) 2s (©) osa0h ) —4-0529K Which of the following statements is false? (2018) (a) Photon has momentum as well as wavelength (B)_Spliting of spectral tines in electrical field is called Stark eect (©) Frequency of emitted radiation from a black body goes from a lower wavelength to higher wavelength asthe temperature increases (Rydberg constant has unit of energy 1, the plot of wave number (¥) against B tony For emission line of atomic hydrogen form. (the Rydberg constant, Ryy is in wave number unit) Deo) (8) Non linear will be (A) Linear with slope-Ry (©) Linear with slope Ry, (D) Linear with intercept Which of the following combination of statements is true regarding the interpretation of the atomic Deis, orbital? (a) e nucleus than an An electron in an orbital of high angular momentum stays away from electron on the orbital of lower angular momentum, ©) For a given value of the principal quantum number, the size of the orbit is universally Proportional to the azimuthal quantum number. According to wave mechanics, the ground state angular momentum is equal to 2x ©) @ The Hot of y ss rforvasious azimuthal quantum numbers, shows peak shifting towne higher + value, w @.0) ® wo © wt ” ae The ground sate energy of hydrogen atom is ~1.6eV. The enengy of second excited state He’ V w 272 ®) 34 tc) 544 o 6.04 . Heat reatment of muscular pus hwveves radi of wavelength of about 900%, Whig spectral ine oF Hata i stable tr this purpose? [Ry

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