1. a.

Order 0 Order 1
Free Fatty Acid Storage Free Fatty Acid
Storage (days)
25℃ 35℃ 45℃ (days) 25℃ 35℃
0 0.32 0.32 0.32 0 -1.139434 -1.139434
5 0.62 0.83 0.83 5 -0.478036 -0.18633
10 1.34 1.12 1.32 10 0.29267 0.113329
15 1.45 1.34 1.67 15 0.371564 0.29267
20 1.68 1.76 1.92 20 0.518794 0.565314
25 1.85 1.97 2.18 25 0.615186 0.678034
30 2.01 2.11 2.49 30 0.698135 0.746688

Order 0
3 1.5
2.5 1
f(x) = 0.0700714285714286 x + 0.481785714285714 f(x) = 0.06
Free fatty acid (%)

Free fatty acid (%)

2 R²
f(x)= 0.978104571177676 x + 0.461785714285714 f(x)
R² ==0.832
0.05
f(x) == 0.0592142857142857
0.0562142857142857 x + 0.481071428571429 0.5 0.842
R² = 0.808
R²
R² == 0.976150231807645
0.924078262633979
1.5
0
1 0 5
-0.5
0.5
-1
0
0 5 10 15 20 25 30 35 -1.5
Storage (days)

25℃ Linear (25℃) 35℃ 25℃

Linear (35℃) 45℃ Linear (45℃) Line

R² at order 0 > order 1 so this kinetic reaction uses order 0

b. Temperature (K) k 1/T ln k Lnkt = Lnko.-(Ea/R)(1/T)

298 0.0562 0.003356 -2.878839 y = ax+b
308 0.0592 0.003247 -2.826834 y = Lnkt
318 0.0701 0.003145 -2.657832 b = Lnko
a = -Ea/R
x = 1/T
Arhenius Equation
-2.5 y = 0,5938 - 1040,8 (1/T)
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 Ln kt = 0,5938 - 1040,8 (1/30
-2.55
Ln kt =
-2.6
kt =
-2.65
ln K

-2.7 f(x) = − 1040.80559900918 x + 0.593781344593819

R² = 0.903798866183589
-2.75
-2.8
-2.85
-2.9
1/T
ree Fatty Acid Temperature Equation order 0 Equation order 1 Order 0
45℃ 25℃ y = 0,0562x + 0,4811 y = 0,0566x - 0,7236 R² = 0,9241
-1.139434 35℃ y = 0,0592x + 0,4618 y = 0,056x - 0,687 R² = 0,9762
-0.18633 45℃ y = 0,0701x + 0,4818 y = 0,0604x - 0,6482 R² = 0,9781
0.277632
0.512824
0.652325
0.779325
0.912283

Order 1
1.5
1 f(x) = 0.0604368095744381 x − 0.648177247193088
Free fatty acid (%)

f(x) 0.0559934146975347 x − 0.723582616518903

R² ==0.832590339533546
0.0566091005378347 0.687005543723321
0.5 0.842572877011889
R² = 0.808309856637919
0
0 5 10 15 20 25 30 35
-0.5
-1
-1.5
Storage (days)

25℃ Linear (25℃) 35℃

Linear (35℃) 45℃ Linear (45℃)

Lnkt = Lnko.-(Ea/R)(1/T) R = 8,314 SHELF LIFE PREDICTION

Q= 1.7
Qo = 0.32
ts = Q-Qo/kt
T=28+273
301 ts = 24.1935483870968 days
The product shelf life at 28°C with FFA maximum 1,70% is 24 days
y = 0,5938 - 1040,8 (1/T)
Ln kt = 0,5938 - 1040,8 (1/301)
-2.864007
0.05704
 Order 1
R² = 0,8083
R² = 0,8426
R² = 0,8326

0% is 24 days
2. a. VISUAL APPEARANCE
Order 0
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 9 9 9 9 9 9
5 8.7 8.5 8.4 9 9 8.9
10 7.5 7.2 7.2 8.6 8.5 8.4
15 6.8 6.3 6.1 7.8 7.6 7.3
20 5.2 5.2 5.1 6.7 6.6 6.5

Order 0
10
9
Visual Appearance (1-9)

f(x) == −− 0.116
0.124
0.202xxx+++9.34
0.132
0.19
0.196 9.38
9.34
9.2
9.18
8 R²
7 R² == 0.954824375793483
0.899812734082397
0.874220374220374
0.925233644859813
0.986847513357994
0.991158181111543
6
5
4
3
2
1
0
0 5 10 15 20 25
Storage (days)

PET 25℃ Linear (PET 25℃) 35℃

Linear ( 35℃) 45℃ Linear ( 45℃)
GLASS 25℃ Linear (GLASS 25℃) 35℃
Linear ( 35℃) 45℃ Linear ( 45℃)

AROMA
Order 0
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 9 9 9 9 9 9
5 8.4 8.2 8 8.8 8.5 8.4
10 7.8 7.1 6.9 8.2 8 8.4
15 6.4 6 5.5 7.5 7.2 7.1
20 4.5 4.4 4.3 7 6.8 6.2

Order 0
10
9 f(x)
8 f(x) == −− 0.138
f(x) 0.22
0.238xxx+++9.42
0.228
0.106
0.114 9.22
9.2
9.16
9.12
9.04
R²
R² == 0.933066008636644
0.985142510612492
0.914170506912442
0.975347222222222
0.996411483253589
0.990548780487805
7
Aroma (1-9)

6
5
4
3
2
1
0
0 5 10 15 20 25
Storage (days)

PET 25℃ Linear (PET 25℃) 35℃

Linear ( 35℃) 45℃ Linear ( 45℃)
GLASS 25℃ Linear (GLASS 25℃) 35℃
Linear ( 35℃) 45℃ Linear ( 45℃)
 2
1
0
0 5 10 15 20 25
Storage (days)

PET 25℃ Linear (PET 25℃) 35℃

Linear ( 35℃) 45℃ Linear ( 45℃)
GLASS 25℃ Linear (GLASS 25℃) 35℃
Linear ( 35℃) 45℃ Linear ( 45℃)

TEXTURE
Order 0
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 9 9 9 9 9 9
5 8.4 8.2 8 8.8 8.5 8.4
10 7.8 7.1 6.9 8.2 8 8.4
15 6.4 6 5.5 7.5 7.2 7.1
20 4.5 4.4 4.3 7 6.8 6.2

Order 0
10
9 f(x)
8 f(x) == −− 0.106
f(x) 0.22
0.238xxx+++9.42
0.228
0.138
0.114 9.22
9.2
9.16
9.12
9.04
R²
R² == 0.933066008636644
0.985142510612492
0.914170506912442
0.975347222222222
0.996411483253589
0.990548780487805
7
Texture (1-9)

6
5
4
3
2
1
0
0 5 10 15 20 25
Storage (days)

PET 25℃ Linear (PET 25℃) 35℃

Linear ( 35℃) 45℃ Linear ( 45℃)
GLASS 25℃ Linear (GLASS 25℃) 35℃
Linear ( 35℃) 45℃ Linear ( 45℃)

b. VISUAL APPEARANCE
PET
Temperature
k 1/T ln k
(K)
298 0.19 0.003356 -1.660731
308 0.196 0.003247 -1.629641
318 0.202 0.003145 -1.599488

Arhenius Equation of PET Visual Appearance

-1.56
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
-1.58

-1.6
f(x) = − 290.130675711476 x − 0.687307735948447
R² = 0.999901898166477
Ln K

-1.62

-1.64

-1.66
 -1.58

-1.6
f(x) = − 290.130675711476 x − 0.687307735948447
R² = 0.999901898166477

Ln K
-1.62

-1.64

-1.66

-1.68
1/T

y = -290,13x - 0,6873
ln K y -Ea/R -290.13
ln Ko -0.6873 Ea/R 290.13
Ea (J/mol) 2412.141 R 8.314
All of the energy activation (Ea) value is marked with light green color

c. VISUAL APPEARANCE
PET
T = 28℃ = 301 K Q= 5.5
y= -0,6873 - 290,13 (1/T) Qo = 9
Ln kt = -0,6873 - 290,13 (1/301) ts = (Qo-Q)/kt
Ln kt = -1.651187 18.24607542
ts =
kt = 0.1918221 days

The shelf life of the product at 28°C assuming the acceptability limit of
the organoleptic acceptance score is 5.5 has marked with green color
 Order 1
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 2.197225 2.197225 2.197225 2.197225 2.197225 2.197225
5 2.163323 2.140066 2.128232 2.197225 2.197225 2.186051
10 2.014903 1.974081 1.974081 2.151762 2.140066 2.128232
15 1.916923 1.84055 1.808289 2.054124 2.028148 1.987874
20 1.648659 1.648659 1.629241 1.902108 1.88707 1.871802

Order 1
Visual Appearance (1-9)

2.5
2 f(x) = − 0.0146666989103854
0.0268706463395231
0.0291182201976376 xx ++ 2.24715551270873
0.0157877237330323
0.0169804345890601
0.0279329686719292 2.25691283565692
2.247823880229
2.2440411628865
2.23859552599978
2.23944569188717
R² = 0.923591849341548
0.883782950519957
0.855664281208519
0.912659016134179
0.979510367643532
0.97482906587433
1.5
1
0.5
0
0 5 10 15 20 25
Storage (days)
20 25

PET 25℃ Linear (PET 25℃)

35℃ Linear ( 35℃)
35℃ 45℃ Linear ( 45℃)
inear ( 45℃) GLASS 25℃ Linear (GLASS 25℃)
35℃ 35℃ Linear ( 35℃)
inear ( 45℃) 45℃ Linear ( 45℃)

Order 1
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 2.197225 2.197225 2.197225 2.197225 2.197225 2.197225
5 2.128232 2.104134 2.079442 2.174752 2.140066 2.128232
10 2.054124 1.960095 1.931521 2.104134 2.079442 2.128232
15 1.856298 1.791759 1.704748 2.014903 1.974081 1.960095
20 1.504077 1.481605 1.458615 1.94591 1.916923 1.824549

Order 1
2.5
2 f(x)
f(x) == −− 0.0132495511500742
0.0331645615320706
0.0370382511742963 xx ++ 2.21988023603837
0.0348722951573232
0.0182697498474469
0.0145317813556516 2.27963669612529
2.25568645673443
2.24469264085441
2.23036391150108
2.2068649976998
Aroma (1-9)

R²
R² == 0.883202696076815
0.949606380734918
0.976589003404661
0.899209523405653
0.969957547115167
0.987519330140165
1.5
1
0.5
0
0 5 10 15 20 25
Storage (days)
20 25

PET 25℃ Linear (PET 25℃)

35℃ Linear ( 35℃)
35℃ 45℃ Linear ( 45℃)
inear ( 45℃) GLASS 25℃ Linear (GLASS 25℃)
35℃ 35℃ Linear ( 35℃)
inear ( 45℃) 45℃ Linear ( 45℃)
 0 5 10 15 20 25
Storage (days)
20 25

PET 25℃ Linear (PET 25℃)

35℃ Linear ( 35℃)
35℃ 45℃ Linear ( 45℃)
inear ( 45℃) GLASS 25℃ Linear (GLASS 25℃)
35℃ 35℃ Linear ( 35℃)
inear ( 45℃) 45℃ Linear ( 45℃)

Order 1
Storage PET GLASS
(days) 25℃ 35℃ 45℃ 25℃ 35℃ 45℃
0 2.197225 2.197225 2.197225 2.197225 2.197225 2.197225
5 2.128232 2.104134 2.079442 2.174752 2.140066 2.128232
10 2.054124 1.960095 1.931521 2.104134 2.079442 2.128232
15 1.856298 1.791759 1.704748 2.014903 1.974081 1.960095
20 1.504077 1.481605 1.458615 1.94591 1.916923 1.824549

Order 1
2.5
2 f(x)
f(x) == −− 0.0132495511500742
0.0331645615320706
0.0370382511742963 xx ++ 2.21988023603837
0.0348722951573232
0.0182697498474469
0.0145317813556516 2.27963669612529
2.25568645673443
2.24469264085441
2.23036391150108
2.2068649976998
Texture (1-9)

R²
R² == 0.883202696076815
0.949606380734918
0.976589003404661
0.899209523405653
0.969957547115167
0.987519330140165
1.5
1
0.5
0
0 5 10 15 20 25
Storage (days)
20 25

PET 25℃ Linear (PET 25℃)

35℃ Linear ( 35℃)
35℃ 45℃ Linear ( 45℃)
inear ( 45℃) GLASS 25℃ Linear (GLASS 25℃)
35℃ 35℃ Linear ( 35℃)
inear ( 45℃) 45℃ Linear ( 45℃)

AROMA
GLASS PET
Temperature Temperature
k 1/T ln k
(K) (K)
298 0.116 0.003356 -2.154165 298
308 0.124 0.003247 -2.087474 308
318 0.132 0.003145 -2.024953 318

Arhenius Equation of Glass Visual Appearance Arhen

-1.95 -1.38
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.0031 0.00315
-1.4
-2
-1.42
f(x) = − 612.229787188474 x − 0.0997066107037734 -1.44
-2.05 R² = 0.999999988346044 f(x) =
R² = 0
Ln K
Ln K

-1.46
-2.1 -1.48
-1.5
-2.15
-1.52
-2.2 -1.54
 -2
-1.42
f(x) = − 612.229787188474 x − 0.0997066107037734 -1.44
-2.05 R² = 0.999999988346044 f(x) =
R² = 0

Ln K
Ln K
-1.46
-2.1 -1.48
-1.5
-2.15
-1.52
-2.2 -1.54
1/T

y = -612,23x - 0,0997
ln K y -Ea/R -612.23 ln K
ln Ko -0.0997 Ea/R 612.23 ln Ko
Ea (J/mol) 5090.08 R 8.314 Ea (J/mol)

AL APPEARANCE
GLASS PET
T = 28℃ = 301 K Q= 5.5 T = 28℃ =
y= - 0,0997 - 612,23 (1/T) Qo = 9 y=
Ln kt = - 0,0997 - 612,23 (1/301) ts = (Qo-Q)/kt Ln kt =
Ln kt = -2.1336867 29.56082 Ln kt =
ts =
kt = 0.11839998 days kt =
PET
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,19x + 9,34 y = -0,0269x + 2,2569 R² = 0,9548 R² = 0,9236
35℃ y = -0,196x + 9,2 y = -0,0279x + 2,2394 R² = 0,9868 R² = 0,9748
45℃ y = -0,202x + 9,18 y = -0,0291x + 2,2386 R² = 0,9912 R² = 0,9795

GLASS
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,116x + 9,38 y = -0,0147x + 2,2472 R² = 0,8742 R² = 0,8557
35℃ y = -0,124x + 9,38 y = -0,0158x + 2,2478 R² = 0,8998 R² = 0,8838
45℃ y = -0,132x + 9,34 y = -0,017x + 2,244 R² = 0,9252 R² = 0,9127

USE ORDER KINETIC REACTION 0 since the R² amount in order 0 is bigger than the order
1

PET
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,22x + 9,42 y = -0,0332x + 2,2796 R² = 0,9331 R² = 0,8832
35℃ y = -0,228x + 9,22 y = -0,0349x + 2,2557 R² = 0,9851 R² = 0,9496
45℃ y = -0,238x + 9,12 y = -0,037x + 2,2447 R² = 0,9964 R² = 0,9766

GLASS
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,106x + 9,16 y = -0,0132x + 2,2199 R² = 0,9753 R² = 0,97
35℃ y = -0,114x + 9,04 y = -0,0145x + 2,2069 R² = 0,9905 R² = 0,9875
45℃ y = -0,138x + 9,2 y = -0,0183x + 2,2304 R² = 0,9142 R² = 0,8992

USE ORDER KINETIC REACTION 0 since the R² amount in order 0 is bigger than the order
1
 PET
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,22x + 9,42 y = -0,0332x + 2,2796 R² = 0,9331 R² = 0,8832
35℃ y = -0,228x + 9,22 y = -0,0349x + 2,2557 R² = 0,9851 R² = 0,9496
45℃ y = -0,238x + 9,12 y = -0,037x + 2,2447 R² = 0,9964 R² = 0,9766

GLASS
Temperature Equation order 0 Equation order 1 Order 0 Order 1
25℃ y = -0,106x + 9,16 y = -0,0132x + 2,2199 R² = 0,9753 R² = 0,97
35℃ y = -0,114x + 9,04 y = -0,0145x + 2,2069 R² = 0,9905 R² = 0,9875
45℃ y = -0,138x + 9,2 y = -0,0183x + 2,2304 R² = 0,9142 R² = 0,8992

USE ORDER KINETIC REACTION 0 since the R² amount in order 0 is bigger than the order
1

GLASS
Temperature
k 1/T ln k
(K)
0.22 0.003355704697987 -1.51412773262978 298
0.228 0.003246753246753 -1.4784096500277 308
0.238 0.00314465408805 -1.43548460531066 318

Arhenius Equation of PET Aroma Arheniu

-1.38 -1.8
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.0031 0.00315
-1.4 -1.85
-1.9
-1.42
-1.95
-1.44 -2
f(x) = − 372.126540555731 x − 0.266954302265599
R² = 0.994881793288146 f(x) = − 1
Ln K

Ln K

-1.46 -2.05 R² = 0.92

-1.48 -2.1
-2.15
-1.5
-2.2
-1.52 -2.25
-1.54 -2.3
 -1.9
-1.42
-1.95
-1.44 -2
f(x) = − 372.126540555731 x − 0.266954302265599
R² = 0.994881793288146 f(x) = − 1
Ln K

Ln K
-1.46 -2.05 R² = 0.92
-1.48 -2.1
-2.15
-1.5
-2.2
-1.52 -2.25
-1.54 -2.3
1/T

y = -372,13x - 0,267
y -Ea/R -372.13
-0.267 Ea/R 372.13
3093.88882 R 8.314

AROMA

301 K Q= 5.5
-0,267 - 372,13 (1/T) Qo = 9
-0,267 - 372,13 (1/301) ts = (Qo-Q)/kt
-1.50331229 15.73795421
ts =
0.22239231 days
 TEXTURE
PET
Temperature
k 1/T ln k
(K)
0.106 0.003356 -2.24431618487 298
0.114 0.003247 -2.17155683059 308
0.138 0.003145 -1.98050159382 318

Arhenius Equation of Glass Aroma Arhenius Equati

-1.8 -1.38
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.0031 0.00315 0.0032
-1.85 -1.4
-1.9
-1.42
-1.95
-2 -1.44
f(x) = − 372.12654
f(x) = − 1243.50323217392 x + 1.90806356928441 R² = 0.994881793
Ln K

Ln K

-2.05 R² = 0.927787357220809 -1.46

-2.1 -1.48
-2.15
-1.5
-2.2
-2.25 -1.52
-2.3 -1.54
 -1.9
-1.42
-1.95
-2 -1.44
f(x) = − 372.12654
f(x) = − 1243.50323217392 x + 1.90806356928441 R² = 0.994881793
Ln K

Ln K
-2.05 R² = 0.927787357220809 -1.46
-2.1 -1.48
-2.15
-1.5
-2.2
-2.25 -1.52
-2.3 -1.54
1/T

y = -1243,5x + 1,9081 y = -372,

ln K y -Ea/R -1243.5 ln K
ln Ko 19081 Ea/R 1243.5 ln Ko
Ea (J/mol) 10338.46 R 8.314 Ea (J/mol)

GLASS PET
T = 28℃ = 301 K Q= 5.5 T = 28℃ =
y= 1,9081 - 1243,5 (1/T) Qo = 9 y=
Ln kt = 1,9081 - 1243,5 (1/301) ts = (Qo-Q)/kt Ln kt =
Ln kt = -2.223129 ts = 32.32666 Ln kt =
kt = 0.10827 days kt =
 GLASS
Temperature
k 1/T ln k k 1/T
(K)
0.22 0.0033557 -1.514128 298 0.106 0.003356
0.228 0.00324675 -1.47841 308 0.114 0.003247
0.238 0.00314465 -1.435485 318 0.138 0.003145

Arhenius Equation of PET Texture Arhenius Equation of Gl

-1.38 -1.8
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.0031 0.00315 0.0032 0.00325
-1.4 -1.85
-1.9
-1.42
-1.95
-1.44 -2
f(x) = − 372.126540555731 x − 0.266954302265599
R² = 0.994881793288146 f(x) = − 1243.50323217392 x +
Ln K

Ln K

-1.46 -2.05 R² = 0.927787357220809

-1.48 -2.1
-2.15
-1.5
-2.2
-1.52 -2.25
-1.54 -2.3
 -1.9
-1.42
-1.95
-1.44 -2
f(x) = − 372.126540555731 x − 0.266954302265599
R² = 0.994881793288146 f(x) = − 1243.50323217392 x +
Ln K

Ln K
-1.46 -2.05 R² = 0.927787357220809
-1.48 -2.1
-2.15
-1.5
-2.2
-1.52 -2.25
-1.54 -2.3
1/T 1/T

y = -372,13x - 0,267 y = -1243,5x + 1,9

y -Ea/R -372.13 ln K y
-0.267 Ea/R 372.13 ln Ko 19081
3093.88882 R 8.314 Ea (J/mol) 10338.46

AROMA
GLASS
301 K Q= 5.5 T = 28℃ 301 K
-0,267 - 372,13 (1/T) Qo = 9 =y = 1,9081 - 1243,5 (1/T)
-0,267 - 372,13 (1/301) ts = (Qo-Q)/kt Ln kt = 1,9081 - 1243,5 (1/30
-1.503312292 15.7379542141544 Ln kt = -2.223129
ts =
0.2223923105 days kt = 0.10827
 ln k

-2.244316
-2.171557
-1.980502

nius Equation of Glass Texture

15 0.0032 0.00325 0.0033 0.00335 0.0034

(x) = − 1243.50323217392 x + 1.90806356928441

² = 0.927787357220809
(x) = − 1243.50323217392 x + 1.90806356928441
² = 0.927787357220809

1/T

y = -1243,5x + 1,9081
-Ea/R -1243.5
Ea/R 1243.5
R 8.314

Q= 5.5
1,9081 - 1243,5 (1/T) Qo = 9
1,9081 - 1243,5 (1/30ts = (Qo-Q)/kt
ts = 32.32666
days
1. a. Order 0
Storage Color Bleaching (%)
(months) 30℃ 40℃ 50℃
0 100 100 100
0.2 97 96 95
0.6 92 90 88
2 88 80 79
3 82 77 75

Order 0
120 4.7
100 4.6
Color Bleaching (%)

Color Bleaching (%)

f(x) = − 5.37170263788969
7.81175059952038 x + 98.031175059952
7.44604316546763 97.2374100719424
96.4616306954436 f(x)
f(x)
80 R² = 0.940047961630695
0.936030932339149 4.5 R²
0.922820583062109 R² ==
60 4.4
40 4.3
20 4.2
0 4.1
0 0.5 1 1.5 2 2.5 3 3.5 0
Storage (months)

Color Bleaching (%) 30℃ Linear (Color Bleaching (%) 30℃)

40℃ Linear ( 40℃)
50℃ Linear ( 50℃)

R² at order 1 > order 0 so this kinetic reaction uses order 1

b. Temperature
k 1/T ln k
(K)
303 0.0594 0.0033 -2.823461
313 0.0855 0.003195 -2.459239
323 0.0909 0.003096 -2.397995

Arhenius Equation
-2.1
0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335
-2.2
-2.3
-2.4 f(x) = − 2097.07122717509 x + 4.14424019082423
R² = 0.868135507142711
ln K

-2.5
-2.6
-2.7
-2.8
-2.9
1/T

c. T = 20℃ = 293 K Q= 50 Ln Q = 3.912023

y= 4,1442 - 2097,1 (1/T) Qo = 100 Ln Qo = 4.60517
Ln kt = 4,1442 - 2097,1 (1/293) ts = (Ln Qo - Ln Q)/kt
Ln kt = -3.013138 14.106348769
ts =
kt = 0.049137 months
Order 1
Storage Color Bleaching (%) Temperature
(months) 30℃ 40℃ 50℃ 30℃
0 4.60517 4.605170186 4.60517018598809 40℃
0.2 4.574711 4.5643481915 4.55387689160054 50℃
0.6 4.521789 4.4998096703 4.47733681447821
2 4.477337 4.3820266347 4.36944785246702
3 4.406719 4.3438054219 4.31748811353631

Order 1
4.7
4.6
Color Bleaching (%)

f(x)
f(x) == −− 0.0594417294857579
0.0909043049777267 xx ++ 4.58609756686007
0.0854557472427186 4.57816068766431
4.5701129653882
4.5 R²
R² == 0.948191966889765
0.949448959250379
0.941051547671727
4.4
4.3
4.2
4.1
0 0.5 1 1.5 2 2.5 3 3.5
Storage (months)

Color Bleaching (%) 30℃ Linear (Color Bleaching (%) 30℃)

40℃ Linear ( 40℃)
50℃ Linear ( 50℃)

y = -2097,1x + 4,1442
ln K y -Ea/R -2097.1
ln Ko 4.1442 Ea/R 2097.1
Ea (J/mol) 17435.29 R 8.314

The energy activation is 17435,29 J/mol

the estimated product shelf life at 20°C assuming the acceptability limit of
color bleaching equal to 50% is 14 months
 Equation order 0 Equation order 1 Order 0 Order 1
y = -5,3717x + 98,031 y = -0,0594x + 4,5861 R² = 0,94 R² = 0,9482
y = -7,446x + 97,237 y = -0,0855x + 4,5782 R² = 0,936 R² = 0,9494
y = -7,8118x + 96,462 y = -0,0909x + 4,5701 R² = 0,9228 R² = 0,9411
2. a. Order 0
Peroxide number of rempeyek
Storage (meg/1000 g)
(days)
25℃ 35℃ 45℃
0 1.35 1.23 1.23
3 2.07 3.54 7.33
6 3.36 29.46 52.31
9 8.61 164.05 1318.84
12 149.89 2055.55 7869.57
15 4078.37 8295.42 17065.88
18 2463.69 7792.4 13655.78

Order 0
Peroxide number of rempeyek (meg/1000 g)

Peroxide number of rempeyek (meg/1000 g)

18000 12
16000 f(x) = 0.5
10
14000 f(x) = 986.881071428571 x − 3171.79535714286 R² ==0.92
f(x) 0.5
12000 R² = 0.783731819522766 8 R² = 0.96
f(
10000 R
6
8000
6000 f(x) = 499.801904761905 x − 1877.98142857143 4
4000 R² = 0.734290595692555
2
2000 f(x) = 186.739880952381 x − 722.4675
0 R² = 0.539171229139175 0
0 2 4 6 8 10 12 14 16 18 20 0 2
Storage (days)

Peroxide number of rempeyek (meg/1000 g) 25℃

Linear (Peroxide number of rempeyek (meg/1000 g) 25℃)
35℃
Linear ( 35℃)
45℃
Linear ( 45℃)

R² at order 1 > order 0 so this kinetic reaction uses order 1

b. Temperature
k 1/T ln k
(K)
298 0.494 0.0033557 -0.70521976
308 0.5479 0.00324675 -0.60166249
318 0.577 0.00314465 -0.54991301

Arhenius Equation
0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
-0.1
-0.2
-0.3
ln K

-0.4
-0.5
f(x) = − 738.271688834775 x + 1.77974053233457
 0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
-0.1
-0.2
-0.3

ln K
-0.4
-0.5
-0.6 f(x) = − 738.271688834775 x + 1.77974053233457
R² = 0.970867575951093
-0.7
-0.8
1/T

T = 30℃ = 303 K Q= 4427.2 Ln Q = 8.395523

y= 1,7797 - 738,27 (1/T) Qo = 1.35 Ln Qo = 0.300105
Ln kt = 1,7797 - 738,27 (1/303) ts = (Ln Qo - Ln Q)/kt
Ln kt = -0.656835 15.61345
ts =
kt = 0.51849 days

the estimated product shelf life at 30°C with critical limit of peroxide number:
4427.20 meq / 1000 g either in Qo = 1,35 or Qo = 1,23 is 15 days
Order 1
Peroxide number of rempeyek
Storage Temperature
(meg/1000 g)
(days)
25℃ 35℃ 45℃ 25℃
0 0.30010459 0.20701417 0.207014169 35℃
3 0.72754861 1.26412673 1.991975516 45℃
6 1.21194097 3.38303341 3.957187557
9 2.15292432 5.10017126 7.184507841
12 5.00990169 7.62829873 8.970758702
15 8.31345268 9.02345883 9.744836428
18 7.80941551 8.96090418 9.521918154

Order 1
Peroxide number of rempeyek (meg/1000 g)

12

10 f(x) = 0.57695243955291 x + 0.747170667997662

R² ==0.927648572474225
f(x) 0.5479238043116 x + 0.149686805617972
8 R² = 0.966312202656699
f(x) = 0.494020257101788 x − 0.799712547244095
6 R² = 0.893333196321123

0
0 2 4 6 8 10 12 14 16 18 20

Storage (days)

Peroxide number of rempeyek (meg/1000 g) 25℃

Linear (Peroxide number of rempeyek (meg/1000 g) 25℃)
35℃
Linear ( 35℃)
45℃
Linear ( 45℃)

y = -738,27x + 1,7797
ln K y -Ea/R -738.27
ln Ko 1.7797 Ea/R 738.27
Ea (J/mol) 6137.97678 R 8.314
The energy activation is 6137,9768 J/mol

Q= 4427.2 Ln Q = 8.395523
Qo = 1.23 Ln Qo = 0.207014
ts = (Ln Qo - Ln Q)/kt
15.7929939
ts =
days
 Equation order 0 Equation order 1 Order 0 Order 1
y = 186,74x - 722,47 y = 0,494x - 0,7997 R² = 0,5392 R² = 0,8933
y = 499,8x - 1878 y = 0,5479x + 0,1497 R² = 0,7343 R² = 0,9663
y = 986,88x - 3171,8 y = 0,577x + 0,7472 R² = 0,7837 R² = 0,9276
3. a. Order 0
Temperature 60℃
Time (days) H3O+ Concentration (M)
0 5.5
0.02 5.62
0.08 6.46
0.17 7.08
0.31 8.91
0.94 11.48
1 13.49
1.28 13.8

Order 0 Temperature 60℃

16
14
f(x) = 6.58729987018607 x + 5.91353256166162
H3O+ Concentration (M)

12 R² = 0.964735672644525

10
8
6
4
2
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4
Time (days)

Temperature Equation order 0 Order 0

20℃ y = -0,0187x + 5,2395 R² = 0,92
30℃ y = 0,5403x + 5,7549 R² = 0,9477
45℃ y = 1,8689x + 5,4623 R² = 0,9798
60℃ y = 6,5873x + 5,9135 R² = 0,9647

b. Temperature
k 1/T ln k
(K)
293 0.0187 0.00341296928327645 -3.97923176
303 0.5403 0.0033003300330033 -0.61563074
318 1.8689 0.00314465408805031 0.62535002
333 6.5873 0.003003003003003 1.88514355

Arhenius Equation
3
2 f(x) = − 13318.5979271141 x + 42.3013846073818
R² = 0.896265721085338
1
0
0.00295 0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.00345
ln K

-1
 Arhenius Equation
3
2 f(x) = − 13318.5979271141 x + 42.3013846073818
R² = 0.896265721085338
1
0
0.00295 0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.00345

ln K
-1
-2
-3
-4
-5
1/T
 Temperature 45℃
Time (days) H3O+ Concentration (M)
0 5.5
0.09 5.37
0.31 6.03
1 6.92
1.28 7.94
2 9.12
2.28 10.72
5 14.45

Order 0 Temperature 45℃ Or

16 16
f(x) = 0.5403
14 f(x) = 1.86889584907244 x + 5.4622507056367 14 R² = 0.94767
R² = 0.979796769953112
H3O+ Concentration (M)

H3O+ Concentration (M)

12 12
10 10
8 8
6 6
4 4
2 2
0 0
0 1 2 3 4 5 6 0
Time (days)

T = 25℃ = 298 K
y= 42,301 - 13319 (1/T)
Ln kt = 42,301 - 13319 (1/298)
Ln kt = -2.39363087
kt = 0.09129759
Q= 8 Q= 8
Qo = 5.5 Qo = 5.26
ts = (Qo - Q)/kt ts = (Qo - Q)/kt
27.3829787 30.0117446349724
ts = ts =
days days

The shelf life of a coffee brew at 25oC, assuming the acceptability limit for H3O + ·10-6
equal to 8.0 for Qo = 5,5 is 27 days and for Qo = 5,26 is 30 days
 Temperature 30℃ Temperature 20℃
Time (days) H3O+ Concentration (M) Time (days)
0 5.5 0
0.17 5.13 1
1 6.03 2
2 6.03 3.29
3.17 7.08 7
6 9.77 9
7 10.47 11
8 10.47 15
10 12.59 18
14 14.13 21
17 14.45 24
20 15.14

Order 0 Temperature 30℃ Order 0 Temper

16 5.4
f(x) = 0.540306046237764 x + 5.75494698961299
14 R² = 0.947679936519038 5.3
H3O+ Concentration (M)

H3O+ Concentration (M)

12 5.2 f(x) = − 0.018725433570987 x + 5
5.1 R² = 0.9200415792961
10
5
8
4.9
6
4.8
4 4.7
2 4.6
0 4.5
0 5 10 15 20 25 0 5 10
Time (days) Time
 Temperature 20℃
H3O+ Concentration (M)
5.26
5.28
5.2
5.2
5.1
4.98
4.96
4.95
4.92
4.9
4.8

Order 0 Temperature 20℃

5.4
5.3
H3O+ Concentration (M)

5.2 f(x) = − 0.018725433570987 x + 5.2394503183741

5.1 R² = 0.9200415792961

5
4.9
4.8
4.7
4.6
4.5
0 5 10 15 20 25 30
Time (days)