Force acting on a body is given by the equation F= ze *" where xis the position of the body. The dimensional formula for 8 is O [ML2T1] O [ML 17] O [M?2L377] O [M'LT)]A ball is projected vertically upwards from a point with initial velocity 20 m/s at t= 0. One second later, another ball is projected vertically upwards from the same point with initial velocity of 30 m/s. [g = 10 m/s?]. The time instant t when they collide is O 225s © 2.00s © 250s O 175sThe acceleration (a) versus position (x) graph for a particle moving in one dimension is given in figure below. If initial velocity of the particle is zero, then find its velocity when it is at x = 4 m. a(m/s’) x(m) O 2m/s O 8m/s O amis O 6m/sA particle is projected with velocity 60 m/s at an angle 6 = 60° with the horizontal from a point on the ground. The time ‘? after which its velocity becomes perpendicular to its initial velocity is O 48s O4s O 6s O 68sThe acceleration of a particle moving in circular motion of radius 10 m is 2 m/s? along negative x-direction at point P. The speed of the particle at Pis Yy O 5m/s O 42 mis O 542 mis O 4m/sFind the maximum value of applied force Fwhich can be exerted on the rope so that block A of mass m does not slip on block Bof mass 3m. The coefficient of static friction between the two blocks is ps. 3 O ghsng O Znmg O Lug O 2 mgIn the figure shown, a block of mass Mis dropped. It falls freely for 2m and then strikes an ideal spring. It compresses the spring by 0.5 m before it rebounds. The spring constant of the spring is k = 500 N/m. Then, Mis equal to (g = 10 m/s?) 2m 05m k= 500 Nim O 2.5kg O 3kg O 1.5kg O 3.5kgTo measure acceleration due to gravity, a simple pendulum is used. If the percentage error in the measurement of time period is 1% and percentage error in measurement of length of the pendulum is 0.5%, the percentage error in calculation of acceleration due to gravity will be O 1.5% O 25% O 2%In the figures shown, forces are applied as indicated and pulleys, strings are ideal. The acceleration of block Ais maximum in F,=3mg a A“ F,22mq 4 emg (a) (b) (c) O Case (a) O Case (b) © Case (c) O same in all casesA small block of mass m slides down a smooth track which ends into a vertical circular loop of radius R. Find the force it exerts on the circular track at the highest point. mThe potential energy of particle of mass m= 0.2 kg 4 moving in one dimension is given by u(x) = —4.x? ae where u(x) is in joules and xis in meters. The velocity of the particle at x = 0 is v= 5 m/s. The maximum kinetic energy of the particle during its journey is © 4.254 © 6.504 © 3.504 O 10.5uA wooden block of mass 0.5 kg is kept on two tables as shown. A bullet of mass m= 20 gm moving vertically with velocity 300 m/s strikes the block and comes out with velocity 100 m/s. Find the height to which block rises. (g = 10 m/s?) f 00 m/sFigure shows five identical blocks lying on a smooth horizontal surface. They are given speeds as shown in figure. They undergo several head-on elastic collisions. The final velocity of block 4 is 5m/s 3ms 4 m/s —> + mmm mm BLIZZ se. O Zero O 5m/s O 3 m/s O amis SCsA body is projected from the ground for horizontal range equal to 50 m. At highest point, it breaks into three parts A, Band C. Part A retraces its path and B comes to rest. If m4: Mg: Me= 2:1: 1, then find where part Clands on the ground from the point of projection. O 175m © 150m © 100m O 125mFour thin identical rods, each of mass mand length ‘¢ ’ are joined to form a square frame as shown in figure. Find the moment of inertia of frame about the axis AA’.A uniform ring is released from rest at point A as shown. In part AB, friction is sufficiently large to prevent slipping while part BC of the inclined plane is smooth. m Find the velocity of the ring at point C. O 2Jgn ashown. In part AB, friction is sufficiently large to prevent slipping while part BC of the inclined plane is smooth. m Find the velocity of the ring at point C. O 2Jon O 3Jon O Jean O aAn ornament weighs 60 gm in air and 56 gm in water. But when it is submerged in an unknown liquid, it weighs 57 gm. Find the specific gravity of the unknown liquid. O 0.75 O 08 O12 O09The terminal velocity of a rain drop is 5 m/s. Find its acceleration when its velocity is 2.0 m/s at a certain height A. O 4%Three blocks of equal mass are suspended from three wires of equal cross-sectional areas and equal lengths as shown in the figure. Y;, Yo and Y3 are Young's modulii of the wire segments as shown. If ¥: Yo: ¥3=1:2:3andA¢,,A¢2and A¢ 3 are the extensions in three wire segments from top to bottom respectively then the ratio of extension Afé,:Af2: Ag 3 IS © 3:2:1 O 1:2:3 O1:3:5A spherical ball contracts in volume by 0.0002% when it is submerged in a lake up to a depth of 10 m. The bulk modulus of material is © 2x 101° N/m? O 4x 1019 N/m? O 5x 1010 N/m? © 6x 101° N/m2If gis the acceleration due to gravity at the surface of earth. The amount of work required to lift a body of mass m from the surface of earth to a height twice the radius of earth is = mar. Find k.A drop of liquid of radius 3 cm is split into 27 identical liquid drops. The amount of work required to split it is 1x x 10-5J. Find x. [Surface tension of liquid is equal to 3 x 1072 N/m]The displacement of a particle of mass 2 kg along x-axis under the action of force varies as x -0 + 3t +1. Where xis in meters and ¢ is in seconds. Starting at t= 0, the amount of work done by the force in first four seconds is kx 10? J. Find k.In the given figure, system is released from rest. Block B after colliding with the floor comes to rest. Find the maximum height (above ground) in meters to which block A rises. (g = 10 m/s?)A particle of mass mis attached to one end of uniform rod of mass mand length L. The rod is falling vertically with velocity v. Suddenly its other end gets stuck in a frictionless hook at point O (see figure). The angular velocity of the rod is n rad/s. Find n. [L = 10 cm, v = 4 m/s] —y,Two men A and Bof mass 80 kg and 60 kg are standing on a horizontal platform resting on a smooth horizontal surface. To measure the mass of the platform they exchange their position and observe that platform is displaced by 0.5 m. The mass of the platform is 10x kg. Find x. B m, = 80 kg eR OO hie Smooth L=10m surfaceA planet has twice the density of earth and its radius is three times that of earth. The escape velocity on the surface of this planet is x2 times the escape velocity on the surface of earth. Find x.In the figure shown, a block of mass 2M is attached to a uniform rope of mass M, length L and cross- section area A. Young’s modulus of the material of kMgL YA rope is Y. If elongation of the rope is _ then find k ‘ L MWater level in a tank is kept at height H = 10 m. Two small holes are made on the vertical walls of the tank such that water emerging from the two holes strikes the floor a same distance das shown in figure. If h, is 2.2 m then fy = xm. Find x 10mConsider the following overall reaction for formation of C and D Ao +2B 5 C+D The mechanism of the reaction follows given steps Kee A= A, -E—25D (Slow) The rate law is found to be - Hl asic E=c (Fast equilibrium) where K' represents a constant] The value of x + y isThe time required, in minutes to deposit 2.54 g of copper by passing a current of 4 A through an aqueous solution of CuSO, is [The current efficiency is 80%.] [Molar mass of Cu = 63.5 g/mol] [Round off to the nearest integer]What is the weight of solute, in grams, required in 36.0 g of water to reduce the vapour pressure to 4/7" of pure water. [Given : Molar mass of solute = 50 g/mol]LiCl has rock salt structure. The distance between Lit and CI” in LiCl, if density is 3 g/cm? is a x 10-8 cm. The number of second nearest neighbour of CI- is y. Then, the sum of a and y is [Round off to the nearest integer] [Molar Mass of LiCl = 42 g/mol, Na = 6 x 1023, (93.3)1/9 = 4.5]Consider the following balanced Redox reaction KoCr207 + 14HCI = xA + yB + 3Clp + 7H20 The value of sum of x andy isThe vapour density of PCls at a certain temperature is 60. The percentage dissociation of PCls at this temperature is [Round off to the nearest integer] [Molar masses of P and Cl are 31 and 35.5 g/mol respectively]The magnitude of work done by 2 moles of a gas when it undergoes isothermal reversible expansion from 1 L to 2 L at 300 K is 34.4 x 10% J. The value of x is [Assume gas behaves ideally] log2 =0.3 R=8.3 JK™ molThe density of vapour of a substance (X) at 1 atm pressure and 400 K is 1.2 kg/m®. The vapour effuses through a small hole at a rate of 2/3 times slower than oxygen under the same condition. The compressibility factor (z) of the vapour is (Take R = 0.08 L atm K"! mol") [Round off to the nearest integer]The velocity of an electron in a certain Bohr's orbit (n) of He® ion has the ratio 1/300 (approx) to the velocity of light. The wave number of radiations emitted when electron jumps from (n — 2) state of H atom to ground state is 3Ry . The value of a is a (Ry = Rydberg constant)An alloy was discovered which contains 68% iron, 22% nickel and 10% manganese. The density of alloy is 9.5 g/cm3. Number of iron atoms in a block of alloy measuring 5 cm x 10 cm x 20 cmis x x 1025. Then the value of x is [Molar mass of Fe = 56 g/mol] [Round off to the nearest integer]An alloy was discovered which contains 68% iron, 22% nickel and 10% manganese. The density of alloy is 9.5 g/cm’. Number of iron atoms in a block of alloy measuring 5 cm x 10 cm x 20 cmis x x 1025. Then the value of x is [Molar mass of Fe = 56 g/mol] [Round off to the nearest integer]The conductivity of 100 ml, 0.1 M NaOH solution is 0.015 S cm~7. When equal volume of 0.05 M HCI solution is added, the conductivity of the final solution becomes [Given : (Ay sc, = 200 S cm? mol] Consider molar conductivity of the strong electrolyte remains constant when the solutions are mixed. © 3.60 x 1072S cm © 4.50 1073 Sem" © 8.75x 10-3 Som © 1.175x10-2ScmConsider the following cell, which contains buffer solution of HA and Nad in both the compartments. pK, =5 HAY HA (2M) NaA (0.2 M) Find the cell e.m.f. at 25°C. © 0.059 Vv O 0.118V © 0.177V OovA gaseous compound A reacts by three different first- order processes in order to form B(g), C(g) and D(g). The rate constants for the formation of B, C and D are 0.3 x 1074 s“1, 0.755 x 1074s“! and 0.331 x 1074 s71 respectively. Initially pure A was taken in a closed container with a pressure of 16 atm. The partial pressure of B after 5 x 10° sec will be Bg) A(g) ————> Cig) D(g) © o8atm © 1.2atm O 1.5 atm © 1.73 atmConsider the following reaction X+Y5Z+W This reaction has been started with 1 M of X and Y each. This follows rate law r=K [x]/2 [y]"/2 Rate constant is given as 0.046 s The time taken for concentration of Y to become 0.5 M is [log 2 = 0.3] -1 © 15sec © 30 sec © 35 sec © 40 secA solution contains 12 g of a non-volatile solute (neither dissociates nor associates in solution) in 100 g of water (which) has a density of 1.2 g/mL and an osmotic pressure of 10 atm at 127°C. The molar mass of solute is nearly [R = 0.08 L atm K~? mol™*] © 350 g/mol © 365 g/mol © 461 g/mol © 482 g/molAn industrial waste water is found to contain 16.4% Nag3PO, and 24% MgSO, by mass in solution. If the percentage ionisation of NagPO, and MgSO, are 70 and 80 respectively, then its normal boiling point is Given : Kyu) = 0.5K kg mol7! © 102.6°c © 110.3°c © 105.6°C © 115.9°CA pure substance A forms a cubic closed packed arrangement with density 2 g/cc. Another solid is made in which all the tetrahedral voids in the above solid is occupied by B atom, then density of the resulting solid is [Given : Atomic mass of A = 50 g/mol and B = 80 g/mol] O 84 g/cc © 64g/cc O44 g/cc O24 g/ccA solid consists of three atoms A, B and C. A is present at all the corners and all the face centres, B is present at all the octahedral voids and C is present at all the tetrahedral voids. If atoms along one of the three fold axes of symmetry are removed, then formula of crystal becomes © ABCs © AoB3Co O AsBaCg © AsB11CayA 250 ml of solution of iodine is divided into two parts. Part | reacts with hypo solution in acidic medium. It was observed that 20 ml of 0.5 M hypo was used. Part Il was reacted with 50 ml of 0.7 M conc. NaOH solution. Excess NaOH required 50 ml of 0.2 M H2SO, solution for complete neutralizations. Find the initial concentration of iodine. © 0.01M © 0.02M © 0.05M © 008Mlodometric titrations are used to determine strength of unknown solution. A solution of NazS203 is standardized iodometrically against 0.501 g of KBrO3. This process required 100 ml of Na2S203 solution. What is the normality of NazS203 solution? [Molar masses of K and Br are 39 g/mol and 80 g/mol respectively] O2Nn © 0.18N Os8n O 6NConsider the following wave function for H-atom 1 r The value of principal quantum number of the above wave function and the number of radial nodes are respectively 2 Wr, 8b) = e~® (3 cos? 6-1) © 3and1 © 3and0 © 3and2The molarity of HNO3 solution is 0.8 M. The density of the solution is 1.08 g/cm. The molality of the solution (approx) and % a of the solution respectively are © 0.8 mand 4.67% © 1.2mand 8% © 0.8 mand 10% © 1.2m and 5%A buffer solution contains 0.2 mole of NH3 and 0.1 mole of NH,Cl. The change in pOH when 0.04 moles of HCI was dissolved in above solution is | Given: log? = -0.08 andlog2 = 03, © 0.12 O 0.24 © 0.50 )S?- ion concentration in a saturated solution (0.1 M) of H2S whose pOH was adjusted to 11 by addition of HCI is [Given : K,K,, =1.2x107"] © 1.010718 M O 1.21071 M O 1.0x10774M O 1.6«10-4MAt 400 K, 12 g magnesium is dissolved in dilute hydrochloric acid (aqueous) in an open vessel at the atmospheric pressure of 0.8 atm. The work done by the system is © -43Latm © -16.4L atm © -19.6Latm © -0.3LatmTwo mole sample of a triatomic non-linear ideal gas at 600 K is allowed to expand under reversible adiabatic condition from 2 L to 54 L. The values of AH and AU for the process respectively are (R = 8.3 JK"! mol") © 12.43 kJ and 16.35 kJ © -12.35 kJ and -18.65 kJ © ~26.56 kJ and -19.92 kJ © 13.56 kJ and 19.68 kJThe van der Waals constant b for a real gas is 41.67 mL mol". The molecular diameter of gas is [Take (33.6)'/ = 3.23, Ny = 6 x 1023, m= 3.1] © 3.23A O 5.68A © 268A © 9.60AWhich one of the following is incorrect with regards to Maxwell distribution of molecular speed? The numerical value of Ump (most probable O speed) increases with increase in temperature for a gas The sharpness of maxima in curve increases with increase in temperature for a gas A very small fraction of molecules have very high and very low speeds . O Urms > Yay > UmpAn electron in H-atom jumps from a higher energy level (n) to 2™ energy level. If six spectral lines are possible for the transition, then the degeneracy of higher energy level nis O 9 O16 © 2525 g of a mixture contains NaCl and Na,CO, . This mixture is heated with dilute HCI in order to evolve 8.8 g of CO, at STP. The percentage of NaCl in the original mixture is nearly © 15% © 20% O 25% © 30%Number of real solutions of the equation (sinx ~ J cos x|cos3x = lying in [0, 2z]is equal toIf z;, Oand Zz form an equilateral triangle in the Argand Plane, where z, and zp are the roots of the equation 32° ~ 3z = 2. =0 and Ois the origin, then the value of AisFive balls are to be placed in four boxes. Each can hold all the five balls. Number of ways in which we can place the balls so that no box remains empty, if the balls as well as boxes are identical, is equal toThe letters of the word 'SEVEN' are written in all possible orders and these words are rewritten out as in a dictionary. The rank of the word 'SEVEN' is equal toThe remainder (less than 53) when 232°'9 is divided by 53, is equal toThe least possible value of n EN if 3, 7, 11, ..., nand 2, 9, 16, ..., 709 have 14 terms in common, is equal to k. The sum of the digits of kis equal to Ancwer:The number of distinct terms in the expansion of {x =afy? —4 r +(x =x? =1 ' will be equal toIf a complex number z moves such that Re(Z)| = |im/z}| =-V3,, then the area (in sq. units) bounded by all such positions of zis AmritsarConsider three complex numbers Z}, Z2, Z3 such that lz,|=1 |z,|=2, |z,| =3. The value ofIf a and B be the real roots of the equation x? —(m-2)x =(m* = 3m = 5)=0, then the maximum value of a2 + B? is Answer:Let y= Fee —r(n—2)=+1 ;n€Nthen re (n-r)"C, O yen-1 n O yz2 O yen-+The number of ways in which three people can divide among themselves six identical apples, one orange, one lemon, one banana, one pear, one plum and one apricot is © 8c, O (3) © 8, x (3)8 © 8e, x (3)6If maximum and minimum values of the determinant j=sin?x cos’ x sin 2x sin? x 1=cos’x sin2x | areaandB sin’ x cos’x 1=sin2x| respectively, then © a+p%=5 O a8- p17 =25 (a2" — 82") is always an even integer for néEN A triangle can be constructed having its sides as a,B anda-Bx? 4x43 14 If the expression |2x* +x°+2x+1 2 3] is equal x? +X 11 to ax* + bx? + cx* + dx+ e, then the value of eis equal to © Zero O14 OsIf (x) = a+ bx+ cx? and a, B, ¥ are the roots of the abe bca c ab equation x° = 1, then is equal to © fa) + 8) + £7) © fa) AB) + AB) AY) + KT) Ka) © fa) AB) £7) O - Ka) AB) (7)If Ais a square matrix of order n such that |adj (adj A)| = |AI°, then the value of ncan be O4 O2 O14 O3lf Aand Bare symmetric matrices of the same order and X= AB+ BAand Y= AB - BA, then (XY)"is equal to O xy © yx © -yxThe sum of the radii of the circles inscribed and circumscribed about a regular polygon of '6' sides, if length of the side of polygon is 8 units, will be O 8-43 O 8-48 © 3cot15° © 3tan15°The coefficient of x1°8 in the expression (x-1)}(x-2)(x -3)...(x- 110) is not a multiple of © 37 © 55 Ou © 823If S, =5n? = 2n, S, is the sum of first n terms of a sequence, then 247 is a term lying © Between 20 and 24" term O Between 15 and 19" term O Between 24" and 27%" term O Between 27" and 30" termIf one of the middle terms in the expansion of ¢ a\F f 3) | 3x- as | is given by -5x for a, b, c& Nwith \ } \ / greatest common divisor(a, 6) = 1, then O a+b=34 O at+c=39 O b+c=35 oo)Consider a square OABC in the Argand Plane, where ‘0’ is origin and A = A(Zo). Then the equation of the circle that can be inscribed in this square is ( vertices of square are given in anticlockwise order) O |z- 2(1+ Dl =lzol = [ol O 2h Zalt+)If (a—9c¢)’ ;If z(2- 238i y = i(¥3 + i} , then the argument of zis | 3 O O O Ola ela oO | OlaIf the equations x* + ay + =0 and x® —2y° = x* +ax* + bx? +1 =0 have aas one of the common roots, then the value of a+ bmay be O -1 O2 O41 © ZeroIf a, B are the roots of the equation dx’ + ex =f =0 and T, = «” +p", then AThars = Taos is equal to Thora O -2e O -2018e O -e © 2018eThe general solution of cosec8 + cot@ = V3 is O Qnnze,nel 3 O 2nx~F.nel © anz-Z,nel eyIf 3cota.cotB = 4, then the value of easta=f) is cos(a—f)If sin? 6 — sin6 =1, then the value of sin? 6 = cos* 6 + cos*6 is O nla O rh] ow" sin(c.—p)=~ and cos(a+p)=--“ where 0 7 Sa ASF, then tan(o = 28)is OB 1 O-% O al