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SAFETY DATA SHEET

Revision nr : 2.0
Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : ANYCUBIC
Water-Wash Resin +

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Main use category : Consumer use

IC
Use of the substance/mixture : Resin

1.2.2. Uses advised against

No additional information available
UB
1.3. Details of the supplier of the safety data sheet
Shenzhen Anycubic Technology Co.,Ltd
12-13th floor，Building #3B，Vanke Times Square, No.85 Longcheng Avenue,Longcheng Street,Longgang District
518000 Shenzhen, Guangdong Province - China
YC

T 17688757950
weiwulin@anycubic.com

1.4. Emergency telephone number

Emergency number : 17688757950
AN

Only available during office hours.

Country Official advisory body Address Emergency number
PO Box 1297
Ireland National Poisons Information Centre Beaumont Road
+353 1 809 2566
Beaumont Hospital
9 Dublin (Healthcare
professionals-24/7)
+353 1 809 2166 (public,
8am - 10pm, 7/7)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU > 2015: According to
Regulation (EU) 2015/830, 2020/878 (REACH Annex II)
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Skin Sens. 1 H317
STOT SE 3 H335
Aquatic Chronic 2 H411

Full text of H- and EUH-statements: see section 16

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SAFETY DATA SHEET
Revision nr : 2.0
Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS07 GHS09

Signal word : Warning

Contains : (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate, Oxirane,
2-methyl-, polymer with oxirane, bis(2-methyl-2-propenoate), block, phenyl
bis (2,4,6-trimethylbenzoyl)-phosphine oxide
Hazard statements (CLP) : H315 - Causes skin irritation.

IC
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H411 - Toxic to aquatic life with long lasting effects.
UB
Precautionary statements (CLP) : P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face
protection.
YC

P391 - Collect spillage.

Child-resistant fastening : Not applicable
Tactile warning : Not applicable

2.3. Other hazards

AN

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for
having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with
the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a
concentration equal to or greater than 0,1 %

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Substance name Product identifier % Classification according

to Regulation (EC) No.
1272/2008 [CLP]
Oxirane, 2-methyl-, polymer with oxirane, bis(2-methyl-2- (CAS-No.) 122985-55-1 30 – 40 Skin Irrit. 2, H315
propenoate), block Eye Irrit. 2, H319
STOT SE 3, H335
Polyethylene glycol diacrylate (CAS-No.) 26570-48-9 10 – 25 Eye Irrit. 2, H319
(EC-No.) 607-960-5
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SAFETY DATA SHEET
Revision nr : 2.0
Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] (CAS-No.) 42978-66-5 15 – 25 Skin Irrit. 2, H315

diacrylate (EC-No.) 256-032-2
(EC Index) 607-249-00-X
Poly(oxy-1,2-ethanediyl), .alpha.,.alpha.'-[(1- (CAS-No.) 64401-02-1
methylethylidene)di-4,1-phenylene]bis[.omega.-[(1-oxo-2- (EC-No.) 613-584-2
propen-1-yl)oxy]-
phenyl bis (2,4,6-trimethylbenzoyl)-phosphine oxide (CAS-No.) 162881-26-7
(EC-No.) 423-340-5
(EC Index) 015-189-00-5
Eye Irrit. 2, H319
Skin Sens. 1, H317
STOT SE 3, H335
Aquatic Chronic 2, H411
10 – 20 Aquatic Chronic 2, H411
2–5 Skin Sens. 1A, H317
Aquatic Chronic 4, H413

Specific concentration limits:

Substance name Product identifier Specific concentration limits
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] (CAS-No.) 42978-66-5 ( 10 ≤C < 100) STOT SE 3, H335
diacrylate (EC-No.) 256-032-2
(EC Index) 607-249-00-X

IC
Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

UB
4.1. Description of first aid measures
Additional advice : First aider: Pay attention to self-protection!. Concerning personal protective
equipment to use, see section 8. Never give anything by mouth to an
unconscious person. In case of doubt or persistent symptoms, consult always a
physician. Show this safety data sheet to the doctor in attendance.
YC

Inhalation : Remove casualty to fresh air and keep warm and at rest. In case of doubt or
persistent symptoms, consult always a physician.
Skin contact : Remove contaminated clothing and shoes. Gently wash with plenty of soap
and water. In case of doubt or persistent symptoms, consult always a
physician.
AN

Eyes contact : Rinse immediately carefully and thoroughly with eye-bath or water. Remove
contact lenses, if present and easy to do. Continue rinsing. In case of doubt or
persistent symptoms, consult always a physician.
Ingestion : Rinse mouth thoroughly with water. Get medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation : May cause respiratory irritation.
Skin contact : May cause an allergic skin reaction. Causes skin irritation.
Eyes contact : Causes serious eye irritation.
Ingestion : May cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : carbon dioxide (CO2), powder, alcohol-resistant foam, water spray.
Unsuitable extinguishing media : Strong water jet.
5.2. Special hazards arising from the substance or mixture
Specific hazards : Not flammable. Heating will cause a rise in pressure with a risk of bursting.
Hazardous decomposition products in : Carbon oxides (CO, CO2).
case of fire

5.3. Advice for firefighters
Firefighting instructions
Protection during firefighting
Other information
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
For non-emergency personnel
UB
6.1.2. For emergency responders
For emergency responders
YC
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
AN
Methods for cleaning up
6.4. Reference to other sections
Concerning personal protective equipment to use, see section 8. Concerning disposal elimination after cleaning, see
section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling
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SAFETY DATA SHEET
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Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +
: Evacuate area. Use water spray or fog for cooling exposed containers. Contain
the extinguishing fluids by bunding. Prevent fire fighting water from entering
the environment.
: Do not attempt to take action without suitable protective equipment. Self-
contained breathing apparatus.
: Do not allow run-off from fire-fighting to enter drains or water courses.
Dispose of waste in accordance with environmental legislation.
IC
: Evacuate unnecessary personnel. Keep upwind. Provide adequate ventilation.
Do not breathe vapours. Avoid contact with skin, eyes and clothing. Wear
recommended personal protective equipment. Concerning personal protective
equipment to use, see section 8. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. Ensure equipment is
adequately earthed. Use explosion-proof equipment. Use only non-sparking
tools.
: Ensure procedures and training for emergency decontamination and disposal
are in place. Concerning personal protective equipment to use, see section 8.
: Stop leak if safe to do so. Dam up the liquid spill. Small quantities of liquid
spill: take up in non-combustible absorbent material and shovel into container
for disposal. Recover large spills by pumping (use an explosion proof or hand
pump). Place in a suitable container for disposal in accordance with the waste
regulations (see Section 13). This material and its container must be disposed
of in a safe way, and as per local legislation.
: Provide adequate ventilation. Do not breathe vapours. Avoid contact with skin,
eyes and clothing. Use personal protective equipment as required. Concerning
personal protective equipment to use, see section 8. Take any precaution to
avoid mixing with Incompatible materials, Refer to Section 10 on Incompatible
Materials. Ensure proper process control to avoid excess waste discharge
(temperature, concentration, pH, time). Avoid release to the environment. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking. Ground/bond container and receiving equipment. Use explosion-
proof equipment. Use only non-sparking tools.
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SAFETY DATA SHEET
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Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

Hygiene measures : Keep good industrial hygiene. Wash hands and other exposed areas with mild
soap and water before eating, drinking or smoking and when leaving work. Do
not eat, drink or smoke when using this product. Keep away from food, drink
and animal feedingstuffs. Remove contaminated clothes. Separate working
clothes from town clothes. Launder separately. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a dry, cool and well-ventilated place. Do not store near or with any of
the incompatible materials listed in section 10. Bund storage facilities to
prevent soil and water pollution in the event of spillage.
Heat and ignition sources : Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Protect from sunlight.
Special rules on packaging : Containers which are opened should be properly resealed and kept upright to

IC
prevent leakage.
Packaging materials : Keep only in the original container.
7.3. Specific end use(s)
UB
Reference to other sections 1.2.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
YC

Additional information : Recommended monitoring procedures :. Personal air monitoring. Room air
monitoring
8.2. Exposure controls
Engineering measure(s) : Organisational measures to prevent /limit releases, dispersion and exposure.
See Section 7 for information on safe handling. Use only outdoors or in a well-
AN

ventilated area. Take precautionary measures against static discharges. Ensure

Personal protective equipment
Hand protection
Eye protection
Body protection
Respiratory protection
Thermal hazard protection
Environmental exposure controls
equipment is adequately earthed.
: The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific
workplace.
: Wear chemically resistant gloves (tested to EN374) . Suitable material: Not
determined. The quality of the protective gloves resistant to chemicals must be
chosen as a function of the specific working place concentration and quantity
of hazardous substances.
: Use suitable eye protection (EN166): goggles
: Wear suitable protective clothing
: In case of insufficient ventilation, wear suitable respiratory equipment. Half-
face mask (DIN EN 140). full face mask (DIN EN 136). The filter class must be
suitable for the maximum contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product. If
the concentration is exceeded, self-contained breathing apparatus must be
used. (EN 137)
: Not required for normal conditions of use. Use dedicated equipment.
: Avoid release to the environment. Comply with applicable Community
environmental protection legislation.
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SAFETY DATA SHEET
Revision nr : 2.0
Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Colour : Grey.
Odour : odourless.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting / freezing point : No data available
Freezing point : No data available
Initial boiling point and boiling range : 238 °C

IC
Flash point : No data available
Auto-ignition temperature : 252 °C
Decomposition temperature : No data available
UB
Flammability (solid, gas) : Not applicable,liquid
Vapour pressure : No data available
Vapour density : No data available
Relative density : No data available
YC

Density : 0,8 – 0,9 mg/cm³

Solubility : Water: Not soluble in water alone
Ethanol: Soluble
Partition coefficient n-octanol/water : No data available
AN

Kinematic viscosity : 1,54 m²/s

Dynamic viscosity : No data available
Explosive properties : Not applicable. The study does not need to be conducted because there are
no chemical groups associated with explosive properties present in the
molecule.
Oxidising properties : Not applicable. The classification procedure needs not to be applied because
there are no chemical groups present in the molecule which are associated
with oxidising properties.
Explosive limits : No data available
Particle size : Not applicable
Particle size distribution : Not applicable
Particle shape : Not applicable
Particle aspect ratio : Not applicable
Particle aggregation state : Not applicable
Particle agglomeration state : Not applicable
Particle specific surface area : Not applicable
Particle dustiness : Not applicable

9.2. Other information

9.2.1. Information with regard to physical hazard classes
No additional information available
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SAFETY DATA SHEET
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Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

9.2.2. Other safety characteristics

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Combustible. Reference to other sections: 10.4 & 10.5. None under normal conditions.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid

IC
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Protect from sunlight.
See Section 7 for information on safe handling.
10.5. Incompatible materials
UB
Strong oxidizing agents. See Section 7 for information on safe handling.
10.6. Hazardous decomposition products
Reference to other sections 5.2.

SECTION 11: Toxicological information

YC

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity : Not classified (Based on available data, the classification criteria are not met)

(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate (42978-66-5)

AN

LD50/oral/rat 3000 - 8100 mg/kg

LD50/dermal/rabbit > 2000 mg/kg
phenyl bis (2,4,6-trimethylbenzoyl)-phosphine oxide (162881-26-7)
LD50/oral/rat > 2000 mg/kg
LD50/dermal/rat > 2000 mg/kg
Skin corrosion/irritation : Causes skin irritation.
pH: No data available
Serious eye damage/irritation : Causes serious eye irritation.
pH: No data available
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met)
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)
ANYCUBIC
Water-Wash Resin +
Kinematic viscosity 1540000 mm²/s
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SAFETY DATA SHEET
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Water-Wash Resin +

Other information : Symptoms related to the physical, chemical and toxicological characteristics.
For further information see section 4.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

Adverse health effects caused by
endocrine disrupting properties
11.2.2 Other information
: The mixture does not contain substance(s) included in the list established in
accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in
accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration
equal to or greater than 0,1 %

IC
Other information : Symptoms related to the physical, chemical and toxicological
characteristics,For further information see section 4
UB
SECTION 12: Ecological information
12.1. Toxicity
Environmental properties : Toxic to aquatic life with long lasting effects.
YC

Hazardous to the aquatic environment, : Not classified

short–term (acute)
Hazardous to the aquatic environment, : Toxic to aquatic life with long lasting effects.
long–term (chronic)
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate (42978-66-5)
AN

LC50 - Fish [1] 4,5 - 10 mg/l (Leuciscus idus)

EC50 - Crustacea [1] 88,7 mg/l (Daphnia Magna)
EC50 72h - Algae [1] > 28 mg/l (Species: Desmodesmus subspicatus)

phenyl bis (2,4,6-trimethylbenzoyl)-phosphine oxide (162881-26-7)

LC50 - Fish [1] > 90 μg/l (Exposure time: 96 h - Species: Danio rerio [semi-static])

12.2. Persistence and degradability

ANYCUBIC
Water-Wash Resin +
Persistence and degradability No additional information available.

12.3. Bioaccumulative potential

ANYCUBIC
Water-Wash Resin +
Partition coefficient n-octanol/water No data available
Bioaccumulative potential No additional information available.

(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate (42978-66-5)

BCF - Fish [1] (no significant bioaccumulation expected)
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SAFETY DATA SHEET
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Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

Partition coefficient n-octanol/water 2 (at 25 °C)

Poly(oxy-1,2-ethanediyl), .alpha.,.alpha.'-[(1-methylethylidene)di-4,1-phenylene]bis[.omega.-[(1-oxo-2-propen-1-yl)oxy]-
(64401-02-1)
Partition coefficient n-octanol/water 2,45 – 4,16 (at pH 6.97)

phenyl bis (2,4,6-trimethylbenzoyl)-phosphine oxide (162881-26-7)

Partition coefficient n-octanol/water 5,8 (at 22 °C (at pH 8.3)

12.4. Mobility in soil

ANYCUBIC

IC
Water-Wash Resin +
Mobility in soil No data available
UB
12.5. Results of PBT and vPvB assessment
ANYCUBIC
Water-Wash Resin +
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
YC

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

12.6. Endocrine disrupting properties

Adverse effects on the environment : The mixture does not contain substance(s) included in the list established in
caused by endocrine disrupting properties accordance with Article 59(1) of REACH for having endocrine disrupting
AN

properties, or is not identified as having endocrine disrupting properties in

accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration
equal to or greater than 0,1 %

12.7. Other adverse effects

Other adverse effects : No data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal
recommendations
European waste catalogue
(2001/573/EC, 75/442/EEC, 91/689/EEC)
: Avoid release to the environment. Dispose of empty containers and wastes
safely. See Section 7 for information on safe handling. Refer to
manufacturer/supplier for information on recovery/recycling. Recycling is
preferred to disposal or incineration. If recycling is not possible, eliminate in
accordance with local valid waste disposal regulations. Handle contaminated
packages in the same way as the substance itself. Dispose of contaminated
materials in accordance with current regulations. Packaging contaminated by
the product : Do not pierce or burn, even after use. Never use pressure to
empty container.
: This material and its container must be disposed of as hazardous waste
Waste codes should be assigned by the user, preferably in discussion with the
waste disposal authorities
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SAFETY DATA SHEET
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Issue date : 22/06/2022
Supersedes : 21/12/2021
ANYCUBIC
Water-Wash Resin +

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
3082 3082 3082 3082 3082
14.2. UN proper shipping name
ENVIRONMENTALLY ENVIRONMENTALLY Environmentally ENVIRONMENTALLY ENVIRONMENTALLY
HAZARDOUS HAZARDOUS hazardous substance, HAZARDOUS HAZARDOUS
SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, liquid, n.o.s. SUBSTANCE, LIQUID, SUBSTANCE, LIQUID,
N.O.S. (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2- (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2-
ethanediyl), ethanediyl), ethanediyl), ethanediyl), ethanediyl),
.alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1-
methylethylidene)di- methylethylidene)di- methylethylidene)di- methylethylidene)di- methylethylidene)di-

IC
4,1- 4,1- 4,1- 4,1- 4,1-
phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega
.-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1-
yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl-
UB
1,2- 1,2- 1,2- 1,2- 1,2-
ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me
thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)]
diacrylate) diacrylate) diacrylate) diacrylate) diacrylate)
Transport document description
UN 3082 UN 3082 UN 3082 UN 3082 UN 3082
YC

ENVIRONMENTALLY ENVIRONMENTALLY Environmentally ENVIRONMENTALLY ENVIRONMENTALLY

HAZARDOUS HAZARDOUS hazardous substance, HAZARDOUS HAZARDOUS
SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, liquid, n.o.s. SUBSTANCE, LIQUID, SUBSTANCE, LIQUID,
N.O.S. (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2- (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2- N.O.S. (Poly(oxy-1,2-
ethanediyl), ethanediyl), ethanediyl), ethanediyl), ethanediyl),
AN

.alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1- .alpha.,.alpha.'-[(1-

methylethylidene)di- methylethylidene)di- methylethylidene)di- methylethylidene)di- methylethylidene)di-
4,1- 4,1- 4,1- 4,1- 4,1-
phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega phenylene]bis[.omega
.-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1- .-[(1-oxo-2-propen-1-
yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl- yl)oxy]- ; (1-methyl-
1,2- 1,2- 1,2- 1,2- 1,2-
ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me ethanediyl)bis[oxy(me
thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)] thyl-2,1-ethanediyl)]
diacrylate), 9, III, (-) diacrylate), 9, III, diacrylate), 9, III diacrylate), 9, III diacrylate), 9, III
MARINE POLLUTANT

14.3. Transport hazard class(es)

9 9 9 9 9

14.4. Packing group

III III III III III
14.5. Environmental hazards
Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : Yes environment : Yes environment : Yes environment : Yes environment : Yes
Marine pollutant : Yes
No supplementary information available
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Water-Wash Resin +

14.6. Special precautions for user

Special precautions for user : No data available

- Overland transport
Classification code (ADR) : M6
Special provisions : 274, 335, 375, 601
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Special packing provisions (ADR) : PP1
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container : T4

IC
instructions (ADR)
Portable tank and bulk container : TP1, TP29
special provisions (ADR)
UB
Tank code (ADR) : LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - : V12
Packages (ADR)
YC

Special provisions for carriage - : CV13

Loading, unloading and handling
(ADR)
Hazard identification number (Kemler : 90
No.)
AN

Orange plates :

Tunnel restriction code : -

EAC code : •3Z

- Transport by sea
Special provisions (IMDG) : 274, 335, 969
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : LP01, P001
Special packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP29
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A

- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
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PCA limited quantity max net quantity : 30kgG

(IATA)
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
CAO max net quantity (IATA) : 450L
Special provisions (IATA) : A97, A158, A197, A215
ERG code (IATA) : 9L

- Inland waterway transport

Classification code (ADN) : M6
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5L

IC
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP
UB
Number of blue cones/lights (ADN) : 0

- Rail transport
Classification code (RID) : M6
Special provisions (RID) : 274, 335, 375, 601
YC

Limited quantities (RID) : 5L

Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Special packing provisions (RID) : PP1
AN

Mixed packing provisions (RID) : MP19

Portable tank and bulk container : T4
instructions (RID)
Portable tank and bulk container special : TP1, TP29
provisions (RID)
Tank codes for RID tanks (RID) : LGBV
Transport category (RID) : 3
Special provisions for carriage – : W12
Packages (RID)
Special provisions for carriage - : CW13, CW31
Loading, unloading and handling (RID)
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 90
14.7. Maritime transport in bulk according to IMO instruments
Code: IBC : No data available.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
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3(b) Substances or mixtures fulfilling the criteria for any of the following hazard ANYCUBIC
classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard Water-Wash Resin +
classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on
development, 3.8 effects other than narcotic effects, 3.9 and 3.10 ; Polyethylene glycol diacrylate ; (1-methyl-
1,2-ethanediyl)bis[oxy(methyl-2,1-
ethanediyl)] diacrylate ; Oxirane, 2-methyl-,
polymer with oxirane, bis(2-methyl-2-
propenoate), block
3(c) Substances or mixtures fulfilling the criteria for any of the following hazard classes ANYCUBIC
or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Water-Wash Resin +

; (1-methyl-1,2-ethanediyl)bis[oxy(methyl-
2,1-ethanediyl)] diacrylate ; Poly(oxy-1,2-
ethanediyl), .alpha.,.alpha.'-[(1-
methylethylidene)di-4,1-
phenylene]bis[.omega.-[(1-oxo-2-propen-1-

IC
yl)oxy]-

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances
UB
15.1.2. National regulations
YC

France
Installations classées
No ICPE Désignation de la rubrique Code Régime Rayon
4511.text Dangereux pour l'environnement aquatique de catégorie chronique 2.
AN

4511.1 La quantité totale susceptible d'être présente dans l'installation étant : A 1

1. Supérieure ou égale à 200 t
Quantité seuil bas au sens de l'article R. 511-10 : 200 t.
Quantité seuil haut au sens de l'article R. 511-10 : 500 t.
4511.2 La quantité totale susceptible d'être présente dans l'installation étant : DC
2. Supérieure ou égale à 100 t mais inférieure à 200 t
Quantité seuil bas au sens de l'article R. 511-10 : 200 t.
Quantité seuil haut au sens de l'article R. 511-10 : 500 t.

Germany
Regulatory reference : WGK 2, Significantly hazardous to water (Classification according to AwSV,
Annex 1)
Hazardous Incident Ordinance (12. : Listed in the 12. BlmSchV (Annex I) under: 1.3.2
BImSchV) Quantity threshold for operational area under § 1 para. 1
- Sentence 1: 200000 kg
- Sentence 2: 500000 kg

Netherlands
Waterbezwaarlijkheid : A (2) - Vergiftig voor in water levende organismen
kan in het aquatische milieu op lange termijn schadelijke effecten veroorzaken
SZW-lijst van kankerverwekkende : None of the components are listed
stoffen
SZW-lijst van mutagene stoffen : None of the components are listed
SZW-lijst van reprotoxische stoffen – : None of the components are listed
Borstvoeding
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SZW-lijst van reprotoxische stoffen – : None of the components are listed

Vruchtbaarheid
SZW-lijst van reprotoxische stoffen – : None of the components are listed
Ontwikkeling

Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

IC
Indication of changes:
1.2 Use of the Added
substance/mixture
UB
2.1 Classification Modified
according to
Regulation (EC) No.
1272/2008 [CLP]
2.2 Hazard statements Modified
(CLP)
YC

2.2 Precautionary Modified

statements (CLP)
2.2 Contains Modified
4.2 Chronic symptoms Removed
5.2 Hazardous Added
decomposition
AN

products in case of
fire
7.2 Heat and ignition Added
sources
7.2 Special rules on Added
packaging
11.1 Reproductive toxicity Removed
15.1 Waterbezwaarlijkheid Modified
Abbreviations and acronyms:
ABM = Algemene beoordelingsmethodiek
ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du
Rhin
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods Code
LEL = Lower Explosive Limit/Lower Explosion Limit
UEL = Upper Explosion Limit/Upper Explosive Limit
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
BTT = Breakthrough time (maximum wearing time)
DMEL = Derived Minimal Effect level
DNEL = Derived No Effect Level
EC50 = Median Effective Concentration
EL50 = Median effective level
ErC50 = EC50 in terms of reduction of growth rate
ErL50 = EL50 in terms of reduction of growth rate
EWC = European waste catalogue
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LC50 = Median lethal concentration

LD50 = Median lethal dose
LL50 = Median lethal level
NA = Not applicable
NOEC = No observed effect concentration
NOEL: no-observed-effect level
NOELR = No observed effect loading rate
NOAEC = No observed adverse effect concentration
NOAEL = No observed adverse effect level
N.O.S. = Not Otherwise Specified
OEL = Occupational Exposure Limits - Short Term Exposure Limits (STELs)
PNEC = Predicted No Effect Concentration
Quantitative structure-activity relationship (QSAR)

IC
STOT = Specific Target Organ Toxicity
TWA = time weighted average
VOC = Volatile organic compounds
WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act)
UB
Sources of key data used to compile the : ECHA (European Chemicals Agency). LOLI. Supplier information.
datasheet
Training advice : Training staff on good practice. Manipulations are to be done only by qualified
and authorised persons.
Other information : Classification - Assessment method: CLP Calculation method (Article 9).
YC

Physicochemical hazard assessment: Information given is based on tests on

the mixture itself.

Full text of H- and EUH-statements:

Aquatic Chronic 2 Hazardous to the aquatic environment – Chronic Hazard, Category 2
AN

Aquatic Chronic 4 Hazardous to the aquatic environment – Chronic Hazard, Category 4

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H411 Toxic to aquatic life with long lasting effects.

H413 May cause long lasting harmful effects to aquatic life.

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

Skin Sens. 1A Skin sensitisation, category 1A

STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Labelling according to Regulation (EC) No. 1272/2008 [CLP]

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable.
However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our
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knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage
or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS
was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS
information may not be applicable.

IC
UB
YC
AN