= QQQ-1205 ; a 3 nats aig ia ale A Tha Wate of aie conatant/of @ Pemuso, frat rset Teaciion core Mn GueRtions are muiole-ctoice questions with one Oa we poe choles a wer Each question caries + mart There is no internal of reactants present in small amount depends on the concent ndent of the concentration of reactants ion of reactants present in excess is indepe depends only on temperature ctronic configuration of @ transition element X in +3 oxidation 1. Limi a molar conductivities of NaOH and KOH are 249.2 and 6 S cm? mot’ respectively. The difference of limiting molar conductivities of K* & Na* jon is- 5 (0 23.4 S cm? mot? is (i) 144.8 om? mor (ii) 33.4 § em? mor" 134°, What is its atomic number? (iv) 46.4 § cm? mor" = a 2. For the reaction, A +2B + AB,, the order w.rt. reactant A is 2 and ad weet reactant 6 is zero. What will be change in rate of reaction if —"\ ar aa +£Qpe)—> 44 __the concentration of A is doubled-and Bis halved? canine a hc it () increases four times n - 6. When 1 mol CrCl, 6H,0 is treated with an excess of AgNO, 3 mel decreases four times of AgCl are obtained. The formula of the complex s (ily increases two times ly (H,O);1.3H,0 (iv) no change [crcl,(H,0)JC12H,0 3. The rate constant of a reaction depends upon I) [CrCKH,O)ICL, HO (i) temperature of the reaction (H,0},1Ch, (i) extent of the reaction 7, Indicate the complex ion whicn “shows geometrical isomerism. itial concentration of the reactants @ [CrH,0),C1)" the time of completion of reaction ) [PHNH,),Cl] {PTO} Xi CHEMISTRY |CHEMIS? (Pr.0] Xl CHEMISTRY() Foc ney 8. Ide fentify the compound y in ne following reaction. @. CH{CH,OH can be converted Ito CH,CHO by: () catalytic hydrogenation (ii) treatment with LIAIH, " treatment with pyridinium chlorochromate lv) treatment with KMnO, . 40. Which of the following species can act as the strongest base? a %H @ wm aH, o © ho, Xi CHEMISTRY [PTO] Tho Standard efectrode potential of three metals X, ¥ and Z are -1.2 %. sos v and 30 V respectively The reducing power of hese metals will be Youoz, Zox¥ \X>YoZ (ia) YoZ>X 12. Which of the folowing compounds wil glve Butanone on oxidation with alkaline KMnO4 solution? () Butan-t-o1 (wv) None of these 43, The correct IUPAC name for CH,=CHCH,NHCH, is (i) Allylmethylamine ) 2-amino-4-pentene i) 4-aminopent-t-ene (iv) Nemethylprop-2-en-1-2mine 14, Amongst the following, the stongest base in aqueous medium is: (CH), NH (iv) CgH,NHCH Xil CHEMISTRY P70}200-1295 18. Given 6 —_—_—_—__—_ below are _ i Reason cy '* ® Slatements felt as Asserton (A) and Assert medio i Adaition reaction of water to but-t-ene in acidic lum yields ‘butan-2-o1 te a ion Of water in atidic medium proceeds through Primary carbocation. Select the most appropriate answer from the options given below 3 Both A and R are true and R is the correct explanation of A > Both A and R are true but R is not the correct explanation of A © Ais true but R is false 4. Ais false but R is true {Given below are wo staterbnts labeled es Assertion (A) and ewe In ea ial oe substrate molecule can Fs Reason (R): Active sites of enzymes hold the substrate molecule in a suitable position. Select the most appropriate answer from the options given below: a. Both A and R are tue and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A c. A is true but R is false. d. A js false but R is tue. Given below are two statements labelled as Assertion (A) and Reason (R) il CHEMISTRY [pT.O} 17. 7 QQQ-1205 samen T Remorse form Fave lass stable complexes as compared to lanthanoids Reason (R). Actinoids can tlize ther Sd orbitals along with 6d Srbitels in bonding but fanthaneds do not use their Af orbital for bonding, answer from the options given below: a Both A and R are true and R is the correct explanation ofA Both A and ave ue bul is not the conect explanation of A. ie but R is false. Select the most appropri cA d. Ais false but R is true. Given beiow are two statem@pts labelled as Assertion (A) and 18 Reason (R) Assertion (A):N-Ethylbenzene sW\phonamide is soluble in alkali Reason (R): Hydrogen attached to nitrogen in sulphonamide ws stronaly acidic. Select the most appropriate answer from the options given below: a, Both A and R are true ang R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A c. Ais true but R is false. 4. A is false but R is true. SECTION B This section contains 7 questions with internat choice in two questions. The following questions are very short answer type and carry 2 marks each. Xi CHEMISTRY {PT.0}19, Rat ite 8 —_ _ 1199 antt3M" Kor rst ondgrpacnon has been found to be 2.54 ST Calculate its three yyeth Metine (Given: tog 4=0.8029) 20. ‘What are vitamins? How are they classified? 20. wi bo 7 hat happens reaseatie When D-giucgse is treated with the following (i) HE Bromine water 21. Give reason for the following @ During the electrophilic substitution reaction of haloarenes, Para substituted derivative is the major product. b.Why is the soliity of aleaanes in water very lm OR am 21. a. Predict the order of reactivity in S42 reaction in the following: C§gH.CH, Br, CH. CH(BAGsM5: CoH, CH(CH,)Br | CgHyC(CH,) (CHs)8° "kanes are hydrolysed with aq. KOH (ii) 2 Chloro- 2- methylpropane 4 BL The following hal ey (i) 2- Chlorobutane Which of the above is most lkely to give a racemic mixture? Justiy your answer 22. Explain why [Fe(H20},)”” has @ magnetic moment value of 5.92 BM whereas [Fe(CN),)* has a value of only 1.74 BM. 23. (a) What advantage do the fuel cells have over primary and secondary batteries [PTO] Xi CHEMISTRY u QQQ-1205 a the mercury cell has a constant cell potential (b) Unlike dry throughout life, Wry? For 9 general reaction A—>B: the plot of concentration of A vs time is given in Fig Cone. of A ‘Answer the following question dr the basis of graph, )) What is the siope of ) What is the unit of the (4) write the rate Jaw for the reaction. “FOR VISUALLY CHALLENGED LEARNERS 1e constant? 24 Explain how and why will the rate of reaction for a given reaction be affected when & a catalyst is added b, the temperature at which the reaction was taking place is decreased 25. Give simple chemical tests to distinguish between the following pairs of compounds. Xi CHEMISTRY IPT.0)(0 Pentan-d-one ang Pentan-3-0e () Phenot and Benzoic acid SECTION © This hort his [Section contains 5 queens wih intemal choice ans SUSSIIONS. The following questions are short answer type and 3 marks each, 26. Wri . Wte the equations for the fatewing reactions: Salieyic acid is treated with acetic anhydride in the presence of conc. H,S0, ©. Tert butyl chloride is treated with sodium ethoxide. © Phenol is treated with dloroform in the presence of NaOH j oR 26 How will you convert: a _ @ — Propene to Propan-t- (i) Ehtanat to Propan-2!- i) Phenol to 2, 4, 6-vivemopheno! Draw structures of geometrical isomers of {Fe(NH3)(CN)T Using 1¥PAC norms Write the systematic name of the following: {CofNH,),CINO,)}CF c. Predict the hybridization of [CoF,}*on the basis of valence bond theory. Xi CHEMISTRY [P70] - — u QQQ-1205 ons SSS~S 28. Answer the following qe: 29, 30 30. 2. State Henry's law. What is the significance of Kyy b. Why is osmotic pressure of 1 M KCI higher than 1 M urea solution? a) Write the structure of the major organic product in each of the following reactions: acetone, (9) CH,CH,cH,C!I + Nal Sr © ethanol (©) (CH,,CBy+ KOH heat lorides with aqueous KOH leads to but in the presence of alcoholic products. Explain. \cteasing order of property specified, b) The treatment of al the formation of al KOH, alkenes are m: Arrange the following in a) CHyrNHy, (CoH), NHACIAGN, NHy- basic strength in gaseous — phase. (©) GHs-OH, CoHs-NH,, CH,-COOH — boiling point CoH NHp, C,He-NH, and CH_-NH-C2H, ~ pKb oR Give chemical test te distinguish between methanamine and a) N-methyl methanamine, (b) Aniline does not react with methyl chloride in the presence of anhydrous AICI, catalyst ine in appreciable amount along with (©) Aniline gives m-niteo a & & p- nitro aniline on nitration. Why? IPT.0}ee a 200-1205 " 290-1205 oR ee SECTION D C. Define the following as related to proteins The tion hag QuOwNE Questions are cagebased questions. Each aries (i) Peptide linkage (i) Primary structure an internal choice and ean, +2) marks each, Read the Passage carefully and pr 32. Read the given passage and answer the questions. answer tne questions that follow. Proteins are the most abundant biomolecules of the living system. The chief sources of proteins I, cheese, pulses, fish, meat, 31 Peanuts, etc. They are found in every pat of the body and form 8 fundamental basis of the siructure and functions of ie, These ate also required for the growth and maintenance of Primary’ or of ‘prime importance’. Chemically, proteins are the Polymers in which the monomeric units are the a-amino acids. Amino acids contain an amirp (-NH,) and carboxylic (COOH) functional groups. Depending upon the relative position of the amino respect to the carporyla.group, the amino, acids @3 a, and -anino acids. Amino acids whi synthesised by the body are. the other hand, those amino acids which cannot be synthesized in the human body and are supplied in the form of diet (because are required for proper health and growth) are called esse amino acids. Answer the follewing questions: ‘a. Amino acids show amphoteric behaviour. Why? 1 b. What type of bonding helps in stabilising the -helix structure of proteins? a What are essential and non-essential amino acids? Give one ‘example of each type. 2 Xi! CHEMISTRY [P.O] ee Xl CHEMISTRY i Boiling point or freezing point of liquid solution would be affected by the dissolved solid liquid phase. A soluble solid in solution bas the effect of rai point and depressing its freezing Point. The addition of non-volatile substances to a solvent decreases the vapour pressure and the added solute particles affect the formation of pure solvent ctyptals. According to many researches the decrease in freezing poi ly correlated to the concentration Of Solutes dissolved in the solfent. This phenomenon is expressed a8 freezing point depression afd it is useful for several application, Such as freeze concentration gh liquid food and the find the molar mass ‘and Unknown solute itHe"solution. Freeze conzenvation is 2 high-quality ‘iquid food concentration method where water \s Femoved by forming ice crystal This is done by cooling liquid food below the freezing point ot the solution. The freezing point depression is referred as a caligative property and it is proportional to the molar concentration of the solution (M) along with vapour Pressure lowering boiling point elevation and osmotic pressure. These are physical characterstics of the solutions that depend orly fon the identity of the solvent and the concentration of the solute The characters are not depending on the solute's identity Answer the following Question What is the effect on toiling point and freezing point, when non- volatile solute is added to pure water? 4 - {PT.0.)— 200-1205 _ 8) What as yoo = —___,——- 14 mean by cgigatve properties? — QaQ-1205 (Atomic weight of Cu=63.5,2n=65.3, Ag=108) 5) Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during recharging (3t2) ¢) 34. (a) Write the reaction for the following conversion’ Ethanol to Propanone (©) An aromatic compound ‘A’ (molecular formula C,H,0) gives Positive 2,4 - ONP test of ‘compound “B’ on ine and sodium hydroxide Solution. Compound ‘A’ does not give Tollen’s or Fehling’s test. On drastic oxidation with potassium permanganate in it forms, "C' (Molecular formula C;H,0,Na), which is also formed alony with the yellow compound in the above reaction. © on acidification produces @ compound D (C;H,0,) which is soluble fq het water. Identify A, B, C, D and ‘write all the reactions. ine (sa) oR e on ©) Why 4 came SECTION E The following questions are tong answer type and cary 5 marks each. Two questions have ie" choice. 8.) Define the molar condudivty of a solution and explain how Molar conductivity ehangés with change in concentration of rr Solution fora..weak-a strong, electrolyte, sy... ome ji) The resistance of a anductivity cell containing 0.001M KCI solution at 298K is 15002 What constant, if the conductivity of 0.001M KCI soluti 298 K is 0.146x10° S cm? iii) Calculate the potential of the following cell reaction at 298 K. ‘Sn**(1.50M) +Zn(s) —> Sn?*(0.5M) + Zn?*(2.0M) :0.301,log3=0.477) (14242) OR 34 a) Give reasons for the folowing: (Carboxylic acids do not give characteristic reactions of carbonyl group. Treatment of benzaldehyde with HCN gives a mixture of two isomers which cannot be Separated even by careful fractional distitaton, Aldehydes are more reactive than ketone in nucieophilic addition reactions (E%cell=0.89V.) (lo 33 (a) Three electrolytic calls A, B and C containing electrolytes 2nS04, AgNO3 and CuSO4 respectively were connected in series. A steady current of 1.50 ampere was passed through them until 1.459 of Ag were deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited? Xi CHEMISTRY [PTO] (©) Convert the following: (3+2) i) ethanol to but2enal Xi CHEMISTRY {PTO}QQQ-1205 ii : 16 ii) Benzoic acid to benzaldehy i 35. Answer the following: that copper iodide? a. Why y are all copper halides know" except paratively tow? b. Why i . y iS the E°(V"~V2) value for vanadium com c. Why HCI sho uld . titrations? not be used for potassium pel rmanganate period, there is a a. phn xplain the observation, at the end of each lock elements. slight increase in the atomic radius of d bl e. What is at is the effect of pH on dichromate ion solution? aneeeeenenne Xil CHEMISTRY [P7.0.]