Patent Application

【Application Classification】 patent application

【Applicant】

【Name】 SEO JUNG YUL

【Patent Customer 4-2003-039583-4

Number】

【Agent】

【Organization Name】 DAE YEON PATENT & LAW FIRM

【Agent's Code】 9-2014-100121-5

【Designated Patent Kwon Yi Jong

Attorney】

【Title of Invention】 METHOD FOR MANUFACTURING GRANULAR WATER

TREATMENT AGENT AND GRANULAR WATER

TREATMENT AGENT MANUFACTURED THEREBY

【English Title of Invention】 Process for producing granular water treatment

agent and granular water treatment agent

【Inventor】

【Name】 SEO JUNG YUL

【Patent Customer 4-2003-039583-4

Number】

【Application Language】 korean language

【Request for Examination】 claimee

【Purport】
 Submit it to the Commissioner of the Korean Intellectual Property Office as
above.

【Official Fee】

【Application Fee】 0 page 46,000 won

【Additional Application 42 pages 0 won

Fee】

【Priority Fee】 0 case 0 won

【Examination Fee】 9 Clause 539,000 won

【Total】 585,000 won

【Reason for Reduction】 Secure Information

【Fee after Reduction and 175,500 won

Exemption】

【Attached Documents】

1.Delegation_1 Tong
 【Description of the Invention】

【Title of Invention】

METHOD FOR MANUFACTURING GRANULAR WATER TREATMENT AGENT AND

GRANULAR WATER TREATMENT AGENT THEREOF

【Technical Field】

【0001】 The present invention provides a method for manufacturing a granular

water treatment agent and a granular water treatment agent manufactured

by the same, wherein the granular water treatment agent is applied to non-

point pollution sources such as effluent, sidestream water, riverside reservoir,

rainwater reuse water, ecological default, ecological wetland, etc. of a sewage/

wastewater treatment plant to facilitate maintenance and management, remove

floating substances included in water, and simultaneously treat pollutants

including total phosphorus (T-P) at an ultra-high temperature.

【Background Technique】

【0002】 In general, in the treatment of total phosphorus in effluent from a

sewage/wastewater treatment plant, phosphorus (phosphoric acid), which is

a main cause of eutrophication and a limiting material for algae proliferation,

has been used in combination with a biological treatment method until now,

and a chemical treatment method using an inorganic liquid coagulant has

been mainly applied. However, when a coagulant is added, it is common to

precipitate and remove soluble phosphorus as insoluble metal phosphate

produced by reacting with one or more metal ions, for example, Al (aluminum),

Fe (iron), or calcium (Ca). In this case, due to the excessive use of chemicals,

there is a problem of continuously destroying the water ecosystem due to

residual aluminum or residual iron in the effluent.

【0003】 In addition, in order to remove suspended solids and phosphorus

contained in non-point pollutants such as riverside reservoirs, rainwater

 reuse water, ecological defaults, ecological wetlands, etc., filter media such
as ceramic, zeolite, volcanic stone, etc. are mainly applied. However, the

characteristics of these media physically function to filter only suspended

solids, and phosphate dissolved in water is difficult to chemically adsorb,

resulting in a problem of low treatment efficiency. This method is not only

inefficient because the removal efficiency of soluble phosphorus is too low

compared to the cost of the filter medium, but also has a problem in that the

concentration of phosphate, which has not been removed, increases as the

treated water flows into the tributary or tributary and accumulates, resulting

in eutrophication of the river.

【0004】 Therefore, there is a need to develop a granular water treatment

agent that can be applied to non-point pollutants such as sewage/wastewater

effluent, sidestream water, riverside reservoirs, rainwater reuse water,

ecological defaults, ecological wetlands, etc. to physically remove suspended

solids and at the same time adsorb pollutants including total phosphorus (T-P).

【Citation List】

【Patent Literature】

【0005】 (Patent literature 0001) Korean Patent No. 10-1334861

【Content of Invention】

【Problem to solve】

【0006】 DISCLOSURE Technical Problem The present invention has been

developed to solve the above-described problems in the related art, and

in particular, an object of the present invention is to adsorb and remove

pollutants including suspended solids in the form of fine particles and total

phosphorus (T-P) contained in water without a secondary problem.

【Solution to the Problem】

 【0007】 To achieve the purpose, the present invention comprises: red teeth
in a state of waste in a workplace; The step that the first additive consisting

of the solidification material class mixing one or two or greater among the

fly ash, calcium sulfate, paper sludge incinerate material, blast furnace slag,

yellow soil, bentonite, illite, talc, silicon oxide with the red mud is added and

mixed The step of obtaining the powder of 5~50μm it screen-processes the

mixture is pulverized The step that adds the second additive consisting of

the acidic chemicals mixing one or two or greater with the powder among

the sulfuric acid, hydrochloric acid, polyaluminum chloride, alum, iron

salt, ferric sulfate, aluminium sulfate and mixed Suggested are a method

for manufacturing a granular water treatment agent and a granular water

treatment agent manufactured by the same.

【Effect of Invention】

【0008】 The granular water treatment agent manufactured by the

manufacturing method forms red mud, and natural minerals including

ferric oxide, aluminum oxide, silicon dioxide, titanium oxide, calcium

oxide, and sodium oxide are activated. In particular, amorphous or semi-

amorphous minerals made of aluminum and iron are newly generated,

thereby quickly adsorbing, agglomerating, substituting, decomposing, and

removing particulate suspended materials and soluble phosphorus contained

in water. Therefore, the present invention has an effect of completely

removing pollutants including fine suspended solids and total phosphorus

(T-P) included in water by adsorbing the pollutants without a secondary

problem.

【0009】 In addition, the granular water treatment agent manufactured by the

manufacturing method remarkably reduces costs and time consumed to

form red mud in a state of industrial waste as a water treatment agent, has a

simple and convenient manufacturing process, and is very convenient to use

 since the water treatment agent manufactured by the manufacturing method
is granular.

【Description of Drawings】

【0010】 FIG. 1 is a block diagram showing a manufacturing method of the

present invention.

FIG. 2 is a block diagram illustrating another manufacturing method of FIG. 1.

FIG. 3 is a block diagram illustrating a subsequent processing method of FIGS.

1 and 2.

【Detailed Description for the Implementation of the Invention】

【0011】 Hereinafter, the present invention will be described in detail with

reference to the accompanying drawings.However, the accompanying

drawings may be exaggerated, omitted, or schematically illustrated for

convenience of description of main parts, and terms and names used in the

description may be implicitly determined by a shape, an operation, a role, and

the like of a configuration rather than a dictionary meaning, and a description

of a position will be described with reference to the drawings unless otherwise

specified. In addition, a detailed description of the previously registered known

technology and the conventional technology may obscure the subject matter,

and thus may be omitted or replaced with a simple symbol or name.

【0012】 First,FIG. 1Granular according to the present invention with reference

towatertreatment agentThe manufacturing method will be described as

follows.

【0013】 As shown, the method for preparing a granular water treatment agent

according to the present invention is red mud; The step that the first additive

consisting of the solidification material class mixing one or two or greater

among the fly ash, calcium sulfate, paper sludge incinerate material, blast

furnace slag, yellow soil, bentonite, illite, talc, silicon oxide with the red mud
is added and mixed The step of obtaining the powder of 5~50μm it screen-
processes the mixture is pulverized The step that adds the second additive

consisting of the acidic chemicals mixing one or two or greater with the powder

among the sulfuric acid, hydrochloric acid, polyaluminum chloride, alum, iron

salt, ferric sulfate, aluminium sulfate and mixed It can be included including.

【0014】 Hereinafter, each step of the preparation method will be described in

more detail.

【0015】 First, red mud will be described as follows.

【0016】 The red mud referred to in the present invention refers to red mud in a

waste state of a workplace generated in a bauxite purification process, and the

red mud in a waste state has a moisture content of 40 to 55% and a pH of 11 to

13. When such red mud is used as a water treatment agent as it is, the water

quality is basified by strong alkali, which adversely affects it.

【0017】 More specifically, red mud itself contains high Na2O because a large

amount of sodium hydroxide is added to the process of extracting alumina

hydroxide by applying the Bayer process to bauxite ore during the purification

process. Because it contains such high Na2O, it is classified as waste, and if it

is injected directly into the water, it adversely affects the water quality, such as

the destruction of the aquatic ecosystem.

【0018】 Therefore, it is necessary to go through a process of treating such red

mud to be suitable for water treatment agents.

【0019】 Next, the step of mixing the first additive will be described as follows.

【0020】 The first additive is included of the mixture mixing one or two or

greater with the red mud among the fly ash, calcium sulfate, paper sludge

incinerate material, blast furnace slag, yellow soil, bentonite, illite, talc, silicon

oxide. The process of mixing after throwing in the first additive in the red mud

is proceed.

【0021】 Although not described in the background art, a company that

generates red teeth puts the red teeth in a waste state into a drying device
called a rotary kiln and performs a drying process of drying the red teeth

at a high temperature of about 800° C., and a pre-treatment process of

pulverizing and screening the dried dried red teeth to produce powder having

a water content of 2-5% and a pH of still 11 or more, which has strong alkali

properties, and is sold at high prices as a product that adds colors to paints,

pigments, bricks, and the like.

【0022】 However, the above-described conventional pretreatment method has

a problem in that the operation of the equipment for the drying apparatus and

the equipment for meeting the drying conditions is enormously costly, and the

dried red mud is merely waste and the price is considerably expensive.
【0023】 Accordingly, the applicant of the present invention has devised a

method in which red mud, which is a waste, is not dried at all or does not

need to be dried at a high temperature of 800° C. in order to reduce the pre-

treatment cost by the drying. As an alternative, the applicant has found that

there is no need to excessively lower the moisture content of red mud to

2-5% through high-temperature drying of red mud in a waste state, and has

classified and applied a composition capable of lowering the moisture content

of red mud and simultaneously lowering the alkalinity of red mud without

drying the red mud in a waste state, and has proposed the above-described

first additive as the composition.

【0024】 The first additive group is a group of solidified materials, and for

example, when only red mud is used without adding the first additive, there is

a problem in that due to a high moisture content, energy costs are high due

to the pre-treatment by the above-described conventional high-temperature

drying, and reactivity with acidic chemicals introduced into a subsequent

process to be described below is lowered.

【0025】 Therefore, the reason why the first additive is added to the red mud
is to compensate for the physicochemical properties insufficient for the red
mud itself, and in particular, to lower the high moisture content of the red mud

itself without going through the pre-treatment process by high-temperature

drying.

【0026】 That is, it is added to lower the high moisture content retained in

the red mud itself, induce ion exchange and substitution reactions of a high

concentration of sodium component with an element such as calcium, facilitate

transfer to a subsequent process, increase physical strength, and enable mass

production.

【0027】 Accordingly, when the first additive is added to and mixed with the

red mud, a hydration reaction and a pozzlan reaction occur between the red
mud and the first additive, and as a result, the moisture content of the red

mud is lowered and solidified, thereby increasing the physical strength, and

increasing the total phosphorus treatment efficiency due to the added calcium

ions.

【0028】 When the final water treatment agent including the first additive is

introduced into the water due to the above-described action, red mud does

not react directly in the water but slowly and continuously reacts for a long

time, and thus a reaction of rapidly adsorbing, aggregating, decomposing, and

removing contaminants including suspended solids in the form of fine particles

and total phosphorus contained in the water occurs, thereby significantly

improving water quality.

【0029】 Meanwhile, since the difference between mixing only one of the first

additive groups, for example, fly ash, and mixing both fly ash and desulfurized

gypsum is small, the calcium component is contained very low, and thus,

the physical and chemical reactions between the first additive groups are

activated, compared to the case in which only one of the first additive groups

is added, so that a pozzlan reaction occurs in a gel state and the chemical
reaction degree is increased, thereby becoming more firm, and minerals
containing calcium ions are further activated. This is because not only the iron

and aluminum ions of the red mud itself but also the calcium ions are more

active, thereby further improving the total phosphorus raising efficiency.

【0030】 Therefore, as the first additive, any one of the groups may be selected

and applied according to cost reduction, special use, and the environment in

which the first additive is placed. However, if possible, it is more preferable to

mix and apply two or more.

【0031】 It returns. It mixes after the process of mixing the first additive about

100 parts by weight to 7~25 parts by weight and ***ing in the rpm 200 5~10

discrimination since the first additive gets wet.

【0032】 When the first additive is mixed with the red mud, a chemical reaction

with the inorganic minerals occurs, so that the basic component is deodorized

together with the moisture of the red mud, and the pH of the mixture is

lowered to 8 to 11 moisture content of 10 to 25%.

【0033】 The reason for this is that, when the first additive is added in an

amount of 7 parts by weight or less, the water content of red mud is not

lowered, and thus additional drying is required, and the reactivity with the

acid solution introduced into the subsequent process to be described below is

low, and thus the activity of minerals is lowered, and when the first additive

is added in an amount of 25 parts by weight or more, the water content is

lowered, but the chemical reaction with the acid solution introduced into the

subsequent process occurs before the reaction with the additive introduced as

the first additive itself, and thus the reactivity with the unique aluminum and

iron of red mud is weakened, and thus the activation of minerals is lowered,

and new trace mineral precipitates in an amorphous or semi-amorphous form

composed of iron and aluminum are not formed, and thus the unique high

adsorption power of red mud is lost.

【0034】 The mixture satisfying the above-described conditions does not
immediately react with red mud in water, but slowly and continuously reacts

for a long time, thereby adsorbing more impurities contained in the water,

more strongly decomposing the impurities, and completely extinguishing the

impurities.

【0035】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0036】 Next, the step of obtaining the powder will be described as follows.

【0037】 After the first additive is mixed with the red mud, in order to facilitate
homogeneous mixing of the mixture agglomerated in the mixing process

with the chemicals, the cross-linking agent, and the binder, a process of

pulverizing the mixture to obtain a powder having a particle size of 5 to 50

μm through a pulverizer or a screen, and then screen-treating the pulverized

product is performed.

【0038】 The reason for this is that when the particle size is 5 μm or less, there is

a problem of scattering during transfer, and when the particle size is 50 μm or

more, it is difficult to homogeneously mix rice straw powder, rice hull powder,

starch, fine powder having a particle size of 0.3 mm or less such as molasses,

hydroxypropyl methylcellulose (HPMC), polyvinyl alcohol (PVA), acrylamide,

methylcellulose (MC), synthetic resin (vinyl, polyethylene, polypropylene),

silica sol, and the like, which may be performed in a subsequent process to be

described below, and the specific surface area is reduced.

【0039】 Therefore, the above-described conditions play a very important role

in the problem of handling, the mixing process to be described later, and the

binding of the mixture, and if the above-described conditions are not satisfied,

the effects of the present invention cannot be ensured.

【0040】 Next, the step of mixing the second additive will be described as
follows.

【0041】 The second additive is included of the mixture mixing one or two or

greater among the sulfuric acid, hydrochloric acid, polyaluminum chloride,

alum, iron salt, ferric sulfate, aluminium sulfate. The process of mixing after

throwing in the second additive in the powder of pre-phase is proceed.

【0042】 Although not described in the background art, as another conventional

method of treating red mud to be used for water treatment, there is a method

of neutralizing red mud by physical stirring and chemical reaction by adding

red mud to an acidic solution.

【0043】 However, this method requires not only a large-scale site, but also
a facility for solid-liquid separation after shaking, and requires a large

neutralization facility and a large amount of water to wash the acid remaining

in the red mud.

【0044】 As a result, a large-scale wastewater treatment facility needs to be

provided, and in the last step, the pretreatment process of drying at the high

temperature described above and the resulting cost are additionally incurred.

As a result, there is a problem in that the cost is increased, and a considerable

cost and time are required for solid-liquid separation, neutralization, acid

washing wastewater treatment, and drying at a high temperature, and thus

productivity is lowered.

【0045】 The group of the second additive is acidic chemicals consisting

of acidic chemicals, and the reason for adding the second additive is to

lower the high pH of red mud, to activate minerals consisting of aluminum

and iron possessed by red mud itself as much as possible, to play a role of

newly forming amorphous or semi-amorphous trace mineral precipitates

consisting of calcium, aluminum and iron, and to supplement the insufficient

physicochemical properties of red mud itself.

【0046】 Accordingly, the second additive is not added to a conventional
pretreatment process and a process before the pretreatment process is

performed, but the first additive is added, the powder is obtained, and then the

second additive is added to the powder.

【0047】 When the second additive is added to and mixed with the mixture

of the previous step, a mineral chemical reaction is caused with the acidic

chemical agent added as the second additive in the mixer, so that diiron

trioxide and aluminum oxide minerals constituting red mud are chemically

reacted with each other to activate gibbsite, boehmite, and hematite minerals

consisting of aluminum and iron, and calcium, aluminum, sulfate ions,

chlorine ions, and the like are substituted into the lattice of the minerals
constituting red mud through the mineral chemical reaction with red mud to

form new amorphous or semi-amorphous trace mineral precipitates, so that

adsorption, substitution, ion exchange, chemical adsorption reaction, and

coordination bonding are more actively performed, thereby further improving

the efficiency of removing suspended materials and total phosphorus.

【0048】 In addition, when a second additive composed of an acidic chemical

is added to and mixed with the mixture in which the first additive is mixed

with red mud, the second additive reacts with the surface of red mud

particles to increase the specific surface area, activates minerals such as

gibsite, boehmite, and hematite, and forms a new trace mineral precipitate

containing amorphous and semi-amorphous calcium, aluminum, and iron,

thereby generating a large amount of fine pores and increasing the chemical

adsorption reactivity to pollutants including total phosphorus (T-P) dissolved

in water.

【0049】 When the final water treatment agent including the second additive

is introduced into water due to the above-described action, high iron and

aluminum ions of red mud and calcium contained in a large amount in the
first additive react with total phosphorus in a very short time through an ion
exchange reaction, a substitution reaction, an adsorption reaction, and a

chemical adsorption reaction, thereby further improving removal efficiency.

【0050】 In addition, the second additive neutralizes red mud having a strong

alkali to prevent water from being basified, and changes the environmental

conditions of water to the vicinity of a charge point that maximizes the

activity of minerals such as gibbsite, boehmite, and hematite constituting red

mud, thereby leading to an action in which red mud reacts with suspended

materials and total phosphorus in water to adsorb, substitute, decompose, and

extinguish. Due to this, there is an effect of further improving the efficiency of

raising suspended solids and phosphorus.

【0051】 Meanwhile, among the groups of the second additive, for example, the

difference between mixing only one sulfuric acid and mixing sulfuric acid,

hydrochloric acid, and aluminum sulfate together is that new trace minerals

are formed as a small number by the reaction between sulfuric acid ions and

red mud when they are mixed alone, but when they are mixed together, more

trace minerals are generated due to the mixed interaction between sulfuric

acid ions and hydrochloric acid ions and aluminum and red mud when they

are mixed together than when they are mixed alone, thereby further improving

the water quality improvement effect.

【0052】 Therefore, as the second additive, any one of the groups may be

selected and applied according to cost reduction, special use, and the

environment in which the second additive is placed. However, if possible, it is

more preferable to mix and apply two or more.

【0053】 It returns. The process of mixing the second additive about the mixture

100 parts by weight in which the first additive is mixed to 15~50 parts by weight

and ***ing in the rpm 150 between 10~30 minutes is passed.

【0054】 The method for mixing the second additive overcomes all problems
such as large-scale site, solid-liquid separation after shaking, large-scale
neutralization facilities, and large-scale wastewater treatment costs, thereby

improving space saving, facility costs reduction, wastewater non-generation,

ease of mass production, production speed, cost reduction, and the like.

【0055】 When the second additive is added in an amount of 15 parts by weight

or less, the mixture in which the first additive is mixed with red mud and the

second additive composed of acidic chemicals are not uniformly mixed, so

that the pH of the mixture cannot be lowered to a desired level, and thus the

activity of useful minerals containing aluminum and iron constituting red

mud is lowered, and thus the ability to adsorb total phosphorus is lowered.

In addition, since the mineral chemical reactivity is low, there is a problem

in that new amorphous or semi-amorphous trace mineral precipitates

cannot be additionally formed. In addition, the activity of minerals such as

gibbsite, boehmite, and hematite composed of aluminum and iron is lowered,

and amorphous or semi-amorphous trace mineral precipitates composed

of calcium, aluminum, and iron are not formed, and thus the adsorption

efficiency of pollutants including total phosphorus is very lowered when

injected into water.

【0056】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0057】 so far,FIG. 1It finishes of the description according to the

manufacturing methodFinally, as described in the effect of the present

invention, the water treatment agent prepared according to the preparation

method of FIG. 1 constitutes red mud, and natural minerals including ferric

oxide, aluminum oxide, silicon dioxide, titanium oxide, calcium oxide, and

sodium oxide are activated, and in particular, amorphous or semi-amorphous

minerals made of aluminum and iron are newly generated, thereby quickly
adsorbing, aggregating, substituting, decomposing, and removing suspended
solids in the form of fine particles and soluble phosphorus contained in

water. Therefore, the present invention has an effect of completely removing

pollutants including fine suspended solids and total phosphorus (T-P) included

in water by adsorbing the pollutants without a secondary problem. In addition,

costs and time consumed to form red mud in a state of industrial waste as

a water treatment agent are remarkably reduced, a manufacturing process

thereof is simple and convenient, and the water treatment agent completed by

the manufacturing process is granular, thereby being very convenient to use.

【0058】 Hereafter,FIG. 2another prize according to the invention with reference

to the figureswatertreatment agentThe manufacturing method will be

described as follows.

【0059】 As shown, the method for preparing a granular water treatment

agent according to the present invention comprises: red mud in the state of

industrial waste; The step that it is dry until it is dry and the percentage of

water content of the red mud lowers the red mud between 25~200°C between

5~25% and it preprocesses The step of obtaining the powder of 5~50μm it

screen-processes after it pulverizes the processed red mud as described above

The step that adds the second additive consisting of the acidic chemicals

mixing one or two or greater with the powder among the sulfuric acid,

hydrochloric acid, polyaluminum chloride, alum, iron salt, ferric sulfate,

aluminium sulfate and mixed It includes and it can be manufactured.

【0060】 Hereinafter, each step of the preparation method will be described in

more detail.

【0061】 However, descriptions of overlapping processes in FIGS. 1 and 2 will be

excluded. That is, redness; The powder acquisition stage The second additive

addition step However, only the pre-treatment step will be described.

【0062】 Hereinafter, the pretreatment step will be described as follows.

【0063】 Until it dries and the percentage of water content of the red mud makes
low the red mud between 25~200°C between 5~25%, the preprocess phase is

proceed the process of drying.

【0064】 The pre-treatment step of FIG. 1 is different from the pre-treatment

step of FIG. 1 in terms of a drying temperature. In the summer season, the

pre-treatment step of FIG. 1 may be performed by natural drying from the

outside, and in the summer season, the pre-treatment step of FIG. 1 may be

performed by a general dryer.

【0065】 In the pretreatment step according to the present invention, by adding

the above-described second additive, it is possible to produce final physical

properties similar to those of the related art without going through the
conventional pretreatment step.

【0066】 In the pretreatment step according to the present invention, the basic

component is deodorized together with the moisture of the red mud during the

drying process, so that the pH of the red mud is lowered to between 8 and 11.

Thereafter, a powder having a particle size of 5 μm to 50 μm may be obtained

through a grinder or a screen of the agglomerated red teeth during the drying

process.

【0067】 In the pre-treatment step, it is very important to dry the red mud

until the moisture content of the red mud is lowered to 5 to 25% regardless

of the drying time. This is because when the moisture content of the red mud

is 5% or less, the drying cost is excessive, and the pre-treated red mud is

scattered during the manufacturing process and blown away. On the other

hand, when the water content of the red mud is 25% or more, it is difficult

to homogeneously mix the red mud with the chemicals introduced into the

subsequent step due to the water content of the red mud itself, and the

chemical reactivity with the minerals constituting the red mud is lowered due

to the reaction between the moisture of the red mud itself and the chemicals,
which may reduce the treatment efficiency when the final product is used as a
water treatment agent.

【0068】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0069】 so far,FIG. 2It finishes of the description according to the

manufacturing methodFinally, the water treatment agent prepared according

to the preparation method of FIG. 2 may have the same effect as that of FIG. 1,

and may be selectively applied according to user convenience in consideration

of conditions such as equipment, site, time, cost, and place possessed by the
operator.

【0070】 Hereafter,FIG. 3the granularity according to the present invention with

referenceWATER TREATMENT AGENTA subsequent treatment method of the

preparation method will be described as follows.

【0071】 As shown in the drawing, the method for manufacturing a granular

water treatment agent according to the present invention comprises the steps

of: adding a third additive consisting of agricultural and forestry by-products

obtained by mixing any one or two or more of rice straw powder, rice hull

powder, starch, and molasses to a final mixture selected from the steps of

FIGS. 1 and 2 and mixing the same The step that adds the fourth additive

consisting of the binder mixing one or two or greater with mixture among the

hydroxypropyl methylcellulose (HPMC), polyvinyl alcohol (PVA), acrylamide,

methyl cellulose (MC), synthetic resin (vinyl, polyethylene, polypropylene),

silica sol and mixed The step of molding to ring mixture, and one moldings

among pellet or the brick type The step that it cures so that the micro pore

is formed in the moldings with foaming by the natural dry it dries naturally

in the place shadying the moldings over at least 6 hours The dry until for the
pH of the curing material, 3~7 is in interval 80~400 puts the curing material
into drier The step of removing the differentiation which sticks to the surface

of the building through the screen processing after naturally letting cool the

building in the shaded place over the minimum 3 hours It can be manufactured

by further including a subsequent treatment method consisting of.

【0072】 Hereinafter, each step of the subsequent treatment method will be

described in more detail.

【0073】 First, the step of adding the third additive will be described as follows.

【0074】 The third additive is included of the mixture mixing one or two or

greater among the rice straw powder, rice hulls powder, starch, molasse. The

process of mixing after throwing in the third additive in the mixture of pre-
phase is proceed.

【0075】 The third additive is a by-product of agriculture and forestry, and is

added to serve as a cross-linking agent for forming a solid binder without

affecting the characteristics of the mixture in the previous step and to increase

the specific surface area of the final product, and the third additive, rice straw

powder, rice hull powder, starch, and molasses, have a particle size of 0.3 mm

or less.

【0076】 For example, rice straw can be easily obtained as rice straw thrown

away after threshing rice in a harvester in a farmhouse. In the case of

rice straw, rice straw powder is an eco-friendly material having high

biodegradability, and can be prepared by pulverizing rice straw in a pulverizer.

The constituent elements of rice straw are composed of carbon, hydrogen,

nitrogen, and oxygen, and the moisture content of rice straw is about 6 to 7%,

and the constituent elements are composed of ash, lignin, and cellulose.

【0077】 The third additive is mixed with 10 to 35 parts by weight of the third

additive based on 100 parts by weight of the mixture in which the second

additive is mixed and stirred at 200 rpm for 5 to 10 minutes.

【0078】 When the third additive is added in an amount of 10 parts by weight or
less, the third additive is not uniformly mixed with the mixture of the previous

step, and thus the crosslinking function as a binder is insufficient, and thus

the binding force is lowered. Therefore, when the binding force of the molded

product is weak when the binding agent to be added in the subsequent process

is added, mixed, molded through a screw extruder or a molding machine,

and then dried, the molded product is loosened or physically broken in the

water. On the other hand, when the third additive is added in an amount of 35

parts by weight or more, the activity of useful minerals such as gibbsite and

boehmite hemata art containing aluminum and iron that chemically react with

total phosphorus, which are unique characteristics of red mud, is lowered due
to biodegradable properties, and the formation of new minerals containing

amorphous or semi-amorphous aluminum and iron is hindered, and thus the

efficiency of treating

【0079】 On the other hand, the difference between the mixture of only one rice

straw powder and the mixture of starch or molasses in the rice straw powder

among the groups of the third additive is that the cross-linking function is

improved due to the bonding of different physical properties of the paper,

thereby achieving a stronger bonding between the upper and lower surfaces.

【0080】 Therefore, as the third additive, any one of the groups may be selected

and applied according to cost reduction, special use, and the environment in

which the third additive is placed. However, if possible, it is more preferable to

mix and apply two or more.

【0081】 The above-described conditions play a very important role in the action

of the finally completed water treatment agent, and if the above-described

conditions are not satisfied, the effect of the present invention cannot be

ensured.

【0082】
【0083】 Next, the step of adding the fourth additive will be described as follows.
【0084】 The fourth additive is included of the thing mixing one or two or greater

among the hydroxypropyl methylcellulose (HPMC), polyvinyl alcohol (PVA),

acrylamide, methyl cellulose (MC), synthetic resin (the vinyl, the polyethylene,

and the polypropylene), silica sol. The process of mixing after throwing in the

fourth additive in the mixture of pre-phase is proceed.

【0085】 The group of the fourth additive is a binder, and the fourth additive is

added and mixed for the purpose of binding the mixture of the previous steps.

【0086】 When the fourth additive is added to and mixed with the mixture

of the previous step, the mixture of the previous step is well preserved in

physicochemical properties, and the mixture of the previous step is bound

to dry the molded product molded through a screw extruder or a molding

machine in a dryer at a predetermined temperature. When the manufactured

final product is introduced into the water, the final product may be prevented

from being quickly loosened or broken in the water.

【0087】 The fourth additive may be mixed in an amount of 1 to 10 parts by

weight based on 100 parts by weight of the mixture in which the third additive

is mixed, and stirred at 150 rpm for 5 to 10 minutes.

【0088】 When the fourth additive is added in an amount of 1 part by weight

or less, the first additive, the second additive, and the third additive are not

uniformly mixed with the mixture of the first additive, the second additive, and

the third additive, and thus the binding force as a binding agent is lowered.

Therefore, when the molded product is molded through a screw extruder or

a molding machine, which is a subsequent process, dried at a predetermined

temperature, and then introduced into water, the binding force of the molded

product is weak, and thus the molded product is loosened or physically

broken. On the other hand, when the fourth additive is added in an amount of

10 parts by weight or more, the first additive, the second additive, and the third
additive are uniformly mixed with the mixture of the first additive, the second
additive, and the third additive, and thus the binding force as a binding agent

is increased.

【0089】 For example, when hydroxypropyl methylcellulose (HPMC) of the fourth

additive is added to the mixture of the previous step, HPMC is added in an

amount of 1 to 10 parts by weight of hydroxypropyl methylcellulose (HPMC)

based on 10 to 35 parts by weight of water based on 100 parts by weight of the

mixture of the previous step, sufficiently dissolved through stirring, and then

added in a liquid phase, and then the mixture is stirred. In this case, when

hydroxypropyl methylcellulose (HPMC), which is a solid phase, is dissolved in

water in a minimum amount to the extent that the mixture is agglomerated

and bound, and then mixed, the mixtures are agglomerated together in a

soft dough state, and at the same time, a chemical reaction of the mixture is

induced to have a strong binding force.

【0090】 Meanwhile, a difference between a mixture of only one HPMC among the

groups of the fourth additive and a mixture of the HPMC and the silica sol is

that, like the third additive, binding between the upper and lower surfaces is

improved due to binding of different physical properties of the paper, thereby

achieving a stronger binding.

【0091】 Therefore, as the fourth additive, any one of the groups may be

selected and applied according to cost reduction, special use, and the

environment in which the additive is placed. However, if possible, it is more

preferable to mix and apply two or more.

【0092】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0093】 Next, the molding step will be described as follows.

【0094】 It makes the mixture of pre-phase in the red mud with the kneading
state and it transfers the kneading to the screw extruder or molder and the

molding step is proceed the process of molding in the form of ring, and pellet

or the brick.

【0095】 The molding step is performed for the purpose of facilitating storage,

handling, and the like of the mixture of the previous step and making it

suitable for use according to the state, place, use, and the like of the water

quality to be treated.

【0096】 For example, the shape in the form of a ring or pellet may be applied

to a place where ultra-high-degree treatment is required up to a very small

concentration of total phosphorus (T-P) dissolved in water, and the brick-

shaped molded product may be usefully applied to treat a large amount of

water, such as tributaries or rivers before being introduced into the main

stream.

【0097】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0098】 Next,curing stepHereinafter, the present invention will be described.

【0099】 In the place where the curing step shadies the moldings of pre-phase,

the process of naturally drying over minimum 6 hours and curing so that

the micro pore be formed with foaming by the natural dry in the moldings is

proceed.

【0100】 The curing step is performed for the purpose of making the finally

formed molded product into a porous material having micropores, preventing

cracks from occurring in the molded product due to excessive moisture

evaporation when the molded product is dried in a dryer, and preserving the

bonding strength of the molded product. In addition, the molded product made
by mixing additives causes a mineral chemical reaction during the curing
process to generate a new trace mineral precipitate, thereby further improving

the water quality improvement effect.

【0101】 The molded product finally completed through the curing process is in

a state in which the mixture is strongly bound in the curing process to rapidly

absorb moisture in water to improve the reaction speed, and rapidly absorbs

moisture to the center by the porous material to activate the reaction with

gibbsite, boehmite, and hematite constituting red mud, and amorphous and

semi-amorphous trace mineral precipitates composed of calcium, aluminum,

and iron are newly formed to continuously generate the reaction of red mud

for a long time, thereby adsorbing more impurities contained in the water,
more strongly decomposing, and completely extinguishing the impurities.

【0102】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0103】 Next, the drying step will be described as follows.

【0104】 It puts the curing material of pre-phase into drier and as to step,

80~400 is proceed the process of drying until for the pH of the curing material,

3~7 is in interval.

【0105】 The reason why the drying step is performed is to increase the bonding

strength of the molded product and to increase the specific surface area by

evaporating the moisture and carbonizing the organic material because the

moisture and the organic material in the amphibious are contained by the

mixing and process of the previous step.

【0106】 In addition, the purpose of the present invention is to activate minerals

such as gibbsite, boehmite, and hematite through a mineral chemical reaction

with acidic chemicals added to red mud, and at the same time, to additionally
generate a large amount of amorphous or semi-amorphous trace mineral
precipitates composed of aluminum, iron, chlorine ions, sulfate ions, and

the like, thereby increasing pollutant adsorption efficiency including total

phosphorus (T-P) when a final product is injected into water.

【0107】 If the drying step is not performed, the pH of the molded product itself

is very low due to a large amount of sulfate ions or chlorine ions remaining

without being volatilized in the mixture of the previous step, and thus the

molded product cannot be applied to the treatment of total phosphorus

dissolved in a weakly acidic and weakly alkaline aqueous solution. In addition,

if the final product is put into water because it does not have sufficient

strength, the final product is easily loosened or easily broken.

【0108】 When the drying temperature is 80° C. or less, the drying time

is prolonged, and the moisture contained in the molded product is not

sufficiently evaporated due to the weak chemical reaction of the molding, and

the additives added to bind and bind the molded product to the molding are

not sufficiently volatilized and carbonized, and thus the physical strength is

weak. In addition, useful minerals such as gibbsite, boehmite, hematite, and

the like are not activated, and at the same time, a large amount of amorphous

or semi-amorphous trace mineral precipitates including calcium, aluminum,

iron, chlorine ions, sulfate ions, and the like are not additionally generated.

【0109】 The molded article satisfying the above conditions not only has strong

physical strength, but also has many micropores and maintains a high specific

surface area. In addition, minerals such as gibbsite, boehmite, and hematite,

which are highly reactive with total phosphorus in mineral chemistry, are

activated as much as possible, and trace mineral precipitates composed

of amorphous or semi-amorphous calcium, aluminum, and iron are newly

formed, leading to the action of rapidly adsorbing, substituting, decomposing,

and extinguishing suspended solids in the form of fine particles contained in

water and total phosphorus, thereby remarkably improving water quality.
【0110】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0111】 Next,fine powder removal stepHereinafter, the present invention will be

described.

【0112】 In the place where the differentiation removal step shadies the building

of pre-phase, the process of eliminating the differentiation sticking to the

surface of building through the screen processing after naturally letting cool

over minimum 3 hours is proceed.

【0113】 The reason why the fine powder is removed is that the fine powder

is formed on the surface of the molded product by the drying process of the

dried product in the previous step, and when the fine powder is put into the

water without being separated, suspended solids are rather increased in the

water due to the fine powder powders, and thus the water quality may be

deteriorated.

【0114】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect of the present invention

cannot be ensured.

【0115】 Hereinafter, the granular water treatment agent is prepared by

applying the above-described preparation method, and then the results of

analysis and experiment thereof will be described as follows.

【Embodiment 1】

【0116】 In Example 1, 15 parts by weight of desulfurized gypsum was mixed

with 100 parts by weight of red mud itself, stirred at 200 rpm for 5 minutes,

and then the mixture was allowed to stand in the shade for 24 hours. The
water content of this mixture was measured at 18%, and it was pulverized
and sieved using a sieve to prepare a mixture having a water content of 50

μm or less. After 30 parts by weight of sulfuric acid was added to 100 parts

by weight of a mixture having a size of 50 μm or less in a mixer, the mixture

was stirred at 150 rpm for 30 minutes. 20 parts by weight of rice straw powder

obtained by finely cutting rice straw and pulverizing it to 0.3 mm or less

was mixed with 100 parts by weight of the mixture into which sulfuric acid

was added, and the mixture was stirred at 150 rpm for 5 minutes. After 2

parts by weight of hydroxypropyl methylcellulose (HPMC) as a binder was

added to 25 parts by weight of water based on 100 parts by weight of the

mixture containing the rice straw powder, the mixture was liquefied through
sufficient stirring, and the liquefied mixture was added thereto, followed

by stirring at 150 rpm for 5 minutes. The kneaded mixture containing the

binder was injected into a stainless steel mold having a width, a length, and

a thickness of 3 cm, respectively, and naturally dried in a shade for 6 hours.

After the mold was disassembled, the molded product was dried in a dryer

set at 260° C. for 40 minutes, and the molded product was allowed to cool in a

shaded place, and then sieved to remove fine powder of the molded product,

thereby completing a water treatment agent. At this time, the pH of the finally

completed water treatment agent was measured to be 3.1.

【0117】 Hereinafter, the phosphate removal experiment and red mud using

Example 1 and the constituent mineral results of Example 1 will be described

as follows.

【0118】 The following experiment was conducted to find out the results of

phosphate removal using the above examples.

【0119】 [Test 1]

【0120】 As for the experimental conditions, 1.4325 g of potassium dihydrogen

phosphate (KH2PO4) was dissolved in distilled water to make the solution

exactly 1000 ml, and a phosphate (PO4-3) standard solution having a
concentration of 1,000 ppm was prepared. A predetermined amount was

taken from the standard solution and diluted with distilled water to prepare a

comparison target (Blank), and an artificial sewage sample solution having a

pH of 7 and a concentration of 30 mgP/L was prepared in a 1 L beaker. Then,

1 L of the artificial sewage sample solution was filled in each of the three (1 L)

beakers (Example 1-1, Example 1-2, and Example 1-3), and then the granular

water treatment agent prepared in Example 1 was cut, 2 g of the granular

water treatment agent was added thereto, and the mixture was stirred at 150

rpm for 12 minutes using a stirrer, and then the artificial sewage sample

solution was allowed to stand for 30 minutes. Thereafter, the sample solution
was filtered through a glass fiber filter, and then phosphate was analyzed.

【0121】

【0122】

【table 1】

redni embodiment 1

hematite Fe2O3 Fe2O3

boehmite r-AlOOH r-AlOOH

Gibbsite Al(OH)3 Al(OH)3

Quartz SiO2 SiO2

sodalite Na4Al3Si3O12Cl Na4Al3Si3O12Cl

cancrinite (Na,Ca,K)8(Al,Si)12 (Na,Ca,K)8(Al,Si)12

)24(SO4CO3)3H2O )24(SO4CO3)3H2O

anatase TiO2 TiO2

gypsum - CaSO42H2O

hydrocalumite - Ca2Al(OH)73H2O

aragonite - CaCO3

p-aluminohydrocalcite - CaAl2(CO3)2(OH4)3H2O
Amorphous & semi amor - Numeric of Al & Fe amorp
phous precipitates hous & semi amorphous p

recipitates

【0123】 Table 1 shows the comparison between the general red mud and

the constituent minerals of the granular water treatment agent prepared in

Example 1. In the case of the granular water treatment agent, it is shown

that new minerals are formed due to calcium ions added as the first additive

compared to the general red mud, and it is also shown that new trace

minerals are formed in a plurality of amorphous or semi-amorphous forms

composed of aluminum and iron.

【0124】

【table 2】

GRANU artificia artificia treated treated water

LAR W l sewage l sewage water phosphate c

ATER (pH) phosphate c (pH) oncentration

TREAT oncentration

MENT

AGENT

input a

mount

(g)

embodi 2.0 7.0 30.0 mg/L 6.78 2.0mg/L

ment 1-1

embodi 2.0 7.0 30.0 mg/L 6.76 1.9mg/L

ment 1-2

embodi 2.0 7.0 30.0 mg/L 6.80 2.1mg/L

ment 1-3
【0125】 As shown in Table 2 above, it was analyzed that the granular water
treatment agent prepared in Example 1 was not loosened or broken in water

even when 1 L of artificial sewage was filled in a 1 L beaker and then stirred,

and the concentration of phosphate was removed by 90% or more without

a significant change in pH of treated water compared to artificial sewage.

The molded article prepared in Example 1 has not only strong physical

strength, but also many micropores and a high specific surface area. In

addition, minerals such as gibbsite, boehmite, and hematite, which constitute

red mud, which are highly reactive with total phosphorus, are maximally

activated to remove total phosphorus in the form of Al—P, Fe—P, Al—P—

H3PO4, and Fe—P—H3PO4, as well as AlPO4 and FePO4, through ion exchange
reaction, adsorption reaction, substitution reaction, chemical adsorption,

and coordination bond. Furthermore, the granular water treatment agent

prepared in Example 1 shows that a new trace mineral precipitate in the form

of a plurality of amorphous or semi-amorphous minerals composed of newly

produced minerals, aluminum, and iron due to calcium ions added as the

first additive can rapidly adsorb and remove total phosphorus contained in

water.

【0126】 [Experiment 2]

【0127】 Based on the above Experiment 1, an experiment was conducted

on the desorption filtrate of Daegu 00 Sewage Treatment Plant, and

the experimental conditions were performed in the same manner as in

Experiment 1, and Table 3 below shows the results of the pH change of the

reflux water and treated water and the concentration change of phosphate.

【0128】

【table 3】

GRANU deinter deintercala treated treated water

LAR W calation tion filtrate water phosphate c

 ATER filtrate phosphate c (pH) oncentration
TREAT (pH) oncentration

MENT

AGENT

input a

mount

(g)

embodi 2.0 7.92 40.0 mg/L 6.88 8.0mg / L

ment 1-1

embodi 2.0 7.92 40.0 mg/L 6.86 7.9mg/L

ment 1-2

embodi 2.0 7.92 40.0 mg/L 6.82 8.1mg/L

ment 1-3

【0129】 As can be seen from the experimental results of Table 3 above, as in

Experiment 1, it can be seen that 80% or more of the sludge is removed in

an experiment targeting the supernatant containing a high concentration

of phosphate generated during dehydration of the sludge in the sewage

treatment plant. This shows that when the granular water treatment agent

is added to the desorption filtrate, the pH 7.92 of the desorption filtrate

is automatically adjusted to around 6.80 due to the chemical reaction

of the granular water treatment agent minerals themselves, so that new

micromineral precipitates of amorphous or semi-amorphous composed

of gibsite, boehmite, aluminum, and iron are maximally activated, and

phosphate contained in the desorption filtrate can be efficiently adsorbed and

removed.

【0130】 Hereinafter, parts that have been tested and analyzed but have not

been described will be described as follows.

【0131】 In the case of the first additive, desulfurization gypsum, paper sludge
incineration ash, blast furnace slag, loess, bentonite, illite, talc, and silicon
oxide were added instead of fly ash, and the results were similar to those

in Tables 1 and 3. In addition, the results of mixing two or more of the first

additive groups were similar to those in Tables 1 and 3, and the second

additive, the third additive, and the fourth additive were the same.

【0132】 In addition, as a result of the experiment while excluding one step

in the reverse order from the final completion step of the above-described

manufacturing process, it can be seen that the removal efficiency is

sequentially lowered, but the water quality is improved without significantly

adversely affecting the water quality.

【0133】 Therefore, in the present invention, it is preferable to complete

the water treatment agent through all the steps of the above-described

preparation method, but it is also possible to complete the water treatment

agent by selecting only some of the steps described above according to cost

reduction, manufacturing convenience, or needs.

【0134】 That is, the water treatment agent described above is red. The first

additive consisting of the solidification material class in the red mud The

second additive consisting of the acidic chemicals in the mixture of pre-

phase The third additive consisting of agriculture and forestry by-product in

the mixture of pre-phase The mixture mixing the fourth additive consisting

of the binder with the mixture of the pre-phase It is most preferable to be

composed of

【0135】 Pretreated red teeth; The second additive consisting of the acid

chemicals in the pre-processed red mud The third additive consisting of

agriculture and forestry by-product in the mixture of pre-phase The mixture

in which the fourth additive consisting of the binder in the mixture of the

pre-phase is mixed It can be made up of.

【0136】 And besides. And the manufacturing method of the above-described

water treating agent, is the red mud of the place of business waste state The
step that adds the first additive consisting of the solidification material class

in the red mud of the place of business waste state and mixed The step that

pulverizes the mixture in which the solidification material is mixed in the red

mud and sieved The step that the second additive consisting of the acidic

chemicals is added in mixture and mixed The step that adds the third additive

consisting of agriculture and forestry by-product in mixture and mixed

The step that adds the fourth additive consisting of binder in mixture and

mixed The step of molding to the specified form mixture The step that dries

naturally the moldings and cured The dry step in the constant temperature

the molded product The step that it screens after it cools down the building It
most desirables to manufacture through

【0137】 The step that the manufacturing method of the above-described

water treating agent dries the red mud of the place of business waste state

in the constant temperature and pre-processed The step that the second

additive is added in the processed red mud and mixed The step that adds the

third additive consisting of agriculture and forestry by-product in mixture

and mixed The step that adds the fourth additive consisting of binder in

mixture and mixed The step of molding to the specified form mixture The

step that dries naturally the moldings and cured The dry step in the constant

temperature the molded product The step that it screens after it cools down

the building It can be produced through.

【0138】 In addition, each step described above may be independently applied

to other technical fields other than the technical field in consideration of use,

function, role, action, and the like. Based on this, the present invention can

specify various claims as follows.

【0139】 As described above, the description of the present invention is

completed.It is expected that those skilled in the art will be able to fully
understand the gist to be pursued in the present invention through the
above-described details, and based on this, it will be possible to further

increase the efficiency of use as well as the development of the technical

field.
 【Claims】

【Claim 1】

Red mud in the waste state of the workplace;

The step that the first additive consisting of the solidification material class

mixing one or two or greater among the fly ash, calcium sulfate, paper sludge

incinerate material, blast furnace slag, yellow soil, bentonite, illite, talc, silicon

oxide with the red mud is added and mixed

The step of obtaining the powder of 5~50μm it screen-processes the mixture is

pulverized

The step that adds the second additive consisting of the acidic chemicals
mixing one or two or greater with the powder among the sulfuric acid,

hydrochloric acid, polyaluminum chloride, alum, iron salt, ferric sulfate,

aluminium sulfate and mixed

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 2】

Red mud in the waste state of the workplace;

The step that it is dry until it is dry and the percentage of water content of

the red mud lowers the red mud between 25~200°C between 5~25% and it

preprocesses

The step of obtaining the powder of 5~50μm it screen-processes after it

pulverizes the processed red mud as described above

The step that adds the second additive consisting of the acidic chemicals

mixing one or two or greater with the powder among the sulfuric acid,

hydrochloric acid, polyaluminum chloride, alum, iron salt, ferric sulfate,

aluminium sulfate and mixed

The present invention relates to a method for producing a granular water

 treatment agent.

【Claim 3】

The method according to claim 1, wherein:

The step that adds and mixed the third additive consisting of agriculture and

forestry by-product mixing one or two or greater with the mixture in which the

second additive is added and mixed among the rice straw powder, rice hulls

powder, starch, molasse

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 4】

The method according to claim 3, wherein:

The step that the fourth additive consisting of the binder mixing one or

two or greater with the mixture in which the third additive is added and

mixed among the hydroxypropyl methylcellulose (HPMC), polyvinyl alcohol

(PVA), acrylamide, methylcellulose (MC), synthetic resin (vinyl, polyethylene,

polypropylene), silica sol is added and mixed

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 5】

The method according to claim 4, wherein:

The ring the mixture which adds the fourth additive and mixed, and the step of

molding to any one molded product among the pellet or the brick type

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 6】

The method according to claim 5, wherein:

 The step that it cures so that the micro pore is formed in the moldings with
foaming by the natural dry it dries naturally in the place shadying the moldings

over at least 6 hours

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 7】

The method according to claim 6, wherein:

The dry until for the pH of the curing material, 3~7 is in interval 80~400 puts

the curing material into drier

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 8】

The method according to claim 7, wherein:

The step of removing the differentiation which sticks to the surface of the

building through the screen processing after naturally letting cool the building

in the shaded place over the minimum 3 hours

The present invention relates to a method for producing a granular water

treatment agent.

【Claim 9】

A granular water treatment agent prepared according to the preparation

method of claim 1.
 【Abstract】

【Summary】

The present invention relates to a method for manufacturing a granular water

treatment agent and the granular water treatment agent, capable of treating

pollutants including suspended solids and soluble phosphorus included in

water at an ultra-high temperature.

the manufacturing method of the granularity water treatment agent according

to the present invention and granularity water treatment agent is the red mud

of the place of business waste state The step that the first additive consisting

of the solidification material class mixing one or two or greater among the
fly ash, calcium sulfate, paper sludge incinerate material, blast furnace slag,

yellow soil, bentonite, illite, talc, silicon oxide with the red mud is added and

mixed The step of obtaining the powder of 5~50μm it screen-processes the

mixture is pulverized The step that adds the second additive consisting of

the acidic chemicals mixing one or two or greater with the powder among

the sulfuric acid, hydrochloric acid, polyaluminum chloride, alum, iron salt,

ferric sulfate, aluminium sulfate and mixed It characterizes to include and be

manufactured.

【Representative Drawing】

Figure1
 【Drawings】

【Figure 1】
【Figure 2】
【Figure 3】