ENVIRONMENTAL CHEMISTRY(Chapter-1)

1. What are the purity criteria of water?

a. DO, BOD b) TDS, COB c) a & b d) None
2. Which one is the kinetic equation of ideal gases?
1
a. PV=nRT b) PV= mN𝑐 2 c) PV=RT d) PV= 𝑃1 𝑉1
3
3. C𝐻4 and 𝐻2 of same masses are in a vacuum vessel at 25°C. What will be the partial pressure of 𝐻2
of total pressure 1 atm?
1 1 8 16
a. b. c. d.
2 9 9 17
4. Of the 25 cm glass tube, if HCI gas at the 1st end and N𝐻3 gas at 2nd end of the tube enter into that
tube at same time, then white fumes of N𝐻4 Cl forms in the tube------------
a. at middle b) 15 cm from 1ST end
C. 10 cm from 1St end d) at 12 cm
5. Which gas of the followings is not responsible for photo chemical smog?
a. hydrocarbon b) N𝑂2 c) 03 d) CFC
6. Which one is not present in homosphere?
a. Ar b) 𝑂2 c) 0 d) C𝐻4

At 17°C and 105 kPa 0.60L H2 gas is collected over water. Vapour pressure of water at 17°C is 3.25kPa.
From this situation, answer the following MCQ 07-08:

7. Pressure of dry H2 gas will be-

a. 10° kPa b. 101.325 pKa c) 101.75 kPa d) 108.25 kPa
8. At STP, the volume of 𝐻2 gas will be ------
A. 0.06L b) 0.567L c) 0.65L d) 0.567L
9. If the absolute temperature of a gas is doubled and the pressure is reduced gas will to one-half, the
volume of the gas will ----------------
A. emain uncharged b) be doubled C. increased four- fold d) be reduced to 1/4TH
10. Under constant pressure, a certain gas at 0°C was cooled until its volume was reduced to one-half.
The temperature at this stage is-
A. 0°C b) - 136.5K c) -136.5°C d) -273°C
11. the temperature at which real gases obey the ideal gas laws over a wide range of pressure is called-
------
A. Critical temperature
B. Boyle temperature
C. Inversion temperature
D. Reduced temperature
12. In van der Wall's equation for a real gas, the temperature that accounts for inter molecular forces
is-
𝐴
A. (v-b) b. RT C. (P+𝑉 ) d. (RT)−1
2
13. Two gases mix with each other to form a homogeneous mixture. This phenomenon is called-
A. effusion b) addition c) synthesis d) diffusion
14. Equal mass of ethane and hydrogen are mixed in an empty container at 25°C. The fraction of the
total pressure exerted by hydrogen is-
A. 1:2 b) 1:1 c) 1:16 d) 15:16
15. If the vapour density of 𝑂2 and 𝐻2 are 16 and 1, then the ratio of the rate of diffusion of 𝐻2 to that
of diffusion of 𝑂2 is-----------------
A. 16 b) 1/16 c) 4 d) ¼
16. At the same temperature and pressure which of the following gases will have the highest K.E. per
mole?
A. 𝐻2 b) 𝑂2 c) C𝐻4 d) All will have equal value
17. Pressure of a mixture of a 4g of 𝑂2 and 2g of 𝐻2 confined in a bulb of litre at 00 C is-
A. 25.15atm b) 31.205 atm c) 45.205 atm d) 15.21 atm
18. Which of the following exhibits the weakest intermolecular forces?
A. N𝐻3 b) HCl c) HE d) 𝐻2 O
19. If 300 mL of a gas at 27°C is cooled to 7°C at constant pressure, its final volume will be ------------
A. 135mL b) 540mL c) 350mL d) 280ML
20. Densities of two gases are in the ratio 1:2 and their temperatures are in the ratio 2:1, then the
ratio of their respective pressure is-
A. l:1 b) 1:2 c) 2:1 d) 4:1
21. The graph given here illustrates-

A. Dalton's law b) Charles's law c) Boyle's law d) Gay Lussac's law

22. 4.4g of a gas at S.T.P. occupies a volume of 2.24L, the gas can be -----------------
A. 𝑂2 b) CO c) N𝑂2 d) C𝑂2
23. At what temperature will the r.m.s. velocity of S𝑂2 be the same as that of 𝑂2 at 303 k ?
A. 273K b) 606K c) 303K d) 403K
24. Among the solids, the higher melting point exhibited by-
A. covalent solids b) ionic solids c) pseudo solids d) molecular solids
25. If the r.m.s. velocity of gaseous molecules is x cm/sec at a pressure of p atm, then r.m.s. velocity at a
pressure 2p atm and constant temperature will be-
A. x b) 2x c) 4x d) x/4
26. The root mean square velocity of an ideal gas at constant pressure varies with the density (d)
as—
1
A. 𝐷 2 b) d c) √𝑑 d)
√𝑑
27. The compressibility for an ideal gas is----------------
A. 1.5 b) 1.0 c) 2.0 d) ∞
28. X mole of H2 gas effuses through the hole in a container is 5 sec. The time taken for effusion of the
same volume of the gas specified below under identical conditions is-
A. 10 sec: He b) 20 sec:𝑂2 c) 25sec: CO d) 55sec:C𝑂2
29. In the equation PV=RT, the value of R will depend on-----
A. a) nature of gas b) temperatures of gas C. the pressure of gas d) units of measurement
30. Among 𝑂2 , N𝐻3 , CO and C𝐻4 the gas with highest root mean square velocity at a particular
temperature is-------------
A. C𝐻4 b) CO c) 𝑂2 d) N𝐻3
31. Number of molecules is 7.0g of nitrogen gas is----------------
A. 6.023 × 1023 b) 3.012 × 1023 c) 1.506 × 1023 d) 4.518 × 1023
32. Plasma is---------------
A. an ionized gas b) neutral gas C. a solid-state d) a liquid state
33. Pressure Is----------------
𝑀 𝑀 𝐹 𝑟
A. b. C. d.
𝑑 𝑉 𝐴 𝑀
34. At STP, the volume of one mole gas is---------------
A. 22.44 litre b) 22.04 litre c) 24.789 litre d) 22.4 litre
35. What is the relationship between absolute scale and degree Celsius scale?
A. 𝑡 0 C=(t+273) K b) 𝑡 0 C= (t-273)K c) (t+273)°C=t K d) (t+274)°C= K
36. The unit of molar gas constant at CGS is------------
A. 8.316 ×107 J𝐾 −1 - mo𝐿−1
B. 8.316 J𝐾 −1 mo𝐿− l
C. 0.082 erg𝐾 −1 mo𝐿−1
D. 8.316 ×107 erg𝐾 −1 mo𝐿−1
37. Isomorphism is-
a. same molecular formula
b. same structural formula
c. same crystalline structure
d. same size
38. The example of amorphous is---------------------
a. quick lime b) sulphur c) diamond d) sugar
39. What is the critical pressure of CO2 at critical temperature?
a. 70.5 atm b) 71.9 atm C) 72.9 atm d) 73.2 atm
40. What is the molar volume of a gas at STP?
a. 22.414 L b) 22.789 L c) 24.414 L d) 24.789 L
41. A cylinder will full of gas is exploded at high temperature. Which gas law is followed by this
process?
a. Boyle's law b) Charle's law c) Gay-Lassac's law d) Avogadro's law
42. Which one of the following diffuses more?
a. N𝐻3 b) C𝑂2 c) 𝑁2 d) C𝐻4
43. What is the RMS velocity of 𝑂2 at STP?
a. 461.34 cm𝑆 −1 b) 560.5 cm𝑆 −1 c) 461.34 m𝑆 −1 d) 560.5 m𝑆 −1
44. Which one is the Vander-wall's equation of 64g of 𝑂2 ?
𝑎 𝑎
a. (p + )(v-nb) =Nrt b. (p + )(v-b) =rt
𝑣2 𝑣2
2𝑎 4𝑎
B. c. (p + )(v-2b) =2rt d. (p + )(v-2b) =2rt
𝑣2 𝑣2
45. What is the mole fraction of NaCI when 10g of NaCI is mixed with 20g of 𝐻2 O?
a. 0.133 b) 0.143 c) 0.150 d) 0.160
46. Charle's law correlates which terms?
a. Volume, pressure
b. b) Volume, temperature
c. Volume, mole number
d. Pressure, temperature
47. What is called absolute zero temperature?
a. - 273'C b) 0°C c) 274°C d) 300°c
48. Plasma is --------------
a. an ionized gas b) an ionic compound c. an organic compound d) colloid
49. What should be the volume (in lit.) of a gas at 0K?
a. 22.4 b) 44.8 c) 0 d) 32.4
50. What is the critical temperature (at 𝑜𝐶 ) of C𝑂2 ?
a. 31.8 b) 31.1 c) 32.4 d) 30.4
51. What is the volume (in lit.) of 0.5 mol C𝑜2 gas at STP?
a. 22.4 b) 20.2 c) 11.2 d) 16.8
52. What is the volume of one mole of a gas at 25 C and 1.01 atm pressure?
0

a. 22.2 d𝑚3 b) 24.8 d𝑚3 c) 24.4148 d𝑚3 d) d𝑚3

53. Which of the following law is used for representing Amaga't curve?
a. Boyle's law b) Charle's law c) Avogadro's law d) All of the above
54. The most possible velocity of the gaseous molecules can be represented by which of the following
equation?
3𝑅𝑇 3𝑅𝑇 2𝑅𝑇 3𝑝
a. 𝛼= √ b. 𝛼 = √ 𝑛 c. 𝛼= √ d. 𝛼 = √ 𝑣
𝑀 𝑀
55. What is the kinetic energy of 22g C𝑂2 gas at STP?
a. 3714.25J b) 1434.5J c) 1858.62J d) 6.172 × 1021 J
56. What is the critical temperature of Helium gas?
a. -83.10 C b) -2400 C c) -2680 c d) -2840 C
57. What is the shape of the NaCl crystal structure?
a. Body centered cubic b) Face centered cubic
C. Normal cubic d) Tetragonal
58. What is the ratio of the coordination number in the crystal structure of NaCl?
a. 6:6 b) 8:8 c) 12:12 d) 4:4
59. Rate of diffusion of two gases A and B are 0.4 and 0.8 respectively. If the density of A is 8 then,
what is the density of B?
a. 2 b) 4 c) 6 d) 8
60. Which one of the following is the correct Vander-wall's equation for 64 gm of methane?
16𝛼 𝛼
a. (p+ 𝑣2 )(v-b) =RT b. (p+𝑣 2 )(v-nb) =nRT
16𝛼 4𝛼
D. (p+ 𝑣2 )(v-4b) =4RT D. (p+ 𝑣 2 )(v-4b) =4RT
61. Critical temperature of 𝑂2 is---------------
a. - 118.80°C b) 118.80°C c) -47.60°c d) 87.60°c
62. Rate of diffusion of NH; is higher than that of C𝑂2 by ------------
a. 1.609 b) 0.621 c) equal d) 2.588
63. What will be the molecular mass of a gas having root mean velocity 483.62 M𝑠 at 270 C
−1

temperature?
a. 28 b) 16 c) 32 d) 44
64. Number of molecules of N𝐻3 present in 0.1 mol of gas at 27°C temperature and 99.99KPa pressure
are ----------------
a. 6.023 × 1023 b) 60.23 × 1022 c) 6.023 × 10−23 d) None of them
65. What is the co-ordination number of the N𝑎 in NaCl lattice?
+

a. 8 b) 4 c) 6 d) 7
66. Which of the following is the property of gaseous substance?
a. Strong inter-molecular force
b. Higher compressible
c. Has definite size and shape
d. High melting point
67. 1 atm equals how many bars?
a. 1.0 bar b) 101.325 bar c) 101325 bar d) 1.01 bar
68. What is the unit of pressure in CGS system?
a. Dyne/c𝑚2 b) Dyne/𝑚2 c) N/𝑚2 d) N/c𝑚2
69. Volume of a gas at 0°C is Xc𝑚3 . At which temperature the volume of the gas will be X/2 c𝑚3 ?
a. 0°C b) - 136.5°C c) -136.5°C d) -273°C
70. Equal mass of C𝐻4 and 𝑂2 gas was mixed in a container at a definite temperature. The fraction of
the total pressure exerted by 𝑂2 is-
1 1 1 2
a. b. c. d.
2 3 4 3
71. The rate of diffusion of an unknown gas is half of the rate of diffusion of methane at the same
temperature and pressure. What is the molecular mass of the unknown gas?
a. 64 b) 32 c) 8 d) 4
72. What is the radius of C𝑠 ?+

a. 95 Pm b) 181 Pm c) 167 Pm d) 167 A

73. In an ionic crystal the radius of 𝐴 and 𝐵 ions are 95 pm and 181pm respectively. What will be
+ −

the shape of the crystal?

a. Octahedral
b. Tetrahedral
c. Body centered cubic form
d. Face centered cubic form
74. What is the critical pressure of C𝑂2 gas?
a. 72.9 atm b) 12.8 atm c) 49.7 atm d) 24.8 atm
75. How many types of crystals are there?
a. five b) six c) three d) seven
76. Molar volume at SATP is-
a. 22.4 d𝑚3 b) 24.8 d𝑚3 c)1 d𝑚3 d) 22400 ml
77. What is the number of molecule of 5g C𝑂2 at STP?
a. 6.84 × 1023 b) 4.4 × 1029 c) 6.023 × 1023 d) 6.84 × 1022
78. What is the value of R in SI unit?
a. 0.0821 L atm 𝐾 −1 mo𝑙 −2 b) 8.316 J𝐾 −1 mo𝑙 −1 c. 0.0821 er𝑔−1 mo𝑙 −1 d) 8.31 er𝑔−1 mo𝑙 −1
79. At STP the volume of N2 gas is 1.5L. What is the volume of that gas at 25°C temperature and 750
mm (Hg) pressure?
a. 1.2659L b) 1.6592L c) 1.26591mL d) 1.26592 cc
80. Which of the following states are not found normally?
a. Plasma b) Ionic state c) Liquid crystal state d) Both a and a C
81. What is the molar volume of a gas at STP?
a. 22.414 L b) 22.789L c) 24.414L d) 24.789L
82. What is the molar gas constant in CGS unit?
a. 8.316 Joule 𝑘 −1 mo𝑙 −1 b) 8.316 ×10−7 Joule𝑘 −1 mo𝑙 −1
B. 8.316 × 10−7 erg 𝑘 −1 𝑔−1 d) 8.316x 10−7 erg𝑘 −1 mo𝑙 −1
83. How many number of collisions occurs in mean free path?
a. 0 b) 1 c) 2 d) 3
84. Which is followed by the adjacent graph?

a. Boyle's law b) Charle's law c) Gas-volume law d) Pressure's law

85. Which one occupies lowest volume of one gram of each of the following gas at STP?
a. C𝑂2 b) N𝐻3 c) 𝑂2 d) 𝐻2
86. What is the critical volume of C𝑂2 ?
a. 95.55ml b) 95.65ml c) 96.65 ml d) 96.66 ml
87. This graph is followed by which law?
a. Charle's law b) Boyle's law c) Pressure's law d) Avogadro's law
88. Which one of the following of 1 litre at ST contains more atoms?
a. 𝐻2 b) N𝐻3 C) C𝑂2 d) C𝐻4
89. What is the inversion temperature of He?
a. -80°C b) -140°c c) -240'C d) 240°c