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The effect and mechanism of natural zeolite on preventing expansion due to alkali±aggregate reaction are studied
in this paper. The results confirm that the expansion can be minimized by increasing the fineness of natural
zeolite powder (even to superfineness) or by a previous heat treatment for the zeolite additive.
17
Potentially harmful
Two kinds of natural zeolite rock were used in the
Rc: mmol/l
400
tests. One was Du Shikou natural zeolite rock from
Chicheng county, Hebei province, China, and the other
300
was Ohya-Rock natural zeolite rock from Japan. Their
chemical compositions are shown in Table 2.
200 It was shown by X ray diffraction that these two
2,3
zeolite rocks contain clinoptilolite. The former con-
Harmless C tains 65% zeolite, while the latter contains 60% zeo-
100
B lite. Their fineness is shown in Table 3. Fineness
levels I, II, III and IV correspond to 2510, 5280, 6860
A
01 2.5
Harmful
5.0 7.5 10 15 20 25 30 50 75 100 150 250 350 500 1000 2500
and 8820, respectively.
40 60 130 200 300 400 750
Expansion (3 1024)
15%
Proportion of mortar 6.0
20%
The cement to sand ratio was 1:2´25, and three
mortar specimens 2:54 3 2:54 3 28:5 cm in size com- 4.0
prise a group. The water content enabling the flow of 30%
5
mortar to reach 105±120 mm was adopted. 2.0 40%
10%
6.0
Evaluation method
According to SD105-82, when the linear free 4.0 15%
expansion of the mortar bar at 90 and 180 days is
less than 0´05% and 0´1%, respectively, if the cement 2.0 20%
30%
were used together with reactive aggregate, no harmful
AAR would occur in concrete. 0.0 40%
30 60 90 120 150 180
Age: days
5.5 12.0
0%
5.0
5%
4.5
10.0
4.0
Expansion (3 1023)
10%
3.5
15%
Expansion (3 1024)
3.0 8.0
20%
2.5
2.0
1.5 6.0
1
1.0 30%
2
0.5 40% 4.0
0.0
3
20.5
30 60 90 120 150 180 210 240 270 300 2.0
Age: days
0.0
Fig. 5. Effect of zeolite powder with fineness II on 10 20 30 40
expansion caused by aggregate B Dosage of blending material: %
4.0
3.5
3.0
10%
2.5 15% 4.0
2.0
3.5
1.5
1.0 20% 3.0
Expansion (3 1023)
0.5 30% 2
2.5
0.0 40%
20.5 2.0 1
30 60 90 120 150 180 210 240 270 300
Age: days 1.5
1.0 4
Fig. 6. Effect of zeolite powder with fineness III on 3
0.5
expansion caused by aggregate B
0.0
5.5 20.5
0% 10 20 30 40
5.0
Dosage of blending material: %
4.5
5%
Expansion (3 1023)
4.0
3.5
Fig. 9. Effect of changes in zeolite powder fineness on
10%
3.0 expansion caused by aggregate B (at 90 days). 1, fineness
2.5 level I; 2, fineness level II; 3, fineness level III; 4, fineness
15%
2.0 level IV
20%
1.5
1.0
0.5 30%
0.0 40%
6.0
20.5
30 60 90 120 150180 210 240 270 300
Age: days 5.0
Expansion (3 1023)
Test series II
0.0
10 20 30 40
The inhibiting effect of reactive zeolite on AAR
Dosage of blending material: %
was investigated.
Natural zeolite heated at 5008C for dehydration, Fig. 10. Effect of changes in zeolite powder fineness on
and ground to a specific surface area of 4350 cm2 =g expansion caused by aggregate B (at 180 days). 1, fineness
(residue on a 0´008 mm sieve was 6´8%) was used. level I; 2, fineness level II; 3, fineness level III; 4, fineness
The sand consisted of 20% aggregate B and 80% level IV
Expansion (3 1023)
4.0 1
0.5 3
5.5 0%
5.0 0.0
4.5 20.5
Expansion (3 1023)
4.0 0 5 10 15 20 25 30 35 40
3.5 Dosage of blending material: %
10%
3.0
2.5 Fig. 14. Inhibiting effect of superfine zeolite powder on AAR
20%
2.0 (at 180 days). 1, fineness level I; 2, fineness level IV; 3,
1.5 superfine zeolite powder
1.0
0.5 30%
0.0 40% was more than 10%, the expansion of the mortar bar
20.5
30 60 90 120 150 180 210 240 270 300 caused by AAR was suppressed efficiently.
Age: days
Test series IV
Fig. 11. Inhibiting effect of heat-treated zeolite powder on
The influence of the alkali content in cement was
AAR
investigated.
Zeolite powder with a specific surface area of
0.6
0%
7000 cm2 =g was used. The sand consisted of 20%
0.5 Natural zeolite aggregate B and 80% quartz sand. The alkali content
Expansion (3 1022)
Table 6. Influence of the alkali content in cement on type, with a zeolite content of 65% and specific
inhibition surface area of 5280 cm2 =g.
Sample Alkali content Dosage of zeolite Content of The alkali content in the cement was 2´2%, and the
in cement: powder: aggregate B in sand used in the mortar consisted of 20% reactive
% % aggregate: % aggregate B and 80% quartz sand.
1 1´09 0, 10, 15, 20, 30 20 The expansion of the mortar bar is shown in
2 1´40 0, 10, 15, 20, 30 20
Fig. 16.
From Fig. 16, it can be seen that both kinds of
3 1´80 0, 10, 15, 20, 30 20
zeolite rock have the same inhibiting effect on AAR
4 2´20 0, 10, 15, 20, 30 20 associated with aggregate B. With a 30% dosage of
zeolite, AAR in mortar can be inhibited.
1
cm2 =g, and silica fume with 200 000 cm2 =g were used
2
0.20 in the test. The plan of the test is shown in Tables 7
3
and 8. The test results are illustrated in Figs 17 and
18.
0.10
4
5
0.55
0.00 0.50
1.2 1.6 2.0 2.4 Du Shikou zeolite
Alkali content: % 0.45 Ohya-Rock zeolite
0.40
Fig. 15. Influence of the alkali content in cement on the
Expansion (3 1022)
0.35
inhibiting effect on AAR. 1, control; 2, 10%; 3, 15%; 0.30
4, 20%; 5, 30% 0.25
0.20
0.15
Test series V
0.10
This was a comparison test between Ohya-Rock 0.05
natural zeolite rock from Japan and Du Shikuo natural 0.00
zeolite rock from China. The properties of the zeolite 20.05
10 20 30 40
rocks are as follows. Ohya-Rock natural zeolite rock
Dosage of blending material: %
is of the clinoplilolite type, with a zeolite content of
60% and a specific surface area of 4830 cm2 =g. Du Fig. 16. Comparison of the inhibiting effect on AAR between
Shikuo natural zeolite rock is also of the clinoplilolite two kinds of natural zeolite
runway in Fu Chenmeng.
6.0 For a long period, the cement used in the Beijing
4 region has had a high alkali content, while a large
1 3
number of high-rise building constructions in this
3.0 region have required the use of concretes. However,
2
major use of high-strength cement or high early
0.0
strength cement (without or with adding a little
10 20 30 40 blending material) leads to the tendency of AAR in
Dosage of blending material: % concrete. Thus, to ensure the durability of concrete
Fig. 17. Influence of various blending materials on AAR
structures in this region, and to reduce maintenance
caused by aggregate A (at 180 days). 1, sample 1; 2, sample costs, investigations on AAR in this region and
2; 3, sample 3; 4, sample 4 prevention techniques are needed urgently.
The Yong Dinghe River region is one of the main
sources of sand and stone in Beijing. Initial investiga-
5.5
tions on aggregates from this region found that they
5.0
4.5
contain a great deal of reactive mineral compounds,
7
4.0 1 such as rhyolites, chert and dacite. Typical rhyolites
and chalcedonies were collected and prepared for the
Expansion (3 1023)
3.5
3.0 test in accordance with SD105-82.
2.5 Based on the above investigations, Du Shikuo zeo-
2.0 4 2 lite powder with a specific surface area of 6960 cm2 =g
1.5 was used in the test, in which typical reactive ag-
1.0
gregate from the Yong Dinghe River region was used.
0.5
The test results are illustrated in Fig. 19.
0.0 3
20.5 It can be seen from Fig. 19 that the expansion of
0 10 20 30 40 the mortar bar without adding zeolite at 90 and 180
Dosage of blending material: %
days is more than 0´05 and 0´1%, respectively, which
Fig. 18. Influence of various blending materials on AAR
are the ASTM limiting values. Thus, aggregates from
caused by aggregate B (at 180 days). 1, sample 5; 2, sample the Yong Dinghe River region are reactive aggregates,
6; 3, sample 7; 4, sample 8 which can cause harmful expansion. When the dosage
of zeolite was 5%, marked expansion still occurred,
and the expansion of the mortar bar at 90 and 180
From Fig. 17, it can be seen that for aggregate A, days was still more than the ASTM limits. However,
fly ash possesses the same inhibition effect on AAR
as the zeolites. When the dosage was 20% the ex-
0.30
pansion of mortar was less than 0´03% at 180 days.
However, to obtain the same effect, 10% silica fume
and 40% slag were needed for silica fume to produce 0.25
5%
zeolite with a 30% dosage possesses the same
inhibiting effect on AAR as 15% silica fume. The 0.15
expansion of the mortar bar was about 0´05% at 180
days. However, when the dosage of fly ash was up to
0.10
30%, the expansion of the mortar bar at 180 days was
20%
double that with the silica fume. Slag possesses the 10%
Test series VII Fig. 19. Inhibiting effect of natural zeolite powder on AAR
Investigations carried out in recent years indicate caused by the reactive aggregate from the Yong Dinghe
that the AAR found in the Beijing region belongs to River region in Beijing
Magazine of Concrete Research, 1998, 50, No. 1 23
Feng Naiqian et al.
when the dosage of zeolite was more than 10%, the (d) When the alkali content in cement is as high as
expansion of the mortar was greatly reduced, to below 2´2%, if 30% natural zeolite powder with a specific
the ASTM limits. When the zeolite dosage was 20 and surface area of 7000 cm2 =g is used, AAR in concrete
30%. AAR could be prevented efficiently. can be inhibited whatever kind of aggregate is used.
(e) Natural zeolite powder can produce a better
inhibiting effect on AAR than slag ± as good as fly
ash, but not quite as good as silica fume. In
Conclusion
particular, for an aggregate with very high alkali
When there is an alkali content in cement, whether reactivity (e.g. aggregate B), natural zeolite powder
or not AAR will occur depends on the alkali reactivity can produce better inhibiting effect on AAR than fly
of the aggregate, and the type of blending material ash or slag, because of higher chemical reactivity
and its fineness and dosage. The following conclu- than the latter.
sions can be drawn from this study: ( f ) For reactive aggregate from the Yong Dinghe
River region in Beijing, when the dosage of natural
(a) When 30% natural zeolite powder is used to zeolite powder (with a specific surface area of about
replace the same content of cement (alkali content is 7000 cm2 =g) is more than 10%, the expansion of the
1´82%), AAR will not take place in concrete even if mortar bar at 90 and 180 days is below ASTM limits.
reactive aggregates are used. This means that harmful AAR in concrete can be
(b) The inhibiting effect of natural zeolite powder prevented.
on AAR is also related to its fineness.
For an aggregate with high alkali reactivity (e.g.
aggregate B), to suppress AAR efficiently, 30%
natural zeolite powder with a specific surface area References
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a specific surface area of 5000±7000 cm2 =g is used 1992, 14, 93±96.
AAR in concrete can be efficiently prevented, but for 7. LIU CHONGXI. Treatise on dam concrete (1). Concrete alkali±
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effect. China).
(c) When 20% heat-treated (under 5008C) natural
zeolite powder is used, AAR in concrete can be Discussion contributions on this paper should reach the editor by
inhibited efficiently. 25 September 1998