Eg Time : 3.15 hours CHEMISTRY - 34 Max. Marks : 70 instructions i) The question paper has four parts A, B, C and D all the parts are compulsory. i) iii) Answer all questions. & aay 7 ws S y 1P.U.C. MID-TERM EXAMINATION, NOVEMBER-2014 @ Write balanced chemical equations and draw labeled diagrams wherever asked Use log tables and simple calculators if necessary. (Use of scientific calculators are not allowed) Part-A (Answer each question in one word or in one sentence) 1. Define molarity of a solution 2. What is critical temperature? 3. Give an example of a reaction where K,=K, : 4. Assign IUPAC name to the element with atomic number 107. : 5. Why is sigma bond stronger than Pi bond? 6. What is the change in oxidation number when MnO, is converted to Mn”? 7. Give an example for covalent hydride. . 8. Why Lithium has properties similar to that of magnesium? 8. Mention the element present in the organic compound when its sodium fusion extract gives violet color with sodium nitroprusside, 10. 3HC=CH—EEE A Identify A Part -B > Answer any FIVE questions (Each questions carries two marks) 5x2=10 ‘11. 2) Whatis the SI unit of thermodynamic temperature? b) Express 22400 in scientific notation. 12, State Boyle's law. Give its mathematical form. 13. What is dipole moment? Why BeF, molecule shows zero dipole moment? 14, Write electronic configuration of lithium molecule. Predict the magnetic properties. 15. Whatis plaster of Paris? How is it prepared? ; 16. What is position isomerism? Give an example. 47. State Markonvikoffs rule. 18. Explain Friedel crafts alkylation reaction, ; Part-c Answer any FIVE questions (Each question carries three marks) 5x3=15 19. Define ionisation enthalpy. Nitrogen has higher ionisation enthalpy than oxygen. Give reason. \ - 2. 24 22. 23. 24, Define the term ionic radii. Why sodium ion size is less than sodium atom and chloride ion size is more than chlorine atorn? ‘What is hybridisation? Mention the type of hybridisation of phosphorus in Pl, and FEF bond angle in BF. Based on MOT draw the energy level diagram for oxygen molecule. Calculate formal charge on each oxygen atom of ozone molecule. Balance the following redox reaction by oxidation number method. Cr,0F),. +S0F),) 4 Crp) +807, (ax) FSO a) 25. a) Show that water is an amphoteric compound with examples. 2 b) Whatis meant by ‘30 vot’ hydrogen peroxide? i, 26. Explain the manufacture of washing soda by solway process. 40x1=10Part -D (IV&V) eos \ IV Answer any FIVE questions. x (Each question carries Five marks. 7. Whats molecular formula? An organic compound contain 40% carbon 6.7% hydrogen and rest is oxygen \fthe molecular mass of the compound is 90. Find out molecular formula. 5 J 28. a) Give three postulates of Bohr’s atomic model. 3 b) Anatom has Z=92 and A=235. Find out number of protons, neutrons and electrons present in the atom. 2 28. a) State Paul's exclusion principle. What conclusion can be drawn from the principle. 2 b) Write the electronic configuration of the elements having atomic number 7 and 17 in accordance with Hunds rule A c) How many azimuthal quantum numbers are possible when n=4. 1 _ 30. a) Give three postulates of Kinetic theory of gases. 3 b) Whats an ideal gas? Write vanderwaals equation for one mole of real gas. 2 31.2) Whatis (Spontaneous process (i) Isothermal process (ii) Reversible process , 3 b) Whatis an intensive property of a system? Give an example. 2 32. a) _ Enthalpy of combustion of CH,OH;y carbon (graphite) and hydrogen are -726 KJ/mol, -393 KJ/mol and -286KJ/mol respectively, Calculate enthalpy of formation of CH,OHy 3 b)_() Whatis an entropy? (i) State second Law of thermodynamics. 33. 2) i) State Lechatelier’s principle. i) Whatis the effect of temperature on the reaction 2NO, ==N,O, Al ‘e b) Define equilibrium constant. j \ Ve and what is the effect of pressure on the reaction CO,,, +3H,,, == CH, +H,0,) ) 34. a) Explain Lewis concept of acids and bases with suitable examples, b) Define ionic product of water. Give its value at 298K. 2 V. Answer an TWO questions (Each question carries Five marks. 2x5=10 q 2). Whatisanelectophle? Give an example, 2 4 b)_ Whatis electromeric effect? Give an example for +ve electromeric effect. 2 ©) Draw the wedge structure of methane. 1 36. a) Give the principle and calculation involved in the estimation of carbon and hy Giannis yydrogéh present in the ») _Incarius method of estimation of halogen 0.15g of an organi 7 . ganic compound gave 0.12: in ‘out the percentage of bromine in the compound : Seer (Atomic mass of Ag=108 & Br = 60) 37.2) Explain the mechanism of chlorination of methane. b) Explain ‘Wurtz reaction” 3EX’ | P.U.C. MID-TERM EXAMINATION, NOVEMBER-2017 @ Time : 3 hr. 15 min. CHEMISTRY - 34 Max, Marks : 70 PART-A |. Answer all questions (Answer each question in one word or one sentence) Stale Gay-Lussac's law of gaseous volume, What is the volume occupied by the gas at zero kelvin? What is the conjugate base of H,0? Write the IUPAC name of the element with atomic number (2) 107. ‘What is the oxidation number of hydrogen in NaH (sodium hydride)? Which colour is imparted by sodium salt to an oxidizing flame? Write the chemical formula of plaster of paris. CH,(g) + 20,(g) — CO,(g) + 2H,0(g). Mention the type of redox reaction. ‘Name the first organic compound synthesized in the laboratory. Which one is more acidic between ethene & ethyne? 10x Seenomsona PART-B Il. Answer any FIVE questions (Each question carries two marks) 5x2=10 11. (a) Write the following number in scientific notation 0.000256. (b) How many mole of CO, is liberated when 16 g of methane is completely burt in presence of excess of oxygen? 42. Calculate the value of universal gas constant (A) for one mole of an ideal gas at ‘STP. 4 13. Define dipole moment. What is its SI unit? 14. How is bleaching powder prepared by slaked lime? Write the reaction. 15. Write any two postulates of VSEPR theory. 16. Write the eclipsed & staggered conformations of ethane based on Newman's projections. 17. State Huckel's rule. Give an example. 18. (a) Write the bond line representation of (CH,), C-CH,. (b) Give an example for heterocyclic compound. PART-C Ill, Answer any FIVE questions (Each question carries three marks) 5x3=15 19. (a) What is electronegativity? How it varies down the group? (b) State modem periodic law. 20. Explain the formation & geometry of methane by hybridization concept. 21. Write the electronic configuration of O, molecule using MOT. What 22. (a) Mention any two factors which favour the formation of ionic bond, (b) Define lattice enthalpy. 23. Balance the following ionic equation by 'Half-Reaction' method Fe™ (aq) +Cr,07 (aq) + Fe” (aq) +Cr* (aq) (Acidic medium) 24. (a) How temporary hardness of water is removed from Clark's method? Write the reaction. (b) Write the composition of water gas. 25. (a) Write any two similarities between lithium & magnesium. (b) Which is the strongest reducing agent among the alkali metals? 26. Explain the preparation of washing soda (Na,CO,,10H,0) by Solvay’s process. bond order & magnetic property? (PT.0)“2. PART-D . IV. Answer any FIVE questions (Each question carries five marks) 5x5 = 25 27. (a) A compound contains 85.6% carbon & 14.4% hydrogen. Its molecular mass is 28 u. Determine tho empirical & molecular formulae of the compound, (Given: Atomic mass of H=1u, C=12u). (b) Classify the following in to pure substances & mixtures. Milk, Water, Marble, Sodium (342) 28. (a) Write any three postulates of Bohr's model of an atom. (b) Arrange the following electromagnetic radiations in the increasing order of their wavelength X- rays, radio waves, visible rays, UV rays (3+2) 29. (a) What are the possible 'n' & //values for L-sholl? () What willbe the wavelength of a ball of mass 0.1 kg moving with a velocity of 10 ms"? (Given: h = 6.626 xI0*Js). (c) How many unpaired electronics are present in nitrogen atom? (24241) 30. (a) State Boyle's law. Write its mathematical form. (b) Define surface tension. What is its SI unit? (c) What is the value of compressibility factor (Z) for an ideal gas? (2+#241) 31. (a) State first law of thermodynamics. Write its mathematical form. (b) Derive the relationship between C, & C, for an ideal gas. (c) What is the change in internal energy during free expansion of an ideal gas? (24241) (2) Calculate the standard enthalpy of formation of CH,OH(|) from the following data CH,OH()) + 9/2 0,(g) > CO,(g) + 2H,0(!) = -726 kJ/mol Cioragniey + O,(9) —* CO,(9) -393 kJ/mol H,(g) + ¥¢ O,(9) > H,0(1) 286 kJ/mol po) ‘Write Gibb's equation for free energy change. Under what condition reaction becomes spontaneous for an exothermic reaction during which entropy decreases. (342) 33. (a) What is homogeneous equilibrium? Give an example. (b) How K, & K, are related for the following equilibrium? N, (g) +3H,(g)-< 2NH,(g) (0) State Lechatelier’s principle. (24241) 34. (a) At equilibrium, the concentrations of N,= 9.0x10° M, 0, = 4.2x10° M and NO = 2.8x10°M in a sealed vessel at 800K. What will be K, for the reaction N,(g)+0,(g) < 2NO(g) (b) Show that pH + pOH = 14 - (c) What is common ion effect? (24241) V. Answer any TWO questions (Each question carries five marks) 2x5=10 35. (a) What is position isomerism? Give an example. (b) Write any two differences between inductive effect & electromeric etfect. (c) Write the IUPAC name of CH,CH,CHO (24241) 36. (a) What is the principle behind simple distillation process? (b) How the presence of chlorine in a given organic compound is detected using Lassaign's extract? (c) What is the principle behind the e: n of carbon & hydrogen for an organic compound? (2+2+1) 37. (a) Explain the mechanism of nitration of benzene. (b) Complete the following reactions (i) CH,-CH=CH, +HBr—> (i) CH,COO™Na* + NaOH S24 (342)1 PUC MIDTERM EXAMINATION NOVEMBER -2018 i Total Questions : 37 Subject Code : 34 Time +18 Hours Subject : CHEMISTRY Max. Marks : 70 Instructions: 1, The question paper has four parts A, B, Roe aa 18, Ht 19. 20. 21. 22, 23. 24. 25. dD. AIL 2. Write balanced chemical equations and draw labelled, ry (Use of sei re compulsory. sms wherever necessary. fic calculator is not allowed.) 3. Use log tables and simple caleutator if ne PART- Answer all the questions in one word. Each question carries one mark. 10x 1= 10 Express 0.0003965 it ntific notation. Write ideal gas equation for 'n’ moles of ga Give the relation between K, and K, for the equilibrium =< Nyt 3Hy, y~N 2NH, Which group of elements in the periodic table are called halogens? What is the oxidation state of alkalimetals ? State modem periodic law. What is the chemical composition of water gas ? What is entropy ? Give an exmaple for heterocyclic aromatic compund. Write the Newman projection of staggered confirmation of ethane. PART -B Answer any five questions, each questions carries 2 marks : 5x2=10 Write any two postulates of Dalton’s atomic theory. State Boyle’s law. Give its mathematical expression, Write Lewis dot structure of the nitrite ion, No; Give two reasons for anomalous properties of lithium, Write the electronic configuration of oxygen molecule Write any two differences between inductive effect and electromeric effect. Write the IUPAC name of the following compounds. i) CH, -CH,-CH-CH, - COOH OH 11 4 cl Explain Wurtz reaction with an example. PART C Answer any five of the following. Each, question carries 3 marks. Define ionisation enthalpy. How does it vary along the period and down the group of the periodic table? Explain Sp° hybridisation by taking CH, as an example. Write any three postulates of VSEPR theory. a) What are the isoelectronic species? Give example. b) Write the IUPAC name of an clement whose atomic number is 108. Balance the redox reaction by oxidation number method. MnO,;,..+ Br, —> MnO,,, + BrO,,,,, (Basic Medium) i) Give the reactions to show amphoterie nature of water. ii) Mention any one method of removal of permanent hardness of water, Write the equations during the preparation of sodium carbonate by solvay process.6. Iv 27. 28. 29. 30. 31. 32. 33. 34) 35. 36. a a) Give the chemical formula for i) Washing soda_ii) Plaster of paris. b) Give any one biological importance of maganesium. PART -D Answer any five of the following (Each question carries 5 marks) §x5=25 | a) An organic compound contains 4.05%, hydrogen, 24.26% carbon and 71.67% molecular mass is 98.96g What are its empirical and molecular formula ? b) What is limiting reagent ? a) Write any three postulates of Bohr’s theory of atomic model. b) State Hund’s rule of maximum multiplicity. a) Explain the significance of four quantum numbers, } b) Write de Broglie equation. a) Write any three postulates of kinetic molecular theory of gases. b) At 298 k and 760 mm of Hg pressure a gas occupies 600 ml volume. What will be its pressure | at a hight where temperature is 283 k and volume of the gas is 640 ml. | a) Write Gibbs equation, Explain the terms in it. \ b) Calculate AG? for conversion of oxygen to Ozone at 298 K. Given Kp = 2.47 x 10” and R=8.314 JK" mol? : a) Derive the relationship between CP and CV for an ideal gas. | b) What is an extensive property. Give an example. a) State Le chatelier’s principle. What is the effect of temperature on the equilibrium. ' 2NO,,. <== N,O,,.; AH=-57.2 KI mol! b) What fs heterogenous equilibrium. Give an example for heterogenous equilbrium, a) Calculate the value of pH of 0.001M HCl. b) What is buffer solution ? Give an example for acidic buffer, c) Write the value of ionic product of water at 298 k. Answer any two of the following, Each question carries 5 marks 2x5=10 a) Explain functional isomerism with an example. b) How many o and x bonds are present in the following molecule ? HC =C-CH=CH - CH, ©) What is nucleophile ? ; a) Explain Kjeldahl’s method for the estimation of itrogen in the organic compound? b) How do you detect sulphur using Lassaigne’s extract ? a) Explain the steps involved in mechanism of nitration of benzene b). State Markounikov rule, Chlorine. Its \FIRST PUC MIDTERM EXAMINATION- 2019 - Subject : CHEMISTRY (34) Time : 3.15 hrs. Max.Marks : 70 Instructions: The quostion paper hy White balanced cho Use og tao and spe eae : rss nt alowed) PART-A Answer all the questions in one word or in one sentence each. How many significant figures are there in 0.0864? State Boyle's law. Write the conjugate acid of HSO,. What are isotopes? four pa 10x1=10 Write the IUPAC name of the elements with atomic number 107. Whatis the oxidation number of oxygen in O,F,? Name the alkali Metal which is radioactive. Give a chemical reaction for which AH = AU Draw the staggered conformation of Ethane. Suggest a Suitable Method to separate sugar and salt from an aqueous solution containing them. Bop ageeean ° PART -B. Il Answer any FIVE of the following questions. Each question carries Two marks. 11, Write any two postulates of Dalton’s atomic theory. 12, Calculate the value of universal gas constant (R) in Sl units. 13. Write the electronic configuration of H, molecule. Whats its bond order. 14. Complete the following equations. a) ALi +O, —— b) 2NaNo, 4 _y + 15. Whatis extensive property ? Give an example. 16. State Markovnikov rule. 17. Howis n-Butane obtained from bromo ethane. 18. Explain Functional somerism with an example. PART -C Il Answer any Five of the following questions. Each question carries three marks, 5x3=15. 19. a) Define atomic radius. How does it vary along a period? b) What are Isoelectronic ions? 241 20. Explain SP? Hybridisation by taking BCI, as an example. 21. Give any three postulates of VSEPR theory. 22. What is hydrogen bond? Mention the type of hydrogen bond in i) Water and ii) Orthonitrophenol. 23. Balance the following equation using oxidation number method C10,! uy + S0% gD CP "yg, # SOF * H,O (Acidic medium ) 40 oa * rio 24, Write the equations during the preparation of sodium carbonate by solvay process. 25. a) Write the resonance structure of O, Molecule. b) Define dipole moment. 5x2=1026. WV. 27. 28. 29. 31. 32. 33. 34. Ber 36. 37. a) Whats disproportion reaction ? Give an example. b) Define oxidation interms of oxidation number. a) a) b) a) b) a) b) a) b) a) Answer any FIVE questions. Each question carries five marks PART-D 5x5=25, Acompound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is 98.96 g. What are its empirical and Molecular formulas? (4+1) (Given atomic mass H=1.008 C = 12.01 and Cl = 35.45) Whatis limiting reagent ? Explain the formation of line spectrum of Hydrogen based on Bohr's atomic theory. State Heisenberg's uncertainty principle. Give its mathematical equation, (3+2) Name the quantum number that specifies (2+3) i) Size of an orbital ii) Shape of an orbital Calculate energy of one mole of photons of radiation whose frequency is 5x10" HZ. Write the expression for the compressibility factor(z) for one mole of a gas. What is the value of Z for an ideal gas? (2+3) Define the terms i) Vapour pressure of a liquid ili) Boyle temperature for a gas. Define Lattice enthalpy. Write Born-Haber's cycle for the Lattice enthalpy of formation of NaCl : Define Entropy. What happens to entropy when ice melts to liquid water ? Calculate the enthalpy of formation of liquid benzene given the enthalpies of formation of combustion of carbon,,, Hydrogen, and Benzene, , are -393.5KJ, -285.8 KJ and -3267 KJ respectively. (441) Write the Matheatical form of first law of thermodynamics. Using Le-chatelier’s principle, explain the effect of temperature on the equilibrium. 2NO, =—— » N,Ojy AH = -$7.2K) : Whatis common ion effect ? Give an example. Whatis a homogeneous equilibrium ? (2+2+1) The concentration of hydrogen ion in a sample of soft drinks is 3.8 x 103 M. What is its pH? (3+2) Define acid and Base according to Lewis theory. Answer any TWO of the following questions. Each question carries five marks . 2x5=10 For the compound H,C = CH - CH = CH, (342) i) Write the bond line formula of the compound ii) Give the IUPAC name of the compound iii) Identify the number of Sigma and pi bonds Give any two deference beween inductive effect & electromeric effect, With a neat labelled diagram describe the estimation of carbon and Hydrogen in an organic compound. (342) Catagorise the following Molecules or ions as Nucleophiles or Electrophiles BF,, NH,, cr, OH. Explain the free radical Mechanism of chlorination of Methane. How do you convert phenol to Benzene ? (3+2) ii) Critical temperature for a gas. (3+2)