SIGMA-ALDRICH igma-alarioh.com SAFETY DATA SHEET Revision Dato 25 12014 Bintbate 11122014 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANYIUNDERTAKING 14 Productidentifers Product name “Fehling’s reagent | for sugar: Product Number score Brena Ane 4. Other means of dertincation Copper(Il) sulfatesolution Corte Sa sence Capi eft slan ae. to Fling Fo FD ine ony Not of phereceutce,hoseto! or oe woe 44 Detals of the supplier ofthe safety datasheet company Sigman Pte Lid heres Pane Ro toxin Coma Srcapae oom Pk Ril SINGAPORE 1828 SINGAPORE Telephone 2656779 1200 te Tee erve tae 18 sieibec ttephte rier Emergency Phone: 1-800-2628200 AAZARDS WENTFICATION 24 GHS Classtcation aes acate iy (Catagory 1) ee ey 22 GH Lebel somanae, infusing procautonary cata, eooen Sionl word wang Hazard tatements) nate Vary to agli wth oe lating sts Precautionary statement(s) Prevention ons Avoid release tthe environment Response be Col plage. Dispos Pabe Ofsposoof conten orsier oan approved wate clapoeal pant. 23. Ofer hazards -none a oe Paget of 762 Environmental precautions Prevent further leakage or spillage If safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 63 Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste, Keep in sultable, closed containers for clepoeal 64 Reference to other sections For disposal see section 13. 7 HANDLING AND STORAGE 7.4 Precautions for safe handling No data available 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed ina cry and wel-ventlated place, Containers which are opened must be caretuly reseaied and kept upright o prevent leakage, 7.3 Specific end use(s) No data available &__ EXPOSURE CONTROLS/PERSONAL PROTECTION 8.4 Control parameters ‘Occupational Exposure Limits 82 Exposure controls Appropriate engineering controls ‘Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday Personal protective equipment Eyelface protection Safety glasses with side-shields conforming to EN186 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique {without touching giove's outer surface) o avoid skin contact with ths product. Dispose of Contaminated gloves after use in accordance with applicable laws end good laboratory practices. Wash ard dry hands, ‘The selected protective gloves have to satisfy the specifications of EU Directive B9I6EGIEEC and the standard EN 374 derived from it Ful contact Material: Nite eubber Minimum layer thickness: 0.171 mm Break through time: 460 min Material tosted:Dermatri® (KCL 740 Aldich 2677272, Size M) Splash contact Metoral: Nittie rubber Minimum layer thickness; 0.11 mm Break through time: 480 min Material tesied:Dermatri@ (KCL 740 | Aldich 2677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0}6659 87300, e-mail sales@kcl de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluates by an industrial hygienist and safety officer familar with the specticsituaton of anticipated F-25018 Page 9 of 7104. Conditions to avoid No data available 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - No data available 71, TOXICOLOGICAL INFORMATION 41.4 “Information on toxicological effects Acute toxicity No data available Skin corrosioniirri No data available Serious eye damageleye irritation No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity ion IARC: No component ofthis product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, Reproductive toxicity No data available ‘Specific target organ toxicity - single exposure No data available ‘Specific target organ toxicity - repeated exposure No data availabie Aspiration hazard No data available Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract initation Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation Eyes May cause eye intation. ‘Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated, Additional Information RTECS: Not available 7% ECOLOGICAL INFORMATION 121 Toxicity No data available 122. Persistence and degradability No data available 123 Bioaccumulative potential No data available Fluka 36018, Page 5 of 7yo init Eye initation His02 Harmful if swallowed, H318 Causes skin imitation. H319 Causes serious eye irritation. Ha10 ‘Very toxic to aquatic life with long lasting effects. Skin It, Skin iritation Further information Copyright 2014 Sigma-Aldrich Co. LLC, License granted to make unlimited paper copies for internal use only. ‘The above information is believed to be correct but does not purport to be all inclusive and shall be used ‘only 28 @ guide. The information in this document is based on the present state of our knowiedge and is applicable to the product with regard to appropriate safety precautions. it does not represent any ‘Quarantee of the properties of the product. Sigma-Aldrich Corporation and its Affliates shall not be held lable for any damage resuiting from handling or from contact with the above product. See www.sigma- aldrich.com and/or the reverse side of invoice or packing slip for additional terms and concltions of sale Fluka 26018 Page 7 of 7