1.

IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier
Product name COPPER POWDER
Synonyms COPPER GOLD ● COPPER POWDER

1.2 Uses and uses advised against

Uses CHEMICAL INDUSTRY ● METALLURGY APPLICATIONS ● PRINTING AND COATING INDUSTRY ●
SURFACE COATING

1.3 Details of the supplier of the product

Supplier name AUSTRALIAN METAL POWDERS SUPPLIES PTY LTD
Address 32 Carrington Road, Guildford, NSW, 2161, AUSTRALIA
Telephone (02) 9681 6155
Email sales@metalpowders.com.au
Website http://www.metalpowders.com.au

1.4 Emergency telephone numbers

Emergency 13 11 26 (Poisons Information Centre)

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Not classified as a Physical Hazard

Health Hazards
Not classified as a Health Hazard

Environmental Hazards
Aquatic Toxicity (Acute): Category 1

2.2 GHS Label elements

Signal word WARNING
Pictograms

Hazard statements
H400 Very toxic to aquatic life.
Prevention statements
P273 Avoid release to the environment.
Response statements
P391 Collect spillage.
Storage statements
None allocated.

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Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards

No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

3.1 Substances / Mixtures
Ingredient CAS Number EC Number Content
COPPER 7440-50-8 231-159-6 >99%

4. FIRST AID MEASURES

4.1 Description of first aid measures
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If
swallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Immediate medical attention and special treatment needed

Treat symptomatically.

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
Use an extinguishing agent suitable for the surrounding fire.

5.2 Special hazards arising from the substance or mixture

Non flammable. May evolve toxic gases (copper oxides) when heated to decomposition.

5.3 Advice for firefighters

Evacuate area and contact emergency services. May cause fire or explosion in contact with incompatible materials (see Reactivity).
Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus
(SCBA) when combating fire. Bund and contain all residues to avoid environmental contamination.

5.4 Hazchem code

2Z
2 Fine Water Spray.
Z Wear full fire kit and breathing apparatus. Contain spill and run-off.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.

6.2 Environmental precautions

Prevent product from entering drains and waterways.

6.3 Methods of cleaning up

Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

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7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities

Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately
labelled, protected from physical damage and sealed when not in use.

7.3 Specific end uses

No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters
Exposure standards
TWA STEL
Ingredient Reference
ppm mg/m³ ppm mg/m³
Copper (fume) SWA [AUS] -- 0.2 -- --
Copper (fume, dusts & mists) SWA [Proposed] -- 0.01 -- --
Copper, dusts & mists (as Cu) SWA [AUS] -- 1 -- --

Biological limits
No biological limit values have been entered for this product.

8.2 Exposure controls

Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction
ventilation is recommended. Maintain dust levels below the recommended exposure standard.

PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance RED POWDERED SOLID
Odour SLIGHT ODOUR
Flammability NON FLAMMABLE
Flash point NOT RELEVANT
Boiling point 2567°C (Approximately)
Melting point 1000°C (Approximately)
Evaporation rate NOT AVAILABLE
pH NOT AVAILABLE
Vapour density NOT AVAILABLE
Specific gravity 2.8 to 3.8
Solubility (water) INSOLUBLE
Vapour pressure NOT AVAILABLE
Upper explosion limit NOT RELEVANT
Lower explosion limit NOT RELEVANT
Partition coefficient NOT AVAILABLE
Autoignition temperature NOT AVAILABLE

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9.1 Information on basic physical and chemical properties

Decomposition temperature NOT AVAILABLE
Viscosity NOT AVAILABLE
Explosive properties NOT AVAILABLE
Oxidising properties NOT AVAILABLE
Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY

10.1 Reactivity
Carefully review all information provided in sections 10.2 to 10.6.

10.2 Chemical stability

Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions

Polymerization will not occur.

10.4 Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid). Reacts violently with chlorine, fluorine, ethylene
oxide, acetylene and hydrogen sulphide.

10.6 Hazardous decomposition products

May evolve toxic gases (copper oxides) when heated to decomposition.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50

Ingredient

COPPER -- > 2000 mg/kg (rat) --

Skin Contact may result in mechanical irritation, redness, rash and dermatitis.
Eye Contact may result in mechanical irritation, lacrimation and redness.
Sensitisation Not classified as causing skin or respiratory sensitisation. Allergic contact dermatitis has been reported,
although rare.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT - single Over exposure to dust may result in mechanical irritation of the nose and throat, with coughing. Over
exposure exposure to fumes (if heated) may result in irritation of the nose and throat with ulceration of the nasal
septum, and could also cause metal fume fever.
STOT - repeated Repeated exposure to copper may result in liver, kidney and blood damage.
exposure
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION

12.1 Toxicity
Very toxic to aquatic life.

12.2 Persistence and degradability

Copper is a natural element and is therefore, by definition, not degradable. As an essential nutrient, copper is homeostatically
regulated by aquatic organisms and does not pose a concern for bioaccumulation or secondary poisoning in aquatic food chains.

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12.3 Bioaccumulative potential

Not expected to bioconcentrate or bioaccumulate. Chemical processing or extended exposure to the environment can result in the
release of copper in a bio-available form.

12.4 Mobility in soil

Copper in the massive form is essentially immobile in the environment.

12.5 Other adverse effects

Soluble copper compounds are highly toxic to aquatic and plant life. Insoluble copper compounds are significantly less
environmentally hazardous. Positive potential for food chain accumulation.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Waste disposal For small amounts, cover with moist sand, vermiculite or similar to avoid dust hazard and dispose of to an
approved landfill site. Contact the manufacturer/supplier for additional information if disposing of large
quantities (if required).
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 3077 3077 3077

14.2 Proper ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY
Shipping Name HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (Copper metal SOLID, N.O.S. (Copper metal SOLID, N.O.S. (Copper metal
powder) powder) powder)

14.3 Transport 9 9 9
hazard class
14.4 Packing Group III III III
14.5 Environmental hazards
Marine Pollutant
14.6 Special precautions for user
Hazchem code 2Z
GTEPG 9C1
EmS F-A, S-F
Other information Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not
subject to this Code when transported by road or rail in;
(a) packagings that do not incorporate a receptacle exceeding 500 kg(L); or
(b) IBCs.
Special Provision AU01 - ADG Code 7th Ed.
Label: Miscellaneous The environmentally hazardous substance mark is not required when
transported in packages of less than 5 kg/L (UN Model Regulations: Special Provision 375; IATA:
Special Provision A197; IMDG: Special Provision 969) or less than 500 kg/L by Australian Road and
Rail.

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the
Uniform Scheduling of Medicines and Poisons (SUSMP).

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Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals.
Inventory listings AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.

16. OTHER INFORMATION

Additional information
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on
the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where
a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the
following circumstances, exposure standards must be reduced: Strenuous work conditions; hot,
humid climates; high altitude conditions; extended shifts (which increase the exposure period and
shorten the period of recuperation).

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:

The recommendation for protective equipment contained within this report is provided as a guide
only. Factors such as form of product, method of application, working environment, quantity used,
product concentration and the availability of engineering controls should be considered before final
selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors
including: form of product; frequency and duration of use; quantity used; effectiveness of control
measures; protective equipment used and method of application. Given that it is impractical to
prepare a report which would encompass all possible scenarios, it is anticipated that users will
assess the risks and apply control methods where appropriate.

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists

CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
CNS Central Nervous System
EC No. EC No - European Community Number
EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)
GHS Globally Harmonized System
GTEPG Group Text Emergency Procedure Guide
IARC International Agency for Research on Cancer
LC50 Lethal Concentration, 50% / Median Lethal Concentration
LD50 Lethal Dose, 50% / Median Lethal Dose
mg/m³ Milligrams per Cubic Metre
OEL Occupational Exposure Limit
pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).
ppm Parts Per Million
STEL Short-Term Exposure Limit
STOT-RE Specific target organ toxicity (repeated exposure)
STOT-SE Specific target organ toxicity (single exposure)
SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
SWA Safe Work Australia
TLV Threshold Limit Value
TWA Time Weighted Average

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Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the
manufacturer, importer or supplier or obtained from third party sources and is believed to represent
the current state of knowledge as to the appropriate safety and handling precautions for the product
at the time of issue. Further clarification regarding any aspect of the product should be obtained
directly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
no liability for any loss, injury or damage (including consequential loss) which may be suffered or
incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies

5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: info@rmt.com.au
Web: www.rmtglobal.com

[ End of SDS ]

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