FIITIEE CBSE Class XI Chemistry Sample Paper - 1 Solution Section A This is because 0 ~ nitro phenol has intramolecular hydrogen bonding whereas p- nitro phenol has intermolecular hydrogen bonding. oR (0.NCH,CH,0'will he more stable because -NO, group has electron withdrawing inductive effect or - effect Oz has. larger bond angle than BF,. This is because CO, hasa linear shape and the 180°, BF, on the other hand has. trigonal planar geometry and hence the oR Bond order of N2is greater than that of O2. Higher is the bond order greater is the stability. Therefore N2 is more stable than 02. . The eclipsed conformation of propane is less stable and has more energy than the eclipsed conformation of ethane. This is because in propane there are additional interactions between C-H and G-C bond of methyl group. In Antarctica, ozone depletion is due to the formation of chlorine nitrate. -_ Alkali metals have low ionization energies. They can lose electrons when light falls on them, and hence are used in photo electric cells. Statement ‘a’ is correct and bi Statement ‘b’ is incorrect because d sub shell can have a maximum of 10 electrons. Therefore it has 10 columns and not 8. . Elements in which transition of electrons to higher energy d-orbital cannot take place are not transition elements. Thus, elements like Zn, Cd and Hg in which all the d-orbitals, are completely filled are not transition elements although they have been grouped with d-block. TFITTSEE Ud, FITC raat esa, Vara Runa Gant Ry Lason = 22600 Pr OR HOT, TICS mn aon ITIEE Li, tor 0 Coma Gt, 4-0, LDA Oy, Karr Rd AA Lice Z012. POE 4 TE FIITJEE Ltd, Four Season House, 41/9, Setor-C, Alga, Linon = 220024, Pr: OS2248764648. Given: 4=456nm =456x10° m c=3»10'm/s Wehave, ver x __ 3x10" © 456x 10 y=6.5« 10's v=6.5x 10" Hz Frequency is 6.5*10!4 Hz 9. Oxidation number of Pb in PbO is +2 while in PbO: it is +4. This causes the compounds to differ in their reactivity. While PbO reacts with HCl to give acid-base reaction, and PbO2 reacts with HCl to give redox reaction. 2PO +4HCI— 2PbCh+2H20 (acid-base reaction) Pb02 + 4HCI— PhCl2+ Cl + 2H20 (redox reaction) 10. 2i,0+ 2, —> 4uF+0, Fris the oxidizing agent and H20 is reducing agent. H20 is getting oxidized to O2 whereas Fz is getting reduced to F- ion. OR (a) PbSig) + H202%00) + PHSO4) + 4H200) (b) CO(g +2 Haig) 22> CHsOH 1L.The energy required to excite outer electrons in the atoms of Be and Mg does not lie in the visible range of radiation, Therefore, no absorption of radiation takes place and hence no colour is imparted to the flame in the flame test. TFITJEE Ud Tie Kaa Cra a0 Pr 2 IGA OTTOS waa FIITSBE Lid, iu 1. Comer Se, Set -@ LOA anes FIITJEE Lic, Four Season Hou, £1)Mass 9 of anelement = M28S0felementin thatcompound sy, Molar massof the compound Molarmassof Na,SO, = 2(23)+32+4(16) 42g / mol 46 Mass % of Na=—>-« 100 ss 142 =32.39% Mass % of S= 32, Mass % of O= 142 =45.07% Given: Weight of CuSO. =100 g Atomic mass of Cu ~ 63.5 amu 1 mole of CuSO contains 1 mole of Cu Molar mass of CuSO4= 63.5 + 32+ (4*16) = 159.5 g/mol So, Cu that can be obtained from 159.5 g of CuSO« = 63.5 g ‘Therefore, Cu that can be obtained from 100 g of CuSO4 “1595” =39.81g FITJEE LS a Se Ro Ler RTO Pr CEST SBT FIITJEE Lis, Ont, arr oa, Ack rd Ph13, (a) The 4f sub shell of an atom contains 12 electrons af Ni Th) tl | th | th) t So maximum 7 electrons will have same spin. (b) Six electrons are filled in three orbitals of 4p subshell. aps TL (ce) Z=29 Electronic configuration 1s*2s'2p"3s?3p*3a"° 4s OR (a) Number of electrons in 1 molecule of methane = 6 + 4 =10 electrons Number of molecules in 1 mole of methane = 6.022 x 103 molecules of methane Number of electrons in 1 mole of methane = 6.022% 1010 = 6.02210" electrons (b)n=3 1=0 to(n-1) FIITSEE Us, om or @, LOA Cy, Rr Rt Aan. Lion FINTSEE Lis, Four Season Hove, £19, Sactor-C, Alga Lcknow 226206. Ph: 05224976464,14.The electronic configuration of $=1s'2s*2p'3s'3p* Is 2s 2p 3p MW) PT! brent | te N Ground state ds 2s 2p 3p Excited State fry] [tu] [te] tu] th] ty — hybridisation {by 2p sp'd spd sp'd sp'd sp'd Hybridise State | t) nN NINN) [TM] ty ty tit Sulphur undergoes spd hybridisation. oR (a) In C02 there are two C=0 bond. Each C=0 bond is polar bond. The net dipole moment of C02 molecule is zero, This is possible only if CO2is a linear molecule (0=C=0), The bond dipoles of two C=0 bond cancel with each other. Whereas H20 molecule has a net dipole moment (1.84 D) H20 molecule has a bent structure because here the -H bonds are oriented at an angle of 104.5° and do not cancel the bond moments of each other. (b) Significance/applications of dipole moment- i) In predicting the nature of the molecules: Molecules with specific dipole moments are polarin nature and those of zero dipole moments are non-polar in nature. ii) In the determination of shapes of molecules. iil) In calculating the percentage ionic character. TFITSEE Ud, FTI Fast rat, Vara Ra ant Rr Lanon = 2600 Pr OR HTT, TTC mn on IVTSBE Li, rr110. Comer Gtk, ec =0, LEA Cony, Kary AAO Lich = E012. POO 4G. TAG FIITJEE Ltd, Four Season House, 41/9, Setor-C, Alga, Linon = 220024, Pr: OS2248764642AL+2NaOH+2H,0 —»2NaAl0, +3H, 2x27 3x22.4L Sig SAgofAlgivel, =3x22.4 L 0.15gof AlgivesH, (20°C+273)K=293K 196.7 «293 274 00.3m1 Volume of dihydrogen is 200.3 ml 16. (a) A process is said to be spontancous if it takes place by itself by own or under some condition. ) i) After freezing, the molecules attain an ordered state and therefore, entropy decreases. ii) AtOK the constituent particles are in static form therefore entropy is minimum. Ifthe temperature is raised to 115 K particles begin to move and entropy increases, Reactant NaHC0s is solid. Tus entropy is less in comparison to product which has high entropy. TINT SEE Lid, TIE Kaa cara Go Nap Laie PERO CERT S87 IITSBE Li, ta 1. Gomer Se, et @ LOA stay, ars ad Ashi Lion 28012 Ph FIITSEE Lic, Four Season Hous, £19, Sator-C, gan Lucknow 726006. Ph: 052-497566,ue [i] (b) Acconding to Henderson's equation, fsalt] ibase] Also, pK, =(logk,) logl.85x10*) 24.733 POH=pk, +log 02 OH= 4.733+logo= Pi B57 =4.733-+0.3010 034 pH=14-poH =14-5034 =8.966 OR (a) The equilibrium will shift the backward direction as the increase in temperature will be compensated by absorbing heat It is an exothermic reaction. (b) The equilibrium will shift in the forward direction since the reaction will shift to the direction of lesser number of moles. (©) The equilibrium will shift in the forward direction so that additional S02 is used up. ° P+ HNO, —> H,P0, +No, + H,0 ‘Caan Gy P+SHNO, —>H,PO, +5NO,+H,0 o=15 o=15 H=5 Hes Oxygen and Hydrogen atoms are balanced. oR FFITSEE Ud, TIE aa Ga, ve x sation FIITSEE Us, ‘amt See, Sat-@ LOA Cay sn Lion 20012 Pc 1644, 4645, FIITSEE Lis, Four Season Move, £1 ow 26006. Ph: 0822497840,(a) tng > tn + 267 Pb". +2” > Ph,,, (b) 2 jay Phang + 2° a) + 27> 2Fe* (OQ) 2Nag) > 2Nagy) + 2° Cl) # 2e" > 2cr 19, Those hydrides which do not have fix composition are called non-stoichiometric hydride, and the composition varies with temperature and pressure. This type of hydrides are formed by d and f block elements. They cannot be formed by alkali metals because alkali metal hydrides form tonic hydrides. 20. (a) 3 - Methylpentanonitrile (>) 3-Chloropropanal (9) 4-Nitroaniline 21, (a) Order of stability (b) (cls), C> (CH), CH> CH CMs >CHe This is because -cH, group has electron releasing inductive effector +1 effect. Due to this, electron density increases on the negatively charged carbon and hence makes it more unstable. As the number of methyl groups increases the instability increases. (c) The negatively charged carbon atom in a carbanion issp" hybridized. 22. (2) Because the discharge potential of alkali metals is much higher than that of hydrogen, therefore when aqueous solution of any alkali metal chloride is subjected to electrolysis Hz instead of alkali metal is produced at cathode. Therefore alkali metals are prepared by electrolysis of their fused chlorides. (b) Due to smallest size of Li? can polarise water molecules easily than the other alkali metal ions. FIITJEE LS Rag Li ER. FOE RTA sation FIITJEE is, Set LOM Cay, ar od Aen Lion - 20012 Ph: OF 1644, 4645, FINTSEE Lis, Four Season Hove, £19, Sator-C, Aga Lcknow 226206. Ph: 0822497646,23. Given: Mole fraction of CaHsOH = 0.040 We know, 7 NumberofmolesofC2HsOH CH,08 ~ Numberofmoles + Numberofmoles ofCgHsOH of #20 LetthemolesofC,HgOH = x Density of wateris 1 Weightof1000 ml ofwater=volumexdensity = 1000 1 ml Molar massof water=18x / mol 1000 18 =55.55 mol No.of molesof wat x Xcuon = 5 S555 x+ 55.55 0.04x42.22 X=2.31mol No.of molesofethanol Molari io Volumeof solution! Molarity= 231M Molarity of solution is 2.31 M 24. (a) ABP: + SLIAIHs > BoHs + 3LiP + 3AIF3 (b) Bells + 6H20 2H5B05 + 6H (c) 8 BH + 302 24 B20 + 320 FIITJEE LS FIITJEE Us, is FINTSEE Lis, Four Season Hove, £19, Sator-C, Aga Lcknow 226206. Ph: 0822497646,Section D 25. NH,Cl(s) ——+NH, (g) + HCI(g) AH= 177 mol" ‘AS=285) K*mol =0.285 kj K*mol™ T= 25°C = 208K AG=AH-TAS =177-(298 x 0.285) = +92.07K) mol” The reaction will be non-spontaneous. This is because the value of AG is positive. OR 6C(s) + 3H, (g)——>G,ti,(1) HF Oy) —> 60, +3H,0,, AcH”=-3266.0k} eqn (1) ApH? = -393.1 kj eqn(2) AWM = -286.0 eqn (3) Multiplying equation (2) by Gand (3) by 3, and adding, 6¢(s)60,(g)311,(8)>3 0,(g)—> 6C0,(g)+3,0(1) an Subtracting eqn (4) - eqn (1) 6€(s)+3H,(g) —6,H, (I) 4\H? = 32166 + 32660 = + 49.4% mot" 26. (@) Boron has a very small size and has a very high sum of three ionisation enthalpies, (1E:+ IE2+IE:). Therefore, it cannot lose its three electrons to form B** ions. (b) AlBrs is predominantly a covalent compound. Even in molten state it does not have ions which can conduct electricity. (c) B exhibits +3 oxidation state and can form stable BC. Thallium shows +3 oxidation state as well as +1 oxidation state but +1 oxidation state is more predominant than +3 oxidation state hecause of inert pair effect. Therefore, TiCh is not stable. It can form stable TiC. FIITJEE Lid, Four sason House 41/9, Sect0r-C, Alga Lihnow = 220026, Pr: 082(4) BCLs molecule has a symmetrical trigonal planar structure in which three B-Cl bonds are oriented at an angle of 120° to one another. The three bonds lie in one plane and the dipole moments of these bonds cancel one another giving net dipole moment zero, (€) Electrical conductivity of aluminium is twice as that of copper. On mass to mass basis, Al conducts electricity twice as Cu. Therefore, itis used in transmission cables. oR @ 2cHijcl +Si 222 (cH, Sic Dictloradimetny! siicon (b) m0 + co—2 47m + CO, (©) 4BF, + LialH, —“stivlether_ 96H, + SLiF #3 AIF, (4) 2 BP, +6 Nal —™°*_ B,H), +6 Nak 13) BH, +6110 ——» 2H,B0,+ 6H, Boricaeid (2) Compound Ais 11,c-C=C- CH, He-C=C- GH, +, ME 5 a H,C-C =C-C,H,+H, —“#4™_, trans - isomer oO (b) Kolbe's electrolytic method ~ 2CH1jC00" Na? + 2110 —BHSS 5 CH,CHl, +200, + My +2NGOH FIITJEE LS sation FIITJEE Us, is ce 484 11480 FINTSEE Lis, Four Season Hove, £19, Sator-C, Aga Lcknow 226206. Ph: 0822497646,Mechanism: Atanode: ° 2cn,-€-0' 225 2cH,-C.04 22H, +2c0, Hy C + GH > HC-CH3 At cathode: Hote OHH zit Ht At cathode hydrogen is liberated. At anode ethane is formed. oR CH,CH= CH, +HBr —> CH, CHCH, Br a + (0, (i) 2n/11,0 CH, CHO + HCHO o ahya Ac, Se Colla + CH,c1 EAC, C a A “Dr CaCz +2 H20 -> Ca(OH)2 + CoH2 ‘ee FIITJEE LS c Gt Nap Loy — 2070 Po FIITSEE Us, Sst, Cty Ran - FINTSEE Lis, Four Season Hove, £19, Sator-C, Aga Lcknow 226206. 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