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〖CO〗 - 2 Capturing and Storage From Oil Wells
〖CO〗 - 2 Capturing and Storage From Oil Wells
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Abstract
The world is currently facing one of the most critical challenges in the Earth’s history which is global
warming. The major cause of global warming and climate change problems is the carbon dioxide
emissions. This novel study addresses the concepts and design precautions for a proposed in-situ
electricity generation project.
The main goal of the study is to reduce the environmental pollution due to the combustion of fossil fuels
and emitting carbon dioxide. This reduction will be attained through a smart gas well design and
completions. The design is based on in-situ combustion for a gas flow in a downhole combustion chamber.
Oxy-fuel combustion technique is the proposed combustion technique due to the ease of 𝐶𝑂2 separation
in this process. The proper well design will be analogous to the wells used for in-situ oil combustion to
handle the high released temperature. Power generation design will combine the fundamentals of
geothermal energy deployment for electricity generation. Finally, the produced 𝐶𝑂2 from the combustion
process will be reinjected downhole into an underground geological structure after being compressed and
transferred to the supercritical phase. This process eliminates the 𝐶𝑂2 production to the surface and hence
reduce the environmental pollution.
Introduction
The world is currently facing one of the most critical challenges in the Earth’s history which is global
warming. The major cause of global warming and climate change problems is the carbon dioxide
emissions (Pielke et al., 2005; Weart, 2008). Throughout history, the Earth’s temperature has been
continuously changing. However, the increase after the industrial revolution in the 1800s are going in
much faster rate. This is due to the greenhouse effect that the 𝐶𝑂2 and the other industry gases
emissions are causing (Martinez, 2005). The average 𝐶𝑂2 concentration before the industrial revolution
was about 270 ppm (Keeling et al., 1976). Meanwhile, it reached 392 ppm by the end of 2011 (Tans and
Keeling, 2012). This results in increasing the average Earth’s temperature, extreme weather events,
harming wildlife regimes, glacier melting, forest fires and ocean levels increase. Figure (1) shows the
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history of the average increase in the globe temperature since the industrial revolution till 2019. With the
continuous emissions, this average is expected to reach 3-4 ℃ by the year 2100 (Boden and Blasing,
2011).
Figure 1 The change in the average global temperature due to global warming. Source: IPCC, 2018
𝐶𝑂2 emissions are continuing to increase a year after year due to the increasing energy demand and the
vast industrial expansion. The chart in Figure (2) shows that in 2019, we reached about 36.44 billion
metric tons of 𝐶𝑂2 emissions from the fossil fuels combustions and industry activities including
electricity and power generation. Although this amount was reduced in 2020 due to the COVID-19
pandemic, it is expected that the amount will be much higher after the world retains the normal regimes
before the pandemic (IEA, 2021). According to the International Energy Agency (IEA), the power and
industrial sectors account for 60% of the 𝐶𝑂2 emissions. Among these power and industrial activities,
natural gas represents the driving force for about 39 % of the electricity generation plants in the US in
2020. According to IEA statistics in 2011, natural gas combustion accounted for about 20% of the global
𝐶𝑂2 emissions. By this stated, reducing the 𝐶𝑂2 emissions from natural gas burning can play a vital role
in alleviating the global warming effects.
One of the studies made by Eickhout et al. (2003), showed that there is an urgent need to reduce the
𝐶𝑂2 emissions by 80% in order to control the earth’s temperature by the year 2100. One of the factors
that lead to reduce 𝐶𝑂2 emissions is the change of energy consumption for individual dispersed sectors
such as transportations and home electricity. This is attained by replacing the 𝐶𝑂2 producing fossil
energy sources by clean sources of energy such as hydrogen and renewables. For large energy sectors
such as large power plants, iron, steel and cement factories, and oil refineries, 𝐶𝑂2 capture and storage
seems to be a more viable solution.
3
Figure 2 Annual global CO2 emissions from 2000 to 2019, billion metric tons
- The pre-combustion approach: in this process, oxygen, air and/or steam are injected to the fuel gas
to make syngas. The composition of these syngas is mainly hydrogen and carbon monoxide. Then
a reaction between carbon monoxide and steam takes place in some catalytic reactor to produce
𝐶𝑂2 and more hydrogen. Finally, the produced 𝐶𝑂2 is separated by any chemical or physical
means and the remaining hydrogen is used as a clean source of energy (Adams et al., 2017; Scholes
et al., 2010; Suresh Kumar et al., 2013).
- Capture from industrial streams: this kind of 𝐶𝑂2 is not related to fuel combustion. However, it is
more related to industrial processes that produce 𝐶𝑂2 as a byproduct. Industries such as ammonia,
alcohols, synthetic liquid fluids and natural gas purification used one or more of 𝐶𝑂2 separation
technique (Zhang et al., 2019).
Figure (3) shows a schematic of the previously mentioned 𝐶𝑂2 capturing approaches. In this study,
we will focus more on the deployment of oxy-fuel combustion for which the oxygen will be
separated on the surface before being injected into the combustion chamber.
Figure 3 𝐶𝑂2 Different capturing mechanisms, adapted from BP, (Zhang et al., 2019)
There are various methods by which 𝐶𝑂2 can be separated from the main fluid streams. Chemical
sorbents and solvents have the ability to absorb 𝐶𝑂2 by contacting a fluid stream saturated with 𝐶𝑂2 .
These absorbents can be regenerated again after releasing the 𝐶𝑂2 by heating, depressurizing or any
other thermodynamic process (Khraisheh et al., 2020). Physical separation by membranes can be also
deployed to capture 𝐶𝑂2 .Membranes are special materials that allow specific gases to flow through
them. The selectivity of the membranes to the𝐶𝑂2 gas is highly depending on the type of the membrane
material as well as the pressure difference across the membrane sides (Scholes et al., 2013). Schematic
representations of the 𝐶𝑂2 separation by chemical sorbents and physical membranes are shown in
figures (4a & 4b).
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2040 USD/kW. While adding a post-combustion carbon capture system to the same plant increases the
cost range to be 2788-4236 USD/kW with a common value of 3333 USD/kW. So, therefore, the post-
combustion carbon capture system increases the capital cost by 63% for the power plants that uses
bituminous coals. The study reported the cost of 𝐶𝑂2 capturing to be within the range of 33-58 USD/t
𝐶𝑂2with an average value of 48 USD/t CO2. However, this saves the cost of 𝐶𝑂2 avoided by 44-86 USD/t
𝐶𝑂2 with an average value of 67 USD/t 𝐶𝑂2 . Although there is an increase in the capital cost for
constructing a carbon capture post-combustion system, the cost of 𝐶𝑂2 avoided will compensate for it.
Adding to it the positive environmental impact, the process of capturing 𝐶𝑂2 will always prove to be
feasible and rewarding. The study continued to include the pre-combustion carbon capture technique for
natural gas combined cycle (NGCC) power plants, see table (1).
Table 1 A summary of the cost of post-combustion carbon capture for coal-fired and natural gas-fired plants
Range Average
Power plants fired by bituminous
Total capital
requirements cost
1862 - 2441 2040
w/o carbon capture
(CC) (USD/kW)
Total capital
requirements cost 2788-4236 3333
coals
with CC (USD/kW)
Cost of 𝐶𝑂2
capturing (USD/t 33-58 48
𝐶𝑂2)
Cost of 𝐶𝑂2 avoided
44-86 67
(USD/t 𝐶𝑂2)
Total capital
Power plants fired by NGCC
The pre-combustion carbon capture technique is usually deployed to coal-based integrated gasification
combined cycles (IGCC). The CO2 separation technique used is usually the solvent scrubbing technique
that uses physical solvents and membranes unlike the chemical solvents used for the post-combustion
carbon capture technique (Rao, 2010). The capital cost for this technique is 37% higher than the
supercritical pulverized coal (SCPC) plants that usually deploy post-combustion separation. Table (2)
shows the summary of the costs associated with the pre-combustion capture at IGCC power plants as
compared to the SCPC plants that use bituminous coals (Rubin et al., 2015).
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Table 2 A summary of the cost of pre-combustion carbon capture for natural gas-fired plants
Oxy-fuel carbon capture technology is one of the recent technologies that are currently used for capturing
𝐶𝑂2 from power plants. This technique has been through a tremendous development over the last decade.
It is currently used for capturing the carbon from supercritical and ultra-supercritical power generation
units that use low-rank coals. The technology of oxy-fuel is quite complex as it includes various flue gas
recycle streams, heat supply, and pollutant removing units. Since the oxygen is separated from the air by
cryogenic separation before being burnt, the produced 𝐶𝑂2 quality reaches more than 99% (Leung et al.,
2014). There is an increase of the capital cost for power plants by 91% to accommodate for oxy-fuel
capturing technique as shown in table (3). This is higher than both the post and pre-combustion techniques
(Rubin et al., 2015).
Table 3 A summary of the cost of oxy-combustion capture at new SCPC/USC plants using sub-bituminous coals
Range Average
Total capital
requirements cost 2455-2681 2589
w/o CC (USD/kW)
Total capital
requirements cost 4278-5372 4939
with CC (USD/kW)
Cost of 𝑪𝑶𝟐
capturing (USD/t 36-67 52
𝑪𝑶𝟐 )
Cost of 𝑪𝑶𝟐 avoided
45-73 62
(USD/t 𝑪𝑶𝟐 )
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Figure 5 Schematic diagram of the double-pipe geothermal system (Cheng et al., 2016)
Working fluid
The working fluid is deployed as geothermal extraction media. The basic process is injecting cooled fluid
from the wellhead and absorbing the heat generated by the chamber when the fluid returns to the surface.
However, the heated working fluid is always less than the injected fluid due to the fluid loss during the
geothermal extraction process. Cheng et al. (2016) analyzed the factors influencing the operating fluid
loss for the traditional double-pipe heat exchange model. For the same injection flow rate, the fluid loss
in the conventional geothermal system increases with the reservoir depth, reservoir length, and reservoir
porosity, as shown in Figure 6.
The advantage of the designed model is that the fluid loss could be avoided during the whole process due
to the sealed annulus bottom. In other words, the working fluid could be collected in the wellhead without
fluid loss, and after being cooled by surface facilities, the working fluid could be reinjected into the
subsurface. The circulation process saves the operation cost, and it is attractive to adopt nanofluid to
improve the heat transfer capacitance.
Figure 6 The outlet mass flow rate varied with the porosity and the reservoir length (Cheng et al., 2016)
The well integrity needs to be assessed because of the high amount of 𝐶𝑂2 in the fluid can cause
𝐶𝑂2 corrosion in tubing and casing of the well (Sholihin et al., 2019). The main issue when converting a
conventional well completion to 𝐶𝑂2 combustion containing completion is the possibility of having
production packer leaks and degradation of cement. This will cause even a formation gas to migrate
through micro channeling inside cement casing major issues to the well integrity and require a well
intervention which very costly to any other rigless operations.
In order to predict the status of the well integrity for 𝐶𝑂2 combustion wells, there are some empirical
models which can predict the corrosion impact and rate of corrosion. Corrosion in the pipeline, casing,
and tubing can always be modeled considering the limitation to be part of the overall corrosion risk
assessment methodology such as considering the existing corrosion rate data and experience with similar
production fluids. This simulation model focusing in predicting corrosion rate and remaining life of the
well tubing and casing using the Norsok M-506 method.
During the initial reaction, carbonic acid is built out of dissolved carbon dioxide and water which resulted
in a reaction between the acid, the calcium hydroxide and the calcium–silicate–hydrate gels and forms
calcium carbonate. The calcium carbonate continues to react with the carbonic acid and builds water-
soluble calcium bicarbonate which is very critical because the formation water allows the dissolution of
more 𝐶𝑂2. This will lead to 𝐶𝑂2 migration along the cement/cap rock and cement/casing interfaces. Figure
(8) shows 𝐶𝑂2 corrosion resulted from the micro annulus and channeling through the outer casings. Micro-
annulus channeling indicates that 𝐶𝑂2 migrated along with the cement behind casings interfaces and in
many cases can be observed at the surface through the annulus and not many options can be done to restore
the well integrity.
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Figure 8 𝐶𝑂2 Corrosion Process by Micro-annulus and Channeling 506 (Sholihin et al., 2019)
Figure 9 Typical 𝐶𝑂2 injection well head (Medimurec & Pasic, 2011)
The requirements for the well design for CO2 injection well type class VI are summarized in the below,
Tables (4 & 5):
Table 4 Mandatory Technical Requirements for 𝐶𝑂2 Injection Well (NETL, 2009)
Mechanical
Integrity test Continuous internal integrity monitoring and annual external integrity testing.
(MIT)
Analysis injectant. Continuous temperature and pressure monitoring in the target
Monitoring formation. Plume tracking required.
Closure 50-day notice and flush well. Must be prevent injection from other resources.
Periodically update the cost estimates for well plugging, post injection site care and
Financial site closure. Also, remediation to account for any amendments to the area of review
Responsibility and action accordingly.
Item Type
Downhole Choke
In order to control the flow through the tubing, downhole choking devices to be used. Flow assurance is
a concern to have a single phase of the fluid. The multi-phase flow will cause slugging which can threat
the safety of the operation causing corrosion, blockage of pipe and leading to stop the production. Another
concern is the free water which can cause hydrate formation at low temperatures which can plug the
production path and become difficult and time-consuming to remove. In addition, the accumulation of
volatile components such as 𝐻2 and 𝐻2 𝑆 at the pipeline will lead to increasing the corrosion rate. In order
to ensure the safety and continuity of the operation under single-phase flow, the pressure should be
maintained at certain levels. Below are different types of controlling the flow downhole:
Downstream Remotely Actuated Ball Valve
Ball valves are one option installed in the well completion in order to increase the backpressure and control
the flow rates. They can also be used for pressure isolation between the upper well completion and the
reservoir pressure while the well is shut-in. Ball valves can be controlled remotely and adjusted to have
certain pressure and flow rate. They are considered as part of the completion which will be added to the
cost to the completion and will increase the risk of tool failure.
A flapper valve means a valve consisting of a hinged flapper that seals the valve orifice. In Class VI wells,
flapper valves can engage to shut off the flow of the carbon dioxide when acceptable operating parameters
are exceeded.
Challenges
There are some persisting challenges that may face the implementation of our idea:
- The purification of the produced gas. The gas coming from the reservoir often contains 𝐶𝑂2 , 𝐻2𝑆,
water and other impurities that need to be removed out from the gas stream before being burnt.
Physical and chemical membranes can be used in our case. However, these membranes will need
to be replaced and maintained frequently. This will increase the operation cost and hence the cost
of the electricity generated.
- The combustor and heat exchanger will need continuous maintenance. This maintenance may
require shutting down the well for some time. This will definitely have an adverse effect on the
well productivity. One solution for this is to create a sidetrack for the produced gas to continue to
flow normally to the surface during the combustor downtime.
Summary
In order to have an accurate figure if the 𝐶𝑂2 amount, the actual gas flow rates should be used as inputs
for the design of the actual combustor. The combustion and heat exchanging efficiencies should be
calculated based on actual material design rather than being assumed to be 100%. Actual production
tubing, 𝐶𝑂2 injection tubing and production casing sizes should be assessed to stop by the validity of the
design. More study and evaluation should be conducted to avoid any issues in the design which may
cause underground problems such as blowout and pollution.
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