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C Ch-21 Hydrocarbons
C Ch-21 Hydrocarbons
Hydrocarbons
?
Br H H
Br
is/are [IIT-JEE-2007 (Paper-1)]
(A) Alcoholic KOH (B) Alcoholic KOH followed by NaNH2
(C) Aqueous KOH followed by NaNH2 (D) Zn/CH3OH
2. The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne.
The bromoalkane and alkyne respectively are [IIT-JEE-2010 (Paper-1)]
O
COOH OCH3
C
O
HO H3C
P Q S
were separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case
respectively, is [IIT-JEE-2010 (Paper-2)]
COOH OCH3 C
O
(A)
HO H3C O2N
NO2 NO2
COOH OCH3 C
O
(B)
HO NO2 H3C NO2
NO2
O NO2
COOH OCH3 C
O
(C)
HO H3C NO2
NO2
O
COOH OCH3 C
O NO2
(D)
HO H3C NO2
NO2
4. In allene (C3H4), the type(s) of hybridisation of the carbon atoms is (are) [IIT-JEE-2012 (Paper-1)]
(A) sp and sp3 (B) sp and sp2
(C) Only sp2 (D) sp2 and sp3
5. The number of optically active products obtained from the complete ozonolysis of the given compound is
[IIT-JEE-2012 (Paper-1)]
CH3 H
CH3 – CH = CH – C – CH = CH – C – CH = CH – CH3
H CH3
(A) 0 (B) 1
(C) 2 (D) 4
6. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure.
and and
I. II.
III.
NaNH 2
Na
liq. NH3
(A) (B)
(C) (D)
H H
Y
X and Y can respectively be [IIT-JEE-2010 (Paper-1)]
(A) H and H (B) H and C2H5
(C) C2H5 and H (D) CH3 and CH3
9. In the following reaction, the major product is [JEE (Adv)-2015 (Paper-1)]
CH3
CH2
1 equivalent HBr
H2C
CH3 CH3
CH3
(A) H2C (B)
H3C
Br Br
CH3 CH3
(C) (D)
H2C Br H3C Br
10. Among the following, reactions(s) which gives (give) tert-butyl benzene as the major product is(are)
[JEE (Adv)-2016 (Paper-2)]
Br
Cl
(A) (B)
NaOC2H5 AlCl3
OH
(C) (D)
H2SO4 BF3OEt2
11. The correct statement(s) for the following addition reactions is(are) [JEE (Adv)-2017 (Paper-1)]
H3C H
Br2/CHCl3
(i) M and N
H CH3
H3C CH3
Br2/CHCl3
(ii) O and P
H H
(A) O and P are identical molecules
(B) Bromination proceeds through trans-addition in both the reactions
12. Choose the correct option(s) that give(s) an aromatic compound as the major product.
[JEE (Adv)-2019 (Paper-2)]
Br
(A) NaOEt
i) alc. KOH
H3C ii) NaNH 2
(B) Br
iii) red hot iron tube, 873 K
Br
UV, 500 K
(C) + Cl2(excess)
NaOMe
(D)
13. Which of the following reactions produce(s) propane as a major product? [JEE (Adv)-2019 (Paper-2)]
Br
(A) H3C Br Zn (B) H3C NaOH, CaO,
COONa
CH 3
(C) P is (D) R is
O
2 C
H3C CH3 [IIT-JEE-2011 (Paper-1)]
H3C H3C
(C) H – C – C C – CH3 (D) H3C – C – C C – H
H3C H3C
H3C OH H3C OH
(A) H – C – C – CH2CH3 (B) H3C – C – C – CH3
H3C H H3C H
H3C OH OH
(C) H – C – CH2CHCH3 (D) CH3CH 2CH 2CHCH 2CH 3
H3C
1. NaNH2 (2 equivalent)
OH
2.
Br
H Y Scheme-2
3. H3O , (mild)
N 4. H2, Pd/C
5. CrO3
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H3CO H
(A) (B) H
H H H3CO
CH3CH2O H
H
(C) (D)
H H CH3CH2O
Pd-BaSO4 i. B2H6
C8H6 C8H8 X
H2 ii. H2O2, NaOH, H2O
H2O
HgSO4, H2SO4
i. EtMgBr, H2O
C8H8O Y
+
ii. H , heat [JEE (Adv)-2015 (Paper-2)]
O OH
CH3 CH3
(A) (B)
OH
CHO
(C) (D)
CH3 CH3
(A) (B)
CH3
CH2
CH3 CH3
(C) (D)
light
CH4 (g) Cl2 (g) CH3 Cl(g) HCl(g)
OH
R. 3. Et-Br
OH
Codes :
P Q R S
(A) 2 3 1 4
(B) 3 2 1 4
(C) 2 3 4 1
(D) 3 2 4 1
Integer / Numerical Value Type Questions
24. The number of hydroxyl group(s) in Q is [JEE (Adv)-2015 (Paper-2)]
H
H
aqueous dilute KMnO4 (excess)
P Q
heat 0 C
HO
H3C CH3
25. Total number of hydroxyl groups present in a molecule of the major product P is ____ [JEE (Adv)-2019 (Paper-2)]
26. In the reaction given below, the total number of atoms having sp2 hybridization in the major product P is
______. [JEE (Adv)-2021 (Paper-1)]
1. O3 (excess)
then Zn/H2O
P
2. NH2OH
(excess)
27. The number of -CH2- (methylene) groups in the product formed from the following reaction sequence
is ________. [JEE (Adv)-2022 (Paper-2)]