INPUT DATA

COMPONENT A
COMPOSITION OF SOLVENT
REQUIRED DISTILLATE RATE
REQUIRED PURITY OF SOLVENT
COMPONENT B
OPEARTING REFUX RATE
OUTPUT DATA
FEED RATE
BOTTOM WITHDRAWL
REFLUX RATE MIN
REFLUX RATE OPTIMUM
RELATIVE VOLATILITY
MINIMUM REFLUX RATE
OPTIMUM REFLUX RATE
MINIMUM PACKING HEIGHT
MAXIMUM PACKING HEIGHT
COLUMN DIAMETER AT R=RMIN(mm)
COLUMN DIAMETER AT R=ROPT(mm)
REQUIRED COLUMN DIA (mm)
REQUIRED HEIGHT AT R MIN(mts)
HEIGHT OF THE COLUMN AT OPERATING REFLUX RATE
DIAMETER OF THE COLUMN AT GIVEN REFLUX (mm)
 METHANOL
20
2000
99.5
WATER
4.000

12600
10600
3495.7548236853
5243.63223552796
3.83260495586264
1.74787741184265
2.62181611776398
6.50075833370087
11.3763270839765
952
1043
998
14.2204088549706
9.28877479668678
1193
 ACETONE
METHANOL
ETHANOL
ISO PROPYL ALCOHOL
ETHYL ACETATE
TETRA HYDRO FURAN

DI METHYL FORMAMIDE
TOULENE

CYCLO HEXANE
O-XYLENE
DIMETHYL ACETAMIDE
N BUTANOL
N HEXANE
METHYLENE CHLORIDE
ACETONITRILE
DI ISOPROPYL ETHER
WATER
 A

S.No Name of the solvent Molecular weight BOILING POINT

1 ACETONE 58.000 56.287

2 METHANOL 32.000 64.504
3 ETHANOL 46.000 78.329
4 ISO PROPYL ALCOHOL 60.000 82.233
5 ETHYL ACETATE 88.000 77.159
6 TETRA HYDRO FURAN 68.000 65.966
7 DI METHYL FORMAMIDE 73.000 153.350
8 TOULENE 92.000 110.625
9 CYCLO HEXANE 84.000 80.733
10 O-XYLENE 106.000 144.411
11 DIMETHYL ACETAMIDE 87.000 165.994
12 N BUTANOL 74.000 117.700
13 N HEXANE 86.000 68.913
14 METHYLENE CHLORIDE 85.000 39.742
15 ACETONITRILE 41.000 81.093
16 DI ISOPROPYL ETHER 102.000 68.262
17 WATER 18.000 100.253

Antonie equations
METHANOL
A 8.0724
B 1574.99
C 238.87

Vapour Pressure
S.No Temp 0C ( MM Hg )
1 64.5035502616688 760.000000000001
2 68.4757125422753 886.972385834186
3 72.4478748228817 1031.08486618033
4 76.4200371034882 1194.07400911378
5 80.3921993840947 1377.78702308567
6 84.3643616647011 1584.18324623119
7 88.3365239453076 1815.33530522784
8 92.3086862259141 2073.42994059567
9 96.2808485065206 2360.76849756229
10 100.253010787127 2679.76708372779
 αAB X intercept Y intercept
3.83260495586264 0.2 0.489314216337946

Rmin
Ropt
Using frnskey Equation Nmin
N-Nmin/N+1
N=No of thoeritical Stages
Plate efficiency as 50%
OPERATING REFLUX RATE
 A

ANTONIE COEFFICIENTS VISCOSITY DENSITY

7.232 1277.030 237.230 0.330 790.000

8.072 1574.990 238.870 0.600 792.000
8.213 1652.050 231.480 1.080 789.000
8.118 1580.920 219.620 2.000 786.000
7.015 1211.900 216.010 0.460 895.000
6.995 1202.290 226.254 0.550 888.000
7.109 1537.780 210.390 0.820 945.000
6.955 1344.800 219.482 0.590 867.000
6.841 1201.531 222.647 0.980 778.000
6.999 1474.679 213.686 0.700 870.000
7.762 1889.100 221.000 0.920 945.000
7.477 1362.390 178.730 3.000 810.000
6.911 1189.640 226.280 0.310 659.000
7.080 1138.910 231.460 0.440 1326.000
7.074 1279.200 224.010 0.380 782.000
7.097 1257.600 230.010 0.330 724.000
18.300 3816.440 -46.130 72.000 998.000

quations BOILING POINT A

64.5035502617
WATER METHANOL
18.3
3816.44 BOILING POINT B
100.253010787
-46.13 WATER

Vapour pressure
(MM Hg) αAB Xa Ya
181.616923385822 4.18463205868473 1 1
216.601349919102 4.09495317626349 0.9 0.9718257833
257.119760846336 4.01013466559869 0.8 0.9387645871
303.849821605625 3.92981639022846 0.7 0.8994241519
357.52581540131 3.85367143779297 0.6 0.8518278685
418.940657208587 3.78140249453621 0.5 0.7930722645
488.94777284082 3.71273867284559 0.4 0.7187115842
568.462832619672 3.64743272843467 0.3 0.6215769241
658.465330406567 3.58525861354711 0.2 0.4893142163
759.999999999999 3.52600932069447 0.1 0.2986614931
αAB 3.83260495586264
 Xd Xb
0.995 0.05

1.74787741184265 1.74787741184265

2.62181611776398 4
5.13135067173084 5.13135067173084
0.414962670981153 0.272762869733866

9.48027256998043 7.43101983734942

18.9605451399609 14.8620396746988
VAPOUR LATENT SPECIFIC
DENSITY HEAT HEAT
2.147 122.000 0.520
1.156 263.130 0.610
1.596 200.000 0.590
2.059 159.000 0.620
3.063 88.000 0.450
2.445 98.000 0.530
2.087 138.000 0.490
2.923 86.790 0.450
2.894 85.000 0.430
3.095 82.000 0.400
2.415 119.080 0.480
2.308 141.000 0.550
3.065 80.000 0.490
3.312 79.000 0.280
1.411 174.000 0.540
3.643 68.000 0.510
0.588 510.000 1.000
 Solvent

DISTILLATE RATE D Kg/Hr 2000 2000 2000

FEED COMPOSITION Xf w/w 0.2 0.2 0.2

DISTILLATE COMPOSITI Xd w/w 0.995 0.995 0.995

BOTTOM COMPOSOTIOXb w/w 0.05 0.05 0.05

FEED RATE F Kg/Hr 12600 12600 12600

BOTTOM COLLECTION RB Kg/Hr 10600 10600 10600

DISTILLATE RATE D Kg/Hr 2000 2000 2000

REFLUX RATE R Kg/Hr 3495.75482 5243.6322 6243.6322

V=R+D Kg/Hr 5495.75482 7243.6322 8243.6322

TOTAL VAPOUR FLOW RATE

Va Kg/sec 1.53 2.01 2.29

VAPOUR DENSITY Vd Kg/Cumt 1.156 1.156 1.156

FEED RATE F Kg/Hr 12600 12600 12600

REFLUX RATE R Kg/Hr 3495.75482 5243.6322 6243.6322

L=F+R Kg/Hr 16095.7548 17843.632 18843.632

TOTAL LIQUID FLOW RATELa Kg/sec 4.471 4.957 5.234

LIQUID DENSITY Ld Kg/Cumt 792.000 792.000 792.000

Cp 0.600 0.600 0.600

LIQUID VISCOSITY µl
 LIQUID VISCOSITY µl Ns/m2 0.0006 0.0006 0.0006
liq

La/Va Ratio A
2.92876144 2.4633542 2.285841
Vd/Ld Ratio B
0.00145902 0.001459 0.001459
sqrt(B) C
0.03819711 0.0381971 0.0381971
FLV=a*c E
0.11187023 0.094093 0.0873125
Dsign for

Packing type

Flooding factor Kv
0.082 0.09 0.09

gas mass low rate, Vm

Vm Kg/M2 s 2.15 2.35 2.35

Area As = V1\Vm M2
0.71163711 0.8545923 0.9725707
trial column dia Dc(DIA_) M 0.952 1.043 1.113

DIA mm
CLOUMN DIA IN mm 952 1043 1113

COMDENSER AREA M2
 METHANOL
Material Balance
2000 2000 2000 2000 2000 2000 2000

0.2 0.2 0.2 0.2 0.2 0.2 0.2

0.995 0.995 0.995 0.995 0.995 0.995 0.995

0.05 0.05 0.05 0.05 0.05 0.05 0.05

12600 12600 12600 12600 12600 12600 12600

10600 10600 10600 10600 10600 10600 10600

VAPOUR PROPERTIES

2000 2000 2000 2000 2000 2000 2000

7243.632236 8243.6322 9243.6322 10243.632 11243.6322 12243.632 13243.632

9243.632236 10243.632 11243.632 12243.632 13243.6322 14243.632 15243.632

2.57 2.85 3.12 3.40 3.68 3.96 4.23

1.156 1.156 1.156 1.156 1.156 1.156 1.156

LIQUID PROPERTIES

12600 12600 12600 12600 12600 12600 12600

7243.632236 8243.6322 9243.6322 10243.632 11243.6322 12243.632 13243.632

19843.63224 20843.632 21843.632 22843.632 23843.6322 24843.632 25843.632

5.512 5.790 6.068 6.345 6.623 6.901 7.179

792.000 792.000 792.000 792.000 792.000 792.000 792.000

0.600 0.600 0.600 0.600 0.600 0.600 0.600

 0.0006 0.0006 0.0006 0.0006 0.0006 0.0006 0.0006
liq-vap.Flow Factor,Flv=(L1/v1)*sqrt(Vd/Ld)

2.146735367 2.0347892 1.9427558 1.8657562 1.80038465 1.7441922 1.6953723

0.001459019 0.001459 0.001459 0.001459 0.00145902 0.001459 0.001459

0.038197113 0.0381971 0.0381971 0.0381971 0.03819711 0.0381971 0.0381971

0.081999093 0.0777231 0.0742077 0.0712665 0.0687695 0.0666231 0.0647583

Dsign for an intiial pressure drop of 20mmH2o/m packing

STRUCTURE PACKING - MELL PACK 250 Y

0.09 0.095 0.095 0.095 0.095 0.095 0.095

Caluclation

From k4 v/s Flv Graph

Flv X (Ld - Vd)0.5

Vd0.5

2.35 2.49 2.49 2.49 2.49 2.49 2.49

1.090549145 1.1449209 1.2566899 1.3684589 1.48022795 1.591997 1.703766

1.178 1.207 1.265 1.320 1.373 1.424 1.473

1178 1207 1265 1320 1373 1424 1473

 2000 2000 2000 2000 2000 2000
0.2 0.2 0.2 0.2 0.2 0.2
0.995 0.995 0.995 0.995 0.995 0.995
0.05 0.05 0.05 0.05 0.05 0.05
12600 12600 12600 12600 12600 12600
10600 10600 10600 10600 10600 10600

2000 2000 2000 2000 2000 2000

14243.632 15243.632 16243.63 17243.632 18243.63 8000
16243.632 17243.632 18243.63 19243.632 20243.63 10000
4.51 4.79 5.07 5.35 5.62 2.78
1.156 1.156 1.156 1.156 1.156 1.156

12600 12600 12600 12600 12600 12600

14243.632 15243.632 16243.63 17243.632 18243.63 8000
26843.632 27843.632 28843.63 29843.632 30843.63 20600
7.457 7.734 8.012 8.290 8.568 5.722
792.000 792.000 792.000 792.000 792.000 792.0
0.600 0.600 0.600 0.600 0.600 0.600
 0.0006 0.0006 0.0006 0.0006 0.0006 0.0006

1.6525634 1.6147197 1.581025 1.5508316 1.523621 2.06

0.001459 0.001459 0.001459 0.001459 0.001459 0.001459

0.0381971 0.0381971 0.038197 0.0381971 0.038197 0.038197

0.0631232 0.0616776 0.060391 0.0592373 0.058198 0.078686

0.095 0.095 0.095 0.10 0.10 0.095

2.49 2.49 2.49 2.62 2.62 2.49

1.815535 1.9273041 2.039073 2.0433 2.149481 1.11769

1.521 1.567 1.611 1.613 1.654 1.193

1521 1567 1611 1613 1654 1193