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Materials and Design: Seok-Jae Lee, Young-Kook Lee
Materials and Design: Seok-Jae Lee, Young-Kook Lee
a r t i c l e i n f o a b s t r a c t
Article history: Although the prior austenite grain size (AGS) of heat treatable low alloy steels is an influential factor in
Received 30 May 2007 phase transformations during quenching and in mechanical properties, there are few equations to predict
Accepted 13 March 2008 the AGS considering alloying element effects. The purpose of this study was to investigate the effects of
Available online 28 March 2008
alloying elements on austenite grain growth and to propose an empirical equation for predicting the AGS
of global low alloy steels. The Arrhenius type equation was proposed based on the measured AGSs of the
Keywords: 16 different low alloy steels and the predicted results were in a good agreement with the measured data.
Austenite grain growth
Ó 2008 Elsevier Ltd. All rights reserved.
Solute drag
Low alloy steels
1. Introduction oped equation for predicting the AGS of low alloy steels containing
Cr, Ni, and Mo was validated by comparing the measured and cal-
In the heat treatment process, the austenite grain size (AGS) be- culated AGSs of various low alloy steels.
fore quenching tremendously influences diffusive and diffusionless
phase transformations, precipitation, and mechanical properties 2. Experimental procedure
such as strength, hardness, toughness, and ductility. A plenty of re-
searches have been made to get better understanding and control- The total 16 different low alloy steels were prepared using a vacuum induction
furnace to investigate the effects of Ni, Cr, Mo, and C on austenite grain growth. The
ling of the austenite grain size during austenitizing process of the
chemical composition range of the low alloy steels used in this study was shown in
steels over the past half a century [1–8]. Even if the austenite grain Table 1. The ingots were homogenized at 1300 °C for 3 h and hot rolled at 1000 °C to
size is fine just after the reverse transformation during heat-up to 8 mm thick plates. The specimens were taken from the plate and austenitized in
austenite region, the grain growth can easily occur especially in nitrogen atmosphere at different temperatures from 850 to 1200 °C for maximum
plain carbon steels to reduce the grain boundary free energy by 3 h using a tube furnace, followed by water quenching. For the measurement of
AGS, the quenched specimens were etched by a saturated picric acid after mechan-
thermally activated atomic processes. As alloying elements are
ical polishing with 1 lm diamond suspension. Two methods by using the line inter-
added in the carbon steels, the grain growth rate usually decreases cept and the area of average grain were tried to measure the AGS of the etched
due to the solute dragging effect of the alloying elements segre- specimens [13].
gated into austenite grain boundaries [9,10]. If the alloying ele-
ments precipitate as carbides or nitrides in austenite, the 3. Results and discussion
precipitates also lower the grain growth rate by pinning the grain
boundaries [11,12]. Fig. 1 shows optical microstructures of the quenched specimens
Up to date, several theoretical and semi-empirical models for of a Cr–Mo steel held at different austenitizing temperatures for
predicting austenite grain size during austenitization considering 10 min. The grains are almost equaxed even at 900 °C and were
the alloying element effects have been suggested [1–8]. The theo- clearly coarsened with increasing austenitizing temperature. The
retical models contain thermodynamic parameters like grain fine and coarse grains still coexist at such a temperature as high
boundary energy, activation energy for grain boundary diffusion, as 1050 °C. On the basis of optical measurements, the average
and so on, which are not easily obtainable. Some empirical equa- AGS was quantitatively evaluated as functions of austenitizing
tions have been suggested simply as functions of temperature temperature and time. The linear proportion between the recipro-
and time of austenitization only for plain carbon–manganese steels cal of temperature and the natural logarithmic values of AGS is
[4,5,8], which are not suitable for low alloy steels. In this study, an shown in Fig. 2a, while the exponential increment of AGS with a
empirical equation for predicting the AGSs of global low alloy holding time is in Fig. 2b, respectively.
steels is proposed from an industrial point of view. A newly devel- The effects of Ni, Cr, and Mo on austenite grain growth are
quantitatively compared based on the analysis of measured AGSs
in Fig. 3. The reduction in AGS with an addition of alloying ele-
* Corresponding author. Tel.: +82 2 2123 2831; fax: +82 2 312 5375.
E-mail address: yklee@yonsei.ac.kr (Y.-K. Lee). ments was greater at 1200 °C. The Mo is more effective to prevent
0261-3069/$ - see front matter Ó 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.matdes.2008.03.009
S.-J. Lee, Y.-K. Lee / Materials and Design 29 (2008) 1840–1844 1841
Fig. 1. Variation of austenite grain size in a water quenched Cr–Mo steel held at different austenitizing temperatures for 10 min: (a) 900 °C, (b) 950 °C, (c) 1000 °C,
(d) 1050 °C, (e) 1100 °C, and (f) 1150 °C.
1842 S.-J. Lee, Y.-K. Lee / Materials and Design 29 (2008) 1840–1844
Fig. 5. Comparison of the austenite grain size calculated by the previous and proposed equations with the measured one: (a) Eq. (2), (b) Eq. (3), (c) Eq. (4), (d) Eq. (5), and (e)
Eq. (7).
XN !,
between the line in the middle of the figure and markers, while the 1
D¼ pffiffiffi ðdcal dexp Þ N ð8Þ
parameter E is the average, signed distance between the line in the
i¼1 2
middle of the figure and markers.
1844 S.-J. Lee, Y.-K. Lee / Materials and Design 29 (2008) 1840–1844
!,
XN
1 References
E¼ pffiffiffi ðdcal dexp Þ N ð9Þ
i¼1 2
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Acknowledgements
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