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ECS MANUAL
Operation, Maintenance & Safety Manual
All rights are reserved to Techcross. Unless otherwise specified, no part of this publication may be
reproduced or utilized in any form orby any means, electronic or mechanical, including photocopying
and microfilm, without permission in writing from Techcross.
ECS MANUAL
Operation, Maintenance & Safety Manual
Class LR
9289518/9289520/ 9289532/
IMO No.
9291640/ 9292620/ 9292967
Table of Contents
1. WARNING................................................................................................................................................... 6
2. ABBREVIATION ........................................................................................................................................ 7
3. ECS OVERVIEW......................................................................................................................................... 9
3.1 Introduction of ECS ........................................................................................................................9
3.2 Specification of ECS .................................................................................................................... 10
3.3 Operation Process ....................................................................................................................... 11
3.4 ECS Components ......................................................................................................................... 12
3.5 Safety Measures............................................................................................................................ 16
4. OPERATION ............................................................................................................................................ 23
4.1 Preparation for Operation ...................................................................................................... 23
4.2 Automatic Operation ................................................................................................................. 35
4.3 Emergency Situation ................................................................................................................ 74
4.4 Stop Procedure ............................................................................................................................. 79
5. MAINTENANCE ..................................................................................................................................... 81
5.1 General Information ................................................................................................................... 81
5.2 Preparation of maintenance ................................................................................................. 82
5.3 Maintenance list of major equipment / Inspection period and method ........ 84
5.4 Regular maintenance Procedure ......................................................................................... 86
5.5 Long-term Lay-up ....................................................................................................................... 92
5.6 Calibration Guide for Sensor ..............................................................................................100
5.7 Detailed Maintenance Procedure ......................................................................................117
5.8 Spare parts ....................................................................................................................................133
6. TROUBLESHOOTING ........................................................................................................................137
6.1 Checking Alarms & Log messages.....................................................................................137
6.2 Trouble shooting for ECS Major Alarm Message ........................................................138
6.3 Main Problems and Measures .............................................................................................147
7. ADDITIONAL FUNCTION ................................................................................................................179
7.1 Additional function of HMI....................................................................................................179
7.2 Additional functions of Equipment ..................................................................................198
8 APPENDIX I ...........................................................................................................................................207
8.1 Health and safety.......................................................................................................................207
8.2 Active substances ......................................................................................................................210
8.3 MSDS ...............................................................................................................................................211
8.4 Letter of International Paint Ltd. ........................................................................................259
Revision Status
00 14/04/01 Established
1. WARNING
Only qualified personnel should operate and maintain ECS after becoming thoroughly
familiar with proper operation, all warnings, safety notices, maintenance requirements and
troubleshooting.
• Do not operate if inlet /outlet valves of ECU are closed. It can cause severe damage to the
equipment and crews.
Make sure that inlet /outlet valves of the ballast pump are open before operation of ECS.
• Do not open the cover of the equipment or maintain the equipment when power is on in
an explosive and flammable environment.
Failure to heed warning and danger labels may result in equipment damage and possible personal injury.
2. ABBREVIATION
Installation Area
Abbr. Full Name
Hazardous Area
Non-Harzardous Area
Ex : Ex-prrof type
CPC Control PC ○
EM Electrode Module ○ ○
E
EPJ ECU Power Junction Box ○
Installation Area
Abbr. Full Name
Hazardous Area
Non-Harzardous Area
Ex : Ex-prrof type
PI Pressure Indicator ○ ○
T-Strainer T-Strainer ○ ○
3. ECS OVERVIEW
3.1.3 Safety
ECS is developed and designed to ensure that the operation is conducted in a safe and efficient
manner, and to familiarize the users with the basic procedures that affect their own safety and the
safety of their fellow users. However, the users should read the manual thoroughly and be educated to
be able to maintain overall control of software and hardware safety before starting to operate ECS.
ECU : Max. 0.2 bar (Based on from inlet to outlet of the ECU)
Pressure drop
T-strainer : Max. 0.2 bar
**1) Fresh water : < 1PSU ** Brackish water : 1 PSU ~ 28PSU **Marine water : > 28PSU
10
11
12
2. Control PC (CPC)
13
14
10. T-Strainer
15
3.5.2.2 Operating Condition and Active Substance Concentration Management of Electro- Cleen™
System
For the ballast water management system using electrolysis, the additional filtration system is not
necessary because ballast water treatment is conducted after large sediments in inflowing water
are removed with a strainer. This electrolysis system disinfects with potential difference, radicals,
and electrode oxidization which are generated instantaneously and disappeared in several
seconds. The maintaining disinfectant is TRO. TRO concentration generated during ballast water
treatment in this system is around 10mg/L even though the generated concentration is different
by characteristics such as ballast water temperature, conductivity, types and concentration of
16
materials dissolved in water. As reviewed in the next paragraph, this range of concentration does
not require particular cautions when the crew or operators handle ballast water. Since the active
substance in ballast water, hypochlorous acid, is affected by voltage and current, TRO generation
is being managed by controlling voltage and current automatically so that the maximum
concentration does not exceed 10mg/L.
2) Skin contact
Hypochlorite solutions can cause mild irritation to corrosive injury depending on the duration of
contact, the concentration and pH of the solution, based on human and animal information. No
irritation was experienced by 20 volunteers following the application of 1% hypochlorite solution
(pH unspecified) for 48 hours in the form of a covered patch. When 2% solution (pH unspecified)
was used, weak or moderate irritation was experienced by 15 out of 69 volunteers. No skin
reaction was observed in 3 volunteers following a 48-hour application of 0.252% solutions in the
form of a covered patch. Severe irritation was experienced by volunteers after 4-hour application
of 5.25% hypochlorite solution (pH 10.7) to unbroken skin in the form of a covered patch.
17
3) Eye contact
Hypochlorite solutions can cause mild irritation to corrosive injury, depending on the
concentration and pH of the solution, and the duration of the contact, based on human and
animal information. There are several reports of pain, and in some cases, slight damage to
the surface of the eye and/or cornea, being experienced after direct contact with commercial
products containing sodium hypochlorite (approximately 5%). The eyes were washed with water
or a salt solution (saline) and the injury cleared within 1-2 days. There are 3 reports of burning
to the eyes with slow recovery following exposure to concentrated solutions (concentration
unspecified).
4) Ingestion
Swallowing hypochlorite solutions can cause irritation, pain and inflammation of the mouth,
throat and stomach, as well as vomiting. In severe cases, serious effects including ulceration
and perforation of the gastrointestinal tract and death can result. The effects depend on several
factors, e.g., the amount ingested, the concentration and pH of the solution. About 29.5ml of a
solution with 15% available chlorine may be lethal. For sodium hypochlorite solution with 3-6%
of available chlorine, a lethal dose for humans of 200 ml has been reported. Severe injury has
been observed in a person who ingested approximately 1 liter of 5.25% sodium hypochlorite
having pH of 10.8. A woman who intentionally swallowed approximately 700ml of 5.25% sodium
hypochlorite having pH of 11.5, showed falling mental status, perforation of the stomach, and
died of cardiac arrest 4.5 hours after ingestion. Deaths have also resulted from aspiration of
sodium hypochlorite solution into the lungs.
2) Skin sensitization
It is not possible to conclude hypochlorite as an occupational skin sensitizer. A few cases of skin
sensitization have been reported, in all but one case, the individuals were predisposed to this
18
type of reaction (reacting to other common allergens as well). Two non-occupational cases
of sensitization to sodium hypochlorite have been confirmed by patch tests. Both individuals
reported a history of skin reactions following exposures to products containing sodium
hypochlorite or chlorine. Other family or personal history of allergies has not been reported.
Negative results (0/86 and 0/90 individuals sensitized) have been obtained in two unpublished
sensitization tests on human volunteers (human repeated insult patch test) using 4% sodium
hypochlorite solution.
3) Carcinogenicity
The International Agency for Research on Cancer (IARC) has concluded that hypochlorite is not
classifiable as to its carcinogenicity to humans
4) Teratogenicity and embryo toxicity No specific conclusions can be drawn about the potential
developmental toxicity of sodium hypochlorite from a human population study that examined
the potential effects of chlorinating drinking water with sodium hypochlorite. Exposure in
this study was based on the chlorination method, and not the measured amount of sodium
hypochlorite or its byproducts in the water.
5) Reproductive toxicity
There is no human information available for reproductive toxicity. No firm conclusion can be
drawn based on the limited animal information available.
6) Mutagenicity There is no information available for human. The available information for animal
suggests that sodium hypochlorite is not mutagenic. A positive result (sperm-head abnormalities)
was obtained in one test using live mice. This test did not directly measure genetic damage.
Negative results have been obtained in other tests with live mice.
7) Potential for accumulation Hypochlorite does not accumulate in the body. It reacts with tissues
(21). A rat study using radio labelled hypochlorous acid has shown that it is absorbed fairly rapidly
in serum and eliminated from plasma with a half-life of 44 hours.
19
20
2) IMDG IMDG Code 8186, UN No.1791, Class 8, Packaging Group II/III, EmS No.8-08, MFAG table
No.741 covers the hypochlorite solutions with more than 5% available chlorine. However, it does
not cover the 0.001% sodium hypochlorite solution which is generated in the Electro-Cleen
System.
2) H2 gas There are no potential effect by low concentration of hydrogen gas on a Vessel’s
infrastructure so far.
When the H2 gas is leaked, an alarm shall be activated in case the concentration of H2 gas is over
25% of LEL and the system shall be shut down in case the concentration of H2 gas is over 50% of
LEL. In such cases the ship’s crew must ensure that enough ventilation (at least 6 air changes per
hour) has been carried out by mechanical ventilation fan or natural ventilation by air vent heads
prior to entering the space where the ECS is installed.
1) It was found that total residual chlorine at the concentration of 10mg/L recommended for
ballast water treatment is completely degraded already after 1.1 days under light condition.
2) The hydrogen peroxide and ozone concentration of the electrolytic solution is very low in
comparison with the free chlorine. The maximum concentration produced during electrolysis of
seawater is below 0.1 mg/L for both hydrogen peroxide and ozone.
3) From the acute toxicity test, no skin irritation was experienced by 20 volunteers after application
of a 1% hypochlorite solution (pH unspecified) for 48 hours under a patch. The possibility of
21
danger to personnel from the electrolytically treated water does not exist.
4) Since chlorine is being used to disinfect drinking water not only in the United Kingdom and the
United States, but also in most other countries, there is almost no concern over PBT levels.
The half-life of total residual chlorine was 0.58 day under light condition and 2.0 days under dark
condition. No danger to humans and environment is expected.
22
4. OPERATION
Component What to do
MSBD/PDE Turn on MCCB.
CPC Turn on the power and selection of control position of ECS
TSU Check remaining quantity and expiration date of CLX reagents.
Check whether ANU fresh water tank contains a sufficient amount of
neutralization solution.
ANU
If "tank full" message is on, put sodium thiosulfate.
Open outlet valve of neutralizing agent.
Check whether water level of FTU tank is normal.
HEU/FTU If water is not sufficient, replenish the tank manually with fresh water.
Open inlet / outlet valves of freshwater of both FTU and HEU.
4.1.1.1 MSBD
1. Turn on BWMS main MCCB in MSBD.
23
4.1.1.2 PDE
1. Open the door of PDE and turn on the main MCCB.
2. On the front door of PDE, flip the switch to “Remote”.
4.1.1.3 CPC
1. Press the power button.
2. The computer will be booted up and HMI will be operated automatically.
24
4.1.1.4 TSU
< Ex-TSU (TSU Panel + Ex-CLX) >
1. Check XGT on the front door of TSU.
2. Press “F1” if it is in “EM'CY” then, make sure that "Remote" is set.
2. Close air inlet Manual valve of Ex-CLX and Verify the "0" pressure of Regulator.
Check replacement cycle and remaining quantity of Ex-CLX Reagent before using it.
Peplace it with new one if it is expired or remaining quantity of regents is lower than 20%
25
4. Close the door of Ex-CLX and Open the Air inlet by opening manual valve.
Check the pressure level of regulator and set the pressure "5~7.5"mber by using regulator
Power shall not be restored after after enclosure has been opend untill Enclosure has
been purged for 5 minutes at a flow rete of 11,8 SLPM.
Caution
26
6. Check whether the state lamp of Ex-CLX is flicking green (Remote mode ready)
(Green : Remote mode ready, Red : Remote mode standby / Emergency mode)
• CLX Reagent, a corrosive substance can cause burns on your skin and stain your
clothes.
Do not handle this reagent without protective equipment such as protective clothes,
Caution
•
gloves and glasses.
27
28
29
Step 1. Flushing and drain need to be implemented before using Spare CLX
30
No.1 CLX
(For Working → Spare)
<After>
31
4.1.1.5 ANU
Step 1: Check whether the fresh water is automatically filled to the high level of Tank.
Ensure that “ALM Left Tank Full” or “ALM Right Tank Full” message with “SDT” is displayed
on the ANU XGT Control Panel and Tower Lamp is operated.
Sodium Thiosulfate
ANU Model
1PKT = 25Kg 1PKT = 12.5Kg
ANU-5T 2 PKT = 50Kg (per tank) 4 PKT = 50Kg (per tank)
ANU-10T 4 PKT = 100Kg (per tank) 8 PKT = 100Kg (per tank)
32
Step 3:
ANU : Press “F1” button for the left tank and “F3” for the right tank to operate each agitator.
※ Sodium Thiosulfate
33
4.1.1.6 HEU/FTU
1. Fill cooling water more than middle level of FTU
4. Refill cooling water more than medium level of FTU after "2" and "3"
34
35
Step 1: Click “OP MODE" Tap → Click “IMO" button or “USCG” button on HMI Screen to select.
Check appropriate HMI operation mode depending on the area BWMS to be operated.
* IMO : The rest of United States
* USCG : United States
Step 2: Ensure that message says, “Do you want to change on Operation mode?"
Click “YES” button
36
37
38
39
40
41
LS
LS
PX
PX
42
*
*
*
* *
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
* *
* *
*
*
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*
*
*
*
*
*
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**
*
*
**
*
*
*
*
*
*
44
4.2.3.2 Preparation
* CAUTION!! Make sure that all the valves on pipelines for operation mode are open.
45
Step 3: Ship’s Valve and Pump Signal will be displayed in Ship’s Signal.
Match Ship’s Signal (ship’s conditions) with Required Signal.
If these two requirements match, "RUN" button will be activated.
4.2.3.3 Operation
Step 1: Select appropriate operation mode after checking related pumps and valves.
Check mode display to see if all the ballasting operation requirements are fulfilled.
Click “RUN” button on HMI Screen to start ECS.
Step 2: Ensure that message says, “Do you want to start the ECS?" Click “YES” button
Click “IMO” button or “USCG” button if HMI operation mode is not selected. v
46
Step 3: Ensure that ECU value and TRO value are displayed in 5 minutes after starting ECS.
Step 4: Click “STOP” and Ensure that message says, “Do you want to stop the ECS?"
Step 5: Click “YES” button. Stop ballast pump after stopping ECS operation.
47
LS
LS
PX
PX
48
*
*
*
* *
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
* *
* *
*
*
*
*
*
*
*
*
*
*
*
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**
*
*
**
*
*
*
*
*
*
50
4.2.4.2 Preparation
* CAUTION!! Make sure that all the valves on pipelines for operation mode are open.
Alarm is activated, if ECS is not running within 5 minutes of ballast pump operation.
[CODE727] ALARM Untreated water is Flowing
Caution
51
Step 3: Ship’s Valve and Pump Signal will be displayed in Ship’s Signal.
Match Ship’s Signal (ship’s conditions) with Required Signal.
If these two requirements match, "RUN" button will be activated.
4.2.4.3 Operation
Step 1: Select appropriate operation mode after checking related pumps and valves.
Check mode display to see if all the ballasting operation requirements are fulfilled.
Click “RUN” button on HMI Screen to start ECS.
Step 2: Ensure that message says, “Do you want to start the ECS?" Click “YES” button
Click “IMO” button or “USCG” button if HMI operation mode is not selected. v
** FEEDBACK CONTROL
Press the [REFRESH] button when you first start deballasting operation.
Press the [CONTINUE] button when you re-start deballasting operation.
52
Step 3: Ensure that ANU value and TRO value are displayed immediately after operating ECS.
Step 4: Click “STOP” and Ensure that message says, “Do you want to stop the ECS?"
Step 5: Click “YES” button. Stop ballast pump after stopping ECS operation.
53
LS
LS
PX
PX
54
*
*
*
* *
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
* *
* *
*
*
*
*
*
*
*
*
*
*
*
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**
*
*
**
*
*
*
*
*
*
56
*
*
*
57
4.2.5.2 Preparation
1. If an alarm(Low salinity) occurs in freshwater zone, please operate according to the below
procedure.
2. Fill sea water(4~5% of total ballast volume) into Sea Water Holding Tank(APT or WBT) before
sailing the fresh water zone. The amount of sea water for mixing ballasting operation is subject to
be changed depending on the salinity of the area where the sea water is pumped in to sea water
holding tank.
30 95.00 5.00
31 95.16 4.84
32 95.31 4.69
33 95.45 4.55
34 95.59 4.41
*34.7 95.70 4.30
35 95.71 4.29
36 95.83 4.17
37 95.95 4.05
3. Open the valve installed before Sea Water Holding Tank (APT or WBT) to be use.
4. Check the status of related pumps and valves
5. Automatic Flow Control Valve function throttling flow rate based on the measured Salinity
of mixed water(Target 1.5 PSU). Check "Measured value of CSU" on HMI screen.
[USCG] The valve after ballast pump should be adjusted so that the flow can be
controlled 70% of treatment rated capacity(TRC)
Caution
58
* CAUTION!! Make sure that all the valves on pipelines for operation mode are open.
Alarm is activated, if ECS is not running within 5 minutes of ballast pump operation.
[CODE727] ALARM Untreated water is Flowing
Caution
59
Step 3: Ship’s Valve and Pump Signal will be displayed in Ship’s Signal.
Match Ship’s Signal (ship’s conditions) with Required Signal.
If these two requirements match, "RUN" button will be activated.
4.2.5.3 Operation
Step 1: Select appropriate operation mode after checking related pumps and valves.
Check mode display to see if all the ballasting operation requirements are fulfilled.
Click “RUN” button on HMI Screen to start ECS.
Step 2: Ensure that message says, “Do you want to start the ECS?" Click “YES” button
Click “IMO” button or “USCG” button if HMI operation mode is not selected. v
60
Step 3: Ensure that ECU value and TRO value are displayed in 5 minutes after starting ECS.
Step 4: Click “STOP” and Ensure that message says, “Do you want to stop the ECS?"
Step 5: Click “YES” button. Stop ballast pump after stopping ECS operation.
61
*
*
*
62
LS
LS
PX
PX
63
*
*
*
* *
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
* *
* *
*
*
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*
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*
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*
*
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**
*
*
*
*
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*
*
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*
65
*
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*
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*
*
*
* *
*
*
*
*
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*
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*
*
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*
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*
* *
* *
*
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*
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*
67
**
*
*
**
*
*
*
*
*
*
68
LS
LS
PX
PX
69
4.2.7.2 Preparation
APT Solution is a procedure for ballasting / de-ballasting when APT is used as a ballas tank v
1. The A.P.T. shall be filled with the untreated ballast water using the Fire & Bilge pump
(or Fire & GS pump) in engine room.
2. When to discharge the untreated water of A.P.T, please procedure the Ballasting / De-ballasting
in the follows;
3. One of the main ballast tank shall be de-ballasted in order to transfer the untreated ballast
water in A.P.T to the ballast tank.
4. The untreated ballast water in A.P.T. shall be transfer to one of main ballast tank using
APT ballasting operation
Fire & Bilge pump(or Fire & GS pump) through Ex-ECU in hazardous area. **
5. In case of multiful chamber, select only one(1) ECU. The unused ECU should be disable
in the HMI and inlet manual valve at ECU should be closed manually.
6. The treated ballast water from A.P.T shall be discharged after neutralization as following the
procedure for de-ballasting operation.
70
* CAUTION!! Make sure that all the valves on pipelines for operation mode are open.
Alarm is activated, if ECS is not running within 5 minutes of ballast pump operation.
[CODE727] ALARM Untreated water is Flowing
Caution
71
Step 3: Ship’s Valve and Pump Signal will be displayed in Ship’s Signal.
Match Ship’s Signal (ship’s conditions) with Required Signal.
If these two requirements match, "RUN" button will be activated.
4.2.7.3 Operation
Step 1: Select appropriate operation mode after checking related pumps and valves.
Check mode display to see if all the ballasting operation requirements are fulfilled.
Click “RUN” button on HMI Screen to start ECS.
Step 2: Ensure that message says, “Do you want to start the ECS?" Click “YES” button
Click “IMO” button or “USCG” button if HMI operation mode is not selected. v
72
Step 3: Ensure that ECU value and TRO value are displayed in 5 minutes after starting ECS.
Step 4: Click “STOP” and Ensure that message says, “Do you want to stop the ECS?"
Step 5: Click “YES” button. Stop ballast pump after stopping ECS operation.
73
74
In those three(3) cases, please conduct ballast, de-ballast operation only by opening by-pass
valve and operating the ballast pump(s).
Please be noted that visual, audible alarms shall be activated and automatically recorded
upon the opening of by-pass valve when
1) the power supply(AC220V) to CPC is on.
2) HMI(Human machine Interface) is in operation.
However, please be noted that visual, audible alarms shall not be activated and automatically
recorded upon the opening of by-pass valve when HMI is not in operation due to the failure of
power supply to CPC.
In case of the failure of power supply to CPC, the record about ballast/de-ballast by opening by-
pass valve must be in writing manually.
75
When emergency by-pass operation, the event is to be recorded by HMI as below procedure.
Step 2: Click “MAINTAIN” Tap → "Emergency Bypass Mode" → Click the password.
76
Step 3: Ensure that message says, “Only Authorised person can have access to this mode. While
bypassing ballast water through this mode, ECS cannot operate and operator shall have
all legal responsibility" and Click "OK" button
77
- If ECS is abnormally stopped during operation, proper action by BWMS operator is necessary to
avoid untreated water cannot be flowed into ballast tank or un-neutralized water cannot be
discharged to sea.
- ECS do not control the ballast pump and valves, it should be carried out by BWMS operator(Crew)
- The procedure for treatment of the remaining water in the pipe between ballast pump and
BWTS ECUs is as follows.
78
79
80
5. MAINTENANCE
5.1.1 Purpose
Potential accidents during ECS operation can be prevented through a systematic mainte-
nance plan.
1. The Techcross will be responsible for all machinery or parts of machinery for guarantee
period. Under the condition of normal operation & proper maintenance use by ship’s crews
on the basis as laid down in this maintenance.
2. However, please keep in mind that Techcross shall be under no obligation with respect to
inappropriate use of our system and poor maintenance regardless of guarantee period.
3. For the safe operation of our BWMS, Regular inspection must be carried out in accordance
with the maintenance list stipulated in the below.
81
82
Step 3 : A message indicates maintenance mode will be appeared. During this message is on, ECS
cannot be operated.
Step 4 : After finishing of maintenance, authorized person should select the “maintain clear”
and then input the password so that BWMS is ready for operation.
83
Every 100
4 ECU EM cleaning
running hour
Whenever
6 TSU CLX hose flushing reagent is Refer to troubleshooting
replaced.
Whenever
7 TSU CLX Cuvette reagent is Refer to troubleshooting
replaced.
84
12 months or
in case pres-
sure difference
16 T-strainer Overhaul
between inlet
and outlet is
over 0.5bar Disassemble the strainer
85
5.4.1 TSU
< Ex-TSU (TSU Panel + Ex-CLX) >
1) Clean Ex-CLX filter and Check leakage
Step 1: Close air inlet Manual valve of Ex-CLX and Verify the "0" pressure of Regulator.
86
Step 4 : Drain the water from the filter and clean it with an air compressor (4~7kg/cm2)
Step 5 : Reassemble the filter, following instructions in reverse order (from stop 2 to step 1).
Step 6 : Check that all pipe connections and valves inside or ourside of Ex-CLX are not leaking.
※ In case that un-neutralized ballast water is contained in the DTU(Drain Tank Unit) of Ex-TSU,
To prevent this ballast water is to be discharged to overboard directly, appropriate means will
be conducted by Crew.
- To Drain
- To be transferred to ballast water line through D1 or D2 line .
87
Power shall not be restored after after enclosure has been opend untill Enclosure has
been purged for 5 minutes at a flow rete of 11,8 SLPM.
Caution
Check whether the state lamp of Ex-CLX is flicking green (Remote mode ready)
(Green : Remote mode ready, Red : Remote mode standby / Emergency mode)
88
5.4.2 ANU
1) Cleaning strainer of ANU tank
Step 1: Open the valve of drain line and drain the remaining neutralizing solution from
ANU tank.
Step 2: Clean ANU tank with freshwater.
Strainer
Step 4: Open the front cover and the side cover of ANU.
Check that all pipe connections and valves are not leaking.
89
5.4.3 PRU
1) Check leakage of cooling water connector
Step 1: Check leakage from both Inlet and Outlet cooling water connector.
Step 2: Tighten the connector using tools in case of leakage.
Step 3: Reassemble the connector if the leakage continues.
** Strainer has been installed to prevent the blockage of cooling water line from PRU.
** Crew should be checked the condition once every quarter.
90
5.4.4 T-Strainer
1. Clean the strainer if the difference between the pressure of Inlet and Outlet is over 0.5 bar.
2. Close both front and back valves of the strainer.
3. Open drain plug (4) slowly to drain all the fluid.
4. Unscrew nut (5) to remove cover (7).
5. Remove filter (8) and clean it. (Clean residuals with high-pressure water and air.)
6. Check condition of filter. If it is damaged, replace it with its cover Gasket (9).
7. Clean residuals in the strainer.
8. Reassemble the filter, following instructions in reverse order.
(Please consider the flow direction and shape of filter.)
91
When the system is not in use for long-term period due to the international purposes such as
“Don’t want to use before IMO D2 ratification” , long-term anchorage , etc
Component What to do
92
5.5.1 CPC
Power Off Main CPC
Step 1: Click “POWER” button on HMI screen of Main CPC to turn off HMI.
Step 2: Ensure that message says, “Are you sure you want to quit the ECS?"
Step 3: Click “YES” button.
Step 4: Click the password (Then HMI will be shut down. )
Step 5: Click “Turn off” button on Window XP
93
94
5.5.3 ANU
Step 1: Open the front cover and the side cover of ANU.
Check all pipe connections and valves are not leaking.
95
Step 3: Turn the draining rubber hose at the bottom of ANU facing outward.
Open drain valve (right and left side of the tank at the bottom) to drain neutralizing
solution from the tank. Use air to clean up ANU strainer.
96
5.5.4 TSU
< Ex-TSU (TSU Panel + Ex-CLX) >
Step 1: Close Sampling valves (Port 1~3).
Step 2: Close air inlet manual valve of Ex-CLX and Verify the "0" oressure Regulator.
97
5.5.5 ECU
Step 1: Close Inlet, Outlet, and Drain valves of ECU.
Step 2: Close PRU cooling water Inlet and Outlet valves of ECU.
98
5.5.6 HEU&FTU
Step 1: Close Inlet / Outlet valves for Sea / fresh water of HEU.
Close Inlet / Outlet valves for fresh water of FTU.
99
1ppm ± 5%
Calibration point Zero Setting
6ppm ± 10%
1) During general dry dock period (every five years), ECS system including the above sensors shall
be duly inspected by Techcross engineer at the owner’s account.
[In case of the above sensors, Calibration can be carried out during dry dock by service engineer
of original maker at the owner’s account.]
[The general dry dock period can be adjusted by the owner's decision according to the
subject vessel’s condition and schedule.]
2) Calibration is not necessary for other sensors (FMU/FTS/CSU/VLS If applicable. ) but ship's crews shall
periodically check the working condition of the sensors.
(1) CSU/VLSIf applicable : It is inspected by vessel's electrician as per the attached manual.
(2) FMU/FTS : If there is a malfunction on sensor, it will be replaced at a cost or free of
charge depending on the guarantee period.
3) The above procedures will be modified and complemented as per future BWMS rules and PSC
requirements.
100
5.6.1.1 GDS
1. Checking installation position
Above ECU
101
3. Calibration procedure
A. Calibration procedure
- GDS calibration item is Zero Setting only.
- It is recommended that GDS should be calibrated every 6 month.
No. Description Picture
102
103
104
A. Close air inlet manual valve of Ex-CLX after turning switch of purge controller clockwise
and open the air inlet manual valve of EX-CLX after calibration.
B. Inspection should be done during normal ballasting operation.
C. Flow rate during ballasting should remain less than ±1%. 3.2.5 The same sampling water
should be used when measured by CLX and Pocket Colorimeter.
D. Prepare a pocket colorimeter kit in the spare part case.
E. Prepare pocket Colorimeter, measurement container and Reagents
105
3. Calibration procedure
A. Error tolerance of CLX should be less than ±5%.
B. In case of 6~7ppm of TRO generation, error tolerance should be less than 10% of 6~7ppm.
C. It is recommended that CLX should be calibrated every 12 month.
106
107
108
109
5.6.2.1 CSU
< Ex-CSU >
Ex-CSU(Sensor + Tranmitter) Installation on the sea cross line or between FMU and ECU
110
F. Prepare 1000Ω register, cable and clip in the spare part case.
3. Inspection procedure
A. Error tolerance of Ex-CSU should be less than ±5%.
B. Error tolerance of the register should be less than ±5%.
C. Ex-CSU should be inspected without calibration every year.
D. Formula for conductivity : 1/1000(resistance) x 1.98 x 1000 = 1.98 mS/cm.
E. Inspection standard is in accordance with the table below.
5℃ 3.0mS/㎠ ±0.5mS/㎠
111
112
113
114
5.6.2.3 VLS
115
3. Inspection procedure
▶ VLS Power On
1 ▶ Turn on the switch of circuit breaker (DC24V)
inside the PDE to supply power to VLS.
116
5.7.1.1 Relay
Voltage: DC 24V Voltage: AC 220V
117
Step 1: Disassemble lamp part and Acryl cover with a screw driver.
Step 2: Remove lamp from the lamp part with a screw driver.
Step 3: Check socket and voltages of a new lamp and reassemble the lamp, following instructions
in reverse order (from step 2 to step 1).
Step 4: After the power is ON, check the operation state using lamp test switch.
118
Step 1: Take apart the power part of button lamp and remove the defective lamp by turning to
the left.
Step 2: Remove defective lamp by turning 90 degrees to the left while pressing inward.
Step 3: Check color and voltages of a new lamp and replace it, following instructions in reverse
order (from step 2 to step 1).
Step 4: After the power is ON, Check operation of lamp.
119
<ANU> <TSU>
Step 1: Remove body / pipe / wiring of defective SOL V/V with a screw driver and a wrench.
Step 2: Check installation direction of a new SOL V/V and replace it, following instructions in
reverse order (from step 2 to step 1).
Step 3: After the power is ON, check operation state.
120
121
Step 8: Immerse the valve in hot water (over 60℃) for 3 minutes and clean inside of the valve with
an air compressor (4~7kg/cm2).
Step 9: Reassemble the valve, following instructions in reverse order (from step 6 to step 1).
122
Previous button
Select \Valve / Pump
Valve open / Pump run
Next button
Select Valve / Pump
Valve close / Pump stop
Displayed valve open
Displayed valve close
Step 3 : Make sure that all the valves on pipelines for flushing are open/close.
* MV01 valve of ANU dosing line : CLOSE
* MV02 valve of ANU flushing line : OPEN
123
Previous button
Select \Valve / Pump
Valve open / Pump run
Next button
Select Valve / Pump
Valve close / Pump stop
Displayed valve open
Displayed valve close
Step2: Make sure that all the valves on pipelines for flushing are open/close.
* MV03 valve of TSU sampling line and MV05 valve of TSU drain line : CLOSE
* MV04 valve and MV06 valve of TSU flushing line : OPEN
124
1. Q'TY : 1EA
3 Hose Ass'y-1 2. Connection
EWU Tank (Camlock) ↔ Pump (Camlock)
1. Q'TY : 1EA
4 Hose Ass'y-2 2. Connection
Pump(Camlock)↔ECU Drain Port (10K-25A)
1. Q'TY : 1EA
2. Connection
5 Hose Ass'y-3
ECU Drain Port(10K-25A)
↔EWU Tank(Camlock)
1. Q'TY : 1EA
6 Hose Ass'y-4 2. Connection
Pump (Camlock) ↔ EWU Tank (Camlock)
125
126
Please refer to the Table 1 (below) for the appropriate amount of cleaning agent and
fresh water.
ECS 150 60 80 8 10
ECS 300 80 100 10 10
ECS 450 110 130 13 10
ECS 600 140 160 16 10
ECS 1000 250 270 27 10
127
128
129
3. Cleaning interval
- Recommended cleaning cycle is approximately 100 hours of operation.
- In case of multiful chamber, repeat the process to each ECU same as Ch.7.1.4 .
130
5.7.5 When HEU / FTU are located in BWTS room on deck without heater
5.7.5.1 When HEU / FTU are located in BWTS room on deck without heater
1. Fill the tank with anti-freezer and cooling water (Refer to 1.5.3 cooling mixture ①~⑥) up to
more than medium level of FTU.
5. Refill the tank with cooling water up to more than medium level of FTU after 2 and 3.
131
• Anti-freeze liquid is hazardous to health. Avoid contact with the eyes and skin.
Never use only water as coolant because it will cause corrosion and cavitation.
Caution
•
132
Spare parts of ECS component installed on ship are defined as the supplies (incl. supplies for
repair) of parts. The spare parts in the ECS manual is classified into standard spare parts and
additional consumable parts of ECS component.
133
134
135
For the information about ECS dealers, please visit TECHCROSS website http://www.techcross.com
136
6. TROUBLESHOOTING
1. Click one of four items on "All / Normal / Warning / Trip" to sort out the list of alarms.
A. “ALL” button: All of log level will be sorted & displayed.
B. “Normal” button: Only the NORMAL part of log level will be sorted & displayed
C. “Alarm” button: Only the ALARM part of log level will be sorted & displayed.
D. “Trip” button: Only the TRIP part of log level will be sorted & displayed.
2. Click one of two items on "TODAY / ALL" to sort out the list of alarms.
A. “TODAY” button: Only the alarms which occurred on today will be sorted & displayed.
B. “ALL” button: All alarms during operation will be sorted & displayed.
137
138
(1) Check that sodium thiosulfate has been added to ANU tank.
TSU (2) Check if other valves except the valve for sampling are closed.
Trouble (3) Check that the valve for sampling is not clogged up and pump
shooting in the ANU is properly working.
(4) If TRO level is over standard when neutralizing agent is injected
properly, contact Techcross A/S team.
Fault
139
Fault
Trouble
(1) Put sodium thiosulfate into the tank according to the manual.
shooting
[CODE302]ANU Tank Level Low[1].
Error message
[CODE302]ANU Tank Level Low[2].
Fault
Fault
140
ANU Fault
(1) Check if voltage from MSBD is normal after turning off MCCB of
PDE.
Trouble
(2) If voltage from MSBD is normal, measure insulation resistance of
shooting
PMU ECS.
(3) If insulation fails, contact Techcross A/S team
Trouble
Check whether the voltage from MSBD is normal or not
shooting
141
Alarm
Flow rate >110% m3/h (Immediately)
(warning)
IMO
Fault Flow rate >115% m3/h (Consecutive during 1 minutes)
* Normal operation
Alarm Flow rate >110% m3/h (Consecutive during 3 minute)
(warning) * Mixing operation
Flow rate >80% m3/h (Consecutive during 3 minute)
USCG
* Normal operation
Flow rate >110% m3/h (Consecutive during 5 minute)
Fault
* Mixing operation
Flow rate >80% m3/h (Consecutive during 5 minute)
(1) Regulate the flow rate so that the flow does not exceed 110%
of ECS capacity.
(2) If flow rate on HMI shows -20 value, check if power supply
Trouble
and cable connection of FMU are normal.
shooting
(3) If they are normal, refer to the troubleshooting for sensor
FMU
failure as described in communication.
(4) If FMU display shows errors, contact Techcross A/S team.
Alarm
Flow rate < 15% m3/h (Immediately)
(warning)
IMO
Fault Flow rate < 10% m3/h (Consecutive during 1 minutes)
Alarm
Flow rate < 15% m3/h (Consecutive during 3 minute)
(warning)
USCG
Fault Flow rate < 15% m3/h (Consecutive during 5 minute)
(1) Regulate the flow rate so that the flow can exceed at least
15% of ECS capacity.
(2) If flow rate on HMI shows -20 value, check if power supply
Trouble
and cable connection of FMU are normal.
shooting
(3) If they are normal, refer to troubleshooting for sensor failure
as described in communication.
(4) If FMU display shows errors, contact Techcross A/S team.
142
GDS (1) Turn off MCCB of PDE or MSBD and check if alarm for H2 gas rings
through AMS of the vessel.
(2) Check if there is any leakage of H2 gas with H2 gas detector
Trouble equipped in the vessel.
shooting (3) If alarm rings or GDS shows - 20 value when there is no leakage of
H2 gas, check if power and cable connection is normal.
(4) If no problem is found, refer to the troubleshooting for sensor
failure.
Alarm (warning)
143
Fault
Alarm (warning)
ECS Fault
(1) Check if signal from VRCS and signal shown on HMI match
Trouble according to the manual.
shooting (2) If two signals do not match, check cable connection.
(3) If alarm persists, contact Techcross A/S team.
144
Alarm (warning)
145
146
6.3.1 TSU * Below image can be different from actual system. The process is same regardless of type of
TRO sensor (Non-ex type / Ex-type)
Cause :
□ In case sampling water flows into the cuvette of CLX normally but TRO value is low.
□ In case sampling water doesn't flow into the cuvette of CLX.
□ In case sampling water cannot be measured due to contaminated cuvette.
□ In case of malfunction of APU (Air pump unit)
Troubleshooting :
1) In case sampling water flows into the cuvette of CLX normally but TRO value is low.
147
2) In case sampling water does not flow into the cuvette in the CLX.
148
□ Check the Y-strainer if sampling is not properly even though Sol. valves are i
n normal condition.
149
150
② In case of the discharge line blockage, disassemble and check TSU Sol.
valves connected to each port.
151
152
Cause :
□ In case of abnormal setting of CLX
Troubleshooting :
153
Cause :
□In case of abnormal CLX setting
Troubleshooting :
6.3.2 ANU
Cause :
□ In case ANU metering pump is not working properly.
□ In case Sol. valves are clogged.
Troubleshooting :
154
155
Cause :
□ In case no power supply to ANU.
□ In case communication fail between ANU and CPC.
Troubleshooting :
- Check power supply and communication status of ANU.
156
Cause :
□ In case neutralizer in ANU tank runs out.
□ In case input Sol. valves are clogged.
Troubleshooting :
- Check if ANU tank is automatically re-filled with freshwater.
157
Cause :
□ In case ANU tank requires addition of sodium thiosulfate to ANU tank.
Troubleshooting :
- Add Sodium thiosulfate to each tank of ANU.
(It should be handled with protective equipment.)
158
Cause :
□ EM'CY mode is set on the ANU control panel.
Troubleshooting :
- Ensure that "REMOTE" mode is set on ANU control panel (XGT).
159
6.3.3 PDE
160
Cause :
□ In case of RTU (PDE) communication failure
□ In case communication fail between CPC and each equipment.
Troubleshooting :
① Check RTU power and communication.
161
Cause :
□ In case of RTU (PDE) communication failure
□ In case communication fail between CPC and each equipment.
Troubleshooting :
① Check communication and operation status of ESJ.
162
Cause :
□ In case no power supply to GDS.
□ In case HMI is turned on before the completion of loading time for GDS (1min.).
□ In case communication fail between CPC and GDS.
Troubleshooting :
① Check power supply of GDS and communication status after completion
of loading time of GDS (1 min.).
- Check communication ststus of ADAM6017
- Check connection of LAN cable
- Check connection of termical jack.
- Check LAN cable connection and LED light between HUB and ADAM6017
Cause :
□ In case communication fail between CPC and Unit.
Troubleshooting :
① Check power and communication status of Sensor.
- Check communication ststus of ADAM6017
- Check connection of LAN cable
- Check connection of termical jack.
- Check LAN cable connection and LED light between HUB and ADAM6017
163
Cause :
□ In case no power supply to FMU.
□ In case communication fail between CPC and FMU.
Troubleshooting :
① Check power and communication status of Sensor.
- Check communication ststus of ADAM6017
- Check connection of LAN cable
- Check connection of termical jack.
- Check LAN cable connection and LED light between HUB and ADAM6017
Cause :
□ In case communication fail between CPC and FTS.
Troubleshooting :
① Check power and communication status of Sensor.
- Check communication ststus of ADAM6017
- Check connection of LAN cable
- Check connection of termical jack.
- Check LAN cable connection and LED light between HUB and ADAM6017
164
Cause :
□ In case PMU does not work properly.
□ In case communication fail between CPC and PMU.
Troubleshooting :
① Check power and communication status of Sensor PMU.
165
6.3.4 CPC
Troubleshooting :
① Check the power (DC24V & AC220V) supply to CPC.
166
Troubleshooting :
① Check LAN communication status between remote CPC and local one.
(LAN lamp flashes)
In case of LAN disconnection, please check and reconnect the cable properly.
Please check if CPC LAN cable is connected to hub inside PDE as well as the signal
is flickering when the HMI of CPC is in working order.
167
Cause :
□ In case of GPS communication failure from the wheelhouse to CPC
Troubleshooting :
① Please check GPS data reception as follows
168
6.3.5 PRU
169
- Check cooling fresh water line circulation and cleanup the valves.
170
171
Cause :
□ In case operate the system when CSU value is less than 2ms/ms (about. 1PSU).
Temp ℃
PSU 5 10 15 20 25 30 35 40
※ This table is based on the data given by UNESCO. Conductivity is theoritically calculated based on
the relationship with temperature and PSU. Therefore the value in the table an the actual measured
value could be different because of the range of error and characteristics of the sensor.
Troubleshooting :
- Check whether the measure value of CSU below 2ms/cm(1PSU) and EM and
bus-bar connection.
172
[3] VLS (Vibration level sensor) error (only for VLS applied vessel)
Cause :
□ In case ECU in/outlet valves are closed.
□ In case sea water is not fully filled with ECU.
173
Troubleshooting :
① Check if ECU in/outlet manual valves are opened properly.
- Check the status of ECU in/out valves and if ECU is fully filleed with sea water.
* In case of vertical ECU installation, the VLS can be installed on the outlet of ECU only.
Cause :
□ In case of PRU power/communication cable connection error
□ In case of PRU fuse error
Troubleshooting :
① Inspect PRU power/communication cable connection.
174
6.3.6 Sensor
[1] FMU (Flow meter unit) check
Cause :
□ In case FMU is normal but there is no actual flow rate.
□ In case of FMU fault
Troubleshooting :
175
Cause :
□ FTS fault.
Troubleshooting :
176
Cause :
□ In case of gas alarm & trip
Troubleshooting :
177
□ When the cartridge is required to be replaced, do not touch the pin inside
of GDS. (Refer to APPENDIX II)
178
7. ADDITIONAL FUNCTION
179
7.1.1 LOG
ECS records proper function status and failure of BWMS operation. This is implemented as LOG
function and LOG function makes it possible to confirm and save every situation occurring during
the ECS operation.
As shown below, normal operating status, alarms and fault (trip) situations of BWMS are recorded
in ECS.
180
And operators can convert recorded logs in PDF form. To check the log data,
- Click
on each “EVENT”, “OPTIME”, “DATE”, “MAINTAIN” tab to choose the period of log data.
- After selecting the date, the selected date is shown on the screen by clicking “OK” .
If clicking “TODAY” , the records saved today is shown on the screen, and clicking “ALL", all records
is shown.
- Click “PDF” on upper side of the page. After pop up the window, choose one or more options
and click “CREATE” to save the log data as PDF file.
181
After converting to PDF, recorded logs can be saved as PDF file below directory.
- c:\TECHCROSS\V2\ECS\Log
- d:\
- Inserted USB driver or External HDD which are connected with CPC of ECS.
Below shows reference of converted PDF document.
And for more detailed reference, please find reference report.
182
① Operation and abnormal status of all equipment connected to ECS can be check in EVENT tab.
It can be categorized by LEVEL. Please see below.
② OPTIME shows the information of operations such as operation time, location, operated line
and that sort of things. It can be checked separately by date and operation mode. Please see
below for more details.
183
③ Data tab on LOG page includes the variation of values according to the time. It is also available
to be checked separately by date. Please see below.
④ History of ECS maintenance can be check in "MAINTAIN" tab by selecting “SELECT UNIT” and
“SELECT WORK” sessions.
A. The ANU neutralizer supplement is recorded automatically.
B. Click “ REGISTER” to make cleaning records with selecting line which is cleaned before.
C. Click “REGISTER” to make TSU reagent changing records with selecting TSU.
184
7.1.2 ABNORMAL
Abnormal status records are indicated on "ABNORMAL" page. In case administrator is aware of the
reason of abnormal, it can be set to be invisible using "INHIBIT" function when they do not want
to know anymore. Please see below for more details.
① In case of alarm situation, the text will be shown on a yellow background, and “TRIP”
situation the text will be shown on a red background.
② After solve the abnormal situation, click “RESET” to remove.
③ Registration of inhibit conditions : Click “INHIBIT” and enter the password. Please make sure
that the user must be aware of abnormal situations before set the inhibit function.
④ Removal of inhibit
185
7.1.3 OP MODE
"OP MODE" page shows the preparation for ECS operation which helps operator check ECS
operation comparing current signals to signals needed on each mode. Please see below for more
details.
186
7.1.4 STATUS
187
All status and the measurement values of ECS analog components can be checked in this
section.
188
Status and signal of ECS digital components can be checked in this section.
189
7.1.5 ADMIN
Admin page can set an equipment of ECS such as ECU, TSU(CLX), ANU(PUMP), and sensors as
disabled to forcely operate ECS in case of that equipment is faulty or broken down.
*CAUTION : When equipment is set disabled, additional trouble on the disabled equipment
cannot be detected. Once trouble is solved, it is required to set the equipment enabled.
① Click the equipment to disable (color changes into grey) and click again to enable (color
changes into green).
190
7.1.6 COMM(Communication)
The communication among ECS components connected to PDE can be monitored in real time.
① Normal operation: BLUE / Abnormal operation: RED
② Numbers in square mean the quantity of equipment and order.
191
Operator easily can get information of ECS components from HMI. If some errors occur during the
ECS operation, color of symbols will be changed to yellow or red. Click the symbols on HMI home
screen to see more details of each ECS component.
7.1.7.1 PMU
Operation signs of PMU
Digital power meter checks input power and current consumption of main power supplied for
PDE. Measurement values will be shown on LCD screen of DPM.
192
193
There are two CLX sensors installed in TSU. HMI indicates the measured value by using an
activated CLX of two.
194
There are two fresh water tanks to inject neutralization solution. In case of normal
communication state during deballasting, ANU is displayed on HMI screen as above. If one
fresh water tank uses up neutralization solution, the other fresh water tank is filled with
neutralization solution automatically. Then, fresh water is automatically supplied to a fresh
water tank using up the solution and indication lamp is on HMI screen if fresh water is filled
up to a specific level. When indication lamp is on ECS operator have to inject neutralization
solution then operate the agitator.
195
7.1.7.5 SENSORS
The sensors installed on ECS are indicated on HMI main screen as follows.
Sensor Description
196
Caution!!!
Carelessness in the above may cause fatal error of ECS due to the residual current.
197
Digital Power Meter is a microprocessor-based unit, and measures all the powers in the PDE. The
measured values can be read from the built-in display. By pressing 4 buttons marked as H, P, E and
V/A, you can read off the measured voltage and amperes of the PDE.
198
7.2.2 RCM(M1)
RCM consists of 4 Digit 7-Segment LEDs, and MODE / SET buttons; setting and checking menus as
well as controlling and monitoring PRU will be done with the buttons.
199
7.2.3 RCM(M4)
RCM consists of 4 Digit 7-Segment LEDs, and MODE / SET buttons; setting and checking menus as
well as controlling and monitoring PRU will be done with the buttons.
200
7.2.4 TSU
201
1 2
3 4
8 5 6 7 9
The text shadow is changed and dark color indicates the current selection
202
1. PASSWORD UNLOCK
2. PASSWORD LOCK
3. PASSWORD CHANGE
4. DATE/TIME SET
5. BUZZER VOLUME SET
6. BACK LIGHT SET
7. DOWNLOAD SPEED
8. SYSTEM INFORMATION
203
7.2.5 ANU
204
1 3
2 4
8 9 5 6 7 10
205
Agent to put into the left tank Agent to put into the right tank
Left fresh water tank not Right fresh water tank not
ready ready
Left fresh water tank ready Right fresh water tank ready
Abort the chosen valve in the Abort the chosen valve in the
direction of P#1 direction of P#2
Abort the valve on the left Abort the valve on the right
fresh water tank fresh water tank
Choose the valve on the left Choose the valve on the right
fresh water tank fresh water tank
Supply the left fresh water Supply the right fresh water
tank with fresh water tank with fresh water
206
8. APPENDIX Ⅰ
The hypochlorite solution produced in the electrolysis unit is much more highly concentrated
compared to the hypochlorite solution diluted to the ballast water.
If splashed onto skin it should be washed off, removing any affected clothing. If the eye is affected,
irrigate immediately using an approved eyewash station or fresh running water for at least 15
minutes, keeping the eyelid open and rotating the eye. Seek medical treatment immediately. If
swallowed, do not induce vomiting. Keep patient warm and quiet and seek immediate medical
help. If breathing stops, apply rescue breaths and cardiopulmonary resuscitation as necessary
until medical help arrives.
Warning notices advising operatives of the possible dangers should be prominently displayed
wherever hypochlorite is generated
Warning
TRO solution is alkaline and will cause oxidisation and bleaching. It is corrosive and could cause damage to
skin or clothing. When handling solution we recommend wearing protective clothing and goggles.
Before carrying out any form of inspection, maintenance or repair work on the system, operatives
must carry out tests to ensure that the plant has been satisfactorily isolated.
207
The electrolytic process of converting brine into sodium hypochlorite generates very low
concentration of hydrogen gas which is flowed in to the ballast tank during ballast operation by
ECS. There are no reports that there is potential effect by low concentration of hydrogen gas on a
Vessel’s infrastructure so far. But for the precaution and prevention for H2 gas, the GDS is installed
in ECS installed area.
The equipment should be regularly checked to ensure that no gas leakages occur. Always use
a hydrogen detector to check for leakages, never a match or any form of naked flame. A sign
prohibiting smoking and naked flames should be displayed within the room.
If required, a hydrogen detector can be fitted within the plant room to inhibit the Electro-Cleen™
System in the unlikely event of a build-up of hydrogen levels, thereby preventing the situation of
an operator ever working in a potentially explosive environment.
Warning
When checking equipment only hydrogen detectors should be used, never use a match or any type of flame.
The residual oxidant in the treated water is automatically neutralized by ANU. The Neutralizing
material applied to ANU is sodium thiosulfate. The caution is required to the operator who carries
and inserts neutralizing material to ANU.
If the eye is affected, Flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. Get medical aid.
208
Warning
When handling agent and solution, avoid breathing dust, avoid contacting with skin and eyes. We
recommend wearing protective clothing and goggles.
The stored water in the ballast tank after electrolysis may contain TRO, which is not degraded for a
long time. Even after the ballast water tank is empty, the harmful gas(H2 gas) may be still present
in the air of the tank.
When personnel enters to the ballast tank for the inspection etc., below procedure should be
followed.
- allow sufficient time for the space to be thoroughly ventilated naturally or mechanically
- emptying of a full ballast tank and thereby replacing the atmosphere in the tank;
- full ventilation of a ballast tank prior to personnel entry;
- atmosphere testing before tank entry and regularly testing throughout tank entry
- do not enter an enclosed space alone – enter in pairs and monitor each other
- continuous ventilation during tank entry;
- adequate lighting
- respiratory protection; or breathing apparatus equipment available
- skin and eye protection.
Due to the range of hazardous chemicals any information provided in this section is only
general. It is the duty of the operative to ensure that they have obtained information on all safety
precautions relevant to the type of task they are undertaking and to ensure that they are adhered
to. "Grundfos Alldos" would recommend that good practice is always followed when handling
209
any substance, to include the use of basic ’personal protective equipment’ such as ventilated,
enclosed goggles, face shields, chemical aprons, boots and gloves. An eye irrigation unit may also
be advisable.
The Active Substance (AS), as produced by the Electro-Cleen™ System and their simulated
concentrations, are presented in Table below. A chlorine-based compound, hypochlorous acid,
is commonly accepted term for measuring biocide and/or algaecide concentration. Therefore,
the TRO term will be used in this application and it will be conservatively assumed that all TRO is
composed of HOCl.
210
8.3 MSDS
0.1 mg/L/0.417 d
3.0832/15 d 0.8976/- 0.87
(Acute LC50, Fish)
NO NO
NO
a
Persistence Half life : > 60 days in marine water
or > 40 days in freshwater
or > 180 days in marine sediment or > 120 days in freshwater sediment.
b
V, numerical value from ultimate biodegradation timeframe model; T, total degradation time
c
Bioaccumulation: BCF > 2,000 or log Pow ≥ 3.
d
B, BCF from Arnot-Gobas Method; P, log Pow
e
Toxicity: Chronic NOEC < 0.01 mg/L.
GHS CLASSIFICATION**
Physical hazards Health hazards Environmental hazards
Corrosive to metals:
Category 1
AQUATIC ORGANISM TOXICITY – This active ingredient of this product is expected to be toxic
to aquatic organisms. However, the low concentration in the solution makes it unlikely that
mammals and other warm-blooded organisms will be harmed by incidental contact with
this product. Aquatic organisms and air-breathing amphibians and reptiles may have greater
exposure and effects (Wysiwash, 2010).
211
Crustacea
N/A
Toxicity
4. Sediment Toxicity – Hypochlorous acid might be not to have the potential to be absorbed to
sediments to a significant extent based on their low Koc (< 500 L/kg) (IMO, 2011a).
5. Bioconcentration
Measured/Calculated Reference
212
MAMMALIAN TOXICITY
Dermal LD50
N/A
(mg/kg)
Inhalation LC50
N/A
(mg/kg/4 hr)
Oral LD50
Mouse, Rat 14 mg/kg/d IMO, 2011a
(mg/kg)
Dermal LD50
N/A
(mg/kg)
Inhalation
LC50 N/A
(mg/kg/4 hr)
8. Corrosion/Irritation
Species Method Results Refernce
213
9. Sensitization
Skin N/A
10.Repeated-Dose Toxicity – From the literature, in case of hypochlorous acid, the repeated
dose toxicity on oral intake of rats is reported as NOAEL 10 mg/kg/day after exposed 90 days of
drinking water. That on oral intake of mice is reported that spleen/liver weight of mice depressed
in males, but not females at the higher doses (IMO, 2011a).
214
ENVIRONMENTAL FATE
Hydrolysis pH 5
Hypochlorous acid decay in seconds to hours;
this is after all their mechanism of action and how
Hydrolysis pH 7 they produce an oxidizing environment. As a
consequence of this oxidizing environment, along
with the presence of organic matter, THMs and IMO, 2011a
HAAs are also produced. Biotic degradation for all
Hydrolysis pH 9 of these simple halogenated organic compounds is
on the order of days to weeks.
Abiotic degradation of these compounds is longer.
Biodegradatioin
Flammability
N/A
(flash point for liquids; °C)
1.85E-012 mmHg at 25 °C
Vapour pressure (20°C; Pa) EPI Suite, 2012
(MPBPVP v. 1.43)
215
pH in solution N/A
Surface tension
N/A
(newtons/m (SI) or dynes/cm (cgs))
1.28E-019 atm-m3/mole
Henry’s Law Constant (Pa.m3/mol) EPI Suite, 2012
(via VP/WS estimate)
- 0.87
Log Pow (Kow) EPI Suite, 2012
(KOWWIN v. 1.68)
216
217
218
Remove all contaminated clothing. For skin contact, wash thoroughly with soap and water for at
least 20 minutes. Seek immediate medical attention if irritation develops or persists.
First Aid: Ingestion
DO NOT INDUCE VOMITING. If swallowed, wash out mouth with water provided person is
conscious. Never give anything by mouth to a victim who is unconscious or having convulsions.
Contact a physician or poison control center immediately.
First Aid: Inhalation
Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is
not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance;
induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Administer oxygen if breathing is difficult. Get immediate
medical attention.
First Aid: Notes to Physician
Provide general supportive measures and treat symptomatically.
219
220
secondary containers or in a diked area, as appropriate. Store containers away from incompatible
chemicals (see Section 10, Stability and Reactivity). Storage areas should be made of corrosion-
and fire resistant materials. Post warning and “NO SMOKING” signs in storage and use areas, as
appropriate. Use corrosion-resistant structural materials, lighting, and ventilation systems in the
storage area. Floors should be sealed to prevent absorption of this material.
Inspect all incoming containers before storage, to ensure containers are properly labeled and not
damaged. Have appropriate extinguishing equipment in the storage area (i.e., sprinkler system,
portable fire extinguishers). Empty containers may contain residual particulates; therefore, empty
containers should be handled with care. Do not cut, grind, weld,or drill near this container. Never
store food, feed, or drinking water in containers that held this product. Keep this material away
from food, drink and animal feed. Do not store this material in open or unlabeled containers. Limit
quantity of material stored.
221
222
223
Epidemiology
Prolonged skin contact may cause allergic skin reactions (allergic dermatitis).
Neurotoxicity - No information available.
Mutagenicity - No information available.
Teratogenicity - No information available.
Other Toxicological Information
Thiosulfate occurs naturally in the body.
224
225
exceed 1kg. The inner receptacles must be securely packed in an intermediate packaging with
cushioning material to prevent movement in the inner receptacles and packed in a strong outer
box with a gross mass not to exceed 29kg. The completed package must meet a drop test. The
requirements are found in 2.7.6.1. The package must not be opened or otherwise altered until it
is no longer in commerce. For air transportation no shipping paper is required. The package must
be legibly marked with the following marking:.
NOTE: The “*” must be replaced by the primary hazard class, or when assigned, the division of
each of the hazardous materials contained in the package. The “**” must be replaced by the
name of the shipper or consignee if not shown elsewhere on the package. The symbol shall be
not less than 100 mm x 100 mm and must be durable and clearly visible.
International Maritime Organization (I.M.O.) Classification
I.M.O. Classification: Sodium Thiosulfate is not regulated under I.M.D.G./I.M.O. regulations.
Sodium
Thiosulfate No No No Yes Yes
10102-17-7
226
State Regulations
A: General Product Information California Proposition 65
Sodium Thiosulfate is not on the California Proposition 65 chemical lists.
B: Component Analysis – State
Component CAS # CA FL MA MN NJ PA
Sodium
Thiosulfate No No No No No No
10102-17-7
Other Regulations
A: General Product Information
Not determined.
B: Component Analysis – Inventory
Component CAS # TSCA DSL EINECS
Sodium
Thiosulfate Yes Yes Yes
10102-17-7
227
228
Trade name: Hydrogen High Purity, Hydrogen CP Grade N5.0, Hydrogen Research Grade
N5.5, Hydrogen Zero Grade N4.5
Additional identification
Chemical name: hydrogen
Chemical formula: H2
INDEX No. 001-001- 00- 9
CAS-No. 1333- 74- 0
EC No. 215-605- 7
REACH Registration No. Listed i n Annex IV/ V of Regulati on (EC) No 1907/ 2006 (REACH) , exempt ed
from regi stration.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Indust rial and professional. Perf orm ri sk assessment prior t o use.
Aerosol propellant. Bal ance gas for mixtures. Calibration gas. Carrier gas.
Chemical synt hesis. Combust ion, melting and cutt ing processes. Fuel cells.
Fuel gas for w el ding, cutti ng, heati ng, brazing and soldering applicati ons.
Laborat ory use. Laser gas. Process gas. Test gas.
Consumer use.
Fuel gas Propell ant gas. Shielding gas in gas w elding.
Uses advised against This gas i s not i nt ended t o be filled into ball oons f or consumer use and
adverti sing purposes because of t he danger of expl osion. Do not infl at e
commerci al ball oons.
E-mail: ReachSDS@boc.com
SDS_GB - 000010021694
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F+; R12
Physical Hazards
Flammable gas Category 1 H220: Extremely fl ammabl e gas.
Gases under pressure Compressed gas H280: Contai ns gas under pressure; may explode i f
heat ed.
Precautionary St atement
Prevention: P210: Keep aw ay f rom heat, hot surfaces, sparks, open fl ames and ot her
i gni tion sources. No smoki ng.
Response: P377: Leaki ng gas fire: Do not ext inguish, unl ess leak can be stopped safely.
P381: Eli minate all ignition sources if saf e to do so.
Disposal: None.
SDS_GB - 000010021694
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3.1 Substances
General: In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/ consciousness. Victi m may not be aw are of asphyxiation. Remove victim
t o uncont aminat ed area w eari ng sel f contained breat hing apparatus. Keep victim
w arm and rested. Call a doctor. Appl y arti fici al respirat ion if breat hi ng st opped.
Eye cont act: Adverse eff ect s not expected from this product .
Skin Contact : Adverse eff ect s not expected from this product .
4.3 Indication of any immediat e medical attention and special treatment needed
Hazards: None.
Treatment: None.
SDS_GB - 000010021694
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General Fire Hazards: Heat may cause t he contai ners to expl ode.
Special prot ective equipment Fi refighters must use standard prot ective equi pment including flame ret ardant
for firefight ers: coat, hel met w i th face shield, gloves, rubber boots, and in encl osed spaces, SCBA.
Guideline: EN 469 Prot ect ive clothing for firefi ght ers. Performance requirements
f or protective clothing f or firef ight ing. EN 15090 Foot w ear for firefi ght ers. EN 659
Prot ective gl oves for firef ight ers. EN 443 Helmets for fire fighting in buil di ngs and
ot her st ruct ures. EN 137 Respirat ory protective devices - Self-cont ai ned open-
ci rcuit compressed air breat hing apparatus w ith full face mask - Requi rements,
t est ing, marking.
6.1 Personal precautions, Evacuat e area. Provi de adequat e ventil at ion. Consi der the ri sk of pot ent ially
protective equipment and explosive atmospheres . Eli minate all i gnition sources if saf e to do so. Moni tor t he
emergency procedures: concent rati on of the rel eased product. Prevent from ent ering sew ers, basements
and w orkpits, or any place w here it s accumul ation can be dangerous. Wear self-
contained breat hing apparat us w hen ent ering area unl ess atmosphere is proved
t o be saf e. EN 137 Respirat ory prot ective devices - Self-cont ai ned open-circui t
compressed ai r breat hing apparat us w i th full f ace mask - Requi rements, testi ng,
marki ng.
6.2 Environment al Precautions: Prevent furt her l eakage or spillage if saf e to do so.
6.3 M ethods and mat erial for Provide adequat e venti lation. Elimi nat e sources of igniti on.
containment and cleaning up:
SDS_GB - 000010021694
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7.1 Precautions for safe handling: Only experi enced and properly i nstructed persons shoul d handle gases under
pressure. Use only properl y speci fied equi pment w hich is suitable f or t his product,
i ts supply pressure and temperature. Purge syst em w ith dry inert gas (e.g. hel ium
or nitrogen) bef ore gas i s i nt roduced and w hen syst em i s placed out of service.
Purge air from system before introducing gas. Containers, w hi ch cont ai n or have
contained flammable or explosive subst ances, must not be inert ed w ith liquid
carbon dioxide. Assess t he risk of a potentiall y expl osi ve at mosphere and t he
need for suit abl e equipment i.e. explosion-proof. Take precautionary measures
against st at ic discharges. Keep aw ay from i gnition sources (including st atic
discharges) . Provide electri cal earthing of equipment and el ectrical equipment
usable in explosive atmospheres. Use only non-sparki ng tool s. Refer to suppli er's
handl ing instructi ons. The substance must be handl ed i n accordance w ith good
i ndustri al hygiene and safet y procedures. Ensure t he complet e system has been
( or is regularly) checked for leaks bef ore use. Prot ect cont ai ners from physical
damage; do not drag, rol l, slide or drop. Do not remove or deface l abels provi ded
by t he supplier for t he i denti ficati on of the cont ai ner contents. When moving
containers, even for short distances, use appropriate equipment eg. trol ley, hand
t ruck, fork truck etc. Secure cyli nders i n an upright position at all times, close all
valves w hen not in use. Provi de adequat e ventil at ion. Suck back of w at er into the
container must be prevent ed. Do not al low backfeed into the cont ainer. Avoi d
suckback of w at er, acid and alkalis. Keep container below 50° C in a w ell
ventil at ed pl ace. Observe all regul at ions and local requirement s regardi ng storage
of cont ai ners. When usi ng do not eat, drink or smoke. Store in accordance w i th
l ocal / regional / national/ internati onal regul at ions. Never use direct fl ame or
electrical heating devi ces to rai se the pressure of a cont ainer. Leave val ve
protection caps i n pl ace unti l the container has been secured agai nst either a w all
or bench or placed in a contai ner stand and i s ready for use. Damaged valves
should be reported immediately t o the suppli er Close container valve aft er each
use and w hen empty, even i f still connect ed t o equipment. Never at t empt to
repair or modify cont ainer valves or saf et y reli ef devi ces. Repl ace valve outlet
caps or pl ugs and container caps w here suppli ed as soon as container i s
disconnect ed from equipment. Keep cont ai ner val ve outl et s clean and free from
contaminat es particularl y oil and w at er. If user experiences any di fficult y
operating cont ai ner val ve di sconti nue use and cont act suppli er. Never att empt to
t ransf er gases from one contai ner to anot her. Container valve guards or caps
should be in pl ace.
7.2 Conditions for safe storage, All electri cal equi pment in t he st orage areas shoul d be compatibl e w ith the risk of
including any incompatibilities: a pot entiall y expl osi ve atmosphere. Segregat e f rom oxidant gases and ot her
oxidants being st ored. Cont ai ners should not be st ored i n conditions li kel y to
encourage corrosion. Stored containers should be peri odicall y checked for general
condi tions and leakage. Container valve guards or caps should be in place. Store
containers i n location free f rom fi re ri sk and aw ay from sources of heat and
i gni tion. Keep aw ay from combustible mat erial.
SDS_GB - 000010021694
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General informat ion: A risk assessment should be conduct ed and document ed in each w ork area to
assess t he risks rel at ed t o the use of the product and to select t he PPE that
mat ches t he rel evant risk. The f ollow ing recommendations shoul d be consi dered.
Keep sel f cont ained breat hing apparatus readil y available for emergency use.
Personal protective equi pment f or the body should be select ed based on the task
being performed and t he risks i nvolved. Refer to local regulati ons for restriction of
emi ssions to the atmosphere. See sect ion 13 for specifi c methods for w ast e gas
t reat ment. Do not eat , dri nk or smoke w hen usi ng t he product.
Eye/ face protection: Wear eye prot ection t o EN 166 w hen usi ng gases.
Guideline: EN 166 Personal Eye Prot ection.
Skin protection
Hand Protect ion: Wear w orki ng gl oves w hi le handling cont ainers
Guideline: EN 388 Prot ect ive gloves against mechanical risks.
Hygiene measures: Specifi c ri sk management measures are not required beyond good indust ri al
hygiene and safet y procedures. Do not eat, drink or smoke w hen using t he
product .
SDS_GB - 000010021694
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10.1 Reactivity: No reactivit y hazard ot her than t he eff ect s descri bed i n sub- secti on below .
SDS_GB - 000010021694
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10.3 Possibility of Hazardous Can form a potenti ally explosive atmosphere in air. May react violent ly w i th
React ions: oxidants.
10.4 Conditions to Avoid: Keep aw ay from heat, hot surf aces, sparks, open flames and other igniti on
sources. No smoking.
10.5 Incompatible M aterials: Air and oxi di sers. For material compati bilit y see latest versi on of ISO-11114.
10.6 Hazardous Decomposit ion Under normal condit ions of st orage and use, hazardous decomposition product s
Products: should not be produced.
Carcinogenicity
Product Based on avail able data, the classification criteria are not met.
SDS_GB - 000010021694
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Aspiration Hazard
Product Not appl icable to gases and gas mixtures..
12.1 Toxicity
Acute toxicity
Product No ecol ogi cal damage caused by this product .
12.6 Other Adverse Effects: No ecol ogi cal damage caused by this product .
General informat ion: Do not discharge into any place w here its accumulati on coul d be dangerous.
Consul t supplier for specifi c recommendations. Do not discharge into areas w here
t here i s a risk of forming an explosive mixt ure w ith ai r. Waste gas should be f lared
t hrough a suitable burner w i th fl ash back arrest or.
Disposal methods: Refer t o the EIGA code of pract ice ( Doc.30 "Disposal of Gases", dow nloadable at
htt p:/ / w w w .ei ga.org) for more guidance on sui tabl e disposal methods. Di spose
of cont ai ner vi a suppl ier only. Di scharge, treat ment, or di sposal may be subject to
national, state, or local law s.
SDS_GB - 000010021694
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ADR
14.1 UN Number: UN 1049
14.2 UN Proper Shipping Name: HYDROGEN, COMPRESSED
14.3 Transport Hazard Cl ass( es)
Class: 2
Label (s): 2.1
Hazard No. (ADR): 23
Tunnel rest ricti on code: (B/ D)
Emergency Action Code: 2SE
14.4 Packing Group: –
14.5 Environmental hazards: not applicable
14.6 Special precautions for user: –
RID
14.1 UN Number: UN 1049
14.2 UN Proper Shipping Name HYDROGEN, COMPRESSED
14.3 Transport Hazard Cl ass( es)
Class: 2
Label( s): 2.1
14.4 Packing Group: –
14.5 Environmental hazards: not applicable
14.6 Special precautions for user: –
IMDG
14.1 UN Number: UN 1049
14.2 UN Proper Shipping Name: HYDROGEN, COMPRESSED
14.3 Transport Hazard Cl ass( es)
Class: 2.1
Label (s): 2.1
EmS No.: F-D, S-U
14.3 Packing Group: –
14.5 Environmental hazards: not applicable
14.6 Special precautions for user: –
IATA
14.1 UN Number: UN 1049
14.2 Proper Shippi ng Name: Hydrogen, compressed
14.3 Transport Hazard Cl ass( es):
Class: 2.1
Label( s): 2.1
14.4 Packing Group: –
14.5 Environmental hazards: not applicable
14.6 Special precautions for user: –
Ot her information
Passenger and cargo aircraf t: Forbidden.
Cargo aircraft only: All ow ed.
14.7 Transport in bulk according to Annex II of MARPOL73 / 78 and the IBC Code : not applicable
SDS_GB - 000010021694
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Additional identification: Avoid transport on vehi cles w here t he l oad space is not separat ed from
t he dri ver's compartment. Ensure vehi cle dri ver is aw are of t he potenti al
hazards of t he load and know s w hat t o do in the event of an accident or
an emergency. Bef ore t ransporting product cont ai ners ensure t hat t hey
are firmly secured. Ensure t hat the cont ai ner val ve is closed and not
l eaking. Cont ainer valve guards or caps shoul d be in place. Ensure
adequate air venti lati on.
15.1 Safety, health and environmental regulations/ legislation specific for t he substance or mixture:
EU Regulations
Regulation ( EC) No. 19 07/ 2 006 Annex XVII Substances subject to restriction on marketing and use:
Directive 96/ 82/ EC ( Seveso II) : on the control of major accident hazards involving dangerous substances:
Directive 98/ 24/ EC on the prot ection of w orkers from the risks related t o chemical agents at w ork:
National Regulations
Dangerous Subst ances and Explosive Atmospheres Regul at ions (DSEAR 2002 No.
2776) . Management of Health and Safet y at Work Regulations (1999 No. 3242). The
Regul atory Ref orm (Fire Saf et y) Order 2005 ( 2005 No. 1541). Control of Substances
Hazardous t o Health Regul ations (COSHH, 2002 No. 2677). Provi sion and Use of Work
Equipment Regulati ons (PUWER, 1998 No. 2306). Personal Prot ect ive Equi pment
Regul ations (1992 No. 2966). Control of Major Accident Hazards Regulat ions (COMAH,
2015 No. 483). Equi pment and Protective Syst ems Intended f or Use in Potent ially
Explosive Atmospheres Regul at ions (EPS, 1996 No. 192). Pressure Systems Safety
Regul ations (PSSR, 2000 No. 128). Onl y products t hat comply w i th the food
regulati ons (EC) No. 1333/ 2008 and (EU) No. 231/ 2012 and are labelled as such may
be used as f ood addi tives.
Thi s Safety Dat a Sheet has been produced to compl y w it h Regulation (EU) 453/ 2010.
15.2 Chemical safety assessment: No Chemical Safety Assessment has been carri ed out.
SDS_GB - 000010021694
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Key literature references and Vari ous sources of data have been used in the compil ation of t hi s SDS, they i ncl ude
sources for data: but are not exclusive to:
Agency f or Toxic Substances and Diseases Registry (ATSDR)
(ht t p:/ / w w w .atsdr.cdc.gov/ ).
European Chemical Agency: Guidance on t he Compil ation of Safety Dat a Sheets.
European Chemical Agency: Informati on on Regi stered Substances
ht t p:/ / apps.echa.europa.eu/ registered/ registered-sub.aspx#search
European Industri al Gases Associati on (EIGA) Doc. 169 Classif ication and Labelling
guide.
Internat ional Programme on Chemical Saf ety (htt p:/ / w w w .inchem.org/ )
ISO 10156:2010 Gases and gas mixtures - Det erminat ion of f ire potent ial and
oxi di zing abi li ty for the selection of cylinder val ve outl et s.
Matheson Gas Dat a Book, 7t h Editi on.
National Institute for Standards and Technology (NIST) Standard Reference Dat abase
Number 69.
The ESIS (European chemi cal Subst ances 5 Inf ormat ion Syst em) platform of the
former European Chemi cal s Bureau (ECB) ESIS (http:/ / ecb.jrc.ec.europa.eu/ esis/ ).
The European Chemical Industry Council (CEFIC) ERICards.
United States of America’s National Li brary of Medicine’s toxi cology data netw ork
TOXNET ( ht tp:/ / t oxnet.nl m.nih.gov/ i ndex.html)
Threshold Limit Val ues ( TLV) from t he American Conference of Governmental
Indust rial Hygieni sts ( ACGIH).
Substance specific i nf ormation from suppli ers.
Detail s given in t hi s document are beli eved to be correct at t he t ime of publi cat ion.
EH40 (as amended) Workplace exposure li mits.
Training information: Users of breat hi ng apparat us must be trai ned. Ensure operat ors understand the
flammability hazard.
SDS_GB - 000010021694
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Other information: Before using t hi s product in any new process or experi ment, a t horough mat erial
compatibilit y and saf et y study should be carri ed out. Ensure adequate ai r vent ilati on.
Ensure all national/ local regulations are observed. Ensure equi pment is adequately
eart hed. Whi lst proper care has been taken i n the preparati on of this document, no
liability for i njury or damage resul ting from its use can be accept ed. Note: When t he
Product Name appears in the SDS header t he decimal si gn and it s positi on comply
w ith rules for the structure and draf ting of internat ional standards, and i s a comma
on the line. As an example 2,000 is tw o (t o three deci mal places) and not tw o
thousand, w hil st 1.000 is one t housand and not one (to t hree deci mal pl aces).
SDS_GB - 000010021694
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He a lt h 2
0 0
F ir e
2 0
Re a c t iv it y 0
Pe rson a l E
P r o t e c t io n
Toxicological Data on Ingredients: Sodium thiosulfate pentahydrate LD50: Not available. LC50: Not available.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
p. 1
242
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
If you feel unwell, seek medical attention and show the label when possible. Keep away from incompatibles such as oxidizing
agents, acids, alkalis.
p. 2
243
Storage: Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
244
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
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The information above is believed to be accurate and represents the best information currently available to us. However, we
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